Patents by Inventor Timothy L. Hilbert

Timothy L. Hilbert has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5326463
    Abstract: Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization and treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5 in an octane restoration step, followed by separation of a C.sub.9 -containing fraction, and recycling the C.sub.9 -containing fraction to the octane restoration step. A hydrocarbon fraction comprising C.sub.1 to C.sub.3 hydrocarbons may also be separated from the octane restored product and recycled for purposes of alkylating aromatic hydrocarbons and for this purpose, it may be advantageous to introduce a benzene-rich feed, such as a reformate, to the process. The treatment over the acidic catalyst in the octane restoration step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: July 5, 1994
    Assignee: Mobil Oil Corporation
    Inventors: David L. Fletcher, Timothy L. Hilbert, Michael S. Sarli, Stuart S. Shih
  • Patent number: 5320742
    Abstract: A sulfur-containing catalytically cracked naphtha is upgraded to form a low-sulfur gasoline product by a process which retains the octane contribution from the olefinic front end of the naphtha. Initially, the mercaptan sulfur in the front end of the cracked naphtha is converted to higher boiling disulfides by oxidation. The front end, which is then essentially an olefinic, high octane sulfur-free material, may be blended directly into the gasoline pool. The back end, which now contains the original higher boiling sulfur components such as thiophenes, together with the sulfur transferred from the front end as disulfides, is hydrotreated to produce a desulfurized product. This desulfurized product, which has undergone a loss in octane by saturation of olefins, is then treated in a second stage, by contact with a catalyst of acidic functionality, preferably a zeolite such as ZSM-5, under conditions which produce a product in the gasoline boiling range of higher octane value.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: June 14, 1994
    Assignee: Mobil Oil Corporation
    Inventors: David L. Fletcher, Timothy L. Hilbert, David A. Pappal, David W. Rumsey, Gerald J. Teitman
  • Patent number: 5318690
    Abstract: Low sulfur gasoline is produced from a catalytically cracked, sulfur-containing naphtha by fractionating the naphtha feed into a low boiling fraction in which the majority of the sulfur is present in the form of mercaptans and a high-boiling fraction in which the sulfur is predominantly in non-mercaptan form such as thiophenes. The low boiling fraction is desulfurized by a non-hydrogenatile mercaptan extraction process which retains the olefins present in this fraction. The second fraction is desulfurized by hydrodesulfurization, which results in some saturation of olefins and loss of octane. The octane loss is restored by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5, to form a low sulfur gasoline product with an octane number comparable to that of the feed naphtha but which contains some recombined sulfur in the form or mercaptans which are removed in a final hydrotreatment.
    Type: Grant
    Filed: January 7, 1993
    Date of Patent: June 7, 1994
    Assignee: Mobil Oil Corporation
    Inventors: David L. Fletcher, Timothy L. Hilbert, Stephen J. McGovern, John E. Sauer
  • Patent number: 5290427
    Abstract: Low sulfur gasoline is produced from a catalytically cracked, sulfur-containing naphtha by fractionating the naphtha feed into a number of fractions of differing boiling range and hydrodesulfurizing them by by feeding them into a hydrodesulfurization reactor at spaced locations along the length of the reactor in order of descending boiling range, with the highest boiling fraction first. Staged introduction of the feed into the hydrodesulfurization reactor in this way promotes desulfurization of the sulfur-rich, olefin poor back end of the feed while reducing the saturation of the high octane olefins in the olefin-rich, sulfur-poor front end, so preserving octane while achieving the desired desulfurization. The hydrodesulfurization is followed by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5.
    Type: Grant
    Filed: August 5, 1992
    Date of Patent: March 1, 1994
    Assignee: Mobil Oil Corporation
    Inventors: David L. Fletcher, Timothy L. Hilbert, Michael S. Sarli, Stuart S. Shih
  • Patent number: 4678483
    Abstract: Method for measuring particulates in flue gas streams containing chemicals reactive with trace elements in the filters is disclosed which features pretreating the filters with chemicals comparable to those in the process stream whereby the reactions are completed prior to the measurement step, in particular, prior to establishment of the tare weight of said filter.
    Type: Grant
    Filed: December 30, 1981
    Date of Patent: July 7, 1987
    Assignee: Mobil Oil Corporation
    Inventors: Michael J. Dolan, Timothy L. Hilbert, John D. Snyder