Abstract: A base-neutralized, water-diluted coating comprises (A) a polyhydroxyl-functional resin of an acrylate resin or an oil-free polyester containing urethane groups, (B) an amino resin partially etherified with an alcohol, (C) a basic neutralizing agent, (D) water, and (E) a water-insoluble crosslinking catalyst of a strong organic or inorganic acid such as p-toluenesulfonic acid blocked with a monoepoxide, diepoxide or lactone.

Abstract: The invention relates to enamels which are water-dilutable after neutralization with bases and which contain non-ionically blocked strong acids as the cross-linking catalysts. In comparison with enamels with ionically blocked strong acids, the hardened enamel films exhibit no wrinkling and improved acid-resistance.

Abstract: A low-solvent aqueous binder includes: a water-insoluble synthetic resin component A; and an emulsifier resin B in a mass ratio of A to B of from 70:30 to 30:70. The emulsifier resin B is a reaction product of a water-insoluble synthetic resin B1 that includes hydroxyl groups as functional groups, a synthetic resin B2 that includes carboxyl groups as functional groups, and a neutralizing agent for the carboxyl groups of B. The amount of the neutralizing agent is such that the neutralizing agent is able to neutralize from 5 to 200% of the carboxyl groups of B. A process for preparing a low-solvent aqueous binder includes: mixing the water-insoluble synthetic resin component B1 comprising hydroxyl functional groups and the synthetic resin B2 in bulk or dissolved in an organic solvent to form a mixture; removing the solvent by applying subatmospheric pressure and heating until the content of the mixture is at least 85% by mass; maintaining the mixture at a temperature from 90° to 150° C.

Abstract: A water-dilutable coating after base neutralization comprises a polyhydroxyl-functional resin including a condensation resin such as a polyester or alkyd resin, and/or a polyhydroxyl-functional addition resin such as an acrylate resin or the reaction product of a carboxyl-functional acrylate resin and a hydroxyl-functional acrylate resin, and/or an emulsion copolymer, an at least partially monoalcohol-etherified amino resin, and a strong organic or inorganic acid crosslinking catalyst non-ionically blocked with a monoepoxide, a diepoxide or a lactone.

Abstract: A process is disclosed for preparing water-dilutable, acrylate copolymer-based lacquer binders. A polycarboxylic component is reacted with an epoxide group-containing polyhydroxylic component, and the carboxylic groups are then at least partially neutralized. As epoxide group-containing monomers for the polyhydroxylic components, glycidyl(meth)acrylate and/or glycidylallylether are used in proportions from 0.1 to 3% by weight. Associated with cross-linking components and if required with other lacquer binders, these lacquer binders are suitable for producing water-dilutable baking enamels with a low auxiliary organic solvent content.

Abstract: A process is disclosed for preparing water-dilutable enamel paint binders based on oligourethane-acrylate copolymers. A specific monomer mixture is polymerized in the presence of a water-insoluble oligourethane obtained by reacting an aliphatic ester diol with a diisocyanate. Water dilutability is achieved by using (meth)acrylic acid. These enamel paint binders are used in combination with cross-linking components and if required other enamel paint binders to formulate baking enamels.

Abstract: A copolymer containing a hydroxy and a carboxyl moiety and is dilutable with water after neutralization with an organic base, which copolymer is from an alkyl ester and/or hydroxyalkyl ester of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid in which the alkyl moiety is interrupted by one or more oxygen atoms and the alkyl moiety of the hydroxyalkyl ester can contain one or more hydroxyl groups, an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, and an optionally copolymerizable vinyl monomer, and has an acid number of from about 20 to about 50, and an OH number of from about 40 to about 90, and contains incorporated by polymerization from about 0.5 to about 5% wt. based on the monomers used for its preparation of one or more perfluoroalkyl ethyl ester of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid containing a C.sub.6-18 alkyl moiety.

Abstract: Water-dilutable coating compositions comprising a combination of specifically selected acrylic copolymers, dissolved in a specifically defined solvent blend, combined with coloring and/or optical effect imparting pigments, and, optionally, polymer dispersions and amine resins, are described. The compositions when used as a base coat for wet-on-wet application of a multi-coat paint system exhibit excellent performance on application and give finishes with outstanding properties.

Abstract: The invention is concerned with stabilized metal pigments, in particular aluminum pigments, particularly against water and moisture, with improved resistance characteristics in aqueous paints. The stabilization of the metal particles is carried out through treatment with carboxyalkylene phosphoric acid esters, and/or carboxyalkylene phosphonic acids, and/or carboxyalkylene phosphinic acids. The carboxylic group of the compounds can be at least partially neutralized if desired.

Abstract: Metal pigments stabilized against chemical influences particularly for use in aqueous paint systems by blending with the reaction product of an amine-aldehyde condensation product etherified with low molecular weight alcohols and an acidic phosphoric acid derivative of the general formulaP (O) R.sub.x (OH).sub.yor a derivative of a polyphosphoric acid of the general formula[P (O) R.sub.x (OH).sub.y-z O.sub.0.5 z ]n,wherein R is a radical linked to the phosphoric or polyphosphoric acid radical through a C--P-- or C--O--P--linkage and which contains a group reactive with said amine-aldehyde condensation product; x being a number less than 3 and x+y equaling 3, z being the number of P--O--links stemming from a P-atom and being less than y, and n being the degree of polymerization.

Abstract: A spray coating process for application of water-dilutable paint systems which includes spraying a water-dilutable paint through a main nozzle which atomizes the paint and simultaneously therewith spraying at least one additional material from at least one lateral ancillary nozzle into and/or around the paint stream from the main nozzle. The additional material can be water to control the water content of the paint film, or it can be an additive such as a leveling aid for the paint. The spraying of the additional material into and around the paint stream while it is being projected to the surface to be painted causes the material to locate primarily at the surface of the atomized paint droplets.