Process for producing metallic ultrafine powder
A process for producing metallic ultra-fine powder, which can use a raw material which is spread over a wide range, and control freely the grain size of the metallic powder to be produced, at low cost and high safety. The process for producing the metallic ultra fine powder consists of using a burner and a furnace which can generate a high temperature reductive atmosphere, and an apparatus for separating gas which is generated in the furnace from powder to recover the powder. The burner has a function of blowing a powdery metallic compound as a raw material into a high temperature reductive flame. The raw material powder is efficiently heated in airflow of a high temperature reductive flame, thereby being reduced rapidly into metallic ultra-fine powder. At this time, the grain size of the metallic ultra-fine powder is controlled by adjusting the oxygen ratio (i.e. the ratio of amount of the burning-assist gas supplied to the burner to the amount of the burning-assist gas required for completely burning the fuel).
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This application is a divisional application of U.S. Ser. No. 11/793,424 filed Jun. 20, 2007, which in turn is the U.S. national phase of International Application No. PCT/JP2005/023618 filed 22 Dec. 2005, which designated the U.S. and claims priority to JP 2004-370893 filed 22 Dec. 2004, the entire contents of each of which are hereby incorporated by reference.
TECHNICAL FIELDThe present invention relates to a process for producing metallic ultra-fine powder, for obtaining metallic ultra-fine powder having controlled grain size from a metallic compound in a high temperature reductive atmosphere using a burner, a burner for producing metallic ultra-fine powder, and an apparatus for producing metallic ultra-fine powder.
Priority is claimed on Japanese Patent Application No. 2004-370893, filed Dec. 22, 2004, the content of which is incorporated herein by reference.
BACKGROUND ARTIn recent years, the needs to lower the grain size of metallic powders used in electronic parts are increasing with the advance of miniaturization of the electronic parts used in portable terminals, etc. Nickel ultra-fine powder used for laminated ceramic capacitors are exemplary. As a process for producing nickel ultra-fine powder, there is a method including the step of heating and evaporating a chloride raw material having a high vapor pressure within a CVD apparatus, and further supplying hydrogen gas as a reducing agent into the apparatus to reduce the raw material, thereby producing metallic nickel ultra-fine powder having a grain size of not larger than 1 μm.
Such a production method is recognized to be suitable for producing fine powder, because in the method the raw material is evaporated to be reduced and deposited at a relatively low temperature of approximately 1000° C. (i.e. not higher than the melting point of nickel). However, since such a method uses a CVD apparatus, it necessitates expensive electrical energy to heat the raw material, and since the method uses expensive hydrogen as a reductive gas, it is costly. Moreover, since the method is reductive reaction of a chloride by hydrogen, there is a problem that it necessitates costly equipment in which the possibility of corrosion, leaks and the like of the apparatus is properly addressed, because poisonous gases such as chloride gas and hydrogen chloride gas are generated in a furnace, as is disclosed in Patent Document 1 (Japanese Unexamined Patent Application, First Publication No. H04-365806).
On the other hand, there is a method for producing iron fine powder which includes burning a hydrogen-containing fuel with an oxygen-containing gas using a burner, and supplying vaporized iron chloride into the flame to cause high-temperature hydrolysis, thereby producing iron fine powder, as is disclosed in Patent Document 2 (Japanese Unexamined Patent Application, First Publication No. Showa 56-149330). This method is relatively low cost, because it does not use costly electrical energy to control the atmosphere of the reductive reaction field, and further it necessitates no hydrogen gas. However, similarly to the above method, it necessitates countermeasures against generation of chloride gas and hydrogen chloride, because the method uses chloride as a raw material. Moreover, the metallic powders which are produced have a grain size which diverges widely from 40 to 80 μm, and hence there is a problem in the controllability of grain size. Moreover, there is a problem in that it is not suitable for producing ultra-fine powder having a grain size of not higher than 1.0 μm, which meets the needs people have these days.
