Patents by Inventor Tomoyuki Kurumada

Tomoyuki Kurumada has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5739377
    Abstract: Compounds of formula (I): ##STR1## wherein: R.sup.1 represents an alkyl group having from 1 to 6 carbon atoms;R.sup.2 represents an alkyl group having from 8 to 24 carbon atoms;EO represents an ethyleneoxy group;PO represents a propyleneoxy group;k is 0 or an integer from 1 to 10; andm is an integer from 1 to 4;provided that the total of (k+m) is greater than 1 and not greater than 10;are useful as antioxidant stabilizers for polymeric materials.
    Type: Grant
    Filed: April 7, 1995
    Date of Patent: April 14, 1998
    Assignee: Sankyo Company, Limited
    Inventors: Hisayu Ohsawa, Tomoyuki Kurumada, Takaaki Yamazaki, Satoru Naito, Kohtaro Kanetaki
  • Patent number: 5096948
    Abstract: The present invention relates to weather resistant resin compositions consisting essentially of at least one polymeric substance and comprising discoloration effective amounts of:(i) a hindered amine stabilizer;(ii) a hindered-phenol-hindered amine stabilizer; and(iii) a UV absorber.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: March 17, 1992
    Assignees: Sankyo Company, Limited, Monsanto Kasei Company
    Inventors: Tomoyuki Kurumada, Hisayu Osawa, Toshimasa Toda, Hiromi Tomono, Ryuichi Hasegawa
  • Patent number: 4572912
    Abstract: The compounds of formula (I): ##STR1## [in which: R.sup.1 and R.sup.2 are the same or different and each represents hydrogen or C.sub.1 -C.sub.5 alkyl;R.sup.3 represents hydrogen, an acyl group, a (C.sub.1 -C.sub.6 alkoxy)carbonyl group or an aralkyloxycarbonyl group;R.sup.4 and R.sup.5 are the same or different and each represents hydrogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy, or R.sup.4 and R.sup.5 together represent a C.sub.1 14 C.sub.4 alkylenedioxy group;n is 1, 2 or 3;W represents the --CH.sub.2 --, >CO or >CH--OR.sup.6 group (in which R.sup.6 represents any one of the atoms or groups defined for R.sup.3 and may be the same as or different from R.sup.3); andY and Z are the same or different and each represents oxygen or imino]and pharmaceutically acceptable salts thereof have various valuable therapeutic effects on the blood system and may be prepared by a process which includes reacting a corresponding halopropionic acid derivative with thiourea.
    Type: Grant
    Filed: August 28, 1984
    Date of Patent: February 25, 1986
    Assignee: Sankyo Company Limited
    Inventors: Takao Yoshioka, Eiici Kitazawa, Tomoyuki Kurumada, Mitsuo Yamazaki, Kazou Hasegawa
  • Patent number: 4533688
    Abstract: Bis(piperidylaminotriazylamino)-(piperidylaminotriazylaminomethyl)-octane derivatives are novel compounds which are valuable as stabilizers for synthetic polymers.
    Type: Grant
    Filed: December 19, 1983
    Date of Patent: August 6, 1985
    Assignee: Sankyo Company Limited
    Inventors: Toshimasa Toda, Tomoyuki Kurumada
  • Patent number: 4413076
    Abstract: Polymers containing polyalkylpiperidines, preparation and use thereof as stabilizers for synthetic polymer compositions are described. In said polymer, sterically hindered polyalkylpiperidines are laterally linked to the main chain. The polymers are distinguished by an improved stabilizing effect in various synthetic polymer compositions, such as polyolefins, against light- and/or heat-induced deterioration thereof. The polyalkylpiperidine-containing polymers of the invention are hardly volatile upon heat-processing or during storage of shaped articles containing said polymers, and are resistant to extraction with solvents.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: November 1, 1983
    Assignee: Sankyo Company Ltd.
    Inventors: Nobuo Soma, Syoji Morimura, Takao Yoshioka, Tomoyuki Kurumada
  • Patent number: 4371644
    Abstract: Piperidine derivatives in which two or three piperidine residues each substituted at the 2- and the 6-position by two methyl groups or by one methyl group and one ethyl group, the piperidine residues being attached by means of substituted alkylene groups, by means of polyoxyalkylene groups (whose oxyalkylene chain is optionally interrupted by one or more phenylene or cyclohexylene groups), by means of substituted isocyanurate groups or by means of glyceryl groups, and acid addition salts thereof are valuable as stabilizers for synthetic polymers.
    Type: Grant
    Filed: July 10, 1980
    Date of Patent: February 1, 1983
    Assignee: Sankyo Company Ltd.
    Inventors: Nobuo Soma, Syoji Moromura, Takao Yoshioka, Tomoyuki Kurumada
  • Patent number: 4321374
    Abstract: Novel triazine derivatives represented by the general formula (I) and use thereof as light stabilizers for synthetic polymers are described. ##STR1## The compounds are distinguished by an improved stabilizing effect in various synthetic polymer compositions, such as polyolefins, against light- and/or heat-induced deterioration thereof, low volatility upon heat-processing or during storage of shaped articles containing the compounds, and resistance to extraction with water and solvents.
