Patents by Inventor Wilfried Stubbe

Wilfried Stubbe has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9777190
    Abstract: Disclosed are aqueous coating compositions comprising at least one hydroxyl-containing compound (A), at least one compound (B) having isocyanate groups and also having hydrolyzable silane groups, and at least one catalyst (C) wherein the compound (B) has 10 mol % to less than 90 mol % of at least one structural unit (I) —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(I) Where R?=hydrogen, alkyl or cycloalkyl, X, X?=linear and/or branched alkylene or cycloalkylene radical having 1 to 20 carbon atoms, R?=alkyl, cycloalkyl, aryl or aralkyl, n=0 to 2, m=0 to 2, m+n=2, and x, y=0 to 2, and more than 10 to 90 mol % of at least one structural unit (II) —Z—(X—SiR?x(OR?)3-x) (II), where Z=—NH—, —NR—, —O— or —S—, where R=alkyl, cycloalkyl, aryl or aralkyl, and x, X, R? and R? have the definition indicated for formula (I).
    Type: Grant
    Filed: January 4, 2012
    Date of Patent: October 3, 2017
    Assignee: BASF Coatings GmbH
    Inventors: Matthijs Groenewolt, Manuela Niemeier, Wilfried Stübbe, Alexandra Steffens, Britta Schnieders
  • Patent number: 9353287
    Abstract: Disclosed are coating compositions comprising at least one hydroxyl-containing compound (A) and at least one isocyanato-containing compound (B), wherein one or more of the constituents of the coating composition comprise between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (I) —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(I) and between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (II) —Z—(X—SiR?x(OR?)3-x)??(II).
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: May 31, 2016
    Assignee: BASF Coatings GmbH
    Inventors: Matthijs Groenewolt, Andreas Poppe, Gunter Klein, Manuela Niemeier, Elke Westhoff, Wilfried Stubbe, Simone Hesener
  • Patent number: 8679589
    Abstract: The present invention relates to a coating composition comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (C) for the crosslinking of silane groups, one or more constituents of the coating composition containing hydrolyzable silane groups, wherein the coating composition contains a water scavenger as further constituent (D).
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: March 25, 2014
    Assignee: BASF Coatings GmbH
    Inventors: Matthijs Groenewolt, Günter Klein, Andreas Poppe, Simone Hesener, Wilfried Stübbe, Manuela Niemeier, Sabine Holtschulte, Oliver Hilge, Björn Feldmann
  • Patent number: 8658752
    Abstract: The invention relates to the use of partly silanized compounds based on polyisocyanate as crosslinking agents with heightened refractive index in curable coating compositions, more particularly in clearcoat materials for automotive finishing. The invention likewise relates to a coating composition which comprises these compounds as crosslinking agents, and to the use of the coating composition to produce a coating.
    Type: Grant
    Filed: June 25, 2009
    Date of Patent: February 25, 2014
    Assignee: BASF Coatings GmbH
    Inventors: Matthijs Groenewolt, Simone Hesener, Wilfried Stübbe, Manuela Niemeier, Elke Westhoff
  • Publication number: 20140037851
    Abstract: Disclosed are aqueous coating compositions comprising at least one hydroxyl-containing compound (A), at least one compound (B) having isocyanate groups and also having hydrolyzable silane groups, and at least one catalyst (C) wherein the compound (B) has 10 mol % to less than 90 mol % of at least one structural unit (I) —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(I) Where R?=hydrogen, alkyl or cycloalkyl, X, X?=linear and/or branched alkylene or cycloalkylene radical having 1 to 20 carbon atoms, R?=alkyl, cycloalkyl, aryl or aralkyl, n=0 to 2, m=0 to 2, m+n=2, and x, y=0 to 2, and more than 10 to 90 mol % of at least one structural unit (II) —Z—(X—SiR?x(OR?)3-x) (II), where Z=—NH—, —NR—, —O— or —S—, where R=alkyl, cycloalkyl, aryl or aralkyl, and x, X, R? and R? have the definition indicated for formula (I).
    Type: Application
    Filed: January 4, 2012
    Publication date: February 6, 2014
    Applicant: BASF COATINGS GMBH
    Inventors: Matthijs Groenewolt, Manuela Niemeier, Wilfried Stübbe, Alexandra Steffens, Britta Schnieders
  • Publication number: 20140023789
    Abstract: Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, said catalyst (D) comprising phosphorus. It is an aspect of the disclosed coating compositions that (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (ii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network.