With all of the above-mentioned conventional technology, it is necessary to use a chloride having a high vapor pressure for producing metallic powder particularly fine powder, and hence the form of raw material is restricted.
The present invention was made in view of the above circumstances, and it is an object of the present invention to provide a process for producing metallic ultra-fine powder, which makes it possible to use a raw material which is spread over a wide range, freely control the grain size of the metallic powder to be produced, and reduce the grain size to be not higher than 1/10 of that of the raw material in the case in which the raw material is a powdery one, at low cost and with high safety.
DISCLOSURE OF INVENTIONThe first aspect of the present invention is a process for producing metallic ultra-fine powder comprising jetting a powdery metallic compound into a high temperature reductive airflow generated in a furnace by a burner to heat and reduce said metallic compound, thereby forming spherical metallic ultra-fine powder having a controlled grain size.
The grain size of the above spherical metallic powder may be controlled by adjusting the oxygen ratio of the burner.
The grain size of the above metallic ultra-fine powder can be lowered to be smaller than the grain size of a raw material. The grain size of the above metallic ultra-fine powder can be lowered to be not larger than 1/10 of the grain size of the raw material.
The above high temperature reductive atmosphere (airflow) may be generated using a hydrocarbon type fuel in gaseous or liquid form with oxygen or oxygen-enriched air. The above metallic compound is preferably a substance other than chloride. The grain size of the above metallic ultra-fine powder can be also controlled by way of the temperature in the furnace.
The second aspect of the present invention is a process for producing metallic ultra-fine powder including atomizing a solution of a compound which contains a metallic element of a raw material and puffing it into a furnace in which a high temperature reductive airflow is generated by partially burning a fuel which is supplied from a burner, to heat, decompose and reduce the metallic compound, thereby forming spherical metallic ultra-fine powder having controlled grain size. The above solution may be atomized from the burner into the furnace.
In the above process, the above solution may be an organic solvent, and the solution can be atomized as a fuel for the burner to be partially burned, thereby generating a high temperature reductive atmosphere (airflow) to form spherical metallic ultra-fine powder.
The third aspect of the present invention is metallic ultra-fine powder produced by any of the processes for producing metallic ultra-fine powder as set forth in the above.
The fourth aspect of the present invention is a burner which generates a high temperature reductive airflow from a fuel fluid and oxygen or oxygen-enriched air to reduce a metallic compound, thereby producing metallic ultra-fine powder having a grain size smaller than the grain size of a raw material, including:
a raw material jetting hole for jetting a metallic compound as a raw material in a direction, with a fuel fluid as a carrier gas,
plural primary oxygen jetting orifices disposed circularly around a center of the raw material jetting hole, for jetting of oxygen or oxygen-enriched air parallel to said direction of jetting the raw material, and
plural secondary oxygen jetting orifices disposed circularly around a center on the raw material jetting hole and outward from the primary oxygen jetting orifices, for jetting oxygen or oxygen-enriched air toward a point on a line extended from the raw material jetting hole and parallel to the direction of jetting of said raw material.
The above raw material jetting hole, primary oxygen jetting orifices, and secondary oxygen jetting orifices have different fluid supply channels, and hence the jetting amount of each fluid can be controlled independently.
In the above burner for producing metallic ultra-fine powder, the above career gas may be air, oxygen, oxygen-enriched air, or an inert gas such as nitrogen. In this case, fuel jetting orifices for supplying a fuel fluid are disposed separately.
The fifth aspect of the present invention is a burner which generates a high temperature reductive airflow from an organic solvent and oxygen or oxygen-enriched air to reduce a metallic compound, thereby producing metallic ultra-fine powder, including:
a raw material atomizing hole for atomizing and jetting a liquid raw material containing a metallic compound dissolved in an organic solvent,
plural primary oxygen jetting orifices disposed circularly around a center of said raw material atomizing hole, for jetting oxygen or oxygen-enriched air parallel to a center line of the raw material atomizing hole, and
plural secondary oxygen jetting orifices disposed circularly around a center of the raw material atomizing hole and outward from the primary oxygen jetting orifices, for jetting oxygen or oxygen-enriched air toward a point on a line extended from the raw material atomizing hole and parallel to the center line of the raw material atomizing hole.
