Abstract: A glass article (and methods for forming the same) includes a glass body having first and second opposing primary surfaces and a thickness defined between the primary surfaces. The glass body includes a compressive stress region that includes: a surface stress of greater than about 900 MPa (compressive), a spike region having a first slope, and a tail region having a second slope. The spike region and the tail region can intersect at a knee region having a stress of greater than about 35 MPa (compressive), wherein the stress at the knee region is defined as the point where the asymptotic extrapolation of the spike region and the tail region intersect. The first slope of the spike region can be steeper than about ?30 MPa/?m.

Abstract: A method of reworking lithium containing ion exchanged glass articles is provided. The method includes a reverse ion exchange process that returns the glass article to approximately the composition of the glass from which the glass article was produced, before being subjected to ion exchange. The reworked glass articles exhibit a K2O concentration profile comprising a portion wherein a K2O concentration increases to a local K2O concentration maximum.

Abstract: Chemically strengthened glass articles exhibiting superior resistance to damage when dropped onto an abrasive surface. The strengthened glass article has a stress profile in which the compressive and tensile stresses within the article vary as a function of the thickness t of the glass article. The stress profile has a first region extending from the surface of the glass article to a depth d1 into the glass, wherein d1?0.025t or ?20 um and has a maximum compressive stress of at least about 280 MPa at the surface, a second region extending from a depth of at least d1 to a second depth d2 and having a local compressive stress maximum, and a third region extending from a third depth d3 in the glass to a depth of compression DOC, wherein d2?d3 and DOC?0.15t. A method of strengthening a glass article to provide resistance to damage when dropped is also provided.

Abstract: A non-frangible glass article strengthened by a dual or two-step ion exchange (IOX) process, where the first IOX step leads to a depth of compressive layer FSM_DOL>0.1·t or, in some embodiments, FSM_DOL>0.15·t, where t is the thickness of the glass, is provided. The glass article has a compressive stress CS1 after the first IOX step at the surface of from 100 MPa to 400 MPa or, in some embodiments, from 150 MPa to 300 MPa. The first IOX step is followed by a second IOX step, leading to a “spike” compressive stress CS2 after the second IOX step at the surface of greater than 500 MPa or, in some embodiments, 700 MPa. The width of the spike generated by the second IOX is between 1 ?m and 30 ?m, or between 8 ?m and 15 ?m, using the criteria where the magnitude (absolute value) of the slope of the spike is higher than 20 MPa/?m.

Abstract: Apparatus and methods for measuring mode spectra for ion-exchanged glass substrates having a steep index region are disclosed. An interfacing fluid is provided between the coupling prism and the glass substrate. The interfacing fluid thickness is selected so that the variation in modal birefringence with fluid thickness is reduced to an acceptable level. The coupling prism can include a prism coating on the coupling surface so that the substrate-prism interface includes the prism coating. The coupling prism can also include stand-off members that serve to define the thickness of the interfacing fluid.

Abstract: Chemically strengthened glass articles exhibiting superior resistance to damage when dropped onto an abrasive surface. The strengthened glass article has a stress profile in which the compressive and tensile stresses within the article vary as a function of the thickness t of the glass article. The stress profile has a first region extending from the surface of the glass article to a depth d1 into the glass, wherein d1?0.025t or ?20 ?m and has a maximum compressive stress of at least about 280 MPa at the surface, a second region extending from a depth of at least d1 to a second depth d2 and having a local compressive stress maximum, and a third region extending from a third depth d3 in the glass to a depth of compression DOC, wherein d2?d3 and DOC?0.15t. A method of strengthening a glass article to provide resistance to damage when dropped is also provided.

Abstract: A method of reworking lithium containing ion exchanged glass articles is provided. The method includes a reverse ion exchange process that returns the glass article to approximately the composition of the glass from which the glass article was produced, before being subjected to ion exchange. The reworked glass articles exhibit a K2O concentration profile comprising a portion wherein a K2O concentration increases to a local K2O concentration maximum.

