Patents by Inventor Tohru Shibata

Tohru Shibata has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11643476
    Abstract: A cellulose ester, wherein, in a structural formula of the following general formula (I), a degree of substitution where X is an acyl group is from 2.91 to 3.0; the acyl group includes benzoyl group (A) optionally having a substituent, and benzoyl group (B) optionally having a substituent different from that of benzoyl group (A); and when the degree of substitution is 3.0, a degree of substitution of benzoyl group (A) is from 1.5 to 2.9, and a degree of substitution of benzoyl group (B) is from 0.1 to 1.5, wherein all or some of X represents an acyl group; when some of X represents an acyl group, the remainder represents a group selected from a hydrogen atom and an alkyl group; and n represents an integer of from 20 to 20,000.
    Type: Grant
    Filed: January 20, 2021
    Date of Patent: May 9, 2023
    Assignee: DAICEL CORPORATION
    Inventors: Tomohiro Hashizume, Hiroyuki Matsumura, Tohru Shibata, Hiroshi Koyama, Mitsuru Ohno, Tomoichi Watabe
  • Publication number: 20210139611
    Abstract: A cellulose ester, wherein, in a structural formula of the following general formula (I), a degree of substitution where X is an acyl group is from 2.91 to 3.0; the acyl group includes benzoyl group (A) optionally having a substituent, and benzoyl group (B) optionally having a substituent different from that of benzoyl group (A); and when the degree of substitution is 3.0, a degree of substitution of benzoyl group (A) is from 1.5 to 2.9, and a degree of substitution of benzoyl group (B) is from 0.1 to 1.5, wherein all or some of X represents an acyl group; when some of X represents an acyl group, the remainder represents a group selected from a hydrogen atom and an alkyl group; and n represents an integer of from 20 to 20,000.
    Type: Application
    Filed: January 20, 2021
    Publication date: May 13, 2021
    Applicant: Daicel Corporation
    Inventors: Tomohiro HASHIZUME, Hiroyuki MATSUMURA, Tohru SHIBATA, Hiroshi KOYAMA, Mitsuru OHNO, Tomoichi WATABE
  • Patent number: 10926230
    Abstract: Provided is a semipermeable membrane having a high chlorine resistance. The semipermeable membrane is formed of a cellulose ester, the cellulose ester having an optionally substituted benzoyl group.
    Type: Grant
    Filed: March 24, 2017
    Date of Patent: February 23, 2021
    Assignee: DAICEL CORPORATION
    Inventors: Tomohiro Hashizume, Hiroyuki Matsumura, Tohru Shibata, Mitsuru Ohno
  • Patent number: 10927190
    Abstract: A cellulose ester, wherein, in a structural formula of the following general formula (I), a degree of substitution where X is an acyl group is from 2.91 to 3.0; the acyl group includes benzoyl group (A) optionally having a substituent, and benzoyl group (B) optionally having a substituent different from that of benzoyl group (A); and when the degree of substitution is 3.0, a degree of substitution of benzoyl group (A) is from 1.5 to 2.9, and a degree of substitution of benzoyl group (B) is from 0.1 to 1.5, wherein all or some of X represents an acyl group; when some of X represents an acyl group, the remainder represents a group selected from a hydrogen atom and an alkyl group; and n represents an integer of from 20 to 20,000.
    Type: Grant
    Filed: April 4, 2017
    Date of Patent: February 23, 2021
    Assignee: DAICEL CORPORATION
    Inventors: Tomohiro Hashizume, Hiroyuki Matsumura, Tohru Shibata, Hiroshi Koyama, Mitsuru Ohno, Tomoichi Watabe
  • Publication number: 20200270368
    Abstract: Provided is a semipermeable membrane with high chlorine resistance and high alkali resistance. A cellulose mixed ester represented by a structural formula of General Formula (I), wherein when X is an aromatic acyl group, a degree of substitution is from 2.91 to 3.0; the aromatic acyl group includes a benzoyl group (A) that may include a substituent, and an aromatic acyl group (B) containing a carboxyl group or a salt of a carboxyl group; when the degree of substitution is 3.0, a degree of substitution of the benzoyl group (A) that may include a substituent is from 2.4 to 2.95, and a degree of substitution of the aromatic acyl group (B) containing a carboxyl group or a salt of a carboxyl group is from 0.05 to 0.6; and in General Formula (I), all or part of Xs are aromatic acyl groups; when part of Xs are aromatic acyl groups, the remainder represents a hydrogen atom or an alkyl group; and n represents an integer from 20 to 20000.
    Type: Application
    Filed: August 22, 2018
    Publication date: August 27, 2020
    Applicant: Daicel Corporation
    Inventors: Tomohiro HASHIZUME, Hiroyuki MATSUMURA, Tohru SHIBATA, Hiroshi KOYAMA, Mitsuru OHNO
  • Publication number: 20190161557
    Abstract: A cellulose ester, wherein, in a structural formula of the following general formula (I), a degree of substitution where X is an acyl group is from 2.91 to 3.0; the acyl group includes benzoyl group (A) optionally having a substituent, and benzoyl group (B) optionally having a substituent different from that of benzoyl group (A); and when the degree of substitution is 3.0, a degree of substitution of benzoyl group (A) is from 1.5 to 2.9, and a degree of substitution of benzoyl group (B) is from 0.1 to 1.5, wherein all or some of X represents an acyl group; when some of X represents an acyl group, the remainder represents a group selected from a hydrogen atom and an alkyl group; and n represents an integer of from 20 to 20,000.
