Abstract: Mixed matrix pervaporation membranes are described which include i) a matrix phase comprising a polymeric material, and ii) a zeolitic imidazolate framework (ZIF) dispersed in the matrix phase. In membranes described, the thickness of the membrane is greater than 0.5 ?m. The membranes may in examples be used in a process for separating an organic compound from an aqueous liquid mixture. An example process includes contacting the liquid mixture on one side of a mixed matrix pervaporation membrane to cause the organic compound to permeate the mixed matrix membrane, and removing from the other side of the membrane a permeate composition comprising a portion of the organic compound which permeated the membrane. Example membranes described have relatively good selectivity for separation of the organic compound from the liquid mixture.

Abstract: A method of forming a composite membrane (104) comprising particles of a filler material (110) in a polymer matrix (114) is described. In an example, the method includes the steps of: providing a support surface (100); applying particles of filler material onto the support surface to form an array of particles (110) and interspaces (112) between the particles; and applying matrix material to the filler material on the support surface such that matrix material (114) is applied in interspaces. By applying the particles to the surface, followed by the application of the matrix material, in some examples a more desirable distribution of the particles in the final membrane may be achieved.

Abstract: A composition comprising an electron-conducting component and an oxide ion-conducting component, characterised in that the electron-conducting component is also an oxide ion-conductor, the composition being suitable for use in a selective oxygen permeable membrane for separating oxygen from a gaseous mixture comprising oxygen, such as air, the separation optionally being carried out in a reactor comprising a first and second zone, in which an oxygen-containing gas is fed to the first zone, and a reactant fed to the second zone, in which an oxygen consuming reaction occurs in the second zone of the reactor.