Abstract: The present disclosure provides a fluorine-containing polyether compound having a repeating unit represented by formula (1). In formula (1), n represents an integer of 1 to 8, Ph represents a phenylene group, X1 represents a heterocyclic ring or a hydrocarbon ring, one or both of two phenylene groups represented by Ph, and the heterocyclic ring or hydrocarbon ring represented by X1 are optionally condensed with each other, and the phenylene group, the heterocyclic ring, and the hydrocarbon ring optionally have a substituent.

Abstract: A polybenzimidazole production method for producing the polybenzimidazole including a repeating unit represented by the following formula (1): wherein Rf is —SO2—, —O—, —CO—, an alkylene group optionally containing a substituent, or a group represented by the following formula (a): two Xs are each individually a hydrogen atom or a monovalent organic group; and R1 is a divalent organic group, the production method including a step (1-1) of polymerizing a tetramine compound and a dicarboxylic acid derivative compound to provide a polybenzimidazole precursor polyamide, and a step (1-2) of dehydrocyclizing the polybenzimidazole precursor polyamide.

Abstract: A reclaiming method is disclosed including conducting evaporation by introducing a part of the absorbent to recover CO2 or H2S in a gas in a closed system recovery unit and separating a degraded substance contained in the absorbent from the absorbent to be introduced into an evaporator and obtain recovery steam containing an absorbent and CO2 or H2S by a heating section that is provided on a circulation line that circulates in the evaporator; and removing ionic degraded substance by cooling the concentrate obtained in the evaporation and removing an ionic degraded substance in the concentrate after the cooling, wherein a purified concentrate from which the ionic degraded substance has been removed is reused as a purified absorbent.

Abstract: An absorption column is equipped with: a CO2 absorption section absorbing CO2 from CO2-containing exhaust gas using a lean solution; a main rinse section recovering an entrained CO2 absorbent using rinse water; a rinse water circulation line circulating a rinse water containing the CO2 absorbent recovered in a liquid storage section of the main rinse section; a pre-rinse section provided between the CO2 absorption section and the main rinse section; a rinse section extraction liquid supply line extracting a portion of the rinse water containing the CO2 absorbent from the rinse water circulation line, and introducing the same into a reflux section of an absorption liquid regeneration tower; and a refluxed water supply line extracting a portion of refluxed water, introducing the same as pre-rinse water for the pre-rinse section, and connected on the pre-rinse section side.

Abstract: SOx removal equipment for reducing sulfur oxides from flue gas from a boiler, a cooler which is provided on a downstream side of the SOx removal equipment for reducing the sulfur oxides that remain in the flue gas and for decreasing a gas temperature, CO2 recovery equipment which includes a CO2 absorber, and an absorption liquid regenerator, and mist generation material reduction equipment for reducing a mist generation material which is a generation source of mist that is generated in the CO2 absorber of the CO2 recovery equipment before introducing the flue gas to the CO2 recovery equipment are included.

Abstract: A reclaiming method is disclosed including conducting evaporation by introducing a part of the absorbent to recover CO2 or H2S in a gas in a closed system recovery unit and separating a degraded substance contained in the absorbent from the absorbent to be introduced into an evaporator and obtain recovery steam containing an absorbent and CO2 or H2S by a heating section that is provided on a circulation line that circulates in the evaporator; and removing ionic degraded substance by cooling the concentrate obtained in the evaporation and removing an ionic degraded substance in the concentrate after the cooling, wherein a purified concentrate from which the ionic degraded substance has been removed is reused as a purified absorbent.

Abstract: An evaporator is provided that separates, from a degraded substance, an absorbent branched off and introduced, a heating section which is interposed on a circulation line L21 that circulates the absorbent introduced into this evaporator, heats the circulating absorbent to obtain gaseous recovery steam containing a vaporized absorbent and CO2, a concentrate branch line L22 that branches off a part of the absorbent circulating through the circulation line L21 at a bottom of the evaporator from the circulation line L21 as a concentrate, a cooler that is interposed on this concentrate branch line L22 and cools the concentrate, an ionic degraded substance removal section that removes an ionic degraded substance in the cooled concentrate, and a purified absorbent discharge line L23 that reuses the concentrate as a purified absorbent from which the ionic degraded substance is removed.

Abstract: An absorbing liquid which absorbs the CO2 or H2S or both contained in a gas, and which comprises 1) at least one tertiary-monoamine main agent selected from a tertiary-monoamine group and 2) at least one secondary-diamine first additive selected from a secondary-diamine group, the secondary-diamine concentration being within the range of 0.05 to 0.5 in terms of the additive concentration index represented by the following expression (I). (Additive concentration index)=[(secondary-diamine acid dissociation index) (pKa)/(tertiary-monoamine acid dissociation index) (pKa)] (index ratio)×[(secondary-diamine molar concentration) (mol/L)/(tertiary-monoamine molar concentration) (mol/L)] (molar ratio) (I).