    Type: Application
    Filed: September 25, 2013
    Publication date: January 23, 2014
    Applicant: BASF COATINGS GMBH
    Inventors: Matthijs Groenewolt, Andreas Poppe, Gunter Klein, Manuela Niemeier, Elke Westhoff, Wilfried Stubbe, Simone Hesener
  • Publication number: 20110269897
    Abstract: The invention relates to the use of partly silanized compounds based on polyisocyanate as crosslinking agents with heightened refractive index in curable coating compositions, more particularly in clearcoat materials for automotive finishing. The invention likewise relates to a coating composition which comprises these compounds as crosslinking agents, and to the use of the coating composition to produce a coating.
    Type: Application
    Filed: June 25, 2009
    Publication date: November 3, 2011
    Applicant: BASF COATINGS GMBH
    Inventors: Matthijs Groenewolt, Simone Hesener, Wilfried Stubbe, Manuela Niemeier, Elke Westhoff
  • Patent number: 8034872
    Abstract: Hydrolysates and/or condensates of epoxy- and silane-functional oligomers and polymers, prepared by hydrolyzing and/or condensing at least one oligomer and/or polymer (A) containing at least one epoxide group (a1) and at least one hydrolyzable silane group (a2); and also (meth)acrylate copolymers (A) containing lateral and/or terminal epoxide groups (a1) and lateral and/or terminal hydrolyzable silane groups (a2), in a molar ratio (a1): (a2) of from 15:1 to 1: 1.5, processes for preparing them, and their use.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: October 11, 2011
    Assignee: BASF Coatings GmbH
    Inventors: Andreas Poppe, Wilfried Stübbe, Elke Westhoff, Manuela Niemeier, Dunja Köppen
  • Patent number: 8013099
    Abstract: Disclosed herein is a silane-functional mixture, comprising at least one phosphonic diester (A), at least one diphosphonic diester (A), or at least one phosphonic diester and one diphosphonic diester (A), and at least one compound (B) comprising at least two condensable silane groups.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: September 6, 2011
    Assignee: BASF Coatings AG
    Inventors: Andreas Poppe, Elke Westhoff, Simone Hesener, Manuela Niemeier, Wilfried Stubbe
  • Publication number: 20110027489
    Abstract: The present invention relates to a coating composition comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (C) for the crosslinking of silane groups, ?one or more constituents of the coating composition containing hydrolyzable silane groups, wherein the coating composition contains a water scavenger as further constituent (D).
    Type: Application
    Filed: December 18, 2008
    Publication date: February 3, 2011
    Applicant: BASF COATINGS GMBH
    Inventors: Matthijs Groenewolt, Günter Klein, Andreas Poppe, Simone Hesener, Wilfried Stubbe, Manuela Niemeier, Sabine Holtschulte, Oliver Hilge, Björn Feldmann
  • Publication number: 20100143596
    Abstract: Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, said catalyst (D) comprising phosphorus. It is an aspect of the disclosed coating compositions that (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (ii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network.
    Type: Application
    Filed: December 19, 2007
    Publication date: June 10, 2010
    Applicant: BASF COATINGS AG
    Inventors: Matthijs Groenewolt, Andreas Poppe, Gunter Klein, Manuela Niemeier, Elke Westhoff, Wilfried Stubbe, Simone Hesener
  • Publication number: 20100137503
    Abstract: Hydrolysates and/or condensates of epoxy- and silane-functional oligomers and polymers, prepared by hydrolyzing and/or condensing at least one oligomer and/or polymer (A) containing at least one epoxide group (a1) and at least one hydrolyzable silane group (a2); and also (meth)acrylate copolymers (A) containing lateral and/or terminal epoxide groups (a1) and lateral and/or terminal hydrolyzable silane groups (a2), in a molar ratio (a1):(a2) of from 1.5:1 to 1:1.5, processes for preparing them, and their use.
    Type: Application
    Filed: November 8, 2004
    Publication date: June 3, 2010
    Applicant: BASF Corporation
    Inventors: Andreas POPPE, Wilfried STUBBE, Elke WESTHOFF, Manuela NIEMEIER, Dunja KOPPEN
  • Publication number: 20100028544
    Abstract: Disclosed are coating compositions comprising at least one hydroxyl-containing compound (A) and at least one isocyanato-containing compound (B), wherein one or more of the constituents of the coating composition comprise between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (I) —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m ??(I) and between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (II) —Z—(X—SiR?x(OR?)3-x) ??(II).