Abstract: Methods of characterizing ion-exchanged chemically strengthened Li-containing glasses include: a) measuring a mode spectrum of the glass sample; b) using the mode spectrum, estimating a first contribution to the center tension associated with a spike region and estimating a second contribution to the center tension due to a deep region only, wherein the deep region is assumed to follow a power-law stress profile; and c) determining a total center tension by adding of the first and second contributions to the center tension. The methods can be used for quality control during manufacturing of glass samples by comparing the total center tension to a center tension specification that provides optimum strength and durability.

Abstract: A non-frangible glass article strengthened by a dual or two-step ion exchange (IOX) process, where the first IOX step leads to a depth of compressive layer FSM_DOL>0.1·t or, in some embodiments, FSM_DOL>0.15·t, where t is the thickness of the glass, is provided. The glass article has a compressive stress CS1 after the first IOX step at the surface of from 100 MPa to 400 MPa or, in some embodiments, from 150 MPa to 300 MPa. The first IOX step is followed by a second IOX step, leading to a “spike” compressive stress CS2 after the second IOX step at the surface of greater than 500 MPa or, in some embodiments, 700 MPa. The width of the spike generated by the second IOX is between 1 ?m and 30 ?m, or between 8 ?m and 15 ?m, using the criteria where the magnitude (absolute value) of the slope of the spike is higher than 20 MPa/?m.

Abstract: Methods of improving the measurement of knee stress in an ion-exchanged chemically strengthened Li-containing glass sample that includes a knee are disclosed. One of the methods includes compensating for a shift in the location of the TIR-PR transition location associated with the critical angle location, wherein the shift is due to the presence of a leaky mode. Another method includes applying select criteria to the captured mode spectra image to ensure a high-quality image is used for the knee stress calculation. Another method combines direct and indirect measurements of the knee stress using the mode spectra from multiple samples to obtain greater accuracy and precision as compared to using either the direct measurement method or the indirect measurement method alone. Quality control methods of forming the glass samples using measured mode spectra and related techniques for ensuring an accurate measurement of the knee stress are also disclosed.

Abstract: Glass-based articles are frangible, comprising a peak central tension (CT) in a tensile region that is greater than: (E/68 GPa)*75 MPa*1 mm0.5/?(t), where E is the Young's modulus value of the glass-based substrate utilized to form the glass-based article. The stress profiles of the glass-based articles may comprise: a maximum compressive stress (CSmax) greater than or equal to 150 MPa; a depth of compression (DOC) that is greater than or equal to 0.21t; a peak central tension (CT) in a tensile region that is greater than or equal to 100 MPa to less than or equal to 220 MPa; and/or a negative curvature region, wherein a second derivative of stress as a function of depth is negative.

Abstract: Disclosed devices (100) include a liquid crystal layer (140), a cover glass (105), a polarizer (115), and at least one anti-static coating disposed on at least one major surface (105A, 105C) of the cover glass, at least one major surface (115A, 115C) of the polarizer, or both. Methods for reducing mura (light leakage) in a touch-display device by means of this anti-static coating are also disclosed.

Abstract: Glass-based articles comprise stress profiles providing improved scratch resistance. The glass-based articles comprise: a thickness t; a lithium aluminosilicate composition; and a molar ratio of sodium oxide (Na2O) to lithium oxide (Li2O) that is less than or equal to 0.63 at the center of the glass-based article. The articles have a molar ratio of sodium dioxide (Na2O) to lithium dioxide (Li2O) in a post-spike near region that is greater than or equal to 0.9 and/or less than 1.5.

Abstract: Glass-based articles article are described and have a first surface and a second surface opposing the first surface defining a thickness (t) (mm); and a compressive stress (CS) layer containing ion-exchanged potassium and ion-exchanged silver or ion-exchanged potassium and ion-exchanged copper, the CS layer extending from the first surface to a depth of compress (DOC), wherein the DOC is in a range of 0.1·t and 0.3·t, the CS at the first surface in a range of 300 MPa and 1500 MPa and defining a compressive stress profile including a spike region, a tail region and a knee region between the spike region and the tail region, wherein all points of the stress profile in the spike region comprise a tangent having a value that is in a range of ?15 MPa/micrometer and ?200 MPa/micrometer and all points in the tail region comprise a tangent having a value that is in a range of ?0.01 MPa/micrometer and ?3 MPa/micrometer.