Abstract: A CO2 recovery unit and a CO2 recovery method capable of having an excellent CO2 absorption rate and saving energy are provided. A CO2 recovery unit of the invention includes: a CO2 absorber which includes an upper CO2 absorption unit obtaining a CO2 absorbent by causing a flue gas containing CO2 to contact a CO2 absorbent and a lower CO2 absorption unit obtaining a CO2 absorbent by causing the CO2 absorbent to contact a flue gas containing CO2; a CO2 absorbent regenerator which obtains the CO2 absorbent by heating the CO2 absorbent a thermometer which measures a temperature of the CO2 absorbent supplied from the CO2 absorber to the CO2 absorbent regenerator; and a control device which controls a temperature of the CO2 absorbent supplied to the lower CO2 absorption unit based on the temperature of the CO2 absorbent measured by the thermometer.

Abstract: A CO2 recovery apparatus is provided with: a CO2 absorption tower for bringing exhaust gas into contact with a CO2 absorbing liquid and making the CO2 absorbing liquid absorb the CO2 contained in the exhaust gas; a CO2 absorbing liquid regeneration tower for heating the CO2 absorbing liquid with steam and releasing CO2 from the CO2 absorbing liquid and regenerating the CO2 absorbing liquid; a flowmeter for determining the flow rates of the exhaust gas introduced into the CO2 absorption tower; and a control unit for classifying the flow rates of the exhaust gas into multiple flow rate ranges, and controlling the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of steam supplied to the CO2 absorbing liquid regeneration tower on the basis of prescribed set load values which have been previously established in accordance with the multiple flow rate ranges.

Abstract: An absorption column is equipped with: a CO2 absorption section absorbing CO2 from CO2-containing exhaust gas using a lean solution; a main rinse section recovering an entrained CO2 absorbent using rinse water; a rinse water circulation line circulating a rinse water containing the CO2 absorbent recovered in a liquid storage section of the main rinse section; a pre-rinse section provided between the CO2 absorption section and the main rinse section; a rinse section extraction liquid supply line extracting a portion of the rinse water containing the CO2 absorbent from the rinse water circulation line, and introducing the same into a reflux section of an absorption liquid regeneration tower; and a refluxed water supply line extracting a portion of refluxed water, introducing the same as pre-rinse water for the pre-rinse section, and connected on the pre-rinse section side.

Abstract: A CO2 recovery device includes: a CO2 absorption tower in which CO2 included in an exhaust gas is absorbed by a CO2 absorption liquid; and a CO2 absorption liquid regeneration tower that heats and regenerates the CO2 absorption liquid that has absorbed CO2. The CO2 absorption liquid regeneration tower includes: a main body part in which the CO2 absorption liquid is temporarily stored; a boot part provided downward from a tank end of the main body part, having a relatively smaller capacity than the main body part; a flowmeter provided to the boot part, and measuring the liquid surface level of the CO2 absorption liquid that changes between the main body part and the boot part; and a control device controlling the liquid surface level of the CO2 absorption liquid between the main body part and the boot part on the basis of the measurement result of the flowmeter.

Abstract: An absorption column is equipped with: a CO2 absorption section absorbing CO2 from CO2-containing exhaust gas using a lean solution; a main rinse section recovering an entrained CO2 absorbent using rinse water; a rinse water circulation line circulating a rinse water containing the CO2 absorbent recovered in a liquid storage section of the main rinse section; a pre-rinse section provided between the CO2 absorption section and the main rinse section; a rinse section extraction liquid supply line extracting a portion of the rinse water containing the CO2 absorbent from the rinse water circulation line, and introducing the same into a reflux section of an absorption liquid regeneration tower; and a refluxed water supply line extracting a portion of refluxed water, introducing the same as pre-rinse water for the pre-rinse section, and connected on the pre-rinse section side.

Abstract: An absorbent is prepared by dissolving in water 1) monoethanolamine (MEA) and 2) a primary amine represented by the following formula (1) and having high steric hindrance. Releasability of CO2 or H2S during regeneration of the absorbent is thereby improved, and the amount of water vapor used during regeneration of the absorbent in a facility for recovering CO2 or H2S can be reduced. R1 to R3: H or a hydrocarbon group having 1 to 3 carbon atoms, at least one of R1 to R3 being a hydrocarbon.

