Patent number: 9376636
Abstract: A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q?, wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.
Type:
Grant
Filed:
December 15, 2011
Date of Patent:
June 28, 2016
Assignees:
CNRS, IFP ENERGIES NOUVELLES
Inventors:
Karin Marchand, Elodie Devers, Alexandra Chaumonnot, Audrey Bonduelle, Veronique Dufaud, Frederic Lefebvre, Manuela Bader, Susana Lopes Silva
Publication number: 20140183100
Abstract: The invention relates to a process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q?, wherein X is an element selected from phosphorus (P), silicon (Si), boron (B), nickel (Ni) and cobalt (Co), the said element being taken alone, M is one or more element(s) selected from molybdenum (Mo), tungsten (W), nickel (Ni) and cobalt (Co), O is oxygen, H is hydrogen, h is an integer within the range 0 to 12, x is an integer within the range 0 to 4, m is an integer equal to 5, 6, 7, 8, 9, 10, 11, 12 and 18, y is an integer within the range 17 to 72 and q is an integer within the range 1 to 20, the said polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size within the range 1.
Type:
Application
Filed:
December 15, 2011
Publication date:
July 3, 2014
Applicants:
CNRS, IFP ENERGIES NOUVELLES
Inventors:
Karin Marchand, Elodie Devers, Alexandra Chaumonnot, Audrey Bonduelle, Veronique Dufaud, Frederic Lefebvre, Manuela Bader, Susana Lopes Silva