Patents by Inventor Toshiyuki Nukuda

Toshiyuki Nukuda has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9825281
    Abstract: A lithium secondary battery is produced by employing a charging method where a positive electrode upon charging has a maximum achieved potential of 4.3 V (vs. Li/Li+) or lower. The lithium secondary battery contains an active material including a solid solution of a lithium transition metal composite oxide having an ?-NaFeO2-type crystal structure. The solid solution has a diffraction peak observed near 20 to 30° in X-ray diffractometry using CuK? radiation for a monoclinic Li[Li1/3Mn2/3]O2-type before charge-discharge. The lithium secondary battery is charged to reach at least a region with substantially flat fluctuation of potential appearing in a positive electrode potential region exceeding 4.3 V (vs. Li/Li+) and 4.8 V (vs. Li/Li+) or lower. A dischargeable electric quantity in a potential region of 4.3 V (vs. Li/Li+) or lower is 177 mAh/g or higher.
    Type: Grant
    Filed: September 27, 2012
    Date of Patent: November 21, 2017
    Assignee: GS YUSA INTERNATIONAL LTD.
    Inventors: Daisuke Endo, Miki Yasutomi, Yoshihiro Katayama, Toshiyuki Nukuda
  • Patent number: 9818997
    Abstract: A rubber valve body for sealed battery includes a rubber composition containing a resin in an amount of 20% by mass or more and an inorganic substance, wherein the melting point of the resin is in a range of 100 to 165° C.
    Type: Grant
    Filed: December 16, 2013
    Date of Patent: November 14, 2017
    Assignee: GS Yuasa International Ltd.
    Inventors: Hideto Watanabe, Toshiyuki Nukuda, Mitsuhiro Kodama, Manabu Kanemoto
  • Patent number: 9608247
    Abstract: An energy storage device including a spiral electrode group in which a first electrode plate and a second electrode plate having polarity reverse to that of the first electrode plate are spirally wound with a separator interposed therebetween, wherein the second electrode plate is opposed to an inner circumference and an outer circumference of the first electrode plate, portions of the separator are reinforced, the reinforced portions of the separator include a first reinforced portion formed between a winding-start end of the first electrode plate and the second electrode plate located on a radially outer side of the winding-start end, and a second reinforced portion formed between the winding-start end of the first electrode plate and the second electrode plate located on a radially inner side of the winding-start end, and the first reinforced portion and the second reinforced portion are arranged apart from each other.
    Type: Grant
    Filed: April 23, 2014
    Date of Patent: March 28, 2017
    Assignee: GS Yuasa International Ltd.
    Inventors: Tadashi Kakeya, Manabu Kanemoto, Mitsuhiro Kodama, Toshiyuki Nukuda
  • Patent number: 9514895
    Abstract: Provided are an electric storage device in which a current collector is not easily broken even when vibration is applied, and a vehicle having this electric storage device. This electric storage device includes a case having a first inner surface and a second inner surface adjacent to the first inner surface, an electrode assembly housed in the case and including a positive electrode plate and a negative electrode plate insulated from each other, an electrode terminal disposed outside the case, and a current collector housed in the case and electrically connecting the electrode assembly and the electrode terminal to each other. A distal end edge of a distal end portion of the current collector is supported on the first inner surface of the case.
    Type: Grant
    Filed: December 8, 2011
    Date of Patent: December 6, 2016
    Assignees: GS YUASA INTERNATIONAL LTD., HONDA MOTOR CO., LTD.
    Inventors: Nobuyuki Naganawa, Masamitsu Tononishi, Shinsuke Yoshitake, Yasunori Okuno, Masakazu Tsutsumi, Hajime Kawamoto, Tomonori Kishimoto, Jun Nakamura, Toshiyuki Nukuda
  • Patent number: 9318742
    Abstract: An object is to provide a positive active material for nonaqueous electrolyte secondary battery, which is capable of providing a battery with excellent cycle performance. Provided are a positive active material for nonaqueous electrolyte secondary battery, which includes an Fe-containing lithium vanadium phosphate compound having a NASICON-type structure, wherein in the Fe-containing lithium vanadium phosphate compound, the percentage of iron atoms relative to the sum of vanadium and iron atoms is 2% or more and 20% or less; and the like.
    Type: Grant
    Filed: February 16, 2011
    Date of Patent: April 19, 2016
    Assignee: GS YUASA INTERNATIONAL LTD.
