Abstract: A NOx control for an exhaust is provided. The NOx control includes a nickel compound and a NOx adsorber. Systems for treating an exhaust gas are also provided, including use of a non-thermal plasma reactor and a NOx control, and optionally a particulate trap.

Abstract: Disclosed herein are sensors, and method for making an using the same. In one embodiment, the sensor comprises: a first electrode disposed on a ceramic substrate, wherein the first electrode comprises an amorphous metal material comprising a first metal selected from the group consisting of a Group 9 metal, a Group 10 metal, a Group 11 metal, and combinations comprising at least one of the foregoing first metals, and zirconium or at least one of phosphorus and boron.

Abstract: A catalyst for treating an exhaust gas stream comprising a NOx occluding catalyst structure having an outer layer comprising an alkaline earth component and a rare earth component.

Abstract: In one embodiment, a method for forming the sensor comprises: disposing capacitance electrodes and a heater on green layers; disposing the layers such that the capacitance electrodes are disposed between adjacent green layers and the heater is disposed on a side of a green layer opposite one of the capacitance electrodes; disposing a gap insert in physical contact with the capacitance electrodes, wherein the gap insert has a higher sintering temperature than the green layers; sintering the green layers; and removing the gap insert.

Abstract: A gas treatment system and method for using the same is disclosed. The gas treatment system, comprises: a non-thermal plasma reactor; and a catalyst composition disposed within said non-thermal plasma reactor, said catalyst composition comprising a MZr4(PO4)6, wherein M is a metal selected from the group consisting of platinum, palladium, ruthenium, silver, rhodium, osmium, iridium, and combinations comprising at least one of said foregoing metals. The process comprises exposing said gas to a plasma field and to the catalyst composition.

Abstract: In one embodiment, a method for forming the sensor comprises: disposing capacitance electrodes and a heater on green layers; disposing the layers such that the capacitance electrodes are disposed between adjacent green layers and the heater is disposed on a side of a green layer opposite one of the capacitance electrodes; disposing a gap insert in physical contact with the capacitance electrodes, wherein the gap insert has a higher sintering temperature than the green layers; sintering the green layers; and removing the gap insert.

Abstract: Disclosed herein are sensors, and method for making an using the same. In one embodiment, the sensor comprises: a first electrode disposed on a ceramic substrate, wherein the first electrode comprises an amorphous metal material comprising a first metal selected from the group consisting of a Group 9 metal, a Group 10 metal, a Group 11 metal, and combinations comprising at least one of the foregoing first metals, and zirconium or at least one of phosphorus and boron.

Abstract: An exhaust system can comprise a NOx adsorber, a reformer disposed upstream of a NOx adsorber and in fluid communication with a fuel source, a first valve for controlling the introduction of the fluid to an exhaust conduit; and a particulate filter disposed upstream and in fluid communication with the NOx adsorber and downstream an in fluid communication with the reformer such that the first valve controls introduction of fluid to the exhaust conduit upstream of the particulate filter. The reformer can be designed to generate a fluid comprising sufficient thermal energy, hydrogen, and carbon monoxide. Optionally, the particulate filter can be designed to be regenerated by the thermal energy and to adsorb a sufficient amount of the thermal energy to reduce the temperature of a gas stream comprising the fluid from a first temperature of about 600° C. to about 1,000° C. to a second temperature of less than or equal to about 500° C.

Abstract: A method for manufacturing a planar sensor, comprises disposing a film of a material on a substrate, wherein the material is selected from the group consisting of platinum, rhodium, palladium and mixtures and alloys comprising at least one of the foregoing materials; annealing the material; measuring a resistance value of the material; laser trimming the annealed material; heat treating the laser trimmed material; and laser trimming the heat treated material to form the sensor.

Abstract: In one embodiment, a method of treating a gas stream comprises: controlling an amount of the NH3 entering a catalytic unit and converting NO2 and the NH3 to N2 in the catalytic unit, wherein greater than or equal to about 60 wt % of NOx initially in the gas stream is converted to N2. In one embodiment, a gas treatment system comprises: a plasma reactor disposed downstream of an engine; a cracking catalyst disposed downstream of the engine; and a catalytic unit capable of converting NO and HC to NH3, and capable of converting NH3 and NO2 to N2.

