Abstract: An exhaust gas purification filter that is suitable for arrangement in an exhaust passage of an internal combustion engine and for collecting particulate matter contained in exhaust gas, comprises: exhaust gas inflow passages and exhaust gas outflow passages that are arranged alternately; and porous partitions that separate the exhaust gas inflow passages and the exhaust gas outflow passages from each other. Each of the partitions is divided into a coated zone in which a surface of a partition base is coated with a coating layer having a smaller average pore diameter than an average pore diameter of the partition base and a non-coated zone that is located on a downstream side of the coated zone and in which a surface of the partition base is not coated with the coating layer.

Abstract: An exhaust purification system including a particulate filter , a selective reduction catalyst provided at a downstream side from the filter, an ammonia ingredient feed device which feeds an ammonia ingredient to the selective reduction catalyst, a control device which controls the amount of the ammonia ingredient which is adsorbed at the selective reduction catalyst to become a target adsorption amount, and a filter regeneration system which performs filter regeneration processing to remove PM which has built up on the particulate filter when an execution start condition stands. When removal of PM is demanded, so long as the execution start condition of the filter regeneration processing by the filter regeneration system does not stand, the target adsorption amount is decreased a plurality of times in stages, and the execution start condition of the filter regeneration processing is changed to a different condition at each stage of the target adsorption amount.

Abstract: A gel which contains a component of a catalyst is prepared. The gel and another gel are arranged in layers at a position which faces open ends of exhaust flow passages of a wall flow-type particulate filter. Next, a pusher is used to push and pack the gel and other gel through the open ends to the insides of the exhaust flow passages. Next, the particulate filter is made to dry to thereby make the partition walls carry the catalyst on their surfaces or in their micropores.

Abstract: An object of the present invention is to appropriately remove, from an exhaust gas, HC, CO, and ammonia flowing out from a filter (SCRF) on which an SCR catalyst is carried. In the present invention, a post-catalyst 8 is provided for an exhaust gas passage of an internal combustion engine on a downstream side from SCRF along with a flow of the exhaust gas. The post-catalyst 8 is constructed to include an adsorption reduction part 81c which adsorbs ammonia and which reduces NOx by using ammonia as a reducing agent, a first oxidation part 81b which oxidizes ammonia, and a second oxidation part 82 which oxidizes HO and CO.

Abstract: An estimated trapped amount (PM) that is an estimated value of an amount of particulate matter that is trapped in a particulate filter arranged in an engine exhaust passage is calculated based on an engine operating state, and PM removal control is performed when the estimated trapped amount exceeds an upper limit amount. Reference temperature increase control is performed to remove the particulate matter from the particulate filter, and an actual temperature that is the temperature of the particulate filter while the reference temperature increase control is being performed is detected. A reference temperature that is the temperature of the particulate filter when it is assumed that the reference temperature increase control has been performed when the amount of particulate matter trapped in the particulate filter is a reference initial trapped amount is stored in advance. The estimated trapped amount is corrected based on the actual temperature and the reference temperature.

Abstract: An exhaust gas purification apparatus of an internal combustion engine includes: a reducing agent passage that connects a tank and an injection valve; a heater that heats up a hydrolysis catalyst that is provided in the reducing agent passage; and a controller comprising at least one processor configured to control a pump so that a reducing agent located further toward a side of the injection valve than the hydrolysis catalyst flows toward a side of the hydrolysis catalyst after completion of injection of a reducing agent in a state where the hydrolysis catalyst is at a temperature lower than the hydrolysis temperature and before start of injection of a reducing agent in a state where the hydrolysis catalyst is at a temperature equal to or higher than the hydrolysis temperature.

Abstract: A NOx catalyst is provided that can realize a favorable NOx reduction in a broad temperature region and that can lighten the overhead involved in production.

