Abstract: Methods of making a porous cordierite ceramic honeycomb article are provided. In example methods, a batch composition includes a quantity of non-crosslinked pore former provided as a superaddition of about 20% or less of a dry weight of a quantity of inorganic components. Batch compositions are also provided that include a quantity of clay and other substantially nonfibrous inorganic components sufficient to yield an article including cordierite. Example batch compositions can include clay having a median particle size of about 7 ?m or less and/or provided in an amount that is 10% or less of the dry weight of the quantity of inorganic components.

Abstract: A method for providing a catalyst on a substrate is disclosed comprising providing a first washcoat comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material, contacting the first washcoat with a substrate to form a coated substrate, and then contacting the coated substrate with a second washcoat comprising an oxide or an oxide-supported catalyst to physisorb, chemisorb, bond, or otherwise adhere the oxide or the oxide-supported catalyst to the coated substrate. Also disclosed is a catalyst on a substrate comprising: a substrate; an anchor layer comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material; and a second layer comprising an oxide. The catalyst on a substrate can be in either green or fired form.

Abstract: An article having a flow-through substrate having open channels defined by porous walls, wherein the flow-through substrate includes alumina; and a CO2 sorbent disposed on the flow-through substrate, wherein the CO2 sorbent impregnates the porous walls of the flow-through substrate. Methods of making the article, its use for CO2 capture, and methods for regenerating the article for further use are also disclosed.

Abstract: Described herein is a substrate including a central longitudinal axis, a first support web, and a second support web. A sinuous web may be positioned between the first support web and the second support web. The sinuous web may include transverse web portions and bridging web portions, where the bridging web portions alternatively connect ends of adjacent transverse web portions. The sinuous web may be connected to the first support web by support legs extending between bridging web portions and a surface of the first support web. The sinuous web may be connected to the second support web by support legs extending between bridging web portions and a surface of the second support web. A support leg length to distance between transverse web portions ratio may be from about 1.0 to about 4.0.

Abstract: Disclosed herein are methods for bonding refractory substrates, such as zircon substrates, without the use of a bonding agent. Exemplary methods include (a) providing a plurality of refractory components, each component having at least one surface to be bonded, (b) polishing each surface to be bonded to a surface roughness (Ra) of 200 nm or finer, (c) contacting the surfaces to be bonded to form an unbonded refractory substrate, (d) firing the unbonded refractory substrate, and (e) subjecting the surfaces to be bonded to a compressive force during firing.

Abstract: A method for providing a catalyst on a substrate is disclosed comprising providing a first washcoat comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material, contacting the first washcoat with a substrate to form a coated substrate, and then contacting the coated substrate with a second washcoat comprising an oxide or an oxide-supported catalyst to physisorb, chemisorb, bond, or otherwise adhere the oxide or the oxide-supported catalyst to the coated substrate. Also disclosed is a catalyst on a substrate comprising: a substrate; an anchor layer comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material; and a second layer comprises an oxide or an oxide-supported catalyst. The catalyst on a substrate can be in either green or fired form.

Abstract: An article having a flow-through substrate having open channels defined by porous walls, wherein the flow-through substrate includes alumina; and a CO2 sorbent disposed on the flow-through substrate, wherein the CO2 sorbent impregnates the porous walls of the flow-through substrate. Methods of making the article, its use for CO2 capture, and methods for regenerating the article for further use are also disclosed.

Abstract: A method of coating a substrate with a catalytically active material using a polymer latex is disclosed. A slurry of catalytically active material and water is prepared, the catalytically active material containing activated carbon, and a binder is prepared that contains a polymer latex having a glass transition temperature of 10 C to 30 C. The slurry is combined with the binder to form a mixture, which can then be applied to the substrate to achieve a mixture loading of 20 to 30 weight percent on the substrate. The latex polymer binders can bind a catalytically active platinum on activated carbon powder to a cordierite honeycomb while not interfering with its catalytic activity, such as for hydrogenation.

Abstract: The present invention provides compositions and methods for producing porous ceramic articles. The compositions and methods comprise a ceramic precursor batch comprising an organic peroxide pore forming agent where the pore forming agent is an organo-adduct of hydrogen peroxide and an organic compound or an organic peroxide of the general formula R—O—O—R?. The organic peroxide pore forming agent is stable during extrusion and other methods for forming a green body and does not decompose until the green body is dried.

Abstract: Methods of making supported monolithic gold (Au) catalysts that can be used for generating a hydrogen-rich gas from gas mixtures containing carbon monoxide, hydrogen and water via a water gas shift reaction, and for the removal of carbon monoxide from air at a low reaction temperature via its oxidation reaction are described. Methods of making highly dispersed gold catalysts on washcoated monoliths and the stabilization of monolithic catalyst supports by the addition of a third metal oxide, such as zirconia (ZrO2), lanthanum oxide (La2O3), or manganese oxide (MnxOy). The catalyst supports and/or washcoats may include a variety of transition metal oxides such as alpha iron oxide (?-Fe2O3), cerium oxide (CeO2), ZrO2, gamma alumina (?-Al2O3), or their combinations.