    Inventors: Yukiko Fujino, Yoshinobu Yasunaga, Toru Tabuchi, Tokuo Inamasu, Toshiyuki Nukuda
  • Patent number: 9225022
    Abstract: The positive active material is a positive active material for a lithium secondary battery, including a lithium transition metal compound that has an olivine crystal structure and contains at least Ni, Fe, and Mn as transition metal elements, wherein when the sum of mole atoms of Ni, Fe, and Mn of transition metal elements contained in the lithium transition metal compound is expressed as 1, and the mole atomic ratios of Ni, Fe, and Mn are represented by a, b, and c (a+b+c=1, a>0, b>0, c>0), respectively, the following is satisfied: 0.85?c?0.92 and 0.3?a/(a+b)?0.9.
    Type: Grant
    Filed: June 16, 2010
    Date of Patent: December 29, 2015
    Assignee: GS YUASA INTERNATIONAL LTD.
    Inventors: Mariko Kohmoto, Toru Tabuchi, Tokuo Inamasu, Toshiyuki Nukuda
  • Publication number: 20140322577
    Abstract: An energy storage device including a spiral electrode group in which a first electrode plate and a second electrode plate having polarity reverse to that of the first electrode plate are spirally wound with a separator interposed therebetween, wherein the second electrode plate is opposed to an inner circumference and an outer circumference of the first electrode plate, portions of the separator are reinforced, the reinforced portions of the separator include a first reinforced portion formed between a winding-start end of the first electrode plate and the second electrode plate located on a radially outer side of the winding-start end, and a second reinforced portion formed between the winding-start end of the first electrode plate and the second electrode plate located on a radially inner side of the winding-start end, and the first reinforced portion and the second reinforced portion are arranged apart from each other.
    Type: Application
    Filed: April 23, 2014
    Publication date: October 30, 2014
    Applicant: GS Yuasa International Ltd.
    Inventors: Tadashi Kakeya, Manabu Kanemoto, Mitsuhiro Kodama, Toshiyuki Nukuda
  • Patent number: 8822080
    Abstract: The present invention provides a Li3V2(PO4)3-based positive active material for a lithium secondary battery, which has high discharge capacity and excellent storage performance, particularly high-temperature storage performance; and a lithium secondary battery made using the positive active material. The positive active material for a lithium secondary battery has general formula Li3V2(PO4)3?x(BO3)x (0<x?2?2). It is preferable that x be 2?7?x?2?3. Also provided are a positive electrode for a lithium secondary battery containing the positive active material; and a lithium secondary battery including the positive electrode.
    Type: Grant
    Filed: October 27, 2010
    Date of Patent: September 2, 2014
    Assignee: GS Yuasa International Ltd.
    Inventors: Yukiko Fujino, Yoshinobu Yasunaga, Toru Tabuchi, Tokuo Inamasu, Toshiyuki Nukuda
  • Patent number: 8808584
    Abstract: It is an object of the present invention to provide an active material for a lithium secondary battery having high discharge capacity and excellent in high rate discharge characteristics and a lithium secondary battery using the same. The active material for a lithium secondary battery containing a solid solution of a lithium-transition metal composite oxide having an ?-NaFeO2 type crystal structure and the lithium secondary battery using the same have features that the composition ratios of the metal elements contained in the solid solution satisfy Li1+(x/3)Co1?x?y?zNiy/2Mgz/2Mn(2x/3)+(y/2)+(z/2) (x>0; y>0; z>0; x+y+z<1); the active material has an X-ray diffraction pattern capable of belonging to space group P3112; and the active material has discharge capacity exceeding 200 mAh/g.
    Type: Grant
    Filed: August 20, 2010
    Date of Patent: August 19, 2014
    Assignee: GS Yuasa International Ltd.
    Inventors: Daisuke Endo, Yoshihiro Katayama, Toshiyuki Nukuda
  • Publication number: 20140170444
    Abstract: A rubber valve body for sealed battery includes a rubber composition containing a resin in an amount of 20% by mass or more and an inorganic substance, wherein the melting point of the resin is in a range of 100 to 165° C.
    Type: Application
    Filed: December 16, 2013
    Publication date: June 19, 2014
    Applicant: GS Yuasa International Ltd.
    Inventors: Hideto Watanabe, Toshiyuki Nukuda, Mitsuhiro Kodama, Manabu Kanemoto
  • Patent number: 8663847
    Abstract: It is an object of the present invention to provide a positive electrode material having a large ratio of the discharge capacity around 4 V to the total discharge capacity including the discharge capacity at 4V or lower while making the discharge capacity around 4 V sufficient, for the purpose of providing a lithium secondary battery using a lithium transition metal phosphate compound excellent in thermal stability, utilizing the discharge potential around 4V (vs. Li/Li+) that is higher than the discharge potential of LiFePO4, and being advantageous with respect to the detection of the end of discharge state, and a lithium secondary battery using the same. The present invention uses a positive active material for a lithium secondary battery containing a lithium transition metal phosphate compound represented by LiMn1-x-yFexCoyPO4(0.1?x?0.2, 0<y?0.2).
