Abstract: A continuous contacting device is disclosed wherein a fluid stream may be contacted with particulate exchange materials. The device includes a plurality of rotating chambers filled with particulate material. Fluid is supplied individually to these chambers through a plurality feed ports which are in periodic fluid communicating relation with each of the chambers. A plurality of fixed discharge ports which are likewise in periodic fluid communicating relation with each of the chambers is also provided. A process for continuously contacting fluids with the solid particulates is also disclosed.

Abstract: A continuous contacting device is disclosed wherein a fluid stream may be contacted with particulate exchange materials. The device includes a plurality of rotating chambers filled with particulate material. Fluid is supplied individually to these chambers through a plurality feed ports which are in periodic fluid communicating relation with each of the chambers. A plurality of fixed discharge ports which are likewise in periodic fluid communicating relation with each of the chambers is also provided. A process for continuously contacting fluids with the solid particulates is also disclosed.

Abstract: A process for treating acidic process waste water containing SiF.sub.6.sup.2- is disclosed. The process is carried out by contacting the waste water with a strong base ion exchange resin and loading SiF.sub.6.sup.2- onto the resin. Phosphate ions are then removed from the waste water by raising the pH of the waste water to between about 5.0 and 7.0 and contacting the waste water with a strong base ion exchange resin and loading phosphate ions onto the resin.

Abstract: A process for removing sulfur dioxide from flue gas is disclosed. After passing through a precipitator to remove particulate material, the flue gas is conducted continuously through a fixed bed solid-gas contacting device containing activated carbon or natural zeolite. The bed is regenerated continuously, thereby producing sulfuric acid which may be mixed with ground phosphate rock to produce normal superphosphate, or other by-products.

Abstract: A process for the production of dialkali metal phosphates by ion exchange is disclosed. The process is carried out by first ammoniating a water-soluble phosphate source such as phosphoric acid or monocalcium phosphate. The resulting ammoniated phosphate solution is then contacted with a weak cation exchange resin in the alkali metal form to produce the dialkali metal phosphate as well as an ammonium-loaded weak cation exchange resin. The cation exchange resin is regenerated by contacting it with an alkali metal salt solution which effects an exchange of alkali metal from ammonium to produce a rgenerated weak cation exchange resin in the alkali metal form as well as a water-soluble ammonium salt corresponding to the initial alkali metal salt.

Abstract: A process for producing potassium phosphates by ion exchange using an Advanced Separation Device (ASD) is disclosed. The process is carried out by supplying a phosphate salt solution, a washing solution and a potassium salt regeneration solution to respective fixed feed ports in periodic fluid communication with a plurality of resin-filled chambers moving about a circular path. Passage of the phosphate salt solution through potassium loaded resin forms potassium phosphates and cation loaded resin by ion exchange. After washing out residual salts, the cation loaded resin is regenerated by adding a potassium salt which loads the resin with potassium and strips it of the cation in the form of a soluble cation salt.By virtue of the ASD, potassium phosphate may be produced continuously and with greater efficiency than is possible with conventional ion exchange processes since the potassium salt and phosphate salt feed solutions may be fortified in an intra-stage fashion, i.e.

Abstract: A process is disclosed for the continuous removal of ammonia from wastewater which converts the otherwise undesirable ammonia to a commercially useful end product such as ammonium phosphate. The process is carried out in an Advanced Separation Device which comprises a plurality of chambers moving about a circular path in periodic fluid communication with a plurality of fixed feed and discharge ports. The chambers are filled with a zeolite adsorbent which effectively adsorbs the ammonium ions contained in the wastewater at low pH levels but which, when contacted with an alkaline regeneration solution, releases the previously adsorbed ammonium in the form of ammonia gas, for which the zeolite has no affinity. By virtue of the ASD design, it is possible to add acidic materials to the wastewater in an intra-stage fashion i.e. during the adsorption step so as to optimize process efficiency. Similarly, intra-stage addition of alkaline materials during the regeneration step results in increased process efficiency.

Abstract: A process for the decolorization of pulp mill process streams is described. The effluent from the process contains color bodies and organic materials, and is first fed to an acidification reactor where the pH is reduced. This causes a portion of the color bodies to precipitate. A flocculant is added to coagulate the precipitated lignins, and the solution is filtered. The filtrate then passes through a series of chambers where it is contacted with activated carbon in an advanced separation device (ASD). The regeneration of the carbon occurs simultaneously in other chambers of the ASD. The treated filtrate with significantly lower color bodies passes out of the ASD in a substantially continuous stream.

Abstract: The method of the present invention is a novel comprehensive process for maximizing the recovery of valuable mineral values from coal ash. Options may also be included for the production of saleable inorganic chemical by-products. The process employs both physical and chemical extraction techniques that maximize the yield of products while reducing the quantity of waste produced. Valuable minerals and chemicals such as cenospheres (hollow microspheres), carbon, magnetite (Fe.sub.3 O.sub.4), alumina (Al.sub.2 O.sub.3), iron oxide (Fe.sub.2 O.sub.3) and iron chloride (FeCl.sub.3) may be produced. Due to removal of carbon, magnetite, and iron oxide from the coal ash, the processed ash comprises a quality pozzolan.

Abstract: A process for enhancing the concentration of one component contained in a multi-component gas is disclosed which is particularly well-suited for enriching the oxygen content of air. The process is carried out by a series of adsorption and desorption stages using an Advanced Separation Device comprised of a plurality of adsorbent-filled chambers moving about a circular path in periodic fluid communication with a plurality of fixed feed and discharge ports. By using the Advanced Separation Device, it is possible to load the oxygen content of air onto the adsorbent which is then stripped by a second stream of air. This oxygen-enriched stream of air may then be divided so that the oxygen content of one stream may be adsorbed for subsequent removal by the other stream to produce a doubly-enriched stream.