Abstract: A chemical treatment process and separation module are described for removal of soluble organic compounds and suspended or emulsified oils and/or solids from produced waters that accompany operations for oil and gas recovery. The process occurs in its entirety within an interval of several minutes. The solubility of organic compounds is first reduced, in an optional step, by pH reduction, followed by treatment with coagulants and flocculants, the latter in conjunction with microbubble flotation. The organic compounds that are rendered insoluble, along with other oily solids, are captured in the floe created by the coagulant and flocculant treatment, and simultaneously made buoyant by the concurrent addition of microbubbles. The water and floe is passed over an array of sloped strainers that separates and diverts the floe from the effluent water, which contains significantly reduced soluble organic content. The separated stream of oily solids can be dewatered for disposal as waste.

Abstract: A chemical treatment process and separation module are described for removal of soluble organic compounds and suspended or emulsified oils and/or solids from produced waters that accompany operations for oil and gas recovery. The process occurs in its entirety within an interval of several minutes. The solubility of organic compounds is first reduced, in an optional step, by pH reduction, followed by treatment with coagulants and flocculants, the latter in conjunction with microbubble flotation. The organic compounds that are rendered insoluble, along with other oily solids, are captured in the floe created by the coagulant and flocculant treatment, and simultaneously made buoyant by the concurrent addition of microbubbles. The water and floe is passed over an array of sloped strainers that separates and diverts the floe from the effluent water, which contains significantly reduced soluble organic content. The separated stream of oily solids can be dewatered for disposal as waste.