Apparatus and method for top removal of granular material from a fluidized bed deposition reactor
Removal of the product from the top of the reactor enables a decreased disengaging height and provides a passive means of controlling the bed level despite deposition increasing the weight and height of the bed. The savings from reducing the disengaging height allow use of a taller fluidized bed in a shorter overall reactor length and thus provides increased production with reduced reactor cost. The separation of the gas inlet from the product outlet allows the gas inlet area to be cooler than the product outlet. The separation of the product grinding, caused by the inlet gas, from the product outlet reduces the loss of seed in the product and produces a more uniform product. Removing the hot product and the hot gas at the same place allows energy recovery from both in a single step.
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BACKGROUND OF THE INVENTIONThis invention relates generally to the field of deposition reactors and more specifically to an apparatus and method for top removal of granular material from a fluidized bed deposition reactor.
Fluidized bed reactors have a long tradition in the chemical industry where the bed usually consists of a finely divided valuable catalyst which makes it necessary to design the reactors to prevent catalyst losses. Thus was developed the practice of requiring a large disengaging height above the bed surface and of using cyclones to capture the fine dust and return it to the bed. A concept called total disengaging height, or TDH, was developed to estimate the height where all the particles that would settle out by gravity had settled out. Internal cyclones were provided at this height to capture the finer dust and return it to the bed. Whenever the catalyst was removed it was removed from the bottom by gravity. Other reactors called dilute phase or transport reactors entrained all the solids up through the reactor and out the top, but these reactors did not have a recognizable bed. When these gas-solids reactor concepts were applied to the design of deposition reactors where gases are introduced to make the bed particles grow, the dilute phase reactor had the major problem that it produced mainly a fine dust which was undesirable. Thus the majority of deposition reactors have been fluidized beds and so the basic design of fluidized beds with a large disengaging height and bottom solids outlet has been used. The idea of internal cyclones has seldom been used because of the deposition on the outside of the cyclones and the problems of reintroducing particles without plugging the cyclone outlets. Since some fine dust is always made, most deposition reactors have external cyclones or filters to trap the dust and prevent damage to the equipment used to recover the effluent gases. Thus the historic approach has been to have removal of the product from the bottom, provide a large disengaging height to minimize product loss, and use external dust removal. The primary use for deposition reactors is in high purity silicon deposition and Lord in U.S. Pat. No. 6,451,277 in
The primary deficiency of the prior technology is staying with the inherited fluid bed design of a bottom outlet and large disengaging space and accepting the inherent conflicting demands caused by introducing the cold deposition gas, which also provides the bulk of the seed generation by grinding, at the same location as the hot product was removed. Lord in various patents attempts to deal with the heat and seed generation problem by spreading out the gas injection, but sufficient gas to fully fluidize the bed must be injected at the bottom, so there is a limit to what can be accomplished in this manner. Inevitably the bottom temperature must be maintained above 800° C. to provide the needed crystallization, and some seeds are lost to the product which is in turn contaminated with broken “seed beads.” The combination of high temperature and high deposition gas concentration leads to rapid reactions, increased wall deposits and increased risk of agglomeration and plugging.
This multistage design approach also leads to tall reactors and there are cost and manufacturability issues in producing the high purity liners for such reactors which restrict the number of stages and hence production capacity of a given diameter reactor. It is also necessary to measure the bed level and take corrective action by removing some of the bed as the bed grows by opening valves and changing purge flows to allow the right amount of beads to leave the bed. Errors or stuck valves can lead to situations where the bed is too high or too low. Both of these conditions are undesirable upsets.
BRIEF SUMMARY OF THE INVENTIONThe primary object of the invention is to provide a shorter reactor with greater production.
Another object of the invention is to provide a passive method of level control.
Another object of the invention is to provide a better quality product.
A further object of the invention is to reduce the need for high temperature at the bottom of the reactor.
Yet another object of the invention is to reduce the risk of plugging.
Still yet another object of the invention is to reduce the thickness of wall deposits.
Another object of the invention is to reduce the pressure in the product removal system.
Another object of the invention is to recover energy.
Other objects and advantages of the present invention will become apparent from the following descriptions, taken in connection with the accompanying drawings, wherein, by way of illustration and example, an embodiment of the present invention is disclosed.
In accordance with a preferred embodiment of the invention, there is disclosed an apparatus and method for top removal of granular material from a fluidized bed deposition reactor comprising: removal of the product from the top of the reactor together with the effluent gas, separation of the granular product from the effluent gas, simultaneous recovery of heat from the product and the gas and optional further dust and heat recovery.
