Abstract: The invention provides a process for the production of a pressure sensitive adhesive, comprising dissolving a particulate solid MQ silicone resin having a bulk density in the range 0.4-0.9 g/cm3 in a volatile solvent, and dissolving a polydiorganosiloxane having a viscosity of 0.1 to 40,000 Pa·s at 25° C. in the volatile solvent before, simultaneously with or after dissolving the solid MQ silicone resin. The process of the present invention allows the production of a pressure sensitive adhesive in a solvent different from the solvent in which the MQ silicone resin was prepared.

Abstract: A release-modifier composition comprises a capped polydiorganosiloxane-(MQ resin) copolymer, which comprises a macromolecule having an MQ resin portion covalently bonded to a polydiorganosiloxane portion. An M unit typically has the formula R1SiO1/2 and a Q unit typically has the formula SiO4/2, wherein R1 is an independently selected substituent. The polydiorganosiloxane portion comprises two D segments coupled to each other via a (RV,Alkenyl)SiO2/2 unit, wherein RV is (C1-C6)hydrocarbyl. Alkenyl may be (C2-C6)alkenyl. Each D segment comprises two or more (RD)2SiO2/2 units, which independently may be the same as or different than each other. Each RD independently may be (C1-C6)alkyl, (C3-C6)cycloalkyl, or phenyl. A curable release-coating composition comprising or prepared from the release-modifier composition, cured release-coating composition, coatings comprising the same, manufactured articles, kits, methods and uses, are also disclosed.

Abstract: The invention provides a process for the production of a pressure sensitive adhesive, comprising dissolving a particulate solid MQ silicone resin having a bulk density in the range 0.4-0.9 g/cm3 in a volatile solvent, and dissolving a polydiorganosiloxane having a viscosity of 0.1 to 40,000 Pa·s at 25° C. in the volatile solvent before, simultaneously with or after dissolving the solid MQ silicone resin. The process of the present invention allows the production of a pressure sensitive adhesive in a solvent different from the solvent in which the MQ silicone resin was prepared.

Abstract: A release-modifier composition comprises a capped polydiorganosiloxane-(MQ resin) copolymer, which comprises a macromolecule having an MQ resin portion covalently bonded to a polydiorganosiloxane portion. An M unit typically has the formula R1SiO1/2 and a Q unit typically has the formula SiO4/2, wherein R1 is an independently selected substituent. The polydiorganosiloxane portion comprises two D segments coupled to each other via a (RV,Alkenyl)SiO2/2 unit, wherein RV is (C1-C6)hydrocarbyl. Alkenyl may be (C2-C6)alkenyl. Each D segment comprises two or more (RD)2SiO2/2 units, which independently may be the same as or different than each other. Each RD independently may be (C1-C6)alkyl, (C3-C6)cycloalkyl, or phenyl. A curable release-coating composition comprising or prepared from the release-modifier composition, cured release-coating composition, coatings comprising the same, manufactured articles, kits, methods and uses, are also disclosed.

Abstract: A photovoltaic (PV) cell comprises a base substrate which comprises silicon and includes at least one doped region. The PV cell further comprises a collector disposed on the doped region of the base substrate and having a lower portion in physical contact with the doped region of the base substrate, and an upper portion opposite the lower portion. The PV cell further comprises an electrically conductive layer which is electrically isotropic or anisotropic and disposed adjacent the collector. The electrically conductive layer is in electrical communication with the base substrate via the collector. The electrically conductive layer comprises a binder and electrically conductive particles comprising at least one metal selected from the group consisting of Group 8 through Group 14 metals of the Periodic Table of Elements. The electrically conductive particles impart isotropic or anisotropic electrical conductivity to the electrically conductive layer.

Abstract: A process for preparing silicone emulsions is disclosed based on using an ethylene oxide/propylene oxide block copolymer as the emulsifier. The silicone emulsions comprise: A) 0.5 wt % to 95 wt % of a silicone resin or pressure sensitive adhesive (PSA), B) 0.1 to 90 wt % of a ethylene oxide/propylene oxide block copolymer, and sufficient amount of water to sum to 100 weight percent. The present disclosure further relates to a process for making a silicone resin emulsion comprising: I) forming a dispersion of; A) 100 parts of a silicone resin or PSA, B) 5 to 100 parts of a ethylene oxide/propylene oxide block copolymer, II) admixing a sufficient amount of water to the dispersion from step I) to form an emulsion, III) optionally, further shear mixing the emulsion.

