Patents by Inventor William W. Merrill

William W. Merrill has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11787929
    Abstract: A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25° C.; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.
    Type: Grant
    Filed: January 7, 2022
    Date of Patent: October 17, 2023
    Assignee: 3M Innovative Properties Company
    Inventors: Ning Zhou, Robert S. Clough, Derek J. Dehn, Jeffrey P. Kalish, William W. Merrill, Kevin M. Lewandowski, Jayant Chakravarty
  • Publication number: 20230219274
    Abstract: A sensing system for measurement of a multilayered blown polymeric film. A feedblock supplies polymeric material streams to an annular blown film die to form a plurality of layers of different polymeric materials. A sensing system is positioned adjacent to a film bubble extruded from the blown film die, wherein the blown film bubble includes annular layers of at least two different polymeric materials. The sensing system emits a signal toward selected circumferential positions around the film bubble and receives a plurality of reflected signals at each circumferential position. Each reflected signal in the plurality of reflected signals is generated at an interface between annular layers that includes a refractive index change detectable by the sensing system. A processor processes the reflected signals from the sensing system, and for each circumferential position determines a layer thickness profile for each polymeric material in the film.
    Type: Application
    Filed: June 9, 2021
    Publication date: July 13, 2023
    Inventors: William W. Merrill, Pradeep P. Bhat, Francis T. Caruso, David L. Hofeldt, David D. Nguyen, Ziang Li
  • Publication number: 20220127444
    Abstract: A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25° C.; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.
    Type: Application
    Filed: January 7, 2022
    Publication date: April 28, 2022
    Inventors: Ning Zhou, Robert S. Clough, Derek J. Dehn, Jeffrey P. Kalish, William W. Merrill, Kevin M. Lewandowski, Jayant Chakravarty
  • Patent number: 11286405
    Abstract: A method of making an adhesive article is described comprising melt extruding a core film layer comprising a composition comprising at least 50% of a polylactic acid polymer. The method further comprises melt extruding an adhesive layer on a major surface of the core film layer such that regions of interdiffusion are present between the core film layer and adhesive layer. The adhesive layer may comprise C1-C10 (meth)acrylic acid or ester thereof, vinyl acetate, ethylene vinyl acetate, hydrolysed polyvinyl alcohol and combinations thereof. The adhesive layer may also be a pressure sensitive adhesive. The method further comprises melt extruding a release film layer on an opposing major surface of the core film layer. The layers are sequentially extruded or co-extruded and can be uniaxially or biaxially oriented.
    Type: Grant
    Filed: December 1, 2017
    Date of Patent: March 29, 2022
    Assignee: 3M Innovative Properties Company
    Inventors: William W. Merrill, Jeffrey P. Kalish, Jacob D. Young, Ramesh C. Kumar, Sonja S. Mackey, Kanta Kumar, Ignatius A. Kadoma, Michael D. Crandall, Adam R. Wohl
  • Patent number: 11254812
    Abstract: A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25° C.; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.
    Type: Grant
    Filed: January 21, 2020
    Date of Patent: February 22, 2022
    Assignee: 3M Innovative Properties Company
    Inventors: Ning Zhou, Robert S. Clough, Derek J. Dehn, Jeffrey P. Kalish, William W. Merrill, Kevin M. Lewandowski, Jayant Chakravarty
  • Patent number: 11066551
    Abstract: In one embodiment, a film is described comprising a mixture of semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) midpoint as measured by differential scanning calorimetry of at least 25° C.; and plasticizer; wherein the film is oriented. In another embodiment, a film is described comprising a mixture comprising semicrystalline polylactic acid polymer, polymer having a midpoint Tg as measured by differential scanning calorimetry of at least 25° C., and plasticizer; wherein the mixture exhibits a single midpoint Tg and the single midpoint Tg ranges from 40° C. to 65° C.; and wherein the film is oriented and the oriented film exhibits a higher midpoint Tg ranging from 40° C. to 65° C. and a lower midpoint Tg ranging from 5 to 25° C.
    Type: Grant
    Filed: May 4, 2017
    Date of Patent: July 20, 2021
    Assignee: 3M Innovative Properties Company
    Inventors: William W. Merrill, Jeffrey P. Kalish, Pamela A. Percha, Derek J. Dehn, Bradley L. Givot, Ignatius A. Kadoma
  • Publication number: 20210113859
    Abstract: Various embodiments of a respirator that includes a harness, a mask body, and an exhalation valve are disclosed. The exhalation valve can include a valve seat and a flexible flap that is in engagement with the valve seat. The flexible flap can have one or more materials that can cause the flap to flash when moving from a closed position to an open position or vice versa. The flashing valve can make it easier for a user to ascertain whether the valve is operating properly.