Abstract: Provided are a reclaimer 51 that introduces, through a branch line L11, and stores a part 17a of an absorbent 17 regenerated in a regenerator of a recovery unit that recovers CO2 or H2S in a gas, a first alkaline agent supply section 53A that supplies an alkaline agent 52 to the reclaimer 51, a heating section 54 that heats the absorbent 17 stored in the reclaimer 51 and to which the alkaline agent 52 has been mixed to obtain recovered vapor 61, a first vapor cooler 55A that cools the recovered vapor 61 discharged from the reclaimer 51 through a vapor line L12, a first gas-liquid separator 56A that separates a coexisting substance 62 entrained in the cooled recovered vapor 61 into a recovered absorption agent vapor (gas) 17b and the liquid coexisting substance 62 by gas-liquid separation, and an introduction line L13 that introduces the recovered absorption agent vapor 17b separated in the first gas-liquid separator 56A into a regenerator 20.

Abstract: A CO2 recovery device includes: a CO2 absorption tower in which CO2 included in an exhaust gas is absorbed by a CO2 absorption liquid; and a CO2 absorption liquid regeneration tower that heats and regenerates the CO2 absorption liquid that has absorbed CO2. The CO2 absorption liquid regeneration tower includes: a main body part in which the CO2 absorption liquid is temporarily stored; a boot part provided downward from a tank end of the main body part, having a relatively smaller capacity than the main body part; a flowmeter provided to the boot part, and measuring the liquid surface level of the CO2 absorption liquid that changes between the main body part and the boot part; and a control device controlling the liquid surface level of the CO2 absorption liquid between the main body part and the boot part on the basis of the measurement result of the flowmeter.

Abstract: A gas-liquid contactor is obtained by including a header pipe for supplying washing water, in a direction perpendicular to a vertical axis direction, the header pipe being disposed above a packed bed contacting section through which exhaust gas moves upward and passes; and spray nozzles for discharging spray water, the nozzles being disposed, in an upward orientation, with predetermined intervals on the header pipe. The spray water that has been discharged from the spray nozzles is supplied at a low liquid flow rate. The discharged spray water becomes a liquid film and falls downward along the surface of the header pipe, and then falls and spreads in the packed bed contacting section, so that the washing water is made to contact the exhaust gas moving upward through the packed bed contacting section. Accordingly, the washing water is used to clear and remove water-soluble substances contained in the exhaust gas.

Abstract: When CO2 gas is absorbed by using an absorbent circulating in an absorption tower and an absorbent regeneration tower, a first sampling part at which a lean solution sample is collected in the vicinity of an inlet for a lean solution supply line in the absorption tower, a second sampling part at which a rich solution sample is collected in the vicinity of an outlet for a rich solution supply line in the absorption tower, and an analyzing device which analyzes the collected lean solution sample and rich solution sample are provided; the lean solution sample at the first sampling part and the rich solution sample at the second sampling part are collected, respectively, in the same time period, and concentrations of CO2 gas in the lean solution sample and the rich solution sample are measured, and then the gas absorbing/regenerating operation is controlled based on measured results.

Abstract: A filtration membrane device which uses a filter to collect solid contents remaining in a branched lean solution cleans the filter by using a low-concentration CO2 absorption liquid circulating within the system as cleaning water (containing the absorption liquid); rough cleaning, which returns the low-concentration CO2 absorption liquid used for cleaning to a lean solution supply line, is performed; the filter is finish-cleaned by cleaning water from outside the system which does not include the CO2 absorption liquid; the CO2 absorption liquid which is adhered to the solid contents is washed and removed; finish-cleaning water which includes the CO2 absorption liquid is returned to the lean solution supply line the moisture content within the system is maintained at a prescribed value by adjusting the water balance in an absorption tower and the concentration of the CO2 absorption liquid which circulates within the system is kept at a prescribed concentration.

Abstract: A CO2 recovery device includes: a CO2 absorption tower in which CO2 included in an exhaust gas is absorbed by a CO2 absorption liquid; and a CO2 absorption liquid regeneration tower that heats and regenerates the CO2 absorption liquid that has absorbed CO2. The CO2 absorption liquid regeneration tower includes: a main body part in which the CO2 absorption liquid is temporarily stored; a boot part provided downward from a tank end of the main body part, having a relatively smaller capacity than the main body part; a flowmeter provided to the boot part, and measuring the liquid surface level of the CO2 absorption liquid that changes between the main body part and the boot part; and a control device controlling the liquid surface level of the CO2 absorption liquid between the main body part and the boot part on the basis of the measurement result of the flowmeter.