The technical benefits of this design are passive level control, decreased disengaging height, taller fluidized bed in a shorter reactor, separation of gas inlet from product outlet, separation of product grinding from product outlet and energy recovery which in turn lead to lower capital and operating cost, a better quality product and greater throughput for a given reactor diameter.
BRIEF DESCRIPTION OF THE DRAWINGSThe drawings constitute a part of this specification and include exemplary embodiments of the invention, which may be embodied in various forms. It is to be understood that in some instances various aspects of the invention may be shown exaggerated or enlarged to facilitate an understanding of the invention.
Detailed descriptions of the preferred embodiments are provided herein. It is to be understood, however, that the present invention may be embodied in various forms. Therefore, specific details disclosed herein are not to be interpreted as limiting, but rather as a basis for the claims and as a representative basis for teaching one skilled in the art to employ the present invention in virtually any appropriately detailed system, structure or manner.
Turning first to
In accordance with the present invention,
To accomplish the removal of large granules the average top level, 222, is very close to the gas/dust/granular mixture exit, 216, and consequently some of the product granules, 236, thrown up above the bed do not describe arcs as they rise then fall under gravity in the disengaging space, 224, but continue with the entrained dust, 225, out the gas/dust/granular mixture exit, 216. Since the average bed level, 222, is closer to the exit, 216, the bed level, 222, can be taller and/or the overall height, 244, can be shorter compared to the prior art as shown in
Turning to
Turning now to
The heat recovery system, 301, is comprised of a heat transfer fluid, 360, contained in a container, 351, which is shaped to capture heat, 350, from the wall of the product separator and has an inlet, 354, and an outlet, 355, for the heat transfer fluid, 360. The container can use various heat transfer fluids such as water or hot oil. It is usually advantageous for the container to be a pressure vessel to permit heat recovery at higher temperatures. The heat may be transferred from the wall to the container by radiation, conduction or convection and well-known heat transfer techniques can be used to enhance the heat transfer from the gas and solids to the wall. Similarly, well-known gas-solids removal techniques, such as cyclones or filters, can be used to enhance the gas-solids separation.
In a particularly advantageous design, the heat is transferred by radiation from the hot surface of the product separator to a pressurized container which has water, 352, coming in through the inlet, 354, and steam, 353, leaving through the exit, 355.
An example using
In comparison, for
The granules and gas at the bottom of the reactor are at 700° C., then are heated up and leave the reactor as stream, 233, via exit, 216, at a temperature of 800° C. They enter the cyclonic product separator, 230, through a tangential inlet which forces the gas and solids to the wall of the vessel to improve gas to wall heat transfer. The diameter of the cyclone is 10 inches (250 mm) and the length is 6 ft (1.8 m). This is longer than needed for solely the solids removal in order to provide sufficient surface area for heat transfer. The gas and granules both leave at 600° C. The dust/gas separator, 217, is of a similar size but only removes about half the heat because of the reduction in the temperature difference. The gas and dust then leave the dust/gas separator at 500° C. Both heat recovery systems recover the heat as 150 psig steam, which is a standard utility useful in the facility for a variety of purposes and thus always in demand.
While the invention has been described in connection with a preferred embodiment, it is not intended to limit the scope of the invention to the particular form set forth, but on the contrary, it is intended to cover such alternatives, modifications, and equivalents as may be included within the spirit and scope of the invention as defined by the appended claims.
Claims
1. An apparatus and method of operation for top removal of granular material from a fluidized bed deposition reactor comprising:
- a container of a set height with at least one gas inlet at or near the bottom and at least one gas and solids outlet at or near the top,
- a bed of granular particles of variable height which is fluidized and deposited on by a gas flow,
- a gas/granular product separator means and
- a method of operation where the height of the bed of granular particles is allowed to increase until it reaches a stable height.
2. An apparatus for recovering heat while separating the granular product comprising: one or more product separator means and one or more heat recovery means.
3. An apparatus of claim 1 where at least one means for granular product removal is also provided at the bottom.
4. An apparatus of claim 2 where at least one of the heat recovery means is primarily by radiation to a heat recovery boiler.
5. An apparatus of claim 2 where more than one separator means are used to provide more than one product streams of different average particle size.
Type: Application
Filed: Jun 4, 2007
Publication Date: Dec 4, 2008
Inventor: Stephen Michael Lord (Encinitas, CA)
Application Number: 11/810,422
International Classification: F27B 15/09 (20060101);