    Type: Application
    Filed: December 29, 2020
    Publication date: April 22, 2021
    Inventors: Philip G. Martin, Caroline M. Ylitalo, Gina M. Buccellato, James M. Jonza, William W. Merrill, Douglas S. Dunn, David T. Yust
  • Patent number: 10913199
    Abstract: A stretcher for processing a film is described. In particular, stretcher receives a film, graps edge portions of the film, conveys the film in a machine direction, and moves the opposing edge portions along diverging; substantially parabolic paths to form a stretched film.
    Type: Grant
    Filed: April 18, 2016
    Date of Patent: February 9, 2021
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: William W. Merrill, Jeffery N. Jackson, Andrew T. Ruff, John A. Wheatley, Dennis L. Krueger
  • Patent number: 10895673
    Abstract: A dispersion, a resin containing the dispersion and polymer film formed from the resin are disclosed. The dispersion includes an infrared light absorbing pigment including organo-metallic particles being less than 1.5 micrometer or less than one micrometer in size. The dispersion also includes a dispersant including phosphorus and a polyol.
    Type: Grant
    Filed: February 2, 2018
    Date of Patent: January 19, 2021
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: William W. Merrill, David T. Yust, Patrick M. Crain, Neeraj Sharma, Jung-Sheng Wu
  • Publication number: 20200157336
    Abstract: A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25° C.; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.
    Type: Application
    Filed: January 21, 2020
    Publication date: May 21, 2020
    Inventors: Ning Zhou, Robert S. Clough, Derek J. Dehn, Jeffrey P. Kalish, William W. Merrill, Kevin M. Lewandowski, Jayant Chakravarty
  • Publication number: 20200109314
    Abstract: A method of making an adhesive article is described comprising melt extruding a core film layer comprising a comport comprising at least 50% of a polylactic acid polymer. The method further comprises melt extruding an adhesive layer on a major surface of the core film layer such that regions of interdiffusion are present between the core film layer and adhesive layer. The adhesive layer may comprise C1-C10 (meth)acrylic acid or ester thereof, vinyl acetate, ethylene vinyl acetate, hydrolysed polyvinyl alcohol and combinations thereof. The adhesive layer may also be a pressure sensitive adhesive. The method further comprises melt extruding a release film layer on an opposing major surface of the core film layer. The layers are sequentially extruded or co-extruded and can be uniaxially or biaxially oriented. Articles comprising a core film layer comprising a composition comprising at least 50% of a polylactic acid polymer and an adhesive layer disposed on a major surface of the core layer are also described.
    Type: Application
    Filed: December 1, 2017
    Publication date: April 9, 2020
    Inventors: William W. Merrill, Jeffrey P. Kalish, Jacob D. Young, Ramesh C. Kumar, Sonja S. Mackey, Kanta Kumar, Ignatius A. Kadoma, Michael D. Crandall, Adam R. Wohl
  • Patent number: 10577494
    Abstract: A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25 C; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.
    Type: Grant
    Filed: December 14, 2015
    Date of Patent: March 3, 2020
    Assignee: 3M Innovative Properties Company
    Inventors: Ning Zhou, Robert S. Clough, Derek J. Dehn, Jeffrey P. Kalish, William W. Merrill, Kevin M. Lewandowski, Jayant Chakravarty
  • Patent number: 10495801
    Abstract: A multilayer optical film has a packet of microlayers that selectively reflect light by constructive or destructive interference to provide a first reflective characteristic. At least some of the microlayers are birefringent. A stabilizing layer attaches to and covers the microlayer packet proximate an outer exposed surface of the film. Heating element(s) can physically contact the film to deliver heat to the packet through the stabilizing layer by thermal conduction, at altered region(s) of the film, such that the first reflective characteristic changes to an altered reflective characteristic in the altered region(s) to pattern the film. The stabilizing layer provides sufficient heat conduction to allow heat from the heating elements to change (e.g.
    Type: Grant
    Filed: March 8, 2019
    Date of Patent: December 3, 2019
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Michael Benton Free, Martin B. Wolk, Rolf W. Biernath, Stephen A. Johnson, William W. Merrill, William F. Edmonds, Claire A. Jalbert
  • Publication number: 20190315046
    Abstract: A method of making an optical film includes providing a film, substantially uniaxially orienting the film, and heat setting the oriented film. The film includes a polymeric material capable of developing birefringence.
    Type: Application
    Filed: June 27, 2019
    Publication date: October 17, 2019
    Inventors: William W. Merrill, Timothy J. Hebrink
  • Publication number: 20190284357
    Abstract: Compositions and films are described comprising a polylactic (PLA) polymer and a copolymer comprising a first moiety comprising a C12-C30 alkyl group and a second moiety that is miscible in the composition. Suitable first moieties include a C12-C30 alkyl (meth)acrylate or a polyvinyl alcohol comprising pendent C12-C30 alkyl groups. Suitable second moieties include C1-C10 (meth)acrylic acid or ester thereof, vinyl acetate and ethylene vinyl acetate. The aforementioned composition may be used to form a release layer of an adhesive article such as a pressure sensitive adhesive tape. The films may be a monolithic film or a film layer of a multilayer film. The release layer may be disposed upon a substrate layer that may also comprise PLA. The films are produced by melt extrusion of the aforementioned composition and may be oriented.