Abstract: In order to suppress ammonia from flowing out during regeneration treatment of a filter carrying an SCR catalyst, the prevent invention provides an exhaust emission control system of an internal combustion engine, including a first stage catalyst having an oxidation function, a fuel supply device configured to supply fuel to the first stage catalyst, a filter provided in the exhaust passage downstream of the first stage catalyst and carrying a selective redaction type NOx catalyst, an ammonia supply device configured to supply ammonia to the filter, a filter-regeneration-treatment executing unit configured to execute filter regeneration treatment, and a control unit configured to supply, when the filter regeneration treatment is not executed, the ammonia in an amount corresponding to an amount of the NOx emitted from the internal combustion engine, and to supply, when the filter regeneration treatment is executed, the ammonia in an amount corresponding to an amount of the NOx obtained by subtracting, from the

Abstract: An object is to provide technology that enables an NOx catalyst to exercise its NOx reduction capability satisfactorily at any flow speed of the exhaust gas flowing into the NOx catalyst. An exhaust gas purification apparatus for an internal combustion engine includes a selective catalytic reduction NOx catalyst including at least a first catalyst layer having capability of reducing NOx and a second catalyst layer having oxidation capability and arranged closer to a catalyst substrate than the first catalyst layer. The apparatus has a supply valve for adding a specific addition quantity of reducing agent for reducing NOx to inflowing exhaust gas flowing into the selective catalytic reduction NOx catalyst.

Abstract: An apparatus may have a selective catalytic reduction NOx catalyst including a high-temperature catalyst layer having high capability of reducing NOx at high temperatures and a low-temperature catalyst layer having higher capability of reducing NOx at low temperatures than that of the high-temperature catalyst layer. The low-temperature catalyst layer may be arranged closer to a catalyst substrate than the high-temperature catalyst layer. A supply valve may add an addition quantity of reducing agent for reducing NOx to exhaust gas flowing into the selective catalytic reduction NOx catalyst. A controller may comprise at least one processor configured to control addition of the reducing agent by the supply valve such that the reducing agent concentration in a reducing agent atmosphere formed in the exhaust gas flowing into the selective catalytic reduction NOx catalyst is higher when the temperature of the selective catalytic reduction NOx catalyst is in a specific low temperature range.

Abstract: In an exhaust gas purification system for an internal combustion engine provided with a filter supporting an SCR catalyst, the present invention is intended to suppress HC and CO from being discharged to the outside at the time of the execution of filter regeneration processing, and to carry out the filter regeneration processing in an efficient manner. In the present invention, a post-catalyst having an oxidation function is arranged in an exhaust passage at the downstream side of the filter. Then, when the temperature of the post-catalyst is lower than a predetermined activation temperature at the time the execution of the filter regeneration processing is requested, the temperature of the post-catalyst is raised by carrying out control of raising the temperature of the exhaust gas discharged from the internal combustion engine, and control increasing the flow rate of the exhaust gas, before the execution of the filter regeneration processing.

Abstract: An exhaust purification device for an internal combustion engine is provided with an NOx adsorbent for adsorbing NOx in exhaust gas and an NOx purifying catalyst for purifying NOx in exhaust gas, which are arranged in an engine exhaust passage. An electric heater is provided for raising the temperature of the NOx adsorbent. When a signal requesting startup of an internal combustion engine is issued, the device starts to supply electric power to the electric heater before the internal combustion engine completely warms up, and supplies the electric heater with a quantity of electric power making the temperature of the NOx adsorbent equal to or higher than the moisture desorption temperature but lower than the NOx desorption temperature.

Abstract: Micropore zones ZMI are defined at upstream sides of partition walls 72 of a particulate filter and macropore zones ZMA are defined at downstream sides of partition walls. The pore size of the partition walls at the micropore zones is set so that the particulate matter and the ash can be trapped by the partition walls at the micropore zones, while the pore size of the partition walls at the macropore zones is set so that the ash can pass through the partition walls at the macropore zones. When a quantity of trapped particulate matter is smaller than a limit quantity, control for increasing gas which temporarily increases the flow rate of the gas which flows into the particulate filter in order to remove the ash from the particulate filter, is performed.

Abstract: An exhaust gas purification apparatus of an internal combustion engine includes: a reducing agent passage that connects a tank and an injection valve; a heater that heats up a hydrolysis catalyst that is provided in the reducing agent passage; and a controller comprising at least one processor configured to control a pump so that a reducing agent located further toward a side of the injection valve than the hydrolysis catalyst flows toward a side of the hydrolysis catalyst after completion of injection of a reducing agent in a state where the hydrolysis catalyst is at a temperature lower than the hydrolysis temperature and before start of injection of a reducing agent in a state where the hydrolysis catalyst is at a temperature equal to or higher than the hydrolysis temperature.