    Type: Grant
    Filed: November 27, 2009
    Date of Patent: March 4, 2014
    Assignee: GS Yuasa International Ltd.
    Inventors: Yuta Kashiwa, Mariko Kohmoto, Toru Tabuchi, Tokuo Inamasu, Toshiyuki Nukuda
  • Patent number: 8647777
    Abstract: Disclosed is a mixed material of lithium iron phosphate and carbon, which contains secondary particles as aggregates of lithium iron phosphate primary particles and a fibrous carbon which is present inside the secondary particles. An electrode containing such a mixed material, a battery comprising such an electrode, a method for producing such a mixed material, and a method for producing a battery are also disclosed.
    Type: Grant
    Filed: October 13, 2006
    Date of Patent: February 11, 2014
    Assignee: GS Yuasa International Ltd.
    Inventors: Yoshinobu Yasunaga, Tokuo Inamasu, Akihiro Fujii, Toshiyuki Nukuda
  • Patent number: 8551659
    Abstract: The active material for a lithium secondary battery includes a solid solution of a lithium transition metal composite oxide having an ?-NaFeO2 type crystal structure, in which the composition ratio of Li, Co, Ni, and Mn contained in the solid solution satisfies Li1+(1/3)xCo1?x?yNi(1/2)yMn(2/3)x+(1/2)y (x+y?1, 0?y and 1?x?y=z); in an Li[Li1/3Mn2/3]O2(x)-LiNi1/2Mn1/2O2(y)-LiCoO2(z) type ternary phase diagram, (x, y, z) is represented by values in a range present on or within a line of a heptagon (ABCDEFG) defined by the vertexes; point A(0.45, 0.55, 0), point B(0.63, 0.37, 0), point C(0.7, 0.25, 0.05), point D(0.67, 0.18, 0.15), point E(0.75, 0, 0.25), point F(0.55, 0, 0.45), and point G(0.45, 0.2, 0.35); and the intensity ratio between the diffraction peaks on (003) plane and (104) plane measured by X-ray diffractometry before charge-discharge is I(003)/I(104)?1.56 and at the end of discharge is I(003)/I(104)>1.
    Type: Grant
    Filed: November 11, 2008
    Date of Patent: October 8, 2013
    Assignee: GS Yuasa International Ltd.
    Inventors: Daisuke Endo, Miki Yasutomi, Yoshihiro Katayama, Toshiyuki Nukuda
  • Publication number: 20130252080
    Abstract: Provided are an electric storage device in which a current collector is not easily broken even when vibration is applied, and a vehicle having this electric storage device. This electric storage device includes a case having a first inner surface and a second inner surface adjacent to the first inner surface, an electrode assembly housed in the case and including a positive electrode plate and a negative electrode plate insulated from each other, an electrode terminal disposed outside the case, and a current collector housed in the case and electrically connecting the electrode assembly and the electrode terminal to each other. A distal end edge of a distal end portion of the current collector is supported on the first inner surface of the case.
    Type: Application
    Filed: December 8, 2011
    Publication date: September 26, 2013
    Applicant: GS Yuasa International Ltd.
    Inventors: Nobuyuki Naganawa, Masamitsu Tononishi, Shinsuke Yoshitake, Yasunori Okuno, Masakazu Tsutsumi, Hajime Kawamoto, Tomonori Kishimoto, Jun Nakamura, Toshiyuki Nukuda
  • Patent number: 8501356
    Abstract: An additive typified by tris(trimethylsilyl)phosphate, tris(trimethylsilyl)borate, and tetrakis(trimethylsiloxy)titanium (Chem. 3) are applied to a nonaqueous electrolyte containing a chain carbonate and/or a chain carboxylate as a main solvent (contained at a ratio of 70 volume % or higher). It is preferable that 0?a<30 is satisfied, in which “a” denotes the volume of a cyclic carbonate among carbonates having no carbon-carbon double bond in the entire volume, defined as 100, of the carbonates having no carbon-carbon double bond and chain carboxylates in a nonaqueous solvent contained in the nonaqueous electrolyte (0<a<30 in the case no chain carboxylate is contained).
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: August 6, 2013
    Assignee: GS Yuasa International Ltd.
