Abstract: Provided is a silicone based anti-foaming agent oil compound that has not only superior anti-foaming speed but also anti-foaming performance that does not degrade with repeated use or use over a long period. The silicone based anti-foaming agent oil compound comprises: (A) an essentially hydrophobic organopolysiloxane with a viscosity at 25° C. of 2,500 to 50,000 mPa·s: 20 to 80 parts by mass; (B) a hydrophobic organopolysiloxane or cyclic organopolysiloxane having silanol groups at least at both terminals: 20 to 80 parts by mass; (C) a silane or silane condensation product: 1 to 10 parts by mass; and (D) a fine powder silica with a specific surface area of 50 m2/g or more: 2 to 10 parts by mass; where the total amount of (A) and (B) combined is 100 parts by mass. Also provided is a method for manufacturing the silicone based anti-foaming agent oil compound.

Abstract: Provided is a silicone anti-foaming agent composition that not only has superior anti-foaming speed but also in which anti-foaming performance is not reduced even when used repeatedly or over a long period. The composition comprises: a polyorganosiloxane polymer crosslinked product having a polyoxyalkylene group, which includes: moiety structure (I): -R1-(R22SiO)d-R1(where R1 represents an alkylene group bonded to a silicon atom on the polysiloxane chain, R2 represents a monovalent hydrocarbon group, and d is 200 to 1000); and moiety structure (II): —(CeH2e)—O—(EO)x-(PO)y-(BO)z-R3 (where a single bond on the left end is bonded to a silicon atom on the polysiloxane chain, R3 represents a hydrogen atom, an alkyl group, an aryl group or an acyl group, e is 2 to 10, (x+y+z) is 40 to 100, x is 15 to 50, y is 15 to 50, and z is 0 to 50).

Abstract: Provided is a monomer composition for which there is little to no concern about safety when used as a raw material or the like in a cosmetic material and that does not cause deterioration in quality such as gelation or the like. A method for manufacturing the monomer composition is also provided. A monomer composition containing a radical polymerizable monomer having a radical polymerizable organic group and an organosilicon-containing organic group in a molecule, wherein a total concentration of a polymerization inhibitor based on a total mass of the radical polymerizable monomer and the polymerization inhibitor is 130 ppm by mass or less.

Abstract: Provided are silicone elastomer particles that have higher oil absorbency than conventional products and are less prone to aggregation, making the particles superior in handling workability as a cosmetic raw material and imparting a superior tactile sensation and feel during use to a cosmetic product. Specifically, silicone elastomer particles, having a structure in which at least two silicon atoms in a silicone elastomer particle are crosslinked by a divalent organic group having a partial structure formed by radical polymerization of vinyl acetate, as expressed by —{CH2—CH(COOCH3)}t— (where t is 1 or more), as well as a use thereof, are provided. In particular, the silicone elastomer particles have a crosslinked structure that is active with respect to biodegradability. Therefore, primary particles thereof are expected to have a property of disintegrating with the generation of non-crosslinked siloxane molecules due to a decomposition reaction of microorganisms and the like in the natural world.

Abstract: Provided is a monomer composition which has little to no concern about safety when used as a raw material of a cosmetic material or the like and does not cause deterioration in quality such as gelation. A manufacturing method for the monomer composition is also provided. A radical copolymer composition, comprising a radical copolymer of: a) a radical polymerizable monomer having a radical polymerizable organic group and an organic silicon-containing organic group in a molecule; and b) a radical polymerizable monomer other than component a); wherein the total concentration of a polymerization inhibitor based on the total mass of the radical copolymer and the polymerization inhibitor is 50 ppm by mass or less.

Abstract: A composition comprises: a branched organosilicon compound; an acrylate-functional compound other than the branched organosilicon compound; and optionally a carrier vehicle. The branched organosilicon compound has the following general formula (I): (R1)3Si—X (I); where X comprises a acryloxy-functional moiety, and each R1 is selected from —OSi(R4)3 and R, with the proviso that at least one R1 is —OSi(R4)3; where each R is a substituted or unsubstituted hydrocarbyl group; where each R4 is selected from R, —OSi(R5)3, and —[OSiR2]mOSiR3; where each R5 is selected from R, —OSi(R6)3, and —[OSiR2]mOSiR3; where each R6 is selected from R and —[OSiR2]mOSiR3; with the proviso that at least one of R4, R5 and R6 is —[OSiR2]mOSiR3; and where 0?m?100. A method of preparing a copolymer is further provided.

Abstract: Provided is a copolymer having a carbosiloxane dendrimer structure, where the amount of monomers having a carbosiloxane dendrimer structure is significantly reduced. Also provided is a composition, cosmetic raw material, film-forming agent, and a cosmetic material comprising the copolymer, as well as a method of manufacturing the copolymer and the like. The copolymer is a copolymer of (a1) an unsaturated monomer having a carbosiloxane dendrimer structure having a radically polymerizable organic group, and (a2) an unsaturated monomer having a radically polymerizable vinyl group, which is different from component (a1). The amount of unreacted unsaturated monomers (a1) and saturated monomers derived from the unreacted unsaturated monomers (a1) is 2500 ppm or less relative to the copolymer.

