Patents by Inventor Willem Karzijn

Willem Karzijn has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8530610
    Abstract: The invention relates to a process for preparing a polymer polyol, comprising mixing in a reactor vessel, a base polyol, one or more ethylenically unsaturated monomers, a polymerization initiator, optionally a macromer, and optionally a chain transfer agent, and polymerizing the mixture thus obtained at a temperature of 50 to 200° C., wherein after discharging the reactor vessel content, the interior surface of the reactor vessel walls and/or any internals present in the reactor vessel are blasted with round media.
    Type: Grant
    Filed: September 1, 2010
    Date of Patent: September 10, 2013
    Assignee: Shell Oil Company
    Inventors: Andre Buijs, Paulus Jacobus Fennis, Willem Karzijn, Nico Maria Venne
  • Publication number: 20130131205
    Abstract: The invention relates to a process for the preparation of a polymer polyol which is at most 60 wt. %, which process comprises mixing a base polyol, one or more ethylenically unsaturated monomers, a polymerization initiator, optionally a macromer, and optionally a chain transfer agent, and polymerizing the mixture thus obtained at a temperature of 50 to 200° C., optionally below 120 C, wherein the initiator is of formula R1—C(?O)—O—O—R2 (I) wherein R1 is an alkyl group and R2 is an alkyl group of formula —C(R3)(R4)—C(R5)(R6)(R7) (II) wherein R3 and R4 are the same or different and are an alkyl group, R5, R6 and R7 are the same or different and are a hydrogen atom or an alkyl group.
    Type: Application
    Filed: August 3, 2011
    Publication date: May 23, 2013
    Inventors: Paulus Jacobus Fennis, Martinus Johannes Maria Lelieveld, Willem Karzijn
  • Publication number: 20120184707
    Abstract: The invention relates to a process for preparing a polymer polyol, comprising mixing in a reactor vessel, a base polyol, one or more ethylenically unsaturated monomers, a polymerization initiator, optionally a macromer, and optionally a chain transfer agent, and polymerizing the mixture thus obtained at a temperature of 50 to 200° C., wherein after discharging the reactor vessel content, the interior surface of the reactor vessel walls and/or any internals present in the reactor vessel are blasted with round media.
    Type: Application
    Filed: September 1, 2010
    Publication date: July 19, 2012
    Applicant: Shell Internationale Research Maatschappij B.V.
    Inventors: Andre Buijs, Paulus Jacobus Fennis, Willem Karzijn, Nico Maria Venne
  • Patent number: 8198398
    Abstract: The invention relates to a process for removing fouling on a surface, wherein the surface is contacted with an aqueous solution of a guanidine of formula R1R2N—C(?NH)—NR3R4??(I) wherein R1, R2, R3 and R4 may be the same or different and each of R1, R2, R3 and R4 is hydrogen or hydrocarbyl.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: June 12, 2012
    Assignee: Shell Oil Company
    Inventors: Marco Antonius Denneman, Willem Karzijn
  • Patent number: 8017664
    Abstract: The invention relates to a process for the batch or semi-batch preparation of a polymer polyol, which process involves (1) preparing a seed by polymerizing in a base polyol at least one ethylenically unsaturated monomer in the presence of a polymerization initiator and macromer, and in the presence of from 0.5 to 50% wt of polymer polyol heel, based on amount of polymer present in the heel compared with total amount of polymer formed, (2) adding additional ethylenically unsaturated monomer to the seed obtained in step (1) and optionally additional polyol, and (3) polymerizing the mixture obtained in step (2).
    Type: Grant
    Filed: May 14, 2003
    Date of Patent: September 13, 2011
    Assignee: Shell Oil Company
    Inventors: Bob Heinis, Willem Karzijn, Martien Krijger, Martinus Johannes Maria Lelieveld
  • Publication number: 20030220410
    Abstract: The invention relates to a process for the batch or semi-batch preparation of a polymer polyol, which process involves (1) preparing a seed by polymerizing in a base polyol at least one ethylenically unsaturated monomer in the presence of a polymerization initiator and macromer, and in the presence of from 0.5 to 50 % wt of polymer polyol heel, based on amount of polymer present in heel compared with total amount of polymer present, (2) adding additional ethylenically unsaturated monomer to the seed obtained in step (1) and optionally additional polyol, and polymerizing the mixture obtained in step (2).
    Type: Application
    Filed: May 14, 2003
    Publication date: November 27, 2003
    Inventors: Bob Heinis, Willem Karzijn, Martien Krijger, Martinus Johannes Maria Lelieveld
  • Patent number: 6403667
    Abstract: Process for the preparation of a macramer suitable as a stabilizer precursor in a polymer polyol, which process comprises reacting a polyol with a cyclic dicarboxylic acid anhydride not containing any polymerizable double bond, and subsequently reacting the adduct thus obtained with an epoxide compound containing a polymerizable double bond. The macromers can be applied for the preparation of polymer polyols which are, in turn, very suitable for manufacturing flexible polyurethane foams.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: June 11, 2002
    Assignee: Shell Oil Company
    Inventors: Michiel Barend Eleveld, Willem Karzijn, Ronald Van Kempen
  • Patent number: 5300595
    Abstract: A thermosetting epoxy resin powder coating composition comprising:(a) an epoxy resin having at least one 1,2-epoxy group per molecule and(b) a physical blend of isocyanuric acid and 2-phenylimidazoline.
    Type: Grant
    Filed: June 3, 1992
    Date of Patent: April 5, 1994
    Assignee: Shell Oil Company
    Inventors: Christian J. C. De Cock, Marianne N. M. Godts, Willem Karzijn, Wouter W. Jongepier
  • Patent number: 5064913
    Abstract: An epoxy-based coating formulation includes a curing agent comprising oligomeric adducts of trimellitic anhydride and the glycidyl ester of pivalic acid. Such curing agents having a melting point of from 80 to 110.degree. C., making the epoxy-based formulation suitable for powder coating applications.
    Type: Grant
    Filed: February 21, 1991
    Date of Patent: November 12, 1991
    Assignee: Shell Oil Company
    Inventors: Petrus G. Kooijmans, Johannes M. Van Der Mark, Willem Karzijn
  • Patent number: 4769402
    Abstract: Aqueous solutions containing an epoxy resin in which epoxy groups have been replaced with a group M.sup.+ [--CH(OH)--CH.sub.2 --X--Ar--NH--C(O)--Q--C(O)--O].sup.- in which M is an alkali metal or onium ion, Q an organic bridging group having 2-3 carbon atoms in the bridge, Ar is arylene, X is S, O, NH, N-alkyl, SO.sub.2 NH or SO.sub.2 N-allyl, and preparation thereof by reacting an N-substituted imide with an epxoy resin and reacting the adduct thus formed with a base in the presence of water.
    Type: Grant
    Filed: May 11, 1987
    Date of Patent: September 6, 1988
    Assignee: Shell Oil Company
    Inventors: Willem Karzijn, Petrus G. Kooijmans