METHOD OF MANUFACTURING FIBER REINFORCED PLASTICS

Abstract

A method of manufacturing fiber reinforced plastics by means of a drawing method having the steps of immersing resins into fibers for reinforcing aligned in one direction, which are supplied continuously, and curing the resins immersed in the fibers by drawing the fibers into a die, is disclosed. In the method according to the invention, the fibers are moved in a resin supply zone at a substantially same speed as that of resin immersing in the fibers along a direction in which the fibers are aligned.

Description

BACKGROUND OF THE INVENTION

[0001] 1. Field of the Invention

[0002] The present invention relates to a method of manufacturing fiber reinforced plastics (hereinafter, sometimes refer to FRP) by means of a drawing method which is especially preferred for a polymer insulator.

[0003] 2. Description of Related Art

[0004] FRP, in which glass roving aligned in one direction to which thermosetting resins are immersed and the resins are cured, is light in weight and has a high strength. Therefore, it is preferably used as a core member of a polymer insulator for a power-transmission line or the like. As a drawing method of such an FRP, there is a well known manufacturing method having the steps of: aligning a fiber itself or a plurality of fibers for reinforcing such as roving, yarn, mat, cloth or the like, immersing liquid resins into the fiber or the fibers by passing it or them in a resin supply zone, and curing the resins by means of thermosetting reaction by passing it or the, in a die to obtain a forming product having a continuous same cross section.

[0005] In the known drawing method mentioned above, a bubble inclusion in resins is liable to be generated during a pass of the resin supply zone. In addition, the bubble inclusion in resins is also not prevented since a plurality of fibers aligned in one direction to which resins are immersed are drawn in such a manner that the fibers shrink at an inlet of the die. Therefore, there is a drawback such that a forming product including bubbles is hardened as it is. In order to eliminate the bubble inclusion problem, there are known a method of degassing by means of a vapor degassing step arranged prior to the drawing step using the die (JP-A-4-305439) and a method of removing bubbles by using a plurality of divided paths for passing forming materials arranged at an inlet side of the die (JP-A-7-117141).

[0006] The known methods mentioned above can show a sufficient corrosion resistivity and mechanical properties required for a general construction member. However, when the inventors used the thus obtained FRP as the core member of the polymer insulator for a high voltage electric insulation member, it was found that there is a problem such that an electric insulation breakage property is not sufficient. After examining the FRP in detail, it was found that a plurality of invisible slender micro-gaps are generated in the FRP and those micro-gaps affect the electric insulation breakage property. Moreover, if the slender micro-gaps remain in and between single fibers, the fibers including air are supplied into the die. In this case, it was found that the electric insulation property is affected since such an air is extended in or between the fibers when the fibers shrink at the inlet of the die.

SUMMARY OF THE INVENTION

[0007] An object of the invention is to eliminate the drawbacks mentioned above and to provide a method of manufacturing fiber reinforced plastics which can obtain FRP preferred for high voltage electric insulation member such as insulator or the like.

[0008] According to the invention, a method of manufacturing fiber reinforced plastics by means of a drawing method having the steps of immersing resins into fibers for reinforcing aligned in one direction, which are supplied continuously, and curing the resins immersed in the fibers by drawing the fibers into a die, comprises a step of: moving the fibers in a resin supply zone at a substantially same speed as that of resin immersing in the fibers along a direction in which the fibers are aligned.

[0009] In the present invention, the fibers for reinforcing, which are a gathering member of plural single fiber, are moved in the resin supply zone at a substantially same speed as that of resin immersion in the fibers along the direction in which the fibers are aligned. Therefore, it is possible to manufacture the FRP with no bubbles in the fibers for reinforcing. As a result, it is possible to obtain the FRP preferred as the high voltage electric insulation member such as insulator or the like. In the present invention, a term “immersing speed” means generally a moving speed based on a capillary motion of resins in and between single fibers for reinforcing. When the fibers for reinforcing are compressed by a roller during the resin immersing step or when a plurality of fibers for reinforcing, to which resins are immersed, a term “immersing speed” means total speeds of the above moving speed based on the capillary motion and a resin moving speed due to the mechanical compression of the fibers for reinforcing.