Abstract: A gas treatment device, comprises a substrate disposed within a shell. The substrate comprises a catalyst composition comprising a support, a catalyst, and a sufficient amount of SMSI material such that, upon exposure to a gas stream (at a gas treatment device operating temperature), less than or equal to about 35 wt % of hydrocarbons in the gas stream are burned. A method for forming a gas treatment device, comprises applying a slurry to a substrate, wherein the slurry comprises a support and a sufficient amount of SMSI material such that, upon exposure to a gas stream at a gas treatment device operating temperature, greater than or equal to about 50 wt % of hydrocarbons in the gas stream are cracked to a light fraction; applying a catalyst to the substrate; calcining the catalyst; and disposing the calcined substrate into a shell, with a retention material disposed between the shell and the calcined substrate.

Abstract: In one embodiment, a method of making a sensor comprises: forming a slurry comprising a metal oxide, a binder, an acetate, and a reducing material, applying the slurry to at least a portion of a sensing element comprising two electrodes with an electrolyte disposed therebetween, and calcining the slurry to form a protective coating. In one embodiment, a gas sensor, comprises: a sensing element comprising a sensing electrode and a reference electrode having an electrolyte disposed therebetween, and a protective coating disposed over the sensing electrode, wherein the protective coating comprises aluminum oxide, an alpha alumina and about 2 wt % to about 15 wt % solid solution, based upon the total weight of the protective coating.

Abstract: An air cleaner assembly includes an adsorber member disposed in a fluid passageway of the air cleaner assembly for eliminating pollutants from being discharged into the atmosphere contained within the air cleaner assembly. The adsorber member comprises a support and a silicate pollutant treating material free from zeolite disposed onto a surface of the support.

Abstract: A catalyst for preferentially reducing carbon monoxide in a hydrogen stream. The catalyst is formed from a chemical composition including a hexaaluminate, a metal hydroxide and a precious metal. The composition may be disposed on a support or may be extruded or cast into or onto a support. Incorporation of hexaaluminates allows inclusion of metal hydroxides that flux the active precious metal surface at higher temperatures than can aluminum oxide-based catalytic compositions, thereby enhancing resistance of the catalyst and monolithic support and increasing the durability and thermal range of the PROX catalyst. An additional advantage is that lesser amounts of precious metal oxides need be deposited onto the hexaaluminate, while retaining activity similar to aluminum oxide compositions.

Abstract: A gas treatment device, comprises a substrate disposed within a shell. The substrate comprises a catalyst composition comprising a support, a catalyst, and a sufficient amount of SMSI material such that, upon exposure to a gas stream (at a gas treatment device operating temperature), less than or equal to about 35 wt % of hydrocarbons in the gas stream are burned.

Abstract: Disclosed herein are various embodiments of systems (including vehicle systems and fuel cell systems), as well as reformers and methods for operating the systems. In one embodiment, the reformer comprises: a support comprising a reforming catalyst and a hexaaluminate comprising a crystal stabilizer disposed in a hexaaluminate crystal structure. Meanwhile, one embodiment of the system comprises: a device selected from the group consisting of an engine, a fuel cell, and combinations thereof, and the reformer.

Abstract: Gas treatment devices and vehicle exhaust systems are disclosed herein. In one embodiment, the vehicle exhaust system, comprises: an engine, a gas treatment device disposed downstream from the engine, the gas treatment device comprising a housing, a substrate disposed within the housing, the substrate comprising a catalyst and a hexaaluminate comprising a catalyst stabilizer disposed in a hexaaluminate crystal structure.

Abstract: Disclosed herein are methods for depositing catalytic material on a support, methods for making a gas treatment device, and the gas treatment devices formed therefrom. In one embodiment, the method for disposing a catalytic material on a support comprises: contacting the support with a catalytic material and a supercritical fluid, changing the supercritical fluid to a non-supercritical fluid, and depositing at least a portion of the catalytic material in pores of the support, wherein the catalytic material has a first solubility in the supercritical fluid of greater than or equal to about 70% and a second solubility in the non-supercritical fluid of less than or equal to about 20%. In one embodiment, the method for making the gas treatment device comprises disposing the supported catalytic material onto a substrate and disposing the substrate in a housing comprising an inlet for receiving gas and an outlet.

Abstract: An air cleaner assembly includes an adsorber member disposed in a fluid passageway of the air cleaner assembly for eliminating pollutants from being discharged into the atmosphere contained within the air cleaner assembly. The adsorber member comprises a support and a silicate pollutant treating material free from zeolite disposed onto a surface of the support.

Abstract: Disclosed herein is a gas sensor and a method of making a gas sensor comprising disposing a reference electrode on an inner surface of an electrolyte; sputtering a sensing electrode on an outer surface of the electrolyte; sputtering a zirconia layer on a side of the sensing electrode opposite the electrolyte, wherein the zirconia layer has a thickness of about 20 nanometers to about 1 micrometer, and disposing a protective layer on a side of the zirconia layer opposite the sensing electrode.