Abstract: An optical article includes an optical element, a low refractive index layer disposed on the optical element having an effective refractive index of 1.3 or less and a polymeric protective layer disposed on the low refractive index layer. The low refractive index layer includes a binder, a plurality of metal oxide particles dispersed in the binder, and a plurality of interconnected voids. The polymeric protective layer does not increase an effective refractive index of the optical article by greater than 10%.

Abstract: Light directing film is disclosed. The light directing film includes a first structured major surface and an opposing second major surface. The first structured major surface includes a plurality of unitary discrete structures. Each unitary discrete structure includes a light directing portion that is primarily for directing light and includes a plurality of first side facets. Each first side facet makes an angle with the plane of the light directing film in a range from about 35 degrees to about 55 degrees. Each light directing portion also includes a first base that is defined by the plurality of first side facets and has a first minimum dimension. Each light directing portion also has a first maximum height. Each unitary discrete structure also includes a bonding portion that is primarily for bonding the light directing film to a surface. The bonding portion is disposed on and between the plurality of first side facets and includes a plurality of second side facets.

Abstract: Optical stack is disclosed. The optical stack includes a first optical stack that includes, a first optical adhesive layer, and a reflective polarizer layer that is disposed on the first optical adhesive layer. The reflective polarizer layer substantially reflects light of a first polarization state and substantially transmits light of a second polarization state orthogonal to the first polarization state. The optical stack also includes a second optical stack that includes a second optical adhesive layer, a low index layer that is disposed on the second optical adhesive layer and includes a plurality of voids dispersed in a binder, and a light directing film that is disposed on the low index layer and includes a plurality of unitary discrete structures. Portions of each unitary discrete structure penetrate into the first optical adhesive layer. Portions of each unitary discrete structure do not penetrate into the first optical adhesive layer.

Abstract: Optical stack is disclosed. The optical stack includes a light redirecting film that includes a first structured major surface that includes a plurality of unitary discrete structures. The optical stack also includes an optical adhesive layer that is disposed on the light directing film. At least portions of at least some unitary discrete structures in the plurality of unitary discrete structures penetrate into the optical adhesive layer. At least portions of at least some unitary discrete structures in the plurality of unitary discrete structures do not penetrate into the optical adhesive layer. The peel strength of the light redirecting film and the optical adhesive layer is greater than about 30 grams/inch. The average effective transmission of the optical stack is not less or is less than by no more than about 10% as compared to an optical stack that has the same construction except that no unitary discrete structure penetrates into the optical adhesive layer.

Abstract: A process and apparatus for producing a gradient nanovoided article, a gradient nanovoided coating, and a gradient low refractive index coating is described. The process includes providing a first solution of a polymerizable material in a solvent, and providing a first environment proximate a first region of the coating and a different second environment proximate an adjacent region of the coating. The process further includes at least partially polymerizing the polymerizable material to form a composition that includes an insoluble polymer matrix and a second solution. The insoluble polymer matrix includes a plurality of nanovoids that are filled with the second solution, and a major portion of the solvent from the second solution is removed. A first volume fraction of the plurality of nanovoids proximate the first region of the coating is less than a second volume fraction of the plurality of nanovoids proximate an adjacent of the coating.

Abstract: A gradient optical film and an optical construction including the gradient optical film are described. The gradient optical film includes a binder, a plurality of particles, and a plurality of interconnected voids having a local volume fraction. The local volume fraction of the plurality of interconnected voids varies along a thickness direction of the gradient optical film. The refractive index of the gradient optical film can also varies along a thickness direction of the gradient optical film, as the refractive index can also depend upon the local volume fraction of the plurality of interconnected voids.

Abstract: A voided diffuser and an optical construction incorporating the voided diffuser are provided. The voided diffuser includes a plurality of beads and a binder composition in contact with the plurality of beads. The binder composition includes a binder and a plurality of interconnected voids. The optical construction includes the voided diffuser disposed on a substrate.