Abstract: A conductive carbon carrier for a fuel cell having at least a surface layer graphitized, characterized in that the dimension (La) in a six-membered ring face (carbon plane) direction of a crystallite measured by X-ray diffraction is 4.5 nm or more. This carbon carrier improves the durability in a fuel cell and enables operation for a long period of time.

Abstract: This invention relates to an electrode catalyst for a fuel cell comprising catalyst metal particles of noble metal-base metal-Ce (cerium) ternary alloy carried on carbon materials, wherein the noble metal is at least one member selected from among Pt, Ru, Rh, Pd, Ag and Au, the base metal is at least one member selected from among Ir, Co, Fe, Ni and Mn, and the relative proportion (i.e., the molar proportion) of noble metal:base metal:Ce (cerium) is 20 to 95:5 to 60:0.1 to 3. The electrode catalyst for a fuel cell inhibits deterioration of an electrolyte membrane or an electrolyte in an electrode catalyst layer, improves durability, and, in particular, improves the capacity for power generation in the high current density region.

Abstract: An object of the present invention is to reduce the amount of catalytic metal such as Pt in a fuel cell. The present invention provides a fuel cell electrode catalyst comprising a conductive carrier and catalytic metal particles, wherein the CO adsorption amount of the electrode catalyst is at least 30mL/g·Pt.

Abstract: An object of the present invention is to reduce the amount of catalytic metal such as Pt in a fuel cell. The present invention provides a fuel cell electrode catalyst comprising a conductive carrier and catalytic metal particles, wherein the CO adsorption amount of the electrode catalyst is at least 30 mL/g·Pt.

Abstract: An object of the present invention is to optimize an anode catalyst layer such that high output performance can be achieved even under low-humidity conditions. In addition, another object of the present invention is to provide a polymer electrolyte fuel cell having such an anode catalyst layer. The following is obtained: an anode catalyst layer for a polymer electrolyte fuel cell, which comprises a carbon support on which a catalyst is carried and a hydrogen ion-conductive polyelectrolyte, and wherein the catalyst is carried by a carbon support for which the hydrophilic characteristic value specified based on a value representing the amount of adsorbed water vapor/the amount of adsorbed nitrogen is 0.02 or less, or the hydrophilic characteristic value for the catalyst-carrying carbon support is 0.30 or less.

Abstract: An electrode catalyst for a fuel cell, which is capable of maintaining power generation capacity for long periods and has good durability, is provided. The electrode catalyst for a fuel cell is produced by causing a high crystalline carbon carrier with a carbon crystallization degree ranging from 57% to 90% to support a catalytic metal.

Abstract: To provide a production process of an electrode catalyst for fuel cell whose initial voltage is high and whose endurance characteristics, especially, whose voltage drop being caused by high-potential application is less. A production process according to the present invention of an electrode catalyst for fuel cell is characterized in that: it includes: a dispersing step of dispersing a conductive support in a solution; a loading step of dropping a platinum-salt solution, a base-metal-salt solution and an iridium-salt solution to the resulting dispersion liquid, thereby loading respective metallic salts on the conductive support as hydroxides under an alkaline condition; and an alloying step of heating the conductive support with metallic hydroxides loaded in a reducing atmosphere to reduce them, thereby alloying them.

Abstract: A supported catalyst for fuel cell includes a conductive carrier and platinum supported on the conductive carrier. A 90% particle diameter D90 on a cumulative particle size curve obtained by determining a particle size distribution of the supported catalyst by a light scattering method is 28 ?m or less.

Abstract: A fuel cell having an excellent life property is achieved. A supported catalyst for a fuel cell includes a catalytic particle made of an alloy of platinum and gold, and a conductive carrier supporting the catalytic particle. 50% or more of gold forms a solid solution with platinum.

Abstract: This invention relates to an electrode catalyst for a fuel cell comprising catalyst metal particles of noble metal-base metal-Ce (cerium) ternary alloy carried on carbon materials, wherein the noble metal is at least one member selected from among Pt, Ru, Rh, Pd, Ag and Au, the base metal is at least one member selected from among Ir, Co, Fe, Ni and Mn, and the relative proportion (i.e., the molar proportion) of noble metal:base metal:Ce (cerium) is 20 to 95:5 to 60:0.1 to 3. The electrode catalyst for a fuel cell inhibits deterioration of an electrolyte membrane or an electrolyte in an electrode catalyst layer, improves durability, and, in particular, improves the capacity for power generation in the high current density region.

