Abstract: The present invention relates to the field of petroleum industry phase oilfield chemistry, and specifically relates to a bionic and dual-phobic drilling fluid. The drilling fluid contains a bionic wall-fixing agent, a bionic lubricant, a super dual-phobic agent, a scrap-carrying agent and a bionic shale inhibitor. The present invention uses the theory of bionics and the theory of a downhole rock surface being double phobic as a basis. By means of using the bionic wall-fixing agent, the bionic lubricant, the super dual-phobic agent, the scrap-carrying agent and the bionic shale inhibitor, which have special properties of imitating animals and plants in nature, and using a series of bionic treatment agents, a set of bionic and dual-phobic drilling fluid systems, which corresponds to an unconventional, complex oil and gas well, is formed.

Abstract: The present invention relates to the field of petroleum industry phase oilfield chemistry, and specifically relates to a bionic and dual-phobic drilling fluid. The drilling fluid contains a bionic wall-fixing agent, a bionic lubricant, a super dual-phobic agent, a scrap-carrying agent and a bionic shale inhibitor. The present invention uses the theory of bionics and the theory of a downhole rock surface being double phobic as a basis. By means of using the bionic wall-fixing agent, the bionic lubricant, the super dual-phobic agent, the scrap-carrying agent and the bionic shale inhibitor, which have special properties of imitating animals and plants in nature, and using a series of bionic treatment agents, a set of bionic and dual-phobic drilling fluid systems, which corresponds to an unconventional, complex oil and gas well, is formed.

Abstract: The present disclosure relates to the technical field of oil and gas drilling, and particularly relates to a modified silicon dioxide material of a fluorocarbon active agent type super-amphiphobic cutting-carrying agent suitable for a water-based drilling fluid, and a preparation method thereof. The preparation method of the modified silicon dioxide material comprises the following steps: subjecting silicon dioxide and a silane coupling agent represented by Formula (1) to a first contact reaction in a mixed solvent containing alcohol and water; subjecting the product of the first contact reaction, the compound represented by Formula (2) and the compound represented by Formula (3) to a second contact reaction; subjecting the product of the second contact reaction and the compound represented by Formula (4) to a third contact reaction. The modified silicon dioxide material can be used as a cutting-carrying agent in a water-based drilling fluid and produce an excellent cutting-carrying effect.

Abstract: The invention relates to the field of petroleum drilling fluids, and discloses a super-amphiphobic strongly self-cleaning high-performance water-based drilling fluid comprising polymeric super-amphiphobic agent and a drilling method. The polymeric super-amphiphobic agent comprises structural units A derived from acrylamide, structural units B derived from methyl methacrylate, structural units C derived from butyl acrylate, structural units D derived from a compound represented by the following formula (1), structural units E derived from a silane coupler, and nano-titania; wherein the nano-titania is bonded to the polymeric super-amphiphobic agent via the structural unit E, and the silane coupler is a silane coupler having double bonds; R is a C3-C8 perfluoroalkyl group. A water-based drilling fluid additive prepared from the polymeric super-amphiphobic agent in the present invention has excellent wettability, inhibition, lubrication, reservoir protection, and rheology and fluid loss properties.

Abstract: The present invention relates to the well drilling field in petrochemical industry, in particular to use of dual-cation fluorocarbon surfactant as amphiphobic wettability reversal agent in drilling fluid. The dual-cation fluorocarbon surfactant is a dual-cation fluorocarbon surfactant of which the cation part is represented by the following formula (1). The dual-cation fluorocarbon surfactant of the present invention can serve as wettability reversal agent when it is used for oil-gas drilling to enable rock amphiphobic, and is an amphiphobic wettability reversal agent which can cause rock surface to be non-hydrophilic and non-lipophilic. Using of dual-cation fluorocarbon surfactant, especially when drilling highly hydrous mud shale, can avoid permeation of water and oil into the rock effectively and thereby a capillary phenomenon can be prevented, and an effect of stabilizing the well wall and protecting the reservoir is attained.

Abstract: A super-amphiphobic composite material and use of the same as an inhibitor, lubricant, reservoir protectant, and accelerator in water-based drilling fluids. A method for preparing the amphiphobic composite material includes: performing a first mixing of nano-titanium dioxide and nano-silicon dioxide in an alcohol-water mixed solvent under an alkaline condition, to obtain a dispersion of nano-titanium dioxide and nano-silicon dioxide; then introducing a fluorosilicone-containing coupler into the dispersion of nano-titanium dioxide and nano-silicon dioxide and performing a second mixing. The amphiphobic composite material may be applied in water-based drilling fluids. It has an effect of strongly inhibiting hydrated swelling and disintegration, low toxicity and high compatibility; can solve problems such as well wall instability, blockage of drilling tools, and reservoir damage, etc.

Abstract: The present invention relates to the well drilling field in petrochemical industry, in particular to use of dual-cation fluorocarbon surfactant as amphiphobic wettability reversal agent in drilling fluid. The dual-cation fluorocarbon surfactant is a dual-cation fluorocarbon surfactant of which the cation part is represented by the following formula (1). The dual-cation fluorocarbon surfactant of the present invention can serve as wettability reversal agent when it is used for oil-gas drilling to enable rock amphiphobic, and is an amphiphobic wettability reversal agent which can cause rock surface to be non-hydrophilic and non-lipophilic. Using of dual-cation fluorocarbon surfactant, especially when drilling highly hydrous mud shale, can avoid permeation of water and oil into the rock effectively and thereby a capillary phenomenon can be prevented, and an effect of stabilizing the well wall and protecting the reservoir is attained.