Abstract: A process for making large zircon blocks by bonding multiple zircon components, and bonding materials for use in such process. The invention enables the manufacture of large zircon blocks without the need of larger-size isopressing equipment. The invention is particularly useful in making large-size isopipes for use in a fusion down-draw process in making glass sheets for use in, e.g., LCD production.

Abstract: A composition is disclosed comprising a fine zircon component having a median particle size of less than 5 ?m, a medium zircon component having a median particle size of from 5 ?m to 15 ?m, and a sintering aid, wherein the composition, after firing, has a strain rate of less than about 1×10?6/hr. A method for making a green body comprising contacting a fine zircon component having a median particle size of less than 5 ?m, a medium zircon component having a median particle size of from 5 ?m to 15 ?m, and a sintering aid, and then forming the mixture into a desired shape is disclosed.

Abstract: A zircon composition having a multi-modal particle size distribution is disclosed. The multi-modal zircon composition comprises greater than about 40 parts by weight of a coarse zircon component having a median particle size of from greater than about 3 ?m to about 25 ?m, and less than about 60 parts by weight of a fine zircon component having a median particle size of 3 ?m or less. Methods for manufacturing a green body and a fired refractory ceramic body comprising the multi-modal zircon composition are also disclosed.

Abstract: A cordierite batch composition that includes a hydratable alumina, as defined herein. The hydratable alumina, when hydrated, can provide additional strength to shaped batch compositions at temperatures below those used to fire the compositions. Methods are also provided for forming cordierite ceramic articles from the cordierite batch compositions.

Abstract: A composition is disclosed comprising a fine zircon component having a median particle size of less than 5 ?m, a medium zircon component having a median particle size of from 5 ?m to 15 ?m, and a sintering aid, wherein the composition, after firing, has a strain rate of less than about 1×10?6 /hr. A method for making a green body comprising contacting a fine zircon component having a median particle size of less than 5 ?m, a medium zircon component having a median particle size of from 5 ?m to 15 ?m, and a sintering aid, and then forming the mixture into a desired shape is disclosed.

Abstract: A composition is disclosed comprising a fine zircon component having a median particle size of less than 5 ?m, a medium zircon component having a median particle size of from 5 ?m to 15 ?m, and a sintering aid, wherein the composition, after firing, has a strain rate of less than about 1×10?6/hr. A method for making a green body comprising contacting a fine zircon component having a median particle size of less than 5 ?m, a medium zircon component having a median particle size of from 5 ?m to 15 ?m, and a sintering aid, and then forming the mixture into a desired shape is disclosed.

Abstract: A composition is disclosed comprising a fine zircon component having a median particle size of less than 5 ?m, a medium zircon component having a median particle size of from 5 ?m to 15 ?m, and a sintering aid, wherein the composition, after firing, has a strain rate of less than about 1×10?6/hr. A method for making a green body comprising contacting a fine zircon component having a median particle size of less than 5 ?m, a medium zircon component having a median particle size of from 5 ?m to 15 ?m, and a sintering aid, and then forming the mixture into a desired shape is disclosed.

Abstract: Free-standing ordered mesoporous carbon films and form factors are prepared by depositing an aqueous precursor mixture that includes a water soluble carbon precursor, a non-ionic surfactant, and an oil onto a substrate or scaffold, drying the precursor mixture, and then cross-linking and heat treating (carbonizing) the carbon precursor. After carbonization, the ordered mesoporous carbon films and form factors include discrete domains of ordered, mesoscale pores.

Abstract: The present invention provides compositions and methods for producing porous ceramic articles. The compositions and methods comprise a ceramic precursor batch comprising an organic peroxide pore forming agent where the pore forming agent is an organo-adduct of hydrogen peroxide and an organic compound or an organic peroxide of the general formula R—O—O—R?. The organic peroxide pore forming agent is stable during extrusion and other methods for forming a green body and does not decompose until the green body is dried.

Abstract: Methods of making a porous cordierite ceramic honeycomb article are provided. In example methods, a batch composition includes a quantity of non-crosslinked pore former provided as a superaddition of about 20% or less of a dry weight of a quantity of inorganic components. Batch compositions are also provided that include a quantity of clay and other substantially nonfibrous inorganic components sufficient to yield an article including cordierite. Example batch compositions can include clay having a median particle size of about 7 ?m or less and/or provided in an amount that is 10% or less of the dry weight of the quantity of inorganic components.