    Type: Application
    Filed: April 4, 2017
    Publication date: May 30, 2019
    Applicant: Daicel Corporation
    Inventors: Tomohiro HASHIZUME, Hiroyuki MATSUMURA, Tohru SHIBATA, Hiroshi KOYAMA, Mitsuru OHNO, Tomoichi WATABE
  • Publication number: 20190151806
    Abstract: Provided is a semipermeable membrane having a high chlorine resistance. The semipermeable membrane is formed of a cellulose ester, the cellulose ester having an optionally substituted benzoyl group.
    Type: Application
    Filed: March 24, 2017
    Publication date: May 23, 2019
    Applicant: DAICEL CORPORATION
    Inventors: Tomohiro HASHIZUME, Hiroyuki MATSUMURA, Tohru SHIBATA, Mitsuru OHNO
  • Patent number: 9708986
    Abstract: The internal combustion engine (1) has a throttle (23) for controlling an intake air amount and performs start-up through cranking. The starter switch (36) detects cranking initiation, and the crank angle sensor (33, 34) detects the number of revolutions of the engine. The controller (31) drives the throttle (23) in a closed position along with the cranking initiation. The controller (31) can obtain both the intake negative pressure for promoting vaporization of fuel and the intake air amount necessary to maintain the idle rotation speed by counting the number of strokes or the number of revolutions of the internal combustion engine (1) from the cranking initiation and opening the throttle (23) from the closed position as the count number reaches a predetermined number.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: July 18, 2017
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Hajime Yasuda, Kenichi Satou, Hideaki Takahashi, Hirotada Muraki, Hiroyuki Itoyama, Tohru Shibata, Susumu Shimasaki
  • Patent number: 9133811
    Abstract: The internal combustion engine (1) has a throttle (23) for controlling an intake air amount and performs start-up through cranking. As the cranking is initiated, an atmospheric pressure is detected and an initial opening is set accordingly. The controller (31) controls the throttle (23) to the initial opening when the cranking is initiated, and controls the throttle to start to increase the throttle opening from the initial opening at a predetermined timing after the cranking initiation. By setting the initial opening based on one or both of the atmospheric pressure and the temperature at the time of cranking initiation, the intake negative pressure and the intake air amount are optimized.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: September 15, 2015
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Hideaki Takahashi, Hajime Yasuda, Kenichi Satou, Tohru Shibata, Hiroyuki Itoyama, Hirotada Muraki, Susumu Shimasaki
  • Publication number: 20130282262
    Abstract: The internal combustion engine (1) has a throttle (23) for controlling an intake air amount and performs start-up through cranking. As the cranking is initiated, an atmospheric pressure is detected and an initial opening is set accordingly. The controller (31) controls the throttle (23) to the initial opening when the cranking is initiated, and controls the throttle to start to increase the throttle opening from the initial opening at a predetermined timing after the cranking initiation. By setting the initial opening based on one or both of the atmospheric pressure and the temperature at the time of cranking initiation, the intake negative pressure and the intake air amount are optimized.
    Type: Application
    Filed: December 27, 2011
    Publication date: October 24, 2013
    Inventors: Hideaki Takahashi, Hajime Yasuda, Kenichi Satou, Tohru Shibata, Hiroyuki Itoyama, Hirotada Muraki, Susumu Shimasaki
  • Publication number: 20130173145
    Abstract: The internal combustion engine (1) has a throttle (23) for controlling an intake air amount and performs start-up through cranking. The starter switch (36) detects cranking initiation, and the crank angle sensor (33, 34) detects the number of revolutions of the engine. The controller (31) drives the throttle (23) in a closed position along with the cranking initiation. The controller (31) can obtain both the intake negative pressure for promoting vaporization of fuel and the intake air amount necessary to maintain the idle rotation speed by counting the number of strokes or the number of revolutions of the internal combustion engine (1) from the cranking initiation and opening the throttle (23) from the closed position as the count number reaches a predetermined number.
    Type: Application
    Filed: December 27, 2011
    Publication date: July 4, 2013
    Inventors: Hajime Yasuda, Kenichi Satou, Hideaki Takahashi, Hirotada Muraki, Hiroyuki Itoyama, Tohru Shibata, Susumu Shimasaki
  • Patent number: 8455637
    Abstract: A process for adjusting an intermolecular or intramolecular degree of acetyl substitution of cellulose acetate is disclosed. The process comprises ripening cellulose acetate in the presence of a catalyst, an acetyl donor, and water or an alcohol. The amount of water and the alcohol is in the range of 0.1 to 10 mol % based on the amount of the acetyl donor.
