Abstract: Curable adhesive articles having topographical features and methods of making curable adhesive articles are disclosed.

Abstract: Curable pressure sensitive adhesive compositions comprising an acrylate copolymer, a mono-acrylate oligomer, a multi-acrylate oligomer having from 2 to 5 acrylate functional groups per molecule, and a photoinitiator, the adhesive exhibiting pressure sensitive adhesive characteristics and forms at least a semi-interpenetrating polymer network when cured; wherein the semi-IPN has an average molecular weight between crosslinks (Mc) greater than about 3000, and the cured adhesive has a peel strength greater than about 40 N/dm. Embodiments of the adhesive compositions, when cured, are optically clear and resistant to heat and moisture.

Abstract: A polarizing beam splitter (PBS) includes a multilayer reflective polarizing film, a pressure sensitive adhesive is disposed on the multilayer reflective polarizing film, a first rigid cover is disposed on the pressure sensitive adhesive. The PBS can be used in a variety of applications.

Abstract: Curable pressure sensitive adhesive compositions comprising an acrylate copolymer, a mono-acrylate oligomer, a multi-acrylate oligomer having from 2 to 5 acrylate functional groups per molecule, and a photoinitiator, the adhesive exhibiting pressure sensitive adhesive characteristics and forms at least a semi-interpenetrating polymer network when cured; wherein the semi-IPN has an average molecular weight between crosslinks (Mc) greater than about 3000, and the cured adhesive has a peel strength greater than about 40 N/dm. Embodiments of the adhesive compositions, when cured, are optically clear and resistant to heat and moisture.

Abstract: Described are multilayer optical composites including a first layer having an index of refraction n1, an ith layer having an index of refraction ni greater than n1, and one or two or more intermediate layers between the first layer and the ith layer, wherein the indices of refraction of the intermediate layers are between n1 and ni, and the index of refraction of each intermediate layer increases in the order of position of each layer from the first layer.

Abstract: Epoxy adhesives are reported that comprise: (i) about 20% to about 40% weight of a reactive oligomer having a glass transition temperature of about −40° C. or less after curing and having at least two functional groups selected from epoxide, isocyanate, and amine; (ii) an amine curative; and (iii) an epoxide-group containing compound. The epoxy adhesives are resistant to thermal shock and have a low shear creep. The epoxy adhesives are particularly suitable for bonding substrates having mismatched coefficients of thermal expansion.

Abstract: Described are adhesive compositions containing a mixture of a pressure sensitive adhesive, a high Tg polymer, and a crosslinker to form a compatibilized blend that is optically clear. Methods of using the adhesive compositions, and multilayer assemblies such as optical elements prepared using the adhesives, are also provided.

Abstract: Curable pressure sensitive adhesive compositions comprising an acrylate copolymer, a mono-acrylate oligomer, a multi-acrylate oligomer having from 2 to 5 acrylate functional groups per molecule, and a photoinitiator, the adhesive exhibiting pressure sensitive adhesive characteristics and forms at least a semi-interpenetrating polymer network when cured; wherein the semi-IPN has an average molecular weight between crosslinks (Mc) greater than about 3000, and the cured adhesive has a peel strength greater than about 40 N/dm. Embodiments of the adhesive compositions, when cured, are optically clear and resistant to heat and moisture.

Abstract: The present invention provides pressure-sensitive adhesives having a refractive index of at least 1.48. The pressure-sensitive adhesives comprise at least one monomer containing a substituted or an unsubstituted aromatic moiety.

Abstract: The present invention provides pressure-sensitive adhesives having a refractive index of at least 1.48. The pressure-sensitive adhesives comprise at least one monomer containing a substituted or an unsubstituted aromatic moiety.

Abstract: An integrated optical assembly including a light management component with an entry surface and a light delivery component having an exit surface attached to the entry surface of the light management component is disclosed The light management component and the light delivery component are attached together in a manner that defines voids between the entry surface of the light management component and the exit surface of the light delivery component. The voids between the light management component and the light delivery component may provide an air interface over substantial portions of the entry surface of the light management component.

Abstract: A fluid permeable composite structure having active particulate bonded together using a pressure-sensitive adhesive (PSA) polymer microparticulate. Use of the PSA polymer microparticulate to bond the active particulate together produces a bonded structure that, unlike previously-developed active bonded structures, is flexible and therefore can be conformed into a variety of shapes. The shaped structures may be used as gaseous filters in a wide variety of respirators.