Abstract: Glass-based articles have a first surface and a second surface opposing the first surface defining a thickness (t) and a center between the first surface and the second surface, the glass-based article containing Li2O, ion-exchanged potassium and ion-exchanged sodium. The glass-based article has a stress profile including a hump stress region extending from the first surface (or a point below the first surface) to an apex in a range of 0.001·t and 0.1t. Compressive stress at the apex is from 25 to 750 MPa. The hump region comprises an area of increasing stress and an area of decreasing stress. Depth of compression is from 0.1·t to 0.25·t. A tensile stress region extends from the depth of compression to a maximum tensile stress.

Abstract: Methods of characterizing ion-exchanged chemically strengthened Li-containing glasses include: a) measuring a mode spectrum of the glass sample; b) using the mode spectrum, estimating a first contribution to the center tension associated with a spike region and estimating a second contribution to the center tension due to a deep region only, wherein the deep region is assumed to follow a power-law stress profile; and c) determining a total center tension by adding of the first and second contributions to the center tension. The methods can be used for quality control during manufacturing of glass samples by comparing the total center tension to a center tension specification that provides optimum strength and durability.

Abstract: The systems and methods include generating polarization-switched (PS) detector and reference signals using a polarization switch controlled by a digital control signal generated by digital input/output card. A gain adjustment is performed on the PS detector and reference signals to define gain-adjusted detector and reference signals. The digital control signal is used to synchronize the gain-adjusted PS detector and reference signals to define gain-adjusted synchronized PS detector and reference signals each having respective steady-state portions. The steady state portions are used to define a measurement signal. The measurement signal is then used to calculate a stress-based characteristic of the sample being measured. The sample can be moved continuously or discretely through different measurement positions, which are synchronized with the operation of the polarization switch using the digital control signal.

Abstract: Methods of processing glass-based substrates to reduce birefringent defects and glass-based substrates are disclosed. In one embodiment, a method for processing a glass-based substrate includes rolling a glass-based material to form the glass-based substrate, and heat treating the glass-based substrate by increasing a temperate of the glass-based substrate, holding the temperature at a maximum temperature for a hold period, and then decreasing the temperature at one or more cooling rates, wherein after the heat treating, the glass-based substrate has a retardance over thickness of 5 nm/mm or less at locations outside of and including 5 mm from any corner of the glass-based substrate and outside of and including 5 mm from any edge of the glass-based substrate.

Abstract: Methods of improving the measurement of knee stress in an ion-exchanged chemically strengthened Li-containing glass sample that includes a knee are disclosed. One of the methods includes compensating for a shift in the location of the TIR-PR transition location associated with the critical angle location, wherein the shift is due to the presence of a leaky mode. Another method includes applying select criteria to the captured mode spectra image to ensure a high-quality image is used for the knee stress calculation. Another method combines direct and indirect measurements of the knee stress using the mode spectra from multiple samples to obtain greater accuracy and precision as compared to using either the direct measurement method or the indirect measurement method alone. Quality control methods of forming the glass samples using measured mode spectra and related techniques for ensuring an accurate measurement of the knee stress are also disclosed.

Abstract: Methods of manufacturing a glass-based article comprise: after mechanical polishing of a glass-based substrate, treating at least one surface of the glass-based substrate for protection of the at least one surface from contamination and/or for removal of contaminants from the at least one surface by a treatment other than ultrasonic cleaning; and exposing the glass-based substrate to an ion exchange treatment after the treating step to form the glass-based article. The treating step includes: exposing the at least one surface to a high pH soaking for removal of contaminants; deionizing the at least one surface for removal of contaminants; and/or applying a temporary coating to the at least one surface for protection of the at least one surface from contamination, and removing the temporary coating prior to the ion exchange treatment step. The ion exchange treatment may comprise a molten salt bath having an increased pH and temperature.