    Type: Grant
    Filed: March 16, 2011
    Date of Patent: June 4, 2013
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tohru Shibata, Yuichiro Shuto, Masaaki Ito, Tanemi Asai
  • Publication number: 20110166340
    Abstract: A process for adjusting an intermolecular or intramolecular degree of acetyl substitution of cellulose acetate is disclosed. The process comprises ripening cellulose acetate in the presence of a catalyst, an acetyl donor, and water or an alcohol. The amount of water and the alcohol is in the range of 0.1 to 10 mol % based on the amount of the acetyl donor.
    Type: Application
    Filed: March 16, 2011
    Publication date: July 7, 2011
    Inventors: Tohru SHIBATA, Yuichiro Shuto, Masaaki Ito, Tanemi Asai
  • Patent number: 7671193
    Abstract: A process for adjusting an intermolecular or intermolecular degree of acetyl substitution of cellulose acetate is disclosed. The process comprises ripening cellulose acetate in the presence of a catalyst, an acetyl donor, and water or an alcohol. The amount of water and the alcohol is in the range of 0.1 to 10 mol % based on the amount of the acetyl donor.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: March 2, 2010
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tohru Shibata, Yuichiro Shuto, Masaaki Ito, Tanemi Asai
  • Publication number: 20090062525
    Abstract: A process for adjusting an intermolecular or intramolecular degree of acetyl substitution of cellulose acetate is disclosed. The process comprises ripening cellulose acetate in the presence of a catalyst, an acetyl donor, and water or an alcohol. The amount of water and the alcohol is in the range of 0.1 to 10 mol % based on the amount of the acetyl donor.
    Type: Application
    Filed: October 27, 2008
    Publication date: March 5, 2009
    Applicant: Daicel Chemical Industries, Ltd.
    Inventors: Tohru SHIBATA, Yuichiro Shuto, Masaaki Ito, Tanemi Asai
  • Patent number: 7302954
    Abstract: To a constitutive element of a tobacco (a leaf-tobacco component or a filter) is added a proanthocyanidin or a proanthocyanidin-carrying porous material (such as an active carbon) to obtain an element for tobacco smoke. The proanthocyanidin may be at least one extract selected from a grape seed or pip, a grape rind or pericarp and squeezed dregs of a grape fruit.
    Type: Grant
    Filed: October 18, 2000
    Date of Patent: December 4, 2007
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Masato Shigematsu, Tohru Shibata, Shoichi Tokutake, Fumio Yamaguchi, Norikazu Fujii
  • Publication number: 20040024198
    Abstract: A process for adjusting an intermolecular or intramolecular degree of acetyl substitution of cellulose acetate is disclosed. The process comprises ripening cellulose acetate in the presence of a catalyst, an acetyl donor, and water or an alcohol. The amount of water and the alcohol is in the range of 0.1 to 10 mol % based on the amount of the acetyl donor.
    Type: Application
    Filed: October 15, 2002
    Publication date: February 5, 2004
    Inventors: Tohru Shibata, Yuichiro Shuto, Masaaki Ito, Tanemi Asai
  • Patent number: 6344239
    Abstract: A method for producing a tobacco filter material which is either (A) a coating process for coating the surface of a fibrous or particulate cellulose with a cellulose ester having an average substitution degree of about 2.0 to about 2.6 to give a coated cellulose, and wet webbing the coated cellulose into a sheet, or (B) a treating process for treating a naturally-occurring or regenerated cellulose fiber or particle with an organic acid and an organic acid anhydride or organic acid halide in a liquid phase to give a cellulose derivative.
    Type: Grant
    Filed: October 20, 1998
    Date of Patent: February 5, 2002
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tanemi Asai, Syu Shimamoto, Hiroyuki Matsumura, Tohru Shibata
  • Patent number: 5927287
    Abstract: A tobacco filter is produced by wrapping up a sheet-like filter material having a web structure and comprising a cellulose ester short staple into a rodform. As the cellulose ester short staple, a short staple that is non-crimped and/or has a modified cross section where a ratio D1/D2 of a diameter D1 of the circumscribed circle to a diameter D2 of the inscribed circle, each circle being of the cross section, of not less than 2 is used. The short staple includes e.g. a cellulose acetate fiber with an average fiber length of 1 to 10 mm and fineness of 1 to 10 deniers. The short staple may be incorporated with a beaten pulp with a Schopper-Riegler freeness of 20 to 90.degree. SR and/or a binder. The ratio of the short staple to the beaten pulp may for example be about 90/10 to 20/80 (by weight).
    Type: Grant
    Filed: May 30, 1997
    Date of Patent: July 27, 1999
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hiroyuki Matsumura, Syu Shimamoto, Tohru Shibata
  • Patent number: RE38435
    Abstract: A mixture of chemical substances such as optical isomers, geometrical isomers and polymers having different molecular weight ranges is separated to each ingredient by use of a cellulose derivative having an aromatic ring in the chromatographic method.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: February 24, 2004
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Yoshio Okamoto, Koichi Hatada, Tohru Shibata, Ichiro Okamoto, Hiroyuki Nakamura