Abstract: The present invention provides a pre-sintered body for obtaining a zirconia sintered body that can satisfy both high strength and high translucency, and a method of production of such a pre-sintered body. The present invention relates to a zirconia pre-sintered body comprising a secondary aggregate having an average particle diameter of 275 nm or less, the secondary aggregate comprising zirconia, and a stabilizer capable of preventing a phase transformation of zirconia, the secondary aggregate comprising a larger particle having an average primary particle diameter of 100 nm or more and 200 nm or less, and a smaller particle having an average primary particle diameter of 10 nm or more and less than 60 nm.

Abstract: The present invention provides a granule and green compact suited for obtaining a high-translucency and high-strength zirconia sintered body, and a high-density and uniform pre-sintered body. The invention also provides methods of production of such a granule and green compact. The present invention relates to a granule comprising zirconia, a stabilizing agent capable of preventing a phase transformation of zirconia, and a binder, the granule having a compression ratio R of 0.46 to 0.53 as calculated by the formula (1) below when tapped and filled into a columnar die in compliance with JIS R 1628:1997, and compressed by uniaxial pressing at a rate of 1 mm/s to 33 MPa, R=(H?D)/H??(1) wherein H represents a height of the granule tapped and filled into the columnar die before applying pressure, and D represents an amount of strain up to 33 MPa.

Abstract: The present invention provides a method for producing a powder containing zirconia particles and a fluorescent agent that enables easy production of a zirconia sintered body having both high translucency and high strength despite containing a fluorescent agent. The present invention relates to a method for producing a zirconia particle- and fluorescent agent-containing powder, comprising: a mixing step of mixing a zirconia particle-containing slurry and a liquid-state fluorescent agent; and a drying step of drying the slurry containing the zirconia particles and the fluorescent agent. Preferably, the fluorescent agent comprises a metallic element, and the powder comprises the fluorescent agent in an amount of 0.001 to 1 mass % in terms of an oxide of the metallic element relative to a mass of zirconia. Preferably, the zirconia particles have an average primary particle diameter of 30 nm or less. Preferably, the zirconia particles comprises 2.0 to 9.0 mol % yttria.

Abstract: The present invention provides a method for producing a zirconia particle-containing powder that enables easy production of a zirconia sintered body having both high translucency and high strength. The present invention relates to a method for producing a zirconia particle-containing powder, comprising a drying step of spray drying a slurry containing zirconia particles, wherein the zirconia particles have an average primary particle diameter of 30 nm or less, and the slurry comprises a dispersion medium containing a liquid having a surface tension at 25° C. of 50 mN/m or less. Preferably, the zirconia particles comprise 2.0 to 9.0 mol % yttria. Preferably, wherein the content of the liquid in the dispersion medium is 50 mass % or more.

Abstract: The present invention provides a zirconia sintered body containing a fluorescent agent and having excellent translucency and excellent strength. The present invention also provides a zirconia shaped body and a zirconia calcined body from which the zirconia sintered body can be obtained. The present invention relates to a zirconia sintered body comprising a fluorescent agent, wherein the zirconia sintered body comprises 4.5 to 9.0 mol % yttria, and has a crystal grain size of 180 nm or less, and a three-point flexural strength of 500 MPa or more. The present invention relates to a zirconia shaped body comprising a fluorescent agent, wherein the zirconia shaped body comprises 4.5 to 9.0 mol % yttria, and has a three-point flexural strength of 500 MPa or more after being sintered at 1,100° C. for 2 hours under ordinary pressure, and a crystal grain size of 180 nm or less after being sintered at 1,100° C. for 2 hours under ordinary pressure.

Abstract: A zirconia sintered body may excel in translucency, strength, and linear light transmittance with no use of an HIP device, and a zirconia molded body and a zirconia pre-sintered body from which such a zirconia sintered body can be obtained. A zirconia molded body may include zirconia particles with 2.0 to 9.0 mol % yttria, an average primary particle diameter of 60 nm or less, and 0.5 mass % or less zirconia particles having a particle diameter >100 nm, wherein the zirconia molded body has ?L*(W?B) of 5+ through a thickness of 1.5 mm. A zirconia pre-sintered body may include 2.0 to 9.0 mol % yttria, and have a ?L*(W?B) of 5+ through a thickness of 1.5 mm. A zirconia sintered body may include: a fluorescent agent; 2.0 to 9.0 mol % yttria, and have a linear light transmittance of 1% or more through a thickness of 1.0 mm.

Abstract: A zirconia sintered body may excel in translucency, strength, in linear light transmittance, and can be produced by short-time sintering without an HIP device, and be used in zirconia molded bodies and pre-sintered bodies from which such a zirconia sintered body can be obtained. A zirconia molded body with zirconia particles and 2.0 to 9.0 mol % yttria, having an average primary particle diameter less than 60 nm, and a monoclinic crystal system in a fraction of ?55%. The zirconia molded body may have ?1% undissolved yttria. A zirconia pre-sintered body may have such zirconia particles, wherein the zirconia pre-sintered body has ?L*(W?B) of ?5 through a thickness of 1.5 mm. A zirconia sintered body may have a fluorescent agent and 2.0 to 9.0 mol % yttria, and a crystal grain size of ?180 nm.

