Abstract: The present invention relates to the field of polyol components suitable for forming polyurethane foam, in particular two component polyurethane foam the resulting foams and methods for their production. The present inventors found gaseous hydrohaloolefin containing polyol components possessing improved shelf-life properties, in particular polyol components comprising a gaseous hydrohaloolefin blowing agent, a nitrogen catalyst and a tin catalyst, wherein the tin catalyst comprises a sulfur atom. The present inventors also found that the shelf-life is further improved if the nitrogen catalyst is at least partially protonated by reaction with an acid, such as an organic acid.

Abstract: Apparatuses for producing and dispensing a reaction mixture include a mixing head for mixing the reaction components that are fed via two supply lines. The apparatuses also include a decompression system to relieve pressure from the supply lines to avoid the reaction components seeping into the mixing head. The decompression system includes two pressure vessels each with two sides, separated by a membrane. One of these sides forms an expansion chamber for the reaction component, while the other side is connected to a pneumatic system. With this pneumatic system, the expansion chamber can be pressurized before the production of the reaction mixture. After the production of the reaction mixture, the pressure can be relieved.

Abstract: The present invention relates to the field of polyol components suitable for forming polyurethane foam, in particular two component polyurethane foam the resulting foams and methods for their production. The present inventors found gaseous hydrohaloolefin containing polyol components possessing improved shelf-life properties, in particular polyol components comprising a gaseous hydrohaloolefin blowing agent, a nitrogen catalyst and a tin catalyst, wherein the tin catalyst comprises a sulfur atom. The present inventors also found that the shelf-life is further improved if the nitrogen catalyst is at least partially protonated by reaction with an acid, such as an organic acid.