BRIEF DESCRIPTION OF THE DRAWINGS

[0010] FIG. 1 is a schematic view showing one embodiment of a method of manufacturing fiber reinforced plastics according to the invention;

[0011] FIG. 2 is a schematic view illustrating one preferable embodiment of the method shown in FIG. 1;

[0012] FIG. 3 is a schematic view depicting another embodiment of the method of manufacturing fiber reinforced plastics according to the invention;

[0013] FIG. 4 is a schematic view for explaining an immersing speed of resins in the fibers for reinforcing; and

[0014] FIG. 5 is a schematic view showing one preferable embodiment of an arrangement of resin supply tubes.

DESCRIPTION OF THE PREFERRED EMBODIMENT

[0015] FIG. 1 is a schematic view showing one embodiment of a method of manufacturing fiber reinforced plastics according to the invention. In the embodiment shown in FIG. 1, a numeral 1 is fibers for reinforcing before a resin immersing step, which are plural single fibers are gathered. Numerals 2-1, 2-2 and 2-3 are guides for introducing the fibers 1 into a resin supply zone. A numeral 3 is an immersing tank forming the resin supply zone. A numeral 4 is resins for immersing maintained in the immersing tank 3. In this embodiment, only the resin supply zone is shown. FRP is manufactured according to a drawing method by supplying the fibers 1, in which resins are immersed in the resin supply zone, into a die not shown before the resins are hardened, and curing the resins in the fibers 1 in the die.

[0016] A feature of the present invention is that the fibers 1 for reinforcing are moved in the resins 4 in the immersing tank 3 forming the resin supply zone in such a manner that a moving speed V1 of the fibers 1 is substantially equal to an immersing speed V2 of the resins 4 along a direction in which the fibers 1 are aligned. That is to say, the moving speed V1 of the fibers 1 is controlled in such a manner that V1 is substantially equal to V2. In this embodiment, the immersing speed V2 is a moving speed based on a capillary motion of the resins 4 immersed in the fibers 1.

[0017] Plural fibers 1, in which the resins 4 are immersed according to the method mentioned above, are gathered in the die before the resins 4 are hardened. In this case, it is possible to gather the plural fibers 1 in the die in such a manner that bubbles are removed from the resins 4 in the fibers 1. Therefore, it is possible to manufacture the FRP in which no bubbles remain.

[0018] FIG. 2 is a schematic view showing one preferable embodiment of the method of manufacturing fiber reinforced plastics according to the invention. In the embodiment shown in FIG. 2, portions similar to those in FIG. 1 are denoted by the same reference numerals as those in FIG. 1, and the explanations thereof are omitted here. In the embodiment shown in FIG. 2, a pair of rollers 11-1 and 11-2 for compressing the fibers 1 are arranged in the resins 4 in the immersing tank 3 forming the resin supply zone at a vicinity of an inlet of the fibers 1. As shown in FIG. 4, if the fibers 1, in which the resins 4 are immersed, are compressed, the resins 4 are extruded in the fibers 1 along the same direction as that of a resin moving due to a capillary motion. Therefore, the immersing speed V2 of the resins 4 in the fibers 1 can be made faster by the extruded resins 4. As a result, it is possible to set the moving speed V1 of the fibers 1 faster, and thus a productivity of the FRP can be improved.

[0019] In the embodiment shown in FIG. 2, it is necessary to arrange the rollers 11-1 and 11-2 in the resins 4 in the immersing tank 3 at a vicinity of an inlet of the fibers 1. The reasons for limiting the roller arranging position are as follows. That is to say, if the resins 4 is not immersed in the fibers 1, an effect of compression cannot be obtained. In addition, if the compression is performed after a long time from immersing start of the resins 4, the immersing speed V2 cannot be made faster.

