Patents by Inventor Wolfgang Grabarse

Wolfgang Grabarse has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11912950
    Abstract: The invention relates to the use of quaternized nitrogen compounds as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems; the invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.
    Type: Grant
    Filed: August 4, 2021
    Date of Patent: February 27, 2024
    Assignee: BASF SE
    Inventors: Markus Hansch, Harald Boehnke, Wolfgang Grabarse, Ludwig Voelkel, Maxim Peretolchin
  • Patent number: 11879108
    Abstract: The present invention relates to a middle-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer mix comprising the ethylene and the acrylate is polymerized at a pressure of 50 to 400 bar and in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to a liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.
    Type: Grant
    Filed: March 23, 2020
    Date of Patent: January 23, 2024
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Wolfgang Grabarse, Jan Strittmatter, Rene Koschabek, Robert Rupaner
  • Publication number: 20230406968
    Abstract: A process for the preparation of polyisobutene derivatives involves bringing an oxygen-containing gas in contact with polyisobutene, in the presence of a photosensitizer, and irradiating the reaction mixture. The polyisobutene derivatives are useful, for example, in hydrocarbon mixtures or hydrocarbon-containing oils.
    Type: Application
    Filed: November 9, 2021
    Publication date: December 21, 2023
    Applicant: BASF SE
    Inventors: Bernd Schaefer, Klaus Muehlbach, Paul Lederhose, Wolfgang Grabarse, Andreas Minke, Thorsten Schoeppe
  • Patent number: 11667864
    Abstract: Lubricants with a terpolymer made of diester, olefin and acrylate The invention relates to a lubricant comprising a terpolymer which comprises in polymerized forma diester selected from di(C4-C22 alkyl)ester of maleic acid, fumaric acid, 2-methylmaleic acid, 2,3-dimethylmaleic acid, 2-methylfumaric acid, 2,3-dimethylfumaric acid, or mixtures thereof, an olefin selected from C6-C40 alky-1-ene, and an acrylate selected from C4-C40 alkyl (meth)acrylate. The invention further relates to the terpolymer, a process for preparing the terpolymer comprising the step of polymerizing the diester, the olefin, and the acrylate; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the terpolymer.
    Type: Grant
    Filed: October 8, 2019
    Date of Patent: June 6, 2023
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Wolfgang Grabarse, Jan Strittmatter, Markus Scherer, Karolin Monz, Rene Koschabek
  • Patent number: 11634654
    Abstract: An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems; for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.
    Type: Grant
    Filed: March 25, 2021
    Date of Patent: April 25, 2023
    Assignee: BASF SE
    Inventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
  • Patent number: 11608393
    Abstract: The present invention relates to a continuous high-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized for methylene; and a reactive acrylate which is selected from hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, and hydroxybutyl (meth)acrylate, where a monomer feed comprising the ethylene and the reactive acrylate is polymerized in the presence of at least 2 wt % of a chain transfer agent. The present invention also relates to the liquid ethylene copolymer, to a coating material comprising the liquid ethylene copolymer and to a use of the liquid ethylene copolymer to produce a coating material.
    Type: Grant
    Filed: July 17, 2019
    Date of Patent: March 21, 2023
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Wolfgang Grabarse, Werner-Alfons Jung
  • Patent number: 11498986
    Abstract: The present invention relates to a continuous high-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer feed comprising the ethylene and the acrylate is polymerized in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to the liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.
    Type: Grant
    Filed: March 14, 2019
    Date of Patent: November 15, 2022
    Assignee: BASF SE
    Inventors: Martin Wendker, Ivette Garcia Castro, Jan Strittmatter, Karolin Geyer, Wolfgang Grabarse, Markus Scherer, Rene Koschabek
  • Patent number: 11453836
    Abstract: The present invention relates to a lubricant comprising a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate. It further relates to the liquid ethylene copolymer; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.
    Type: Grant
    Filed: March 14, 2019
    Date of Patent: September 27, 2022
    Assignee: BASF SE
    Inventors: Martin Wendker, Ivette Garcia Castro, Jan Strittmatter, Karolin Geyer, Wolfgang Grabarse, Markus Scherer, Rene Koschabek
  • Publication number: 20220177799
    Abstract: The present invention relates to a middle-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer mix comprising the ethylene and the acrylate is polymerized at a pressure of 50 to 400 bar and in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to a liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.
    Type: Application
    Filed: March 23, 2020
    Publication date: June 9, 2022
    Inventors: Ivette GARCIA CASTRO, Wolfgang GRABARSE, Jan STRITTMATTER, Rene KOSCHABEK, Robert RUPANER
  • Patent number: 11214752
    Abstract: The present invention is directed to the use of poly(polyisobutylenemethacrylate) as viscosity index improving component in lubricating oil compositions. The invention is further related to lubricating oil compositions comprising poly(polyisobutylenemethacrylate) with enhanced shear stability.
    Type: Grant
    Filed: July 19, 2018
    Date of Patent: January 4, 2022
    Assignee: BASF SE
    Inventors: Szilard Csihony, Anja Thomas, Kevin J. Desantis, Philippe Rabbat, Andrea Misske, Johannes Barth, Meik Ranft, Peter Mueller, Wolfgang Grabarse, Christoph Fleckenstein
  • Publication number: 20210363451
    Abstract: The invention relates to the use of quaternized nitrogen compounds as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems; the invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.
