Abstract: Disclosed is a meta-structure. The meta-structure includes a lower electrode, a lower insulating layer on the lower electrode, a lower metal oxide layer on the lower insulating layer, a metal layer on the lower metal oxide layer, an upper metal oxide layer on the metal layer, an upper insulating layer on the upper metal oxide layer, and antenna electrodes on the upper insulating layer.

Abstract: The present invention relates to a method of preparing a graft copolymer powder, which includes: preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer and a vinyl cyan-based monomer to a reactor and carrying out polymerization; preparing a core in the presence of the seed by adding an alkyl (meth)acrylate-based monomer and carrying out polymerization; and preparing a graft copolymer latex in the presence of the core by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and carrying out polymerization; adding an alkyl methacrylate-based polymer to the graft copolymer latex and carrying out coagulation, and more particularly, to a method of preparing a graft copolymer powder that is excellent in weather resistance, fluidity, mechanical properties, surface gloss and appearance quality.

Abstract: A display apparatus including a display and a supporter. The supporter being mounted on the display and configured to support the display and rotate the display module between a first position and a second position. The supporter including a drive motor, a first gear, and a detection sensor. The drive motor configured to supply a driving force to rotate the display. The first gear configured to rotate together with the display by receiving the driving force from the drive motor. The detection sensor configured to detect a rotation amount of a second gear configured to rotate in with the first gear.

Abstract: A display apparatus including a display and a supporter. The supporter being mounted on the display and configured to support the display and rotate the display module between a first position and a second position. The supporter including a drive motor, a first gear, and a detection sensor. The drive motor configured to supply a driving force to rotate the display. The first gear configured to rotate together with the display by receiving the driving force from the drive motor. The detection sensor configured to detect a rotation amount of a second gear configured to rotate in with the first gear.

Abstract: The present disclosure relates to a thermoplastic resin having excellent impact strength, gloss, fluidity, and non-whitening properties and a method of preparing the same. The thermoplastic resin including an alkyl acrylate-alkyl methacrylate graft copolymer (A), or an alkyl acrylate-alkyl methacrylate graft copolymer (A) and a matrix resin (B) including one or more selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, an alkyl methacrylate, and an alkyl acrylate, wherein a total content of the alkyl acrylate is 20 to 50% by weight, and a butyl acrylate coverage value (X) as calculated by Equation 1 below is 50 or more. X={(G?Y)/Y}×100??[Equation 1] In Equation 1, G represents the total gel content (%) of the thermoplastic resin, and Y represents the content (% by weight) of butyl acrylate in the gel of the thermoplastic resin.

Abstract: Provided is a thermoplastic resin composition which includes: a graft copolymer including a C4 to C10 alkyl (meth)acrylate-based monomer unit, a styrene-based monomer unit, and a vinyl cyan-based monomer unit; a first styrene-based copolymer including a C1 to C3 alkyl-substituted styrene-based monomer unit and a vinyl cyan-based monomer unit; and a second styrene-based copolymer including an unsubstituted styrene-based monomer unit and a vinyl cyan-based monomer unit. The thermoplastic resin composition is remarkably excellent in heat resistance, chemical resistance, and appearance characteristics while maintaining basic properties.

Abstract: The present disclosure relates to a thermoplastic resin having excellent non-whitening properties, impact strength, gloss, and fluidity, and a method of preparing the thermoplastic resin. The thermoplastic resin includes an alkyl acrylate-alkyl methacrylate graft copolymer (A), or the copolymer (A) and a matrix resin (B) including one or more selected from the group consisting of an aromatic vinyl compound-vinyl cyanide compound-alkyl methacrylate copolymer and an alkyl methacrylate polymer. A transparency measured under a condition of 3 mm thickness is less than 5, the total content of the alkyl acrylate is 20 to 50% by weight, and an alkyl acrylate coverage value (X) as calculated by Equation 1 below is 65 or more: X={(G?Y)/Y}×100,??[Equation 1] wherein G represents the total gel content (%) of the thermoplastic resin, and Y represents the content of alkyl acrylate in the gel contained in the thermoplastic resin.

