Abstract: A process of forming a population of microcapsules is described comprising a liquid hydrophilic core material and a wall material at least partially surrounding the core material. The liquid hydrophilic core material can be anionic, cationic, or neutral but polar. The microcapsule population is formed by providing liquid hydrophilic core material; providing an oil continuous phase which is low boiling and preferably nonflammable, the oil continuous phase comprising preferably one or more organic oil materials such as esters with chain length up to about 42 carbons. A mixture is formed by dispersing the liquid hydrophilic material in the oil continuous phase. Either an oil soluble or dispersible monofunctional amine acrylate or monofunctional amine methacrylate, along with acid; or alternatively monofunctional acid acrylate or monofunctional acid methacrylate along with base; or alternatively, monofunctional amine acrylate or monofunctional amine methacrylate along with acid acrylate or methacrylate; is added.

Abstract: A novel method of forming water in oil microcapsules is disclosed. According to the invention microcapsules are obtained by steps comprising dispersing an oil soluble amine modified polyfunctional polyvinyl monomer and an oil soluble bi- or polyfunctional vinyl monomer along with a thermal or UV free radical initiator (optionally included in one or both of the oil or water phases) and an organic acid into an internal phase oil; heating or UV exposing for a time (and temperature) sufficient to oligomerize the amine modified polyfunctional polyvinyl monomer and oil soluble bi- or polyfunctional vinyl monomer forming a pre-polymer. Thereafter the process involves adding to the oil phase oil a water phase comprising a dispersion in water of an anionic emulsifier (and optionally initiator), and adding an emulsifying agent. Emulsifying the water phase into the oil phase (W/O) is controlled through the quantity of water employed.

Abstract: A process of forming a population of microcapsules is described comprising a solid hydrophilic core material and a wall material at least partially surrounding the core material. The microcapsule population is formed by providing an anionic, or optionally a cationic, solid hydrophilic core material; providing an oil continuous phase which is low boiling and preferably nonflammable, the oil continuous phase comprising one or more esters with chain length up to about 18 carbons. A mixture is formed by dispersing the solid hydrophilic material in the oil continuous phase. Either an oil soluble or dispersible amine acrylate or methacrylate, along with acid, or alternatively acid acrylate or methacrylate along with base is added. A multifunctional acrylate or methacrylate monomer or oligomer is provided and an initiator. Optionally a surfactant is also added to form the mixture.

Abstract: A novel method of forming water in oil microcapsules is disclosed. According to the invention microcapsules are obtained by steps comprising dispersing an oil soluble amine modified polyfunctional polyvinyl monomer and an oil soluble bi- or polyfunctional vinyl monomer along with a thermal or UV free radical initiator (optionally included in one or both of the oil or water phases) and an organic acid into an internal phase oil; heating or UV exposing for a time (and temperature) sufficient to oligomerize the amine modified polyfunctional polyvinyl monomer and oil soluble bi- or polyfunctional vinyl monomer forming a pre-polymer. Thereafter the process involves adding to the oil phase oil a water phase comprising a dispersion in water of an anionic emulsifier (and optionally initiator), and adding an emulsifying agent. Emulsifying the water phase into the oil phase (W/O) is controlled through the quantity of water employed.

Abstract: A novel method of forming oil in water process is disclosed. According to the invention process are obtained by steps comprising dispersing an oil soluble amine modified polyfunctional polyvinyl monomer and an oil soluble bi- or polyfunctional vinyl monomer along with a thermal or UV free radical initiator (optionally included in one or both of the oil or water phases) and an organic acid into an internal phase oil; heating or UV exposing for a time (and temperature) sufficient to oligomerize the amine modified polyfunctional polyvinyl monomer and oil soluble bi- or polyfunctional vinyl monomer forming a pre-polymer. Thereafter the process involves adding to the oil phase oil a water phase comprising a dispersion in water of an anionic emulsifier (and optionally initiator), and adding an emulsifying agent. Emulsification of the oil phase into the water phase (O/W) is controlled through the quantity of water employed.

Abstract: Stock materials for manual and/or high speed industrial automated bonding applications having a curable pre-applied adhesive or sealant compositions on the bonding surfaces wherein the curative for the pre-applied adhesive or sealant composition is contained within a carrier which prevents its premature release.

Abstract: Stock packaging materials for manual and/or high speed industrial automated package formation and/or filing and closing applications having a curable pre-applied adhesive compositions applied to one or more seams or closure surfaces wherein the curative for the pre-applied adhesive composition is contained within a carrier which prevents its premature release.

Abstract: The invention discloses a population of selected permeability microcapsule particles comprising an oil soluble or dispersible core material and a wall material at least partially surrounding the core material. The microcapsule wall material comprises the reaction product of a first composition in the presence of a second composition comprising an anionic emulsifier. The first composition comprises a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator. The anionic emulsifier comprises a water soluble or water dispersible acrylic acid alkyl acid copolymer, an optional initiator and an alkali or alkali salt. The reaction product of the first composition and second composition can result in the formation of a low permeability microcapsule wall. Optionally, one or both of the first composition initiator or water phase initiator is an energy-activated initiator, such as a UV initiator.