Abstract: A branched organosilicon compound (“compound”) is provided having the general formula: (R1)3Si—X—NR2R3, where X is a divalent linking group; R2 is H or R; R3 comprises an acryloxy moiety; each R1 is selected from R and —OSi(R4)3, with the proviso that at least one R1 is —OSi(R4)3; where each R4 is selected from R, —OSi(R5)3, and —[OSiR2]mOSiR3; where each R5 is selected from R, —OSi(R6)3, and —[OSiR2]mOSiR3; and where each R6 is selected from R and —[OSiR2]mOSiR3, with the proviso that at least one of R4, R5 and R6 is —[OSiR2]mOSiR3; 0?m?100; and each R is a substituted or unsubstituted hydrocarbyl group. Also provided is a method of preparing the compound, a copolymer comprising the reaction product of the compound and a second compound reactive with the compound, a method of forming the copolymer, and a composition including at least one of the compound and the copolymer.

Abstract: A composition comprises: a branched organosilicon compound; an acrylate-functional compound other than the branched organosilicon compound; and optionally a carrier vehicle. The branched organosilicon compound has the following general formula (I): (R1)3Si—X (I); where X comprises a acryloxy-functional moiety, and each R1 is selected from —OSi(R4)3 and R, with the proviso that at least one R is —OSi(R4)3; where each R is a substituted or unsubstituted hydrocarbyl group; where each R4 is selected from R, —OSi(R5)3, and —[OSiR2]mOSiR3; where each R5 is selected from R, —OSi(R6)3, and —[OSiR2]mOSiR3; where each R6 is selected from R and —[OSiR2]mOSiR3; with the proviso that at least one of R4, R5 and R6 is —[OSiR2]mOSiR3; and where 0?m?100. A method of preparing a copolymer is further provided.

Abstract: A detergent composition comprises a trisiloxane having at least one carbinol functional group. The trisiloxane comprises the reaction product of (A) an initial trisiloxane and (B) an organic compound. Component (A) has a pendant silicon-bonded functional group selected from a hydrogen atom, an epoxy-containing group, an ethylenically unsaturated group, and an amine group. Typically, component (A) is free of certain terminal silicon-bonded functional groups and is free of polyoxyalkylene groups. Component (B) has a functional group reactive with the pendant silicon-bonded functional group of component (A), and has at least one hydroxyl functional group. The trisiloxane may be of the following general formula (I): (R13SiO1/2)(R1R3SiO2/2)(R13SiO1/2) (I). In formula (I), each R1 is an independently selected hydrocarbyl group. R3 may be selected from the groups (i) to (x) described herein, each of the groups having at least one carbinol group. Typically, the trisiloxane has 1-6 carbinol groups.

Abstract: A detergent composition comprises a trisiloxane having at least one carbinol functional group. The trisiloxane comprises the reaction product of (A) an initial trisiloxane and (B) an organic compound. Component (A) has a pendant silicon-bonded functional group selected from a hydrogen atom, an epoxy-containing group, an ethylenically unsaturated group, and an amine group. Typically, component (A) is free of certain terminal silicon-bonded functional groups and is free of polyoxyalkylene groups. Component (B) has a functional group reactive with the pendant silicon-bonded functional group of component (A), and has at least one hydroxyl functional group. The trisiloxane may be of the following general formula (I): (R13SiO1/2)(R1R3SiO2/2)(R13SiO1/2) (I). In formula (I), each R1 is an independently selected hydrocarbyl group. R3 may be selected from the groups (i) to (x) described herein, each of the groups having at least one carbinol group. Typically, the trisiloxane has 1-6 carbinol groups.

Abstract: A trisiloxane having at least one carbinol functional group comprises the reaction product of (A) an initial trisiloxane and (B) an organic compound. Component (A) has a pendant silicon-bonded functional group selected from a hydrogen atom, an epoxy-containing group, an ethylenically unsaturated group, and an amine group. Typically, component (A) is free of certain terminal silicon-bonded functional groups and is free of polyoxyalkylene groups. Component (B) has a functional group reactive with the pendant silicon-bonded functional group of component (A), and has at least one hydroxyl functional group. The trisiloxane is useful for a number of applications including use as a detergent additive. The trisiloxane may be of the following general formula (I): (R13SiO1/2) (R1R3Si2/2)(R13SiO1/2) (I). In formula (I), each R1 is an independently selected hydrocarbyl group. R3 may be selected from the groups (i) to (iv) described herein. Typically, the trisiloxane has 1-6 carbinol groups.