    Type: Application
    Filed: August 4, 2021
    Publication date: November 25, 2021
    Applicant: BASF SE
    Inventors: Markus Hansch, Harald Boehnke, Wolfgang Grabarse, Ludwig Voelkel, Maxim Peretolchin
  • Publication number: 20210348079
    Abstract: Lubricants with a terpolymer made of diester, olefin and acrylate The invention relates to a lubricant comprising a terpolymer which comprises in polymerized forma diester selected from di(C4-C22 alkyl)ester of maleic acid, fumaric acid, 2-methylmaleic acid, 2,3-dimethylmaleic acid, 2-methylfumaric acid, 2,3-dimethylfumaric acid, or mixtures thereof, an olefin selected from C6-C40 alky-1-ene, and an acrylate selected from C4-C40 alkyl (meth)acrylate. The invention further relates to the terpolymer, a process for preparing the terpolymer comprising the step of polymerizing the diester, the olefin, and the acrylate; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the terpolymer.
    Type: Application
    Filed: October 8, 2019
    Publication date: November 11, 2021
    Inventors: Ivette GARCIA CASTRO, Wolfgang GRABARSE, Jan STRITTMATTER, Markus SCHERER, Karolin MONZ, Rene KOSCHABEK
  • Patent number: 11168273
    Abstract: The present invention relates to the use of an olefin-carboxylic acid copolymer, wherein the copolymer comprises at least one free carboxylic acid side group, or of a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, wherein the copolymer comprises at least one free carboxylic acid side group, as a fuel additive or lubricant additive; to processes for preparing additives of this kind, and to fuels and lubricants additized therewith; such as, more particularly, as a detergent additive; for reduction or prevention of deposits in the injection systems of direct injection diesel engines, especially in common rail injection systems, for reduction of the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operation
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: November 9, 2021
    Assignee: BASF SE
    Inventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
  • Publication number: 20210301047
    Abstract: The present invention relates to a continuous high-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized for methylene; and a reactive acrylate which is selected from hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, and hydroxybutyl (meth)acrylate, where a monomer feed comprising the ethylene and the reactive acrylate is polymerized in the presence of at least 2 wt % of a chain transfer agent. The present invention also relates to the liquid ethylene copolymer, to a coating material comprising the liquid ethylene copolymer and to a use of the liquid ethylene copolymer to produce a coating material.
    Type: Application
    Filed: July 17, 2019
    Publication date: September 30, 2021
    Inventors: Ivette Garcia Castro, Wolfgang Grabarse, Werner-Alfons Jung
  • Patent number: 11111449
    Abstract: The invention relates to the use of quaternized nitrogen compounds as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems; the invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.
    Type: Grant
    Filed: April 28, 2020
    Date of Patent: September 7, 2021
    Assignee: BASF SE
    Inventors: Markus Hansch, Harald Boehnke, Wolfgang Grabarse, Ludwig Voelkel, Maxim Peretolchin
  • Publication number: 20210246395
    Abstract: The present invention relates to a lubricant comprising a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate. It further relates to the liquid ethylene copolymer; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.
    Type: Application
    Filed: March 14, 2019
    Publication date: August 12, 2021
    Inventors: Martin WENDKER, Ivette GARCIA CASTRO, Jan STRITTMATTER, Karolin GEYER, Wolfgang GRABARSE, Markus SCHERER, Rene KOSCHABEK
  • Publication number: 20210222080
    Abstract: An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems; for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.
    Type: Application
    Filed: March 25, 2021
    Publication date: July 22, 2021
    Applicant: BASF SE
    Inventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
  • Publication number: 20210214635
    Abstract: An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems: for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.
    Type: Application
    Filed: March 25, 2021
    Publication date: July 15, 2021
    Applicant: BASF SE
    Inventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
  • Publication number: 20210198590
    Abstract: A lubricant comprising 2,5-(bishydroxymethyl) tetryhydrofuran dialkanoates This invention relates to a lubricant comprising a THF ester of the formula (I) as defined below. This invention further relates to a use of the THF ester as lubricant; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the THF ester.
    Type: Application
    Filed: May 13, 2019
    Publication date: July 1, 2021
    Inventors: Martin Alexander BOHN, Karolin GEYER, Wolfgang GRABARSE, Markus SCHERER, Muriel ECORMIER, Jan STRITTMATTER
  • Publication number: 20210147759
    Abstract: The present invention is directed to the use of poly(polyisobutylenemethacrylate) as viscosity index improving component in lubricating oil compositions. The invention is further related to lubricating oil compositions comprising poly(polyisobutylenemethacrylate) with enhanced shear stability.
    Type: Application
    Filed: July 19, 2018
    Publication date: May 20, 2021
    Inventors: Szilard CSIHONY, Anja THOMAS, Kevin J. DESANTIS, Philippe RABBAT, Andrea MISSKE, Johannes BARTH, Meik RANFT, Peter MUELLER, Wolfgang GRABARSE, Christoph FLECKENSTEIN