    Type: Grant
    Filed: June 3, 1980
    Date of Patent: March 23, 1982
    Assignee: Sankyo Company, Limited
    Inventors: Syoji Morimura, Toshimasa Toda, Tomoyuki Kurumada
  • Patent number: 4265803
    Abstract: The invention entitled "Polymers containing polyalkylpiperidines and use thereof as stabilizers" provides a class of polymers in which groups containing sterically hindered polyalkylpiperidines are linked in the main chain of the polymers via bridging members containing 2-hydroxy-1,3-trimethylene groups.The polymers show superior stabilizing effects for various synthetic polymers such as polyolefins against degradation thereof induced by light and/or heat. The polymers have advantages, as compared with known stabilizer compounds, that they hardly volatile upon processing with heating or during storage of articles containing thereof, and that they are resistant to extraction with solvents from articles containing thereof.
    Type: Grant
    Filed: August 7, 1978
    Date of Patent: May 5, 1981
    Assignee: Sankyo Company Limited
    Inventors: Nobuo Soma, Syoji Morimura, Takao Yoshioka, Tomoyuki Kurumada
  • Patent number: 4241208
    Abstract: Piperidine derivatives having the formula ##STR1## wherein R' represents an alkyl, an acyl, an alkoxycarbonyl, an amino or nitroso group;X represents oxygen or sulfur;Y represents oxygen, sulfur or a group of the formula .dbd.N--R" in which R" is hydrogen or alkyl;Z represents oxygen or a group of the formula >N--R'" in which R'" is hydrogen or alkyl;n is an integer of 1 to 4; andR represents, when n is 1, alkyl, aryl, cycloalkyl, alkoxycarbonyl, substituted phosphino or substituted phosphinyl, when n is 2, alkylene, alkenylene, arylene, aralkylene; alkylenediphenylene, bis-(alkoxycarbonyl) alkylene, alkylene-bis-(oxycarbonylalkyl), dialkylene ether or diphenylene ether, when n is 3, alkanetriyl,tris-(alkoxycarbonyl)alkanetriyl, alkanetriyl-tris-(oxycarbonylalkyl) or a group of the formula ##STR2## in which p is an integer of 1 through 8 inclusive, and, when n is 4, alkanetetrayl,tetrakis-(alkoxycarbonyl) alkanetetrayl or alkanetetrayl-tetrakis-(oxycarbonylalkyl).
    Type: Grant
    Filed: December 12, 1978
    Date of Patent: December 23, 1980
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Ohsawa
  • Patent number: 4237294
    Abstract: 2,2,6,6-Tetramethylpiperidine derivatives having the formula ##STR1## wherein: X represents a group of formula ##STR2## R represents a hydrogen atom, methyl group, ethyl group, phenoxymethyl group or phenyl group;R' represents a methyl group or ethyl group; andm represents 0, 1 or 2,are excellent stabilizers for synthetic polymers.
    Type: Grant
    Filed: June 18, 1979
    Date of Patent: December 2, 1980
    Assignees: Sankyo Company, Limited, Ciba-Geigy Corporation
    Inventors: Nobuo Soma, Syoji Morimura, Takao Yoshioka, Tomoyuki Kurumada
  • Patent number: 4219465
    Abstract: Novel piperidine-spiro-hydantoin derivatives represented by the general formula (I) and use thereof as light stabilizers for synthetic polymers are described: ##STR1## The compounds are distinguished by an improved stabilizing effect in various synthetic polymer compositions, such as polyolefins, against light- and/or heat-induced deterioration thereof, small volatility upon heat-processing or during storage of shaped articles containing the compounds, and resistance to extraction with water and solvents.
    Type: Grant
    Filed: June 5, 1979
    Date of Patent: August 26, 1980
    Assignee: Sankyo Company Limited
    Inventors: Nobuo Soma, Syoji Morimura, Takao Yoshioka, Tomoyuki Kurumada
  • Patent number: 4212974
    Abstract: A novel piperidine derivative having a stabilizing effect on a synthetic polymeric material and a composition comprising said piperidine derivative and a synthetic polymeric material.
    Type: Grant
    Filed: July 14, 1978
    Date of Patent: July 15, 1980
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Osawa
  • Patent number: 4191683
    Abstract: Derivatives of sterically hindered 4-aminopiperidines are effective as light-stabilizers for organic polymers, especially for polyolefins. The piperidine ring is substituted with at least five alkyl groups, preferably methyl and ethyl groups. The 4-amino group is substituted with mono- or divalent acyl groups. The nitrogen in 1-position may also be substituted with a monovalent organic substituent. The compounds can be synthesized starting from higher homologs of acetone in sequence of several reaction steps.