Abstract: Provided is a thermoplastic resin composition which includes: a graft copolymer prepared by graft-polymerizing an aromatic vinyl-based monomer and a vinyl cyan-based monomer onto an acrylic rubber polymer having an average particle diameter of 50.0 to 90.0 nm; a matrix copolymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; and an additive including a polymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, specifically, a thermoplastic resin composition which has improved properties in terms of elongation, processability, weather resistance, colorability, hardness, chemical resistance, scratch resistance, a whitening phenomenon, surface gloss and appearance quality while having excellent basic properties.

Abstract: Disclosed is a thermoplastic resin including an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A), or an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A) and a matrix resin (B) including one or more selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, an alkyl methacrylate, and an alkyl acrylate, wherein the total content of the alkyl acrylate is 20 to 50% by weight, and an alkyl acrylate coverage value (X) as calculated by Equation 1 below is 65 or more: X={(G?Y)/Y}×100, ??[Equation 1] wherein G represents the total gel content (%) of the thermoplastic resin, and Y represents the content (% by weight) of the alkyl acrylate in the gel of the thermoplastic resin.

Abstract: The present invention relates to a method of preparing an ASA graft copolymer, a method of preparing a thermoplastic resin composition including the ASA graft copolymer, and a method of manufacturing a molded article using the thermoplastic resin composition.

Abstract: The present disclosure relates to a thermoplastic resin having excellent non-whitening properties, impact strength, gloss, and fluidity, and a method of preparing the thermoplastic resin. The thermoplastic resin includes an alkyl acrylate-alkyl methacrylate graft copolymer (A), or the copolymer (A) and a matrix resin (B) including an alkyl methacrylate polymer and/or an alkyl methacrylate-alkyl acrylate copolymer. A transparency of the thermoplastic resin having a thickness of 0.15 mm is less than 2, a total content of the alkyl acrylate in the thermoplastic resin is 20 to 50% by weight, and a butyl acrylate coverage value (X) as calculated by Equation 1 below is 50 or more: X={(G?Y)/Y}×100,??[Equation 1] wherein G represents a total gel content (%) of the thermoplastic resin, and Y represents a content (% by weight) of butyl acrylate in the gel of the thermoplastic resin.

Abstract: Provided is a thermoplastic resin composition which includes: a base resin including a polyarylene oxide-based polymer at 100 parts by weight; and an additive including one or more selected from the group consisting of compounds represented by Chemical Formula 1-1 to Chemical Formula 1-3 at 0.1 to 5 parts by weight, and can be used for producing a thermoplastic resin molded article which exhibits an excellent coloring property and thus has an aesthetically pleasing appearance.

Abstract: The present invention relates to a thermoplastic resin composition, including a first graft copolymer including an alkyl (meth)acrylate-based polymer-derived unit, an aromatic vinyl-based monomer-derived unit, and a vinyl cyanide-based monomer-derived unit; a copolymer including an aromatic vinyl-based monomer-derived unit and a vinyl cyanide-based monomer-derived unit; a polyester-based elastomer; and a phthalate-based plasticizer.

Abstract: The present invention provides a graft copolymer comprising (A) a seed comprising units derived from an alkyl methacrylate monomer; (B) a core formed on the seed and comprising units derived from an alkyl acrylate monomer; and (C) a shell formed on the core and comprising units derived from one or more one or more selected from the group consisting of an aromatic vinyl-based monomer, a vinyl cyanide-based monomer and an alkyl methacrylate monomer, wherein an average particle diameter of the core is 40 to 90 nm, and a graft ratio of the shell is 10 to 30%, and a thermoplastic resin composition and a thermoplastic resin molded article including the same.

