Abstract: A method for providing in situ chemical transformation and ionization of a portion (e.g., inorganic oxidizer) of a sample via an analyte detection system is disclosed herein. The method includes introducing a gas into an ionization some of the analyte detection system via an inlet. The method further includes generating ions within the ionization source and directing the gas and generated ions through and out of the ionization source and to the sample. The sample is located proximal to the ionization source in an ambient environment. The ions chemically react with the sample and desorb and ionize an analytic from the sample, the analyte being generated from the inorganic oxidizer, the desorbed analyte having a lower melting point and/or better desorption kinetics than the inorganic oxidizer. The method further includes receiving the desorbed analyte via an analyzer of the analyte detection system.

Abstract: An ion source has an arc chamber defining an arc chamber volume. A reservoir is coupled to the arc chamber, defining a reservoir volume. The reservoir receives a source species to define a liquid within the reservoir volume. A conduit fluidly couples the reservoir volume to the arc chamber volume. First and second openings of the conduit are open to the respective reservoir and arc chamber volume. A heat source selectively heats the reservoir to melt the source species at a predetermined temperature. A liquid control apparatus controls a first volume of the liquid within the reservoir volume to define a predetermined supply of the liquid to the arc chamber volume. The liquid control apparatus is a pressurized gas source fluidly coupled to the reservoir to supply a gas to the reservoir and provide a predetermined amount of liquid to the arc chamber.

Abstract: An ion source has an arc chamber defining an arc chamber volume. A reservoir is coupled to the arc chamber, defining a reservoir volume. The reservoir receives a source species to define a liquid within the reservoir volume. A conduit fluidly couples the reservoir volume to the arc chamber volume. First and second openings of the conduit are open to the respective reservoir and arc chamber volume. A heat source selectively heats the reservoir to melt the source species at a predetermined temperature. A liquid control apparatus controls a first volume of the liquid within the reservoir volume to define a predetermined supply of the liquid to the arc chamber volume. The liquid control apparatus is a pressurized gas source fluidly coupled to the reservoir to supply a gas to the reservoir and provide a predetermined amount of liquid to the arc chamber.

Abstract: An ion source has an arc chamber defining an arc chamber volume. A reservoir is coupled to the arc chamber, defining a reservoir volume. The reservoir receives a source species to define a liquid within the reservoir volume. A conduit fluidly couples the reservoir volume to the arc chamber volume. First and second openings of the conduit are open to the respective reservoir and arc chamber volume. A heat source selectively heats the reservoir to melt the source species at a predetermined temperature. A liquid control apparatus controls a first volume of the liquid within the reservoir volume to define a predetermined supply of the liquid to the arc chamber volume. The liquid control apparatus is a pressurized gas source fluidly coupled to the reservoir to supply a gas to the reservoir and provide a predetermined amount of liquid to the arc chamber.

Abstract: Embodiments of the present specification provide methods and systems for maintaining accuracy and precision of calibration for a detector. The methods and systems include reducing the humidity of an internal calibration assembly by directing flow path of dry air periodically through the internal calibration assembly.

Abstract: Embodiments of the present specification provide methods and systems for sensitivity traps that contain a polymer matrix made from an inert polymer material for encapsulation of trace amounts of explosives and narcotics and a suitable plasticizer material, the types and ratios of which may be selected based on type of analyte that is to be used with the sensitivity trap. The plasticizer material functions by breaking up intra and inter-molecular polymer chain interactions resulting in a larger diffusion coefficient of the analyte within the polymer matrix. Therefore, in embodiments, sufficient amounts of plasticizers are added to the sensitivity trap, which also reduces a glass transition temperature of the polymer matrix and the trap.

Abstract: Embodiments of the present specification provide methods and systems for maintaining accuracy and precision of calibration for a detector. The methods and systems include reducing the humidity of an internal calibration assembly by directing flow path of dry air periodically through the internal calibration assembly.