    Type: Grant
    Filed: November 21, 1977
    Date of Patent: March 4, 1980
    Assignees: Ciba-Geigy Corporation, Sankyo Company Limited
    Inventors: Heimo Brunetti, Jean Rody, Nobuo Soma, Tomoyuki Kurumada
  • Patent number: 4166813
    Abstract: New polyalkylated 4-aminopiperidine derivatives contain in their molecule two or three piperidine rings, each having two alkyl substituents at both the 2- and the 6- positions, optionally having substituents at the 1- and 3- positions and having an amino substituent at the 4- position. The piperidine rings are joined together by attachment of the 4-amino substituents through, where there are two piperidine rings, a polyalkylene, polyether or polyester chain, or through, where there are three piperidine rings, an isocyanurate or glycerol system. These compounds and their acid addition salts are useful as stabilizers for synthetic polymers.
    Type: Grant
    Filed: May 8, 1978
    Date of Patent: September 4, 1979
    Assignee: Sankyo Company Ltd.
    Inventors: Nobuo Soma, Syoji Morimura, Takao Yoshioka, Tomoyuki Kurumada
  • Patent number: 4162246
    Abstract: Hydantoin derivatives in which two or three piperidine spiro hydantoin residues are attached by means of substituted alkylene groups or polyoxyalkylene groups whose oxyalkylene chain is optionally interrupted by one or more phenylene or cyclohexylene groups or by means of substituted isocyanurate or glyceryl groups and, where they exist, acid addition salts thereof, are valuable as stabilizers for synthetic polymers.
    Type: Grant
    Filed: December 13, 1977
    Date of Patent: July 24, 1979
    Assignee: Sankyo Company Limited
    Inventors: Nobuo Soma, Syoji Morimura, Takao Yoshioka, Tomoyuki Kurumada
  • Patent number: 4141883
    Abstract: Polymers, both natural and synthetic, are stabilized against the deterioration resulting from heat and/or light by the incorporation of certain 2,2,6,6-tetra-substituted-4-piperidinol derivatives which additionally have an alkyl, alkenyl, alkynyl or aralkyl substituent at one or both of the 3- and 5- positions.
    Type: Grant
    Filed: July 8, 1977
    Date of Patent: February 27, 1979
    Assignees: Sankyo Company, Limited, Ciba-Geigy Corporation
    Inventors: Nobuo Soma, Tomoyuki Kurumada, Heimo Brunetti, Jean Rody
  • Patent number: 4131599
    Abstract: Sterically hindered piperidines having at least 5 alkyl groups in ring positions 2,3,5 and 6 are usable as light-stabilizers for organic polymers. The nitrogen may be unsubstituted or may bear a mono- to tetravalent substituent. The compounds can be synthesized by a Wolf-Kishner reduction of polyalkyl 4-oxopiperidines optionally followed by a N-substitution reaction in a second step.The stabilizers are added to the polymers in an amount of from 0.01 to 5% by weight. Preferred is the stabilization of polyolefins, styrene polymers, polyamides and polyurethanes.
    Type: Grant
    Filed: May 19, 1976
    Date of Patent: December 26, 1978
    Assignees: Sankyo Company, Limited, Ciba-Geigy Corporation
    Inventors: Heimo Brunetti, Jean Rody, Nobuo Soma, Tomoyuki Kurumada
  • Patent number: 4125533
    Abstract: A novel piperidine derivative having a stabilizing effect on a synthetic polymeric material and a composition comprising said piperidine derivative and a synthetic polymeric material.
    Type: Grant
    Filed: December 23, 1976
    Date of Patent: November 14, 1978
    Assignee: Sankyo Co. Ltd.
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Osawa
  • Patent number: 4118368
    Abstract: Novel derivatives of 4-amino-2,6-dimethylpiperidine have additional methyl or substituted-methyl substituents at positions 2 and 6, and a carboxylate ester substituent at position 4. Positions 1 and 3, and the amino group at position 4, can optionally also be substituted. These derivatives are useful for stabilizing synthetic polymers, especially polyolefins, polyamides and polyurethanes, against photo- and thermal-deterioration, generally in an amount of 0.01 - 5.0% by weight based on the polymer.
    Type: Grant
    Filed: November 5, 1976
    Date of Patent: October 3, 1978
    Assignee: Sankyo Company Limited
    Inventors: Nobuo Soma, Syoji Morimura, Takao Yoshioka, Tomoyuki Kurumada
  • Patent number: 4105626
    Abstract: Cyclic ketals of sterically hindered 4-oxopiperidines are effective light-stabilizers for organic polymers. These compounds have at least five alkyl groups in ring positions 2,3,5 and 6 and four alkyl groups in ring positions 2 and 6, preferably methyl and ethyl groups. The ring nitrogen may be unsubstituted or substituted with a monvalent substitutent. The new compounds can be synthesized by ketalization of the corresponding 4-oxopiperidines with diols, triols or tetrols. Using triols the obtained ketals possess hydroxyl groups which may be esterified or etherified in a subsequent reaction step. Ketalization with tetrols yields cyclic bis-ketals.
    Type: Grant
    Filed: May 19, 1976
    Date of Patent: August 8, 1978
    Assignees: Ciba-Geigy Corporation, Sankyo Company, Limited
    Inventors: Heimo Brunetti, Jean Rody, Nobuo Soma, Tomoyuki Kurumada