    Type: Application
    Filed: December 19, 2007
    Publication date: February 4, 2010
    Applicant: BASF COATINGS AG
    Inventors: Matthijs Groenewolt, Andreas Poppe, Gunter Klein, Manuela Niemeier, Elke Westhoff, Wilfried Stubbe, Simone Hesener
  • Publication number: 20100015344
    Abstract: Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, where (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (iii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network. The finally cured coating obtained from the coating composition has a post-crosslinking index (PCI) of less than 2, wherein (PCI) is defined as the ratio of the storage modulus E?(200) at 200° C. to the minimum of the storage modulus E?(min) at a temperature above the measured glass transition temperature Tg.
    Type: Application
    Filed: December 19, 2007
    Publication date: January 21, 2010
    Applicant: BASF COATINGS AG
    Inventors: Matthijs Groenewolt, Andreas Poppe, Gunter Klein, Manuela Niemeier, Elke Westhoff, Wilfried Stubbe, Simone Hesener
  • Patent number: 7488769
    Abstract: An aqueous dispersion with a pH of from 2 to 7, comprising (A) at least one swellable polymer or oligomer containing anionic and/or potentially anionic functional groups, (B) surface-modified, cationically stabilized, inorganic nanoparticles of at least one kind, and (C) at least one amphiphile; and its use for producing highly scratch-resistant coatings, moldings, and self-supporting films.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: February 10, 2009
    Assignee: BASF Coatings AG
    Inventors: Wolfgang Bremser, Wilfried Stübbe, Elke Westhoff, Manuela Niemeier, Andreas Poppe
  • Publication number: 20080245999
    Abstract: Disclosed herein is a silane-functional mixture, comprising at least one phosphonic diester (A), at least one diphosphonic diester (A), or at least one phosphonic diester and one diphosphonic diester (A), and at least one compound (B) comprising at least two condensable silane groups.
    Type: Application
    Filed: September 13, 2006
    Publication date: October 9, 2008
    Applicant: BASF COATINGS AG
    Inventors: Andreas Poppe, Elke Westhoff, Simone Hesener, Manuela Niemeier, Wilfried Stubbe
  • Patent number: 7416781
    Abstract: Transparent coatings with a thickness of at least 30 ?m, a relative elastic resilience to DIN 55676 of at least 70%, and a scratch resistance corresponding to a score of not more than 2 in the steel wool scratch test to DIN 1041 after 10 double strokes; process for producing them, and their use.
    Type: Grant
    Filed: July 5, 2003
    Date of Patent: August 26, 2008
    Assignee: BASF Coatings AG
    Inventors: Manuela Niemeier, Andreas Poppe, Wilfried Stübbe, Elke Westhoff, Jens-Dieter Fischer
  • Publication number: 20070217671
    Abstract: A method of characterizing surface structures using a chemically curable impression material to take an impression of at least one site of the undamaged surface of an article and of a surface of an article damaged by mechanical and/or chemical exposure and/or by exposure to radiation and/or heat, and/or of a surface of a test specimen mounted on the surface of an article, said test specimen surface being damaged by mechanical and/or chemical exposure and/or by exposure to radiation and/or heat, curing the impression material to produce a negative of the damage pattern, and using image analysis to determine the extent of the surface structures and/or the extent of the surface damage within the damage pattern on the basis of light-microscope pictures of the negative. Use of the method for the preparation, modification and/or development of new and/or existing materials.
    Type: Application
    Filed: July 26, 2004
    Publication date: September 20, 2007
    Applicant: BASF Coatings Aktiengesellschaft
    Inventors: Wilfried Stubbe, Holger Uphoff, Bernd Lodding, Petra Herrmann
  • Publication number: 20070166550
    Abstract: Autocatalyzed, thermally curable compositions free from external catalysts and comprising condensates of silanes which contain at least one of hydrolyzable atoms and hydrolyzable groups and processes for preparing them, and their use for producing thermally cured compositions.
    Type: Application
    Filed: April 23, 2004
    Publication date: July 19, 2007
    Applicant: BASF Coatings Aktiengesellschaft
    Inventors: Elke Westhoff, Manuela Niemeier, Wilfried Stubbe, Andreas Poppe
  • Publication number: 20050233147
    Abstract: Transparent coatings with a thickness of at least 30 ?m, a relative elastic resilience to DIN 55676 of at least 70%, and a scratch resistance corresponding to a score of not more than 2 in the steel wool scratch test to DIN 1041 after 10 double strokes; process for producing them, and their use.
    Type: Application
    Filed: July 5, 2003
    Publication date: October 20, 2005
    Inventors: Manuela Niemeier, Andreas Poppe, Wilfried Stubbe, Elke Westhoff, Jens-Dieter Fischer