Abstract: Embodiments of the present specification provide methods and systems for clearing a detector of contaminants or any other undesirable substances that may affect operation of detector. The methods and systems enable a clear-down mode to clear the detector after an alarm is detected during sampling by the detector. The clear-down mode may be enabled immediately upon detecting a substance of interest. Further, the clear-down mode is effective to increase and direct all air flow through the detector in order to maximally purge contaminants from the detector.

Abstract: A method for providing in situ chemical transformation and ionization of a portion (e.g., inorganic oxidizer) of a sample via an analyte detection system is disclosed herein. The method includes introducing a gas into an ionization some of the analyte detection system via an inlet. The method further includes generating ions within the ionization source and directing the gas and generated ions through and out of the ionization source and to the sample. The sample is located proximal to the ionization source in an ambient environment. The ions chemically react with the sample and desorb and ionize an analytic from the sample, the analyte being generated from the inorganic oxidizer, the desorbed analyte having a lower melting point and/or better desorption kinetics than the inorganic oxidizer. The method further includes receiving the desorbed analyte via an analyzer of the analyte detection system.

Abstract: A surface ionizer for a trace detection system includes an extreme ultraviolet light source and an ion transfer line. Activation of the extreme ultraviolet light disrupts a surface of a sample along with residue and ionizes the resulting vapor. The ionized vapor is collected in the ion transfer line and passed into an analysis device for detection of components in the vapor.

Abstract: The present disclosure is directed to methods and systems for detecting a chemical substance. The methods and systems include using gas-solid phase chemistry to chemically and/or physically modify a substance of interest so that the substance can be vaporized and detected through an analysis of the substance.

Abstract: A desorber for a trace detection system. The desorber includes an inlet configured to receive a sample, a heating element configured to generate a vapor from the sample, and an active cooling element configured to cool the desorber.

Abstract: A method for providing in situ chemical transformation and ionization of a portion (e.g., inorganic oxidizer) of a sample via an analyte detection system is disclosed herein. The method includes introducing a gas into an ionization source of the analyte detection system via an inlet. The method further includes generating ions within the ionization source and directing the gas and generated ions through and out of the ionization source and to the sample. The sample is located proximal to the ionization source in an ambient environment. The ions chemically react with the sample and desorb and ionize an analyte from the sample, the analyte being generated from the inorganic oxidizer, the desorbed analyte having a lower melting point and/or better desorption kinetics than the inorganic oxidizer. The method further includes receiving the desorbed analyte via an analyzer of the analyte detection system.

Abstract: A desorber for a trace detection system. The desorber includes an inlet configured to receive a sample, a heating element configured to generate a vapor from the sample, and an active cooling element configured to cool the desorber.

Abstract: The present disclosure is directed to methods and systems for detecting a chemical substance. The methods and systems include using gas-solid phase chemistry to chemically and/or physically modify a substance of interest so that the substance can be vaporized and detected through an analysis of the substance.

Abstract: A surface ionizer for a trace detection system includes an extreme ultraviolet light source and an ion transfer line. Activation of the extreme ultraviolet light disrupts a surface of a sample along with residue and ionizes the resulting vapor. The ionized vapor is collected in the ion transfer line and passed into an analysis device for detection of components in the vapor.

Abstract: The present disclosure relates to an ion exchange process, as well as a process and system for detecting nitrates, which employ a class of dopants comprising at least two functional groups capable of simultaneous convergent hydrogen bonding with a nitrate ion.

Abstract: The present disclosure is directed to methods and systems for detecting a substance of interest. The methods and systems include contacting the substance of interest with a doped membrane, the doped membrane comprising at least one semi-permeable medium doped with at least one acid. The systems and methods further include desorbing the doped membrane to release the substance of interest, performing an analysis of the substance of interest, and detecting the substance of interest.

Abstract: The present disclosure is directed to methods and systems for detecting a substance of interest. The methods and systems include modifying a dopant precursor to release a dopant, and contacting the dopant with the substance of interest. The systems and methods further include performing an analysis of the substance of interest and detecting the substance of interest.

Abstract: A desorber for a trace detection system. The desorber includes an inlet configured to receive a sample, a heating element configured to generate a vapor from the sample, and an active cooling element configured to cool the desorber.