[0020] FIG. 3 is a schematic view showing another embodiment of the method of manufacturing fiber reinforced plastics according to the invention. In the embodiment shown in FIG. 3, plural fibers 1 are directly introduced into a die 21 as a bundle of the fibers 1, the resins 4 are immersed in the fibers 1 at an inlet 21a of the die 21 continuously. That is to say, a plurality of resin supply tubes 22 are arranged in the bundle of the fibers 1 aligned in one direction at the inlet 21a of the die 21, and an amount of resins supplied from the resin supply tubes 22 is controlled in accordance with a drawing speed i.e. a moving speed of the bundle of the fibers 1. In this embodiment, when the bundle of the fibers 1 is supplied into the die 21, a compression is applied to the bundle of the fibers 1 by the die 21, and the die 21 serves as the rollers shown in FIG. 2. Therefore, it is possible to improve a productivity as is the same as the embodiment shown in FIG. 2.

[0021] Then, a control of an amount of the resins 4 supplied from the resin supply tubes 22 will be explained. At first, as shown in FIG. 4 which shows an embodiment in which four resin supply tubes 22 are used, an immersing speed V11 of the resins 4 due to a capillary motion in respective fibers 1 and between the fibers 1 along a direction, in which the fibers 1 are aligned, is measured previously by supplying a constant amount of resins 4 from a tip of the resin supply tubes 22 arranged in the bundle of the fibers 1 which are not moved. In this case, the resins 4 are immersed also in a direction perpendicular to the fiber aligned direction mentioned above at an immersing speed V12 which is slower than the immersing speed V11. The immersing speed V2 of the resins 4 which is used for controlling is determined from the immersing speed V11 in consideration of an effect of compression by the die 21. Then, in an actual manufacturing according to the invention, since the moving speed V1 of the bundle of the fibers 1 can be known, an amount of the resins 4, at which the thus determined immersing speed V2 is substantially equal to the known moving speed V1, is determined, and the resins 4 are supplied from the resin supply tubes 22 at the thus determined amount of the resins 4.

[0022] In the embodiment shown in FIG. 3, a plurality of the resin supply tubes 22 are arranged. The reasons are as follows. That is to say, as shown in FIG. 4, the immersing speed of the resins 4 supplied in the bundle of the fibers 1 is fast along the direction in which the fibers 1 are aligned (V11) and is slow along the direction perpendicular to the fiber aligned direction (V12). Therefore, a plurality of the resin supply tubes 22 are preferably used so as to immerse the resins 4 uniformly in respective fibers 1 and between the fibers 1. Moreover, as an arrangement of the resin supply tubes 22, as shown in FIG. 5 illustrating a cross section of the die 21, if a plurality of the resin supply tubes 22 are arranged at symmetric positions around a center axis O of the die 21, the resins 4 are uniformly immersed in respective fibers 1 and between the fibers 1, and thus it is a preferred embodiment.

[0023] As clearly understood from the above explanations, according to the invention, since the fibers for reinforcing, which are a gathering member of plural single fiber, are moved in the resin supply zone at a substantially same speed as that of resin immersion in the fibers along the direction in which the fibers are aligned, it is possible to manufacture the FRP with no bubbles in the fibers for reinforcing. As a result, it is possible to obtain the FRP preferred as the high voltage electric insulation member such as insulator or the like.

Claims

1. A method of manufacturing fiber reinforced plastics by means of a drawing method having the steps of immersing resins into fibers for reinforcing aligned in one direction, which are supplied continuously, and curing the resins immersed in the fibers by drawing the fibers into a die, comprising a step of: moving the fibers in a resin supply zone at a substantially same speed as that of resin immersing in the fibers along a direction in which the fibers are aligned.

2. The method according to

claim 1, wherein a roller for compressing the fibers is arranged in the resin supply zone at a vicinity of an inlet of the fibers.

3. The method according to

claim 1, wherein a plurality of resin supply tubes are arranged in a bundle of the fibers aligned in one direction at the inlet of the die, and, an amount of resin supplied from the resin supply tubes is controlled in accordance with a moving speed of the bundle of the fibers.

4. The method according to

claim 3, wherein the resin supply tubes are arranged at symmetric positions around a center axis of the die.