In the above burner for producing metallic ultra-fine powder, when the liquid raw material contains no organic solvents, it is possible to further dispose plural fuel jetting orifices circularly around a center of the raw material atomizing hole, between the above raw material atomizing hole and the above primary oxygen jetting orifices, for jetting the fuel parallel to the center line of the raw material atomizing hole.
The sixth aspect of the present invention is an apparatus for producing metallic ultra-fine powder including a furnace part for performing heat treatment of a raw material in an oxidation-reduction atmosphere, the burner as set forth in the above fourth aspect or fifth aspect of the present invention, disposed in said furnace part, for jetting a fuel, oxygen or oxygen-enriched air, with a raw material toward said furnace part, a fuel supply system for supplying a fuel to said burner, a raw material supply system for supplying a raw material to said burner, and a cooling gas supply system for supplying a cooling gas to said furnace part.
In the above apparatus for producing metallic ultra-fine powder, the cooling gas supply system further includes a gas supplying apparatus for controlling temperature.
The present invention consists of a burner and a furnace which can generate a highly reductive atmosphere (airflow), and an apparatus which separates the gas generated from the furnace and powder to recover the powder (for example, a bag filter). The burner is directly linked to the furnace and which forms a high temperature reductive atmosphere (flame) within the furnace using a burning-assist gas in an amount which is smaller than the amount which is necessary to perform perfect combustion of a fuel, with a fuel.
In addition, the burner has a function of blowing the powdery metallic compound used as a raw material into a high temperature reductive flame. By this, the raw material powder is efficiently heated in the airflow of a high temperature reductive flame, thereby being reduced at high speed into metallic ultra-fine powder. At this time, the grain size of the metallic ultra-fine powder can be controlled by adjusting the oxygen ratio (i.e. the ratio of amount of the burning-assist gas supplied to the burner to the amount of the burning-assist gas required for completely burning the fuel).
The grain size of the metallic powder generated can be lowered to smaller than the grain size of the raw material by increasing the oxygen ratio, whereas the grain size of the metallic powder generated can be increased to be larger than the grain size of the raw material by decreasing the oxygen ratio.
Furthermore, the present invention is characterized by using a fuel, which contains hydrocarbon, in a gaseous or a liquid form, as a fuel for the burner for forming a high temperature reductive atmosphere (airflow), as well as an oxygen-enriched air having oxygen concentration of 50% or more or pure oxygen as a burning-assist gas.
It is possible to generate hydrogen and carbon monoxide by partially oxidizing a hydrocarbon type fuel, and the heating and reductive reaction can be performed at high speed in the high temperature highly reductive atmosphere (airflow) by using a burning-assist gas.
Moreover, the raw material is characterized by using a metallic compound other than a chloride. Becaused of this, it becomes possible to produce metallic ultra-fine powder, without generating substances which contain chlorine in exhaust gas, thereby increasing the safeness of the apparatus.
The present invention is a process which performs a treatment using a high temperature reductive atmosphere (airflow) which is formed by a burner without using electric energy, and which makes it possible to decrease energy cost, and to enlarge the apparatus easily, compared to conventional methods using electrically heating and heating from outside such as CVD, thereby increasing productivity.
In accordance with the present invention, it is possible to produce metallic fine powder with high productivity, and low energy cost, corresponding to various kinds of raw materials. Moreover, the present invention excels in safety, without generating harmful chlorine gas. Furthermore, the present invention can be applied to metals such as copper, cobalt, etc., in addition to nickel.
As an example of the present invention, a process for producing nickel ultra-fine powder from nickel oxide powder will be explained in detail below.