Abstract: A cosmetic composition is disclosed, which comprises: (A) 100 parts by weight of at least one vinyl polymer having at least one carbosiloxane dendrimer group in a side chain; (B) from 0.1 to 30 parts by weight of a surfactant; and (X) water; wherein an emulsified particle comprising at least component (A) and component (B) is in an aqueous phase; and wherein a weight average molecular weight of component (A) is at least 80000. By blending a vinyl polymer emulsion having a carbosiloxane dendrimer structure in an aqueous phase according to the present invention, a cosmetic that exhibits excellent softness, texture during usage and smoothness of finish, waterproofness, and makeup retaining properties can be provided.

Abstract: The present invention relates to a monoalkenyl-containing glycerin derivative with purity of not less than 92% and electrical conductivity of not greater than 50 ?S/cm. The monoalkenyl-containing glycerin derivative can be manufactured by a manufacturing method comprising a step (A): a step of reacting a ketalized glycerin derivative and a monoalkenyl glycidyl ether in the presence of an inorganic base to obtain a ketal of monoalkenyl-containing glycerin derivative; a step (B): a step of purifying the ketal of monoalkenyl-containing glycerin derivative obtained in the step (A) by distillation; and a step (C): a step of hydrolyzing the ketal of monoalkenyl-containing glycerin derivative obtained in the step (B). The present invention is able to provide a high-purity monoalkenyl-containing glycerin derivative that was difficult in the past.

Abstract: A phenol-modified polyorganosiloxane suitable as a modifier for an organic resin, in which a platinum metal content is reduced, and the yellowing is reduced, a method for preparing the same, and a modifier for an organic resin containing the same are provided. The phenol-modified polyorganosiloxane is a compound of formula (I), having a platinum metal content of 0.9 ppm or less. The phenol-modified polyorganosiloxane can be prepared by subjecting a phenol compound substituted with an alkenyl group of formula (IV) and a polyorganohydrogen siloxane of formula (V) to a hydrosilation reaction in the presence of a platinum-based catalyst applicable to a homogenous system, and subsequently, reducing the platinum metal content of the resulting product to 0.

Abstract: The present invention relates to a use of an acid in a manufacture of an organopolysiloxane through a condensation reaction of a silicon-containing compound containing a silicon-bonded hydroxyl group and a silicon-containing compound containing a silicon-bonded aminoxy group. Particularly, the present invention relates to a low-odor composition including such an organopolysiloxane. The composition according to the present invention can have little odor caused by a by-product produced via the condensation reaction described above.

Abstract: The present invention relates to a monoalkenyl-containing glycerin derivative with purity of not less than 92% and electrical conductivity of not greater than 50 ?S/cm. The monoalkenyl-containing glycerin derivative can be manufactured by a manufacturing method comprising a step (A): a step of reacting a ketalized glycerin derivative and a monoalkenyl glycidyl ether in the presence of an inorganic base to obtain a ketal of monoalkenyl-containing glycerin derivative; a step (B): a step of purifying the ketal of monoalkenyl-containing glycerin derivative obtained in the step (A) by distillation; and a step (C): a step of hydrolyzing the ketal of monoalkenyl-containing glycerin derivative obtained in the step (B). The present invention is able to provide a high-purity monoalkenyl-containing glycerin derivative that was difficult in the past.

Abstract: A phenol-modified polyorganosiloxane suitable as a modifier for an organic resin, in which a platinum metal content is reduced, and the yellowing is reduced, a method for preparing the same, and a modifier for an organic resin containing the same are provided. The phenol-modified polyorganosiloxane is a compound of formula (I), having a platinum metal content of 0.9 ppm or less. The phenol-modified polyorganosiloxane can be prepared by subjecting a phenol compound substituted with an alkenyl group of formula (IV) and a polyorganohydrogen siloxane of formula (V) to a hydrosilation reaction in the presence of a platinum-based catalyst applicable to a homogenous system, and subsequently, reducing the platinum metal content of the resulting product to 0.

Abstract: [Problem to be Solved] To provide a non-curable coating composition which is used for preventing or reducing the adhesion of various sticky substances to the surfaces of substrates and is stable at elevated temperature, by using modified silicones having functional groups. [Means to Solve the Problem] A non-curable coating composition characterized by containing a carboxy-modified silicone with a carboxy group at a side chain thereof, and an epoxy/oxyalkylene-modified silicone with an epoxy group and an oxyalkylene group at a side chain thereof in a weight ratio ranging from 1:2 to 1:30, and further comprising an oxyalkylene-modified silicone having an HLB of 10 or more with an oxyalkylene group at a side chain thereof.

Abstract: The present invention relates to a use of an acid in a manufacture of an organopolysiloxane through a condensation reaction of a silicon-containing compound containing a silicon-bonded hydroxyl group and a silicon-containing compound containing a silicon-bonded aminoxy group. Particularly, the present invention relates to a low-odor composition including such an organopolysiloxane. The composition according to the present invention can have little odor caused by a by-product produced via the condensation reaction described above.