Abstract: A silicone acrylate hybrid composition includes the reaction product of a silicon-containing pressure sensitive adhesive composition, an ethylenically unsaturated monomer, and an initiator. The silicon-containing pressure sensitive adhesive composition includes acrylate or methacrylate functionality. A method of making the hybrid composition includes polymerizing the ethylenically unsaturated monomer and the silicon-containing pressure sensitive adhesive composition in the presence of the initiator.

Abstract: This invention provides a single phase silicone acrylate formulation that resists phase separation and includes (A) at least one of a silicone, an acrylate, and combinations thereof. The single phase silicone acrylate formulation also includes (B) a silicone acrylate hybrid compatibilizing agent including silicone functionality and (meth)acrylate functionality and that is the reaction product of a silicon-containing pressure sensitive adhesive composition, a (meth)acrylate, and an initiator. A method of minimizing phase separation of the single phase silicone acrylate formulation includes the step of combining (A) and (B) to form the single phase silicone acrylate formulation.

Abstract: A silicone acrylate hybrid composition includes the reaction product of a silicon-containing pressure sensitive adhesive composition, an ethylenically unsaturated monomer, and an initiator. The silicon-containing pressure sensitive adhesive composition includes acrylate or methacrylate functionality. A method of making the hybrid composition includes polymerizing the ethylenically unsaturated monomer and the silicon-containing pressure sensitive adhesive composition in the presence of the initiator.

Abstract: This invention provides a single phase silicone acrylate formulation that resists phase separation and includes (A) at least one of a silicone, an acrylate, and combinations thereof. The single phase silicone acrylate formulation also includes (B) a silicone acrylate hybrid compatibilizing agent including silicone functionality and (meth)acrylate functionality and that is the reaction product of a silicon-containing pressure sensitive adhesive composition, a (meth)acrylate, and an initiator. A method of minimizing phase separation of the single phase silicone acrylate formulation includes the step of combining (A) and (B) to form the single phase silicone acrylate formulation.

Abstract: This invention relates to silicone compositions suitable for forining pressure sensitive adhesives. More particularly, the present invention relates to solventless curable PSA compositions suitable for forming pressure sensitive adhesive compositions having improved high temperature cohesive strength while maintaining good tack and adhesive properties.

Abstract: A method comprising heating in the presence of a catalyst, a mixture comprising (i) a reaction product obtained by mixing in the presence of a platinum group metal-containing catalyst at least one organohydrogensilicon compound containing at least one silicon-bonded hydrogen atom per molecule and at least one compound having at least one aliphatic unsaturation; (ii) at least one endblocker, and optionally (iii) at least one organosiloxane chosen from a hydrolyzate or a cyclosiloxane, so to cause polymerization of components (i), (ii), and optionally (iii) to form branched polymers.

Abstract: This invention relates to a method comprising (1) heating in the presence of a catalyst a mixture comprising (i) at least one organohydrogensilicon compound containing at least one silicon-bonded hydrogen atom per molecule or a reaction product obtained by mixing in the presence of a platinum group metal-containing catalyst at least one organohydrogensilicon compound containing at least one silicon-bonded hydrogen atom per molecule and at least one compound having at least one aliphatic unsaturation, (ii) at least one endblocker, and optionally (iii) at least one organosiloxane chosen from a hydrolyzate or a cyclosiloxane, so to cause polymerization of components (i), (ii), and optionally (iii) to form silicon-bonded hydrogen containing branched polymers.

Abstract: Organohydrogensilicon compounds containing at least one silicon-bonded hydrogen atom per molecule and at least one cyclosiloxane.

Abstract: A composition comprising (A) at least one compound having at least one aliphatic unsaturation; (B) at least one organohydrogensilicon compound containing at least one silicon-bonded hydrogen atom per molecule and (C) a platinum group metal-containing catalyst.