Abstract: A zirconia composition, a zirconia semi-sintered body, a zirconia sintered body, and a dental product are provided. The zirconia sintered body contains 4 mol % to 7 mol % of yttria as stabilizer, and a shielding material. The zirconia sintered body comprises first region and second region having a higher content ratio of the shielding material than the first region. Difference between content ratio of yttria in the first region and that of yttria in the second region is 1 mol % or less.

Abstract: The present invention provides a zirconia sintered body containing a fluorescent agent and having excellent translucency and excellent strength. The present invention also provides a zirconia shaped body and a zirconia calcined body from which the zirconia sintered body can be obtained. The present invention relates to a zirconia sintered body comprising a fluorescent agent, wherein the zirconia sintered body comprises 4.5 to 9.0 mol % yttria, and has a crystal grain size of 180 nm or less, and a three-point flexural strength of 500 MPa or more. The present invention relates to a zirconia shaped body comprising a fluorescent agent, wherein the zirconia shaped body comprises 4.5 to 9.0 mol % yttria, and has a three-point flexural strength of 500 MPa or more after being sintered at 1,100° C. for 2 hours under ordinary pressure, and a crystal grain size of 180 nm or less after being sintered at 1,100° C. for 2 hours under ordinary pressure.

Abstract: The present invention provides a method for producing a powder containing zirconia particles and a fluorescent agent that enables easy production of a zirconia sintered body having both high translucency and high strength despite containing a fluorescent agent. The present invention relates to a method for producing a zirconia particle- and fluorescent agent-containing powder, comprising: a mixing step of mixing a zirconia particle-containing slurry and a liquid-state fluorescent agent; and a drying step of drying the slurry containing the zirconia particles and the fluorescent agent. Preferably, the fluorescent agent comprises a metallic element, and the powder comprises the fluorescent agent in an amount of 0.001 to 1 mass % in terms of an oxide of the metallic element relative to a mass of zirconia. Preferably, the zirconia particles have an average primary particle diameter of 30 nm or less. Preferably, the zirconia particles comprises 2.0 to 9.0 mol % yttria.

Abstract: The present invention provides a method for producing a zirconia particle-containing powder that enables easy production of a zirconia sintered body having both high translucency and high strength. The present invention relates to a method for producing a zirconia particle-containing powder, comprising a drying step of spray drying a slurry containing zirconia particles, wherein the zirconia particles have an average primary particle diameter of 30 nm or less, and the slurry comprises a dispersion medium containing a liquid having a surface tension at 25° C. of 50 mN/m or less. Preferably, the zirconia particles comprise 2.0 to 9.0 mol % yttria. Preferably, wherein the content of the liquid in the dispersion medium is 50 mass % or more.

Abstract: A zirconia composition, a zirconia semi-sintered body, a zirconia sintered body, and a dental product are provided. The zirconia sintered body contains 4 mol % to 7 mol % of yttria as stabilizer, and a shielding material. The zirconia sintered body comprises first region and second region having a higher content ratio of the shielding material than the first region. Difference between content ratio of yttria in the first region and that of yttria in the second region is 1 mol % or less.

Abstract: A zirconia composition, a zirconia semi-sintered body, a zirconia sintered body, and a dental product are provided. The zirconia sintered body contains 4 mol % to 7 mol % of yttria as stabilizer, and a shielding material. The zirconia sintered body comprises first region and second region having a higher content ratio of the shielding material than the first region. Difference between content ratio of yttria in the first region and that of yttria in the second region is 1 mol % or less.

Abstract: There are provided zirconia composition, zirconia semi-sintered body and zirconia sintered body, and dental product in which defect-generation is suppressed and transparency varies. The zirconia sintered body contains 4 mol % to 7 mol % of yttria as stabilizer. The zirconia sintered body contains shielding material. The zirconia sintered body comprises first region and second region having a higher content ratio of the shielding material than the first region. Difference between content ratio of yttria in the first region and that of yttria in the second region is 1 mol % or less.

Abstract: The present invention provides a self-adhesive composite resin having excellent adhesiveness to tooth structures and excellent mechanical strength. The present invention relates to a self-adhesive dental composite resin containing: an asymmetric acrylamide-methacrylic acid ester compound (a); an acid group-containing (meth)acrylic polymerizable monomer (b); a hydrophobic crosslinkable polymerizable monomer (c); a photopolymerization initiator (d); and a filler (e).

Abstract: The present invention provides a self-adhesive composite resin having excellent adhesiveness to tooth structures and excellent mechanical strength. The present invention relates to a self-adhesive dental composite resin containing: an asymmetric acrylamide-methacrylic acid ester compound (a); an acid group-containing (meth)acrylic polymerizable monomer (b); a hydrophobic crosslinkable polymerizable monomer (c); a photopolymerization initiator (d); and a filler (e).