    Type: Application
    Filed: November 29, 2017
    Publication date: September 19, 2019
    Inventors: William W. Merrill, Jeffrey P. Kalish, Jacob D. Young, Ramesh C. Kumar, Sonja S. Mackey, Kanta Kumar, Adam R. Wohl, David J. Kinning, Michael D. Crandall, Ignatius A. Kadoma
  • Patent number: 10350818
    Abstract: A method of making an optical film includes providing a film, substantially uniaxially orienting the film, and heat setting the oriented film. The film includes a polymeric material capable of developing birefringence.
    Type: Grant
    Filed: April 9, 2015
    Date of Patent: July 16, 2019
    Assignee: 3M Innovative Properties Company
    Inventors: William W. Merrill, Timothy J. Hebrink
  • Publication number: 20190204493
    Abstract: A multilayer optical film has a packet of microlayers that selectively reflect light by constructive or destructive interference to provide a first reflective characteristic. At least some of the microlayers are birefringent. A stabilizing layer attaches to and covers the microlayer packet proximate an outer exposed surface of the film. Heating element(s) can physically contact the film to deliver heat to the packet through the stabilizing layer by thermal conduction, at altered region(s) of the film, such that the first reflective characteristic changes to an altered reflective characteristic in the altered region(s) to pattern the film. The stabilizing layer provides sufficient heat conduction to allow heat from the heating elements to change (e.g.
    Type: Application
    Filed: March 8, 2019
    Publication date: July 4, 2019
    Inventors: Michael Benton Free, Martin B. Wolk, Rolf W. Biernath, Stephen A. Johnson, William W. Merrill, William F. Edmonds, Claire A. Jalbert
  • Publication number: 20190136045
    Abstract: In one embodiment, a film is described comprising a mixture of semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) midpoint as measured by differential scanning calorimetry of at least 25° C.; and plasticizer; wherein the film is oriented. In another embodiment, a film is described comprising a mixture comprising semicrystalline polylactic acid polymer, polymer having a midpoint Tg as measured by differential scanning calorimetry of at least 25° C., and plasticizer; wherein the mixture exhibits a single midpoint Tg and the single midpoint Tg ranges from 40° C. to 65° C.; and wherein the film is oriented and the oriented film exhibits a higher midpoint Tg ranging from 40° C. to 65° C. and a lower midpoint Tg ranging from 5 to 25° C.
    Type: Application
    Filed: May 4, 2017
    Publication date: May 9, 2019
    Inventors: William W. Merrill, Jeffrey P. Kalish, Pamela A. Percha, Derek J. Dehn, Bradley L. Givot, Ignatius A. Kadoma
  • Patent number: 10254460
    Abstract: A multilayer optical film has a packet of microlayers that selectively reflect light by constructive or destructive interference to provide a first reflective characteristic. At least some of the microlayers are birefringent. A stabilizing layer attaches to and covers the microlayer packet proximate an outer exposed surface of the film. Heating element(s) can physically contact the film to deliver heat to the packet through the stabilizing layer by thermal conduction, at altered region(s) of the film, such that the first reflective characteristic changes to an altered reflective characteristic in the altered region(s) to pattern the film. The stabilizing layer provides sufficient heat conduction to allow heat from the heating elements to change (e.g.
    Type: Grant
    Filed: July 9, 2018
    Date of Patent: April 9, 2019
    Assignee: 3M Innovative Properties Company
    Inventors: Michael Benton Free, Martin B. Wolk, Rolf W. Biernath, Stephen A. Johnson, William W. Merrill, William F. Edmonds, Claire A. Jalbert
  • Publication number: 20180313992
    Abstract: A multilayer optical film has a packet of microlayers that selectively reflect light by constructive or destructive interference to provide a first reflective characteristic. At least some of the microlayers are birefringent. A stabilizing layer attaches to and covers the microlayer packet proximate an outer exposed surface of the film. Heating element(s) can physically contact the film to deliver heat to the packet through the stabilizing layer by thermal conduction, at altered region(s) of the film, such that the first reflective characteristic changes to an altered reflective characteristic in the altered region(s) to pattern the film. The stabilizing layer provides sufficient heat conduction to allow heat from the heating elements to change (e.g.
    Type: Application
    Filed: July 9, 2018
    Publication date: November 1, 2018
    Inventors: Michael Benton Free, Martin B. Wolk, Rolf W. Biernath, Stephen A. Johnson, William W. Merrill, William F. Edmonds, Claire A. Jalbert