Abstract: The present invention relates to a water-based high-solids moisture-resistant latex pressure sensitive adhesive which has a low coating viscosity and which has high shear, high compliance, and controlled adhesion buildup.

Abstract: Water resistant, low haze acrylic emulsion pressure sensitive adhesive compositions for use in decorative, light management or optical articles are disclosed. These emulsion pressure sensitive adhesives comprise (a) 50-90% by weight n-butyl acrylate, and (b) 10-50% by weight 2-hydroxy ethyl acrylate, or 2-hydroxy ethyl methacrylate, hydroxy propyl acrylate monomer, or mixtures thereof. These emulsion pressure sensitive adhesives can be used in wet lamination processes, and exhibit less than 2% increase in haze, less than 2% increase in opacity and greater than 95% transmittance after the wet lamination process.

Abstract: A polymerized microemulsion pressure sensitive adhesive composition is described. The composition has peel adhesion of at least 3 Newtons/100 mm as measured according to a PSTC-1 Test. The composition preferably has a bicontinuous structure of a continuous phase of a hydrophobic pressure sensitive adhesive polymer and a continuous phase of a hydrophilic polymer. The bulk properties of both polymers are retained in the bicontinuous structure. The composition is prepared from a microemulsion comprising a free-radically ethylenically unsaturated polar amphiphilic or hydrophilic monomer or oligomer in the aqueous phase, a free-radically ethylenically unsaturated hydrophobic monomer, having a glass transition temperature suitable for forming a pressure sensitive adhesive, in the oil phase, water, and surfactant.

Abstract: A pressure-sensitive adhesive polyacrylate polymer microparticulate obtainable by suspension polymerizing an aqueous mixture that comprises: (a) an acrylic acid ester of a nontertiary alcohol having 1 to 14 carbon atoms; (b) a polar monomer; (c) a styrene sulfonate salt; and (d) an amount of surfactant above the critical micelle concentration.

Abstract: A latex antistatic adhesive comprising an emulsion of polymerized microdrops dispersed in an aqueous medium, having an average diameter less than about 0.1 .mu.m, and a glass transition temperature (Tg) of from about -120.degree. C. to about 25.degree. C., wherein the polymerized microdrops are derived from emulsion microdrops of reactive monomers, said adhesive including at least one (meth)acrylic monomer, at least one polar monomer, at least one reactive oligomer and at least 1% of a lithium salt.

Abstract: A polymerized microemulsion pressure sensitive adhesive composition is described. The composition has peel adhesion of at least 3 Newtons/100 mm as measured according to a PSTC-1 Test. The composition preferably has a bicontinuous structure of a continuous phase of a hydrophobic pressure sensitive adhesive polymer and a continuous phase of a hydrophilic polymer. The bulk properties of both polymers are retained in the bicontinuous structure. The composition is prepared from a microemulsion comprising a free-radically ethylenically unsaturated polar amphiphilic or hydrophilic monomer or oligomer in the aqueous phase, a free-radically ethylenically unsaturated hydrophobic monomer, having a glass transition temperature suitable for forming a pressure sensitive adhesive, in the oil phase, water, and surfactant.

Abstract: A polymerized microemulsion pressure sensitive adhesive composition is described. The composition has peel adhesion of at least 3 Newtons/100 mm as measured according to a PSTC-1 Test. The composition preferably has a bicontinuous structure of a continuous phase of a hydrophobic pressure sensitive adhesive polymer and a continuous phase of a hydrophilic polymer. The bulk properties of both polymers are retained in the bicontinuous structure. The composition is prepared from a microemulsion comprising a free-radically ethylenically unsaturated polar amphiphilic or hydrophilic monomer or oligomer in the aqueous phase, a free-radically ethylenically unsaturated hydrophobic monomer, having a glass transition temperature suitable for forming a pressure sensitive adhesive, in the oil phase, water, and surfactant.

Abstract: This application discloses a core/shell latex thermal adhesive comprising a thermally softenable polymeric shell having a Tg of greater than 20.degree.C., and a thermally softenable, crosslinked polymeric core having a Tg of less than 20.degree. C., the difference between the Tg of the core and the shell being at least 10.degree.C. This application also discloses a thermally activated adhesive composition comprising:a) from about 50 to 100 parts of a transparent film-forming core/shell latex polymer, wherein the ratio of core to shell of said core/shell latex polymer ranges from about 20/80 to about 80/20,the shell having a Tg above 20.degree. C. and the core having a Tg below 20.degree. C. with the core having a Tg lower than the Tg of the shell by at least 10.degree. C.