Abstract: The invention relates to a process for the preparation of a heterophasic polypropylene resin in a multistage polymerisation process in the presence of a metallocene catalyst, said process comprising: (I) in a first polymerisation step, polymerising propylene and optionally at least one C2-10 alpha olefin comonomer; and subsequently (II) in a second polymerisation step, polymerising propylene, ethylene and optionally at least one C3-10 alpha olefin comonomer, in the presence of the metallocene catalyst and polymer from step (I); wherein step (II) takes place in at least one gas phase reactor operating at a pressure of at least 26 bar. The present invention further relates to a heterophasic polypropylene resin comprising a polypropylene matrix phase (A) and an ethylene-propylene copolymer phase (B) dispersed within said polypropylene matrix phase, wherein the ethylene-propylene copolymer phase (B) is an amorphous ethylene-propylene copolymer with an intrinsic viscosity (iV) measured in decalin at 135° C.

Abstract: A complex of formula (I): (I?) M is Hf; each X is a sigma ligand; L is a bridge of formula -(ER82)y—; y is 1 or 2; E is C or Si; each R8 is independently a C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl or L is an alkylene group such as methylene or ethylene; Ar and Ar? are each independently an aryl or heteroaryl group optionally substituted by 1 to 3 groups R1 or R1? respectively; R1 and R1? are each independently the same or can be different and are a linear or branched C1-C6-alkyl group, C7-20 arylalkyl, C7-20 alkylaryl group or C6-20 aryl group with the proviso that if there are four or more R1 and R1? groups present in total, one or more of R1 and R1? is other than tert butyl; R2 and R2? are the same or are different and are a CH2—R9 group, with R9 being H or linear or branched C1-C6-alkyl group, C3-8 cycloalkyl group, C6-10 aryl group; each R is a —CH2—, —CHRx- or C(Rx)2- group wherein Rx is C1-4 alkyl and where m is 2-6; R5 is a linear or branched C1-C6-a

Abstract: A propylene copolymer composition comprising A) a propylene butylene copolymer which is—free of phthalicacid esters as well as decomposition products thereof; —obtained by a Ziegler-Natta catalyst and B) at least one ?-nucleating agent, the propylene copolymer composition having—a MFR (2.16 kg/210° C.) in the range of 2 to 100 g/10 min—a melting point Tm(1) of less than 140° C.—a melting point Tm(2) of at least 150° C., said Tm(2) being associated with more than 75% of the total melting enthalpy and whereby the propylene copolymer—has monomer units derived from a) propylene in an amount of 90.0-98.0 mol.-% b) butylene in an amount of 2.0-10.0 mol.-% with respect to the total weight of the propylene butylene copolymer—an isotacticity mm % as determined by 13C NMR spectroscopy of below 99.0%; and—a Koenig-B parameter with respect to butylene as determined by 13C NMR spectroscopy of more than 0.98.

Abstract: A complex of formula (I): (I?) M is Hf; each X is a sigma ligand; L is a bridge of formula -(ER82)y—; y is 1 or 2; E is C or Si; each R8 is independently a C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20- aryl, C7-C20-arylalkyl or C7-C20-alkylaryl or L is an alkylene group such as methylene or ethylene; Ar and Ar? are each independently an aryl or heteroaryl group optionally substituted by 1 to 3 groups R1 or R1? respectively; R1 and R1? are each independently the same or can be different and are a linear or branched C1-C6-alkyl group, C7-20 arylalkyl, C7-20 alkylaryl group or C6-20 aryl group with the proviso that if there are four or more R1 and R1? groups present in total, one or more of R1 and R1? is other than tert butyl; R2 and R2? are the same or are different and are a CH2—R9 group, with R9 being H or linear or branched C1-C6-alkyl group, C3-8 cycloalkyl group, C6-10 aryl group; each R is a —CH2—, —CHRx- or C(Rx)2-group wherein Rx is C1-4 alkyl and where m is 2-6; R5 is a linear or branched C1-C6-a