Abstract: A fuel cell catalyst in which catalyst particles are supported on a carrier is provided, wherein the value of the average catalyst carrier pore diameter/the catalyst metal (PGM) particle diameter is 0.5 to 1.8. Such fuel cell catalyst is less likely to cause voltage drops even after being used for a long period of time.

Abstract: A conductive carbon carrier for a fuel cell having at least a surface layer graphitized, characterized in that the dimension (La) in a six-membered ring face (carbon plane) direction of a crystallite measured by X-ray diffraction is 4.5 nm or more. This carbon carrier improves the durability in a fuel cell and enables operation for a long period of time.

Abstract: An object of the present invention is to reduce the amount of catalytic metal such as Pt in a fuel cell. The present invention provides a fuel cell electrode catalyst comprising a conductive carrier and catalytic metal particles, wherein the CO adsorption amount of the electrode catalyst is at least 30 mL/g·Pt.

Abstract: To provide a production process of an electrode catalyst for fuel cell whose initial voltage is high and whose endurance characteristics, especially, whose voltage drop being caused by high-potential application is less. A production process according to the present invention of an electrode catalyst for fuel cell is characterized in that: it includes: a dispersing step of dispersing a conductive support in a solution; a loading step of dropping a platinum-salt solution, a base-metal-salt solution and an iridium-salt solution to the resulting dispersion liquid, thereby loading respective metallic salts on the conductive support as hydroxides under an alkaline condition; and an alloying step of heating the conductive support with metallic hydroxides loaded in a reducing atmosphere to reduce them, thereby alloying them.

Abstract: To enhance the activation of a catalyst comprising an alloy of platinum and cobalt, thereby providing an electrode catalyst for fuel cell whose battery output and fuel efficiency are high, and thereby providing a production process of the same. An electrode catalyst according to the present invention for fuel cell is an electrode catalyst for fuel cell in which catalytic particles comprising platinum and cobalt are loaded on a conductive support, and is characterized in that a compositional (molar) ratio of said catalytic particles is platinum:cobalt=3:1-5:1: In the range of platinum:cobalt=3:1-5:1, a high battery voltage is obtainable. When the proportion of platinum is less than platinum: cobalt=3:1, the elution of cobalt from out of catalyst increases. On the contrarily, when the proportion of platinum is more than platinum: cobalt=5:1, the catalytic activities become low.

Abstract: An object of the present invention is to further increase the rate of Pt particles (Pt utilization rate) for three-phase interfaces in order to reduce the amount of catalytic metal such as Pt used for fuel cells. The present invention provides a fuel cell electrode catalyst comprising a conductive carrier and catalytic metal particles, wherein an average particle size of the carried catalytic metal particles is larger than an average pore size of micropores in the conductive carrier.

Abstract: A flooding phenomenon is suppressed in a high current density loading region so as to attempt the improvement of cell performance of fuel cells. An electrode catalyst for fuel cells, in which a catalyst comprising an alloy catalyst composed of a noble metal and one or more transition metals and having surface characteristics such that it shows a pH value in water of 6.0 or more is supported on conductive carriers, and a fuel cell using such electrode catalyst for fuel cells, are provided.

Abstract: Provided is a supported catalyst for a fuel cell, containing a conductive support and a platinum alloy supported thereby, wherein an elution ratio of transition metal other than platinum is 30% or less when 0.5 g of the supported catalyst is stirred at room temperature in 30 mL of 0.1N aqueous sulfuric acid solution for 800 hours.

Abstract: Provided is a supported catalyst for a fuel cell, containing a conductive support and a platinum alloy supported thereby, wherein an elution ratio of transition metal other than platinum is 30% or less when 0.5 g of the supported catalyst is stirred at room temperature in 30 mL of 0.1N aqueous sulfuric acid solution for 800 hours.

Abstract: A hydrogen containing material comprises a first compound including hydrogen containing material and fluoride, and a second compound including a metal which becomes highly reactive with hydrogen when the metal becomes a compound including fluorine, and a compound including fluorine. The first compound and the second compound are integrally formed into a one-piece layer on the surface of the hydrogen containing material. The metal which becomes highly reactive with hydrogen when the metal becomes a compound including fluorine is at least one metal selected from a rare earth metal, rare earth alloy, Fe, Al, Mg, Ca, Mn, Zn, Zr, Li, or alloys comprising these elements.