Patents by Inventor Toshiro Murao

Toshiro Murao has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5458839
    Abstract: A process for efficiently producing a hollow molding or a sheet- or rod-shaped molding includes subjecting a composition containing a polyoxymethylene copolymer resin having substantially a linear molecular structure and a melt flow index (MI) value (190.degree. C., 2160 g load) of 0.1 to 2.0 g/10 min to blow -molding or extrusion-molding operations. The preferred polyoxymethylene copolymer is prepared by copolymerizing trioxane as the principle monomer with a cyclic ether or cyclic formal comonomer in the presence of 1.times.10.sup.-3 to 1.times.10.sup.-2 molar % of a boron trifluoride catalyst or a coordination compound thereof, while regulating the chain-terminating or chain-transferring impurities in the reaction system to 1.times.10.sup.-2 molar % or less, and then cooling the product obtained to a temperature of 45.degree. or below within 30 seconds so as to deactivate the catalyst.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: October 17, 1995
    Assignees: Polyplastics Co., Ltd., Hoechst Aktiengesellschaft
    Inventors: Toshiro Murao, Kaoru Yamamoto, Gerhard Reuschel, Dietrich Fleischer
  • Patent number: 5344911
    Abstract: Processes for producing a polyoxymethylene copolymer includes forming a crude polyoxymethylene copolymer by subjecting a reaction system containing trioxane, a cyclic ether or cyclic formal comonomer, and a catalyst (e.g., boron trifluoride or a coordination compound thereof) to copolymerization reaction conditions. During copolymerization, both the total content of impurities and catalyst in the copolymerization reaction system are adjusted. In this regard, the impurities content (i.e., those compounds which form unstable end groups in the polyoxymethylene copolymer and/or those compounds having a chain-terminating or chain-transfer function) in the copolymerization reaction system is adjusted to 1.times.10.sup.-2 mole percent or less based on the total monomer amount, while the the content of the catalyst in the copolymerization reaction system to between 1.times.10.sup.-3 to 1.times.10.sup.-2 mole percent based on the total monomer amount.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: September 6, 1994
    Assignees: Polyplastics Co., Ltd., Hoechst Aktiengesellschaft
    Inventors: Kaoru Yamamoto, Nagayoshi Maeda, Makoto Kamiya, Toshiro Murao, Gerhard Reuschel, Dietrich Fleischer
  • Patent number: 5232969
    Abstract: Novel moldable, highly stable, normally solid polyoxymethylene resin compositions and molded articles formed of the same include a stabilizing effective amount of an alkoxy-substituted phenoxy-containing compound having the formula (I) or (II):Ar.sup.1 --O--X (I)Ar.sup.2 (--O--X).sub.s (II)where Ar.sup.1 represents an aryl group having no hydroxyl groups directly bonded thereto as a substituent, Ar.sup.2 represents a benzene or naphthalene ring having no hydroxyl groups directly bonded thereto as a substituent, and s represents the number of alkoxy-derivative substituents. Preferably, Ar.sup.1 in formula (I) is a phenyl, biphenyl or naphthyl group, and Ar.sup.2 in formula (II) is benzene (with s being 2). Ar.sup.1 and Ar.sup.2 in formulas (I) and (II) may only be substituted with the --OX group, or may also contain other alkoxy group substituents.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: August 3, 1993
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshiro Murao, Kaoru Yamamoto, Keiichi Kanaka, Mitsuharu Kusagaya
  • Patent number: 4997724
    Abstract: Provided herein is a process for surface treatment of moldings of liquid-crystalline polyester resin which comprises roughening with an alkaline aqueous solution the surface of moldings of melt-processable polyester capable of forming an anisotropic molten phase. The roughened moldings are activated by contacting with an aqueous solution of an ampholytic surface active agent such as an aminocarboxylate. The process is intended to provide the moldings with surface characteristics suitable for surface decoration such as printing, painting, metallizing, and plating and also for bonding with an adhesive.
    Type: Grant
    Filed: May 25, 1988
    Date of Patent: March 5, 1991
    Assignee: Polyplastics Co., Ltd.
    Inventors: Yoshiharu Suzuki, Toshiro Murao, Michiaki Ogura
  • Patent number: 4950360
    Abstract: Three dimensional molded articles comprising liquid crystalline polyesters are recognized to be extremely difficult to finish such as by printing, painting, metallizing, plating, etc. An effective answer to this difficulty is provided by initially blending within the liquid crystalline polyester at least one particulate inorganic filler selected from the group consisting of Group II elements of the periodic table and oxides, sulfates, phosphates, silicates, and carbonates thereof, and elements of aluminum, silicon, tin, lead, antimony, and bismuth and oxides thereof, in an amount of 5 to 80 percent by weight; forming a molded article from the same; and contacting the resulting molded article with an acidic solution containing at least 80 percent by weight of sulfuric acid. The requisite surface modification for finishing to form a quality product is made possible.
    Type: Grant
    Filed: September 27, 1988
    Date of Patent: August 21, 1990
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshiro Murao, Yoshiharu Suzuki, Mitsuo Wada, Hiroaki Konuma