Abstract: A polyurethane composition is disclosed that comprises an isocyanate-terminated polyurethane prepolymer, and a curative agent including a polyaspartic ester. Desirably, the curative agent includes a co-curative selected from the group consisting aromatic diamines and diols. This composition is useful for rotationally casting cylindrical parts. The invention includes the method for coating a cylindrical object.

Abstract: A method for rotationally casting a coating onto a flexible substrate is provided wherein the coating comprises a polyurethane composition formed from (a) a substantially linear isocyanate-terminated polyurethane prepolymer; and, (b) a curative agent containing a diol having a molecular weight of less than 250 and, optionally, a secondary aliphatic diamine. Also provided is a flexible substrate possessing the coating.

Abstract: A method for coating a substrate includes rotating the substrate about an axis, and applying a polymeric reaction mixture to a surface of the rotating substrate by ejecting the polymeric reaction mixture through a die. The die has a branched system of channels for dividing an inlet stream of the polymeric reaction mixture into plural outlet streams. The outlet streams are spaced apart from each other such that the outlet streams flow together seamlessly after application to the substrate. The die and the rotating substrate are moved longitudinally relative to each other. And the material output rate of the mixture and the relative movement of the die are synchronized with the rotational speed of the substrate in such a way that successive convolutions of polymeric reaction mixture overlap and connect together seamlessly.

Abstract: Disclosed herein is a polyurethane elastomer comprising the reaction product of: A) at least one aliphatic diisocyanate monomer; B) at least one high molecular weight polyol; C) at least one low molecular weight diol comprising an aromatic moiety; and D) at least one saturated diol curing agent. These elastomers are useful as components of golf ball covers.

Abstract: A polyurethane composition is disclosed that comprises an isocyanate-terminated polyurethane prepolymer, and a curative agent including a polyaspartic ester. Desirably, the curative agent includes a co-curative selected from the group consisting aromatic diamines and diols. This composition is useful for rotationally casting cylindrical parts. The invention includes the method for coating a cylindrical object.

Abstract: Alkanediol ortho- and meta-diamino benzoates are prepared by reacting either ortho- or meta-amino benzoic acid esters with an alkanediol in the presence of a transesterification catalyst. The ortho-diamine may alternatively be prepared by reacting isatoic anhydride with the alkanediol. These alkanediol ortho- and meta-diamino benzoates are useful in the curing of urethane prepolymers to produce novel polyurethane urea elastomers.

Abstract: Disclosed herein is a polyurethane elastomer comprising the reaction product of:

Abstract: A method for rotationally casting a coating onto a flexible substrate is provided wherein the coating comprises a polyurethane composition formed from (a) a substantially linear isocyanate-terminated polyurethane prepolymer; and, (b) a curative agent containing a diol having a molecular weight of less than 250 and, optionally, a secondary aliphatic diamine. Also provided is a flexible substrate possessing the coating.

Abstract: A process is disclosed for the direct preparation of alkanediol-diaminobenzoates comprising transesterifying an alkyl-p-aminobenzoate with a diol in the presence of a transesterification catalyst.

Abstract: A method for depositing at least two components having dissimilar compositions on a cylindrical surface is disclosed wherein the method comprises the steps of:(a) rotating the cylindrical surface about its axis;(b) locating a mixing head a short distance from the cylindrical surface, said mixing head being connected to separate supply means for each of said components via flow controlling means;(c) opening a first flow controlling means thereby supplying a first component to the mixing head;(d) moving the mixing head in the axial direction along the cylindrical surface while depositing the first component from the mixing head onto the cylindrical surface;(e) opening a second flow controlling means to the extent necessary to supply a second component to the mixing head at a flow rate lower than that at which the first component is supplied;(f) gradually decreasing the flow rate of the first component while gradually increasing the flow rate of the second component until the flow of the first component is termi

Abstract: A polyurethane elastomer exhibiting superior flex fatigue properties is obtained by reacting a mixture of isocyanate-terminated polyether prepolymers with at least one alkylthioaromatic amine curing agent. Optionally, the elastomer can be postcured for further improvement of its properties. The polyurethane elastomer can be utilized for the fabrication of a non-pneumatic tire.

Abstract: An ether-based polyurethane article comprises a toluene diisocyanate-terminated polyether polyol prepolymer cured with a blended polyester polyol/diamine curative. The article may be made by mixing a toluene diisocyanate-terminated polyether polyol prepolymer with a blended polyester polyol/diamine curative to form a reaction mixture. A suitably shaped mold is preheated and filled with the reaction mixture with sufficient pressure to displace air in the mold. The reaction mixture is held in the preheated mold to cure the reaction mixture and form the article. The cast article is removed from the mold and post-cured to complete the chemical cross-linking reaction.

Abstract: A non-pneumatic tire is disclosed having a polyether polyol urethane elastomeric body with a plurality of angular radial ribs interconnected by webbing. The urethane is formed of at least two isocyanate-end capped polyether polyols of differing molecular weights to yield a tire with improved highway life and good vehicle ride characteristics.

Abstract: A non-pneumatic tire is disclosed having a polyether polyol urethane elastomeric body with a plurality of angular radial ribs interconnected by webbing. The urethane is formed of at least two isocyanate-end capped polyether polyols of differing molecular weights to yield a tire with improved highway life and good vehicle ride characteristics.

Abstract: The reaction between an isocyanate-terminated prepolymer and an aromatic diamine to form an elastomeric urethane-urea copolymer is accelerated using a quaternary ammonium compound as the catalyst. The quaternary ammonium compound is optionally employed in combination with a mono- or polyfunctional carboxylic acid containing from 4 to 20 carbon atoms.

Abstract: The curing time for articles prepared by reacting an isocyanate-terminated prepolymer with an aromatic diamine to form an elastomeric urethane/urea copolymer is significantly decreased using a tris(2,4,6-aminophenylthiomethyl)1,3,5-trihydrocarbyl substituted benzene as the crosslinking agent.

Abstract: The maximum concentration of specified sulfur-containing diamines that can be dissolved in polyols employed to prepare elastomeric urethane/urea block copolymers is significantly increased by the addition to said polyols of from 1 to 10% by weight of specified aprotic organic solvents containing oxygen, sulfur or both of these elements.