    Inventors: Kazusa Ohkubo, Koji Sukino, Shigeki Yamate, Suguru Kozono, Yoshihiro Katayama, Toshiyuki Nukuda
  • Patent number: 8431271
    Abstract: The invention provides a polyanion-based positive active material which can improve storage stability (especially, high temperature storage stability), charge and discharge cycle performance and the like of a lithium secondary battery, and a lithium secondary battery using the same. The positive active material for a lithium ion secondary battery contains lithium iron cobalt phosphate represented by the general formula: LiyFe(1-x)CoxPO4(0<x?0.019, 0?y?1.2). By using the positive active material for a lithium secondary battery, high temperature storage stability and charge and discharge cycle performance can be improved in comparison with a case where LiyFePO4 containing no Co is used. By using the positive active material, a lithium ion secondary battery can be suitable for applications in fields of electric automobiles and industrial batteries in which long lives, high capacities, and high output powers are required.
    Type: Grant
    Filed: May 22, 2009
    Date of Patent: April 30, 2013
    Assignee: GS Yuasa International Ltd.
    Inventors: Yukiko Fujino, Yoshinobu Yasunaga, Akihiro Fujii, Yohei Shibata, Mariko Kohmoto, Takashi Egawa, Toru Tabuchi, Hiroe Nakagawa, Tokuo Inamasu, Toshiyuki Nukuda
  • Patent number: 8382860
    Abstract: A process for producing a lithium secondary battery employs a charging method where a positive electrode upon charging has a maximum achieved potential of 4.3 V (vs. Li/Li+) or lower. The process includes charging the lithium secondary battery to reach at least a region with relatively flat fluctuation of potential appearing in a positive electrode potential region exceeding 4.3 V (vs. Li/Li+) and 4.8V (vs. Li/Li+) or lower. The lithium secondary battery includes an active material having a solid solution of a lithium transition metal composite oxide having an ?-NaFeO2 type crystal structure. The composition ratio of Li, Co, Ni, and Mn contained in the solid solution satisfies Li1+1/3xCo1?x?yNiy/2Mn2x/3+y/2(x+y?1, 0?y and 1?x?y=z).
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: February 26, 2013
    Assignee: GS Yuasa International Ltd.
    Inventors: Daisuke Endo, Miki Yasutomi, Yoshihiro Katayama, Toshiyuki Nukuda
  • Publication number: 20120308893
    Abstract: An object is to provide a positive active material for nonaqueous electrolyte secondary battery, which is capable of providing a battery with excellent cycle performance. Provided are a positive active material for nonaqueous electrolyte secondary battery, which includes an Fe-containing lithium vanadium phosphate compound having a NASICON-type structure, wherein in the Fe-containing lithium vanadium phosphate compound, the percentage of iron atoms relative to the sum of vanadium and iron atoms is 2% or more and 20% or less; and the like.
    Type: Application
    Filed: February 16, 2011
    Publication date: December 6, 2012
    Applicant: GS YUASA INTERNATIONAL LTD.
    Inventors: Yukiko Fujino, Yoshinobu Yasunaga, Toru Tabuchi, Tokuo Inamasu, Toshiyuki Nukuda
  • Publication number: 20120301759
    Abstract: An electric storage device includes: an electrode assembly including a positive electrode sheet, a negative electrode sheet, and a separator for insulating between the electrode sheets; positive and negative current collectors disposed on both ends of the electrode assembly; a case in which the electrode assembly and the current collectors are housed and that fixes one ends of the positive and negative current collectors; and a support member extending from the positive current collector to the negative current collector.
    Type: Application
    Filed: May 17, 2012
    Publication date: November 29, 2012
    Applicant: GS Yuasa International Ltd.
    Inventors: Shinsuke YOSHITAKE, Tomonori KISHIMOTO, Toshiyuki NUKUDA
  • Publication number: 20120219862
    Abstract: The present invention provides a Li3V2(PO4)3-based positive active material for a lithium secondary battery, which has high discharge capacity and excellent storage performance, particularly high-temperature storage performance; and a lithium secondary battery made using the positive active material. The positive active material for a lithium secondary battery has general formula Li3V2(PO4)3-x(BO3)x (0<x?2?2). It is preferable that x be 2?7?x?2?3. Also provided are a positive electrode for a lithium secondary battery containing the positive active material; and a lithium secondary battery including the positive electrode.
    Type: Application
    Filed: October 27, 2010
    Publication date: August 30, 2012
    Applicant: GS YUASA INTERNATIONAL LTD.
    Inventors: Yukiko Fujino, Yoshinobu Yasunaga, Toru Tabuchi, Tokuo Inamasu, Toshiyuki Nukuda