Abstract: An exhaust gas purification filter includes an inflow/outflow passage through which exhaust gas flows in/out, and a partition. The outflow passage and the inflow passage is alternately arranged. The partition is configured to divide the inflow passage and the outflow passage from each other, and being porous. The partition includes a coated zone where a surface of a base of the partition is covered with a first coating layer having an average pore diameter smaller than an average pore diameter of the base, and a non-coated zone where the surface of the base is not covered with the first coating layer on a downstream side of the coated zone. The average pore diameter of the base is large enough for ash to pass through the partition, and the first coating layer is constituted by a plurality of particle groups with different average particle diameters from each other.

Abstract: An object of the present invention is to suppress a reduction in a NOx purification ratio accompanying filter regeneration processing in an exhaust gas purification system for an internal combustion engine that includes a filter carrying an SCR catalyst. In the present invention, the temperature of the filter is increased following completion of the filter regeneration processing by increasing the temperature of exhaust gas discharged from the internal combustion engine, and in so doing, HC adhered to the filter is removed.

Abstract: An exhaust cleaning filter for collecting particulate matter contained in exhaust gas and suitable for being disposed in an exhaust passage of an internal combustion engine is provided with: an exhaust gas inflow passage and an exhaust gas outflow passage disposed in alternating fashion; and a porous partition wall for setting the exhaust gas inflow passage and the exhaust gas outflow passage at a distance from each other. A small pore region is sectioned off on the upstream side of the partition wall and a large pore region is sectioned off on the downstream side of the partition wall. The average pore diameter of the partition wall in the large pore region is set to be greater than the average pore diameter of the partition wall in the small pore region, and is set so that ash contained in the exhaust gas is able to pass through the partition wall.

Abstract: In order to suppress ammonia from flowing out during regeneration treatment of a filter carrying an SCR catalyst, the prevent invention provides an exhaust emission control system, of an internal combustion engine, including a first stage catalyst having an oxidation function, a fuel supply device configured to supply fuel to the first stage catalyst, a filter provided in the exhaust passage downstream of the first stage catalyst and carrying a selective redaction type NOx catalyst, an ammonia supply device configured to supply ammonia to the filter, a filter-regeneration-treatment executing unit configured to execute filter regeneration treatment, and a control unit configured to supply, when the filter regeneration treatment is not executed, the ammonia in an amount corresponding to an amount of the NOx emitted from the internal combustion engine, and to supply, when the filter regeneration treatment is executed, the ammonia in an amount corresponding to an amount of the NOx obtained by subtracting, from th

Abstract: A temperature sensor includes temperature detecting means and at least one of a catalyst and an adsorbent applied to the surface of the temperature detecting means. At least one of the catalyst and the adsorbent catalyzes an exothermic reaction of a reactant in gas on the temperature detecting means. A temperature that is increased by the exothermic reaction is detected by the temperature detecting means. The catalytic efficiency for the exothermic reaction of at least one of the catalyst and the adsorbent is reduced by sulfur poisoning. The temperature sensor is disposed upstream of an exhaust purification system. Accordingly, it is determined that the temperature sensor is subjected to sulfur poisoning if the temperature detected by the temperature sensor is below a prescribed temperature.

Abstract: In an exhaust gas purification system for an internal combustion engine provided with a filter supporting an SCR catalyst, the present invention is intended to suppress HC and CO from being discharged to the outside at the time of the execution of filter regeneration processing, and to carry out the filter regeneration processing in an efficient manner. In the present invention, a post-catalyst having an oxidation function is arranged in an exhaust passage at the downstream side of the filter. Then, when the temperature of the post-catalyst is lower than a predetermined activation temperature at the time the execution of the filter regeneration processing is requested, the temperature of the post-catalyst is raised by carrying out control of raising the temperature of the exhaust gas discharged from the internal combustion engine, and control increasing the flow rate of the exhaust gas, before the execution of the filter regeneration processing.