Abstract: The invention discloses a population of low permeability microcapsule particles comprising an oil soluble or dispersible core material and a wall material at least partially surrounding the core material. The microcapsule wall material comprises the reaction product of a first composition in the presence of a second composition comprising an anionic emulsifier. The first composition comprises a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator. The anionic emulsifier comprises a water soluble or water dispersible acrylic acid alkyl acid copolymer, an optional initiator and an alkali or alkali salt. The reaction product of the first composition and second composition results in the formation of a low permeability microcapsule wall.

Abstract: The present invention teaches a cationically charged or neutral microcapsule particle comprising an oil soluble or dispersible core material and a wall material at least partially surrounding the core material, the microcapsule wall material comprising the reaction product of a first composition in the presence of a second composition comprising an emulsifier which is cationic or nonionic, the first composition comprising a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator. The cationic or nonionic emulsifier comprises a water soluble or water dispersible material and optionally a water phase initiator. The first composition initiator and the water phase initiator is an energy-activated initiator.

Abstract: A system and method for rupturing an encapsulated adhesive in a sheet media uses an activator unit. This unit can include one or more of the following: a pressure roller, a pair of pressure rollers, an activator blade, a set of rotatable discs or a series of sets of rotatable discs. A sheet media having an encapsulated adhesive is fed past the activator unit in the system and method whereby the capsules will be ruptured. A feeder, label printer, cutter and label applicator can also be provided in this system.

Abstract: A system and method for transporting an adhesive side of a sheet media, particularly a sheet media having an adhesive side with an encapsulated adhesive ruptured by an activator unit. This activation unit can include one or more of the following: a pressure roller, a pair of pressure rollers, an activator blade, a set of rotatable discs or a series of sets of rotatable discs. A sheet media having an encapsulated adhesive is fed past the activator unit in the system and method, whereby the capsules will be ruptured and the adhesive side of the sheet media is activated. A release liner device such as a belt or roll of releasable sheet media transports the activated sheet media throughout subsequent process steps, e.g. label printing, cutting, die casting, etc.

Abstract: A novel adhesive formed in situ in a microcapsule and method for forming such a pressure sensitive or flowable adhesive in situ in a microcapsule is disclosed. The method for forming the novel adhesive comprises providing an aqueous mixture of wall material in water; adding a substantially water insoluble core material, free radical initiator, and a solvent for the pre-polymers to the aqueous mixture. The core material comprises a first addition polymerizable pre-polymer having a Tg of less than about 0° C., a flash point of at least 75° C., and a boiling point of at least 175° C. These are typically selected from acrylate or methacrylate type materials. Optionally included is a second addition polymerizable pre-polymer for providing cross-linking or interaction between polymer chains. High shear agitation is provided to the aqueous mixture to achieve a particle size of about 0.1 to 250 microns.

Abstract: Dual shell microcapsule aggregate particles and copy materials coated therewith, such aggregate particles having inner shells surrounding chromogenic nucleus material, and outer shells encompassing multiple such inner shells to form aggregate particles thereof. The inner shells are derived from polar pre-polymer compositions. The outer shells are derived from complex colloids such as gelatin and gelatin derivatives. The outer shell material causes agglomeration of the inner shells into aggregate particles, thus increasing the sizes of the particles without increasing the sizes of the respective inner-shell microcapsules which contain the chromogenic material.

Abstract: A novel adhesive formed in situ in a microcapsule and method for forming such a pressure sensitive or flowable adhesive in situ in a microcapsule is disclosed. The method for forming the novel adhesive comprises providing an aqueous mixture of wall material in water; adding a substantially water insoluble core material, free radical initiator, and a solvent for the pre-polymers to the aqueous mixture. The core material comprises a first addition polymerizable pre-polymer having a Tg of less than about 0° C., a flash point of at least 75° C., and a boiling point of at least 175° C. These are typically selected from acrylate or methacrylate type materials. Optionally included is a second addition polymerizable pre-polymer for providing cross-linking or interaction between polymer chains. High shear agitation is provided to the aqueous mixture to achieve a particle size of about 0.1 to 250 microns.

Abstract: A system and method for transporting an adhesive side of a sheet media, particularly a sheet media having an adhesive side with an encapsulated adhesive ruptured by an activator unit. This activation unit can include one or more of the following: a pressure roller, a pair of pressure rollers, an activator blade, a set of rotatable discs or a series of sets of rotatable discs. A sheet media having an encapsulated adhesive is fed past the activator unit in the system and method, whereby the capsules will be ruptured and the adhesive side of the sheet media is activated. A release liner device such as a belt or roll of releasable sheet media transports the activated sheet media throughout subsequent process steps, e.g. label printing, cutting, die casting, etc.

Abstract: A system and method for rupturing an encapsulated adhesive in a sheet media uses an activator unit. This unit can include one or more of the following: a pressure roller, a pair of pressure rollers, an activator blade, a set of rotatable discs or a series of sets of rotatable discs. A sheet media having an encapsulated adhesive is fed past the activator unit in the system and method whereby the capsules will be ruptured. A feeder, label printer, cutter and label applicator can also be provided in this system.