Abstract: Provided is a thermoplastic resin composition which includes: a graft copolymer prepared by graft-polymerizing an aromatic vinyl-based monomer and a vinyl cyan-based monomer onto an acrylic rubber polymer; a first matrix copolymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; a second matrix copolymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; and an additive including a polymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, wherein the first matrix copolymer and the second matrix copolymer have different weight-average molecular weights, specifically, a thermoplastic resin composition which allows high gloss, high hardness, high weather resistance and reduced whitening to be realized.

Abstract: A method for preparing a graft copolymer includes the steps of: 1) preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer and carrying out polymerization; 2) preparing a core in the presence of the seed by adding an alkyl (meth)acrylate-based monomer and carrying out polymerization; and 3) preparing a shell in the presence of the core by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and carrying out polymerization, wherein an activator including a compound represented by Chemical Formula 1 is added in the step 3). In Chemical Formula 1, R1 and R2 are each independently hydrogen, a C1-C10 alkyl group, or *-(C=O)OM2, provided that R1 and R2 are not both hydrogen, and M1 and M2 are each independently an alkali metal.

Abstract: Provided are a method of preparing a graft copolymer, a graft copolymer, and a thermoplastic resin molded article including the graft copolymer, the method including: 1) preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer and performing polymerization; 2) in the presence of the seed, preparing a core by adding an alkyl (meth)acrylate-based monomer and performing polymerization; and 3) in the presence of the core, preparing a shell by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and performing polymerization, wherein the method further includes adding an alkyl acrylate-based polymer. When the alkyl acrylate-based polymer is included in a graft copolymer, a graft copolymer and a thermoplastic resin molded article excellent in weather resistance, fluidity, mechanical properties, and appearance quality can be provided.

Abstract: Provided is a thermoplastic resin composition which includes: a first graft copolymer including a C4 to C10 alkyl (meth)acrylate-based monomer unit, a C1 to C3 alkyl-substituted styrene-based monomer unit, and a vinyl cyan-based monomer unit; a second graft copolymer including a C4 to C10 alkyl (meth)acrylate-based monomer unit, an alkyl-unsubstituted styrene-based monomer unit, and a vinyl cyan-based monomer unit; a first styrene-based copolymer including a C1 to C3 alkyl-substituted styrene-based monomer unit and a vinyl cyan-based monomer unit; a second styrene-based copolymer including an alkyl-unsubstituted styrene-based monomer unit and a vinyl cyan-based monomer unit; and an olefin-based copolymer including a C1 to C3 alkyl (meth)acrylate-based monomer unit. The thermoplastic resin composition exhibits remarkably excellent chemical resistance and remarkably excellent appearance characteristics while maintaining basic properties.

Abstract: The present invention relates to an acrylic graft copolymer, a method of preparing the same, and a thermoplastic resin composition including the same. More specifically, the acrylic graft copolymer of the present invention includes a seed, a core, and a graft shell. In this case, the graft shell includes 0.05 to 2 parts by weight of a reactive ultraviolet stabilizer based on 100 parts by weight of the acrylic graft copolymer, and the graft shell has an average particle diameter of 80 to 140 nm (greater than the average particle diameter of the core). The acrylic graft copolymer of the present invention has excellent impact strength, tensile strength, weather resistance, and surface gloss. In addition, when the acrylic graft copolymer is used, mold deposits may be reduced.

Abstract: The present invention relates to a thermoplastic resin composition including a (meth)acrylate graft copolymer and a method of preparing the thermoplastic resin composition. According to the present invention, the thermoplastic resin composition includes a graft copolymer (A) containing an alkyl acrylate rubber core and an alkyl methacrylate compound (co)polymer shell surrounding the alkyl acrylate rubber core; and a matrix resin (B). In this case, the rubber core has an average particle diameter of 40 to 100 nm, the graft copolymer (A) has a grafting degree of 20 to 100%, and the thermoplastic resin composition has a refractive index of greater than 1.46 and less than 1.49 and a blackness (L value) of less than 25.0.