ExampleA schematic diagram which shows the constitution of the apparatus for producing metallic ultra-fine powder of this example is shown in
The apparatus for producing metallic ultra-fine powder 100 used in this example consists of a feeder 1 for conveying a raw material, a burner 2 and a furnace 3a for forming a high temperature reductive atmosphere (airflow), a bag filter 4b for separating the fine powder and exhaust gas from each other, and a blower 5 for absorbing gas. In the furnace 3, the circumference part of the burner 2 is constituted from refractories and the downstream part behind the middle of the furnace 3 is constructed to be water-cooled furnace wall structure. Moreover, a thermocouple is installed in the refractory wall of the furnace 3, so that the temperature within the furnace wall can be measured.
Moreover, a cooling gas supplying pipe 6 is embedded under the inner wall surface of the furnace 3, so that a cooling gas, for example an inert gas such as nitrogen gas, can be supplied in the tangential direction of the inner wall surface, therethrough. Moreover, a cooling gas supplying apparatus 7 is disposed for this cooling gas supplying pipe 6, and the temperature in the furnace can be controlled by adjusting the flow rate of the cooling gas which is supplied to the cooling gas supplying pipe 6 and measuring the temperature of the portion around the wall surface of the furnace 3. It should be noted that the cooling gas supplying pipe 6 and the cooling gas supplying apparatus 7 can be left out.
The metallic fine particles used as raw material are quantitatively sent out by the feeder 1, and then conveyed by the carrier gas, thereby being supplied to the burner 2. In this example, as the carrier gas, the fuel gas which is burned in the burner 2 is used.
The structure of the tip part 20 of the burner 2 used in this example is shown in
In this example, although fuel gas is used as a carrier gas for powders, in the case in which dedicated channels and dedicated jetting orifices are prepared for the fuel gas, powder may be conveyed by another gas such as air. Moreover, in this example, although the primary oxygen and the secondary oxygen are jetted through multiple holes, another way can be used as long as it can make the gas jet so as to involve the fuel gas and the raw material powdery flow, and one having a slit-like shape may be used.
Moreover, in this example, although the raw material powder channel 11 is constituted from one hole, it is also effective to design so that the raw material powder is jetted from plural holes (multiple holes). Moreover, in this example, the primary oxygen is jetted as a swirl flow, and the secondary oxygen is jetted as an inclined flow (inclined straight flow). The length of flame which is formed immediately after the burner can be controlled by suitably adjusting the flow rates of the fuel, the primary oxygen, and the secondary oxygen. By jetting the raw material into this flame, the raw material can be thermally treated and then cooled in the furnace, thereby being pulverized.
By adjusting the flow rates of the fuel, the primary oxygen, and the secondary oxygen, the jetting rate of the raw material, and the flow rate of the coolant gas which flows into the furnace, the length of flame and the time for which the raw material is in contact with the flame change, thereby changing the grain size of the fine powder finally obtained.
It should be noted that the way of jetting is not particularly limited, and it is possible to select proper flow and combine, based on the way of jetting the powder and the fuel gas.
In this example, two routes consisting of the primary oxygen channel 21 and the secondary oxygen channel 31 are formed as channels for burning-assist gas. If plural channels are formed, then the length of flame can be changed by changing the ratio therebetween, and hence it becomes an effective means for controlling the above grain size.
Experimental conditions, such as flow rate of a fuel fluid (LPG), flow rate of oxygen, flow rate ratio between the primary oxygen and the secondary oxygen, oxygen ratio, and LPG raw material supplying amount, are shown in Table 1.
It should be noted that example was performed under conditions that as the raw material powder a pure nickel oxide (nickel purity of 78.6%) having a grain size of approximately 1 μm was used, and the temperature of the circumference of the burner 2 was maintained at 1500 to 1600° C. (not lower than the melting point of metallic nickel).
An SIM (Scanning Ion Microscope) image of the external appearance of the powder as the product (nickel ultra-fine powder) under the condition that the oxygen ratio was 0.6 is shown in
An SIM image of the product under the condition that the oxygen ratio was 0.8 is shown in
An SIM image (inclined by 60°) of the cross-section of the product (nickel ultra-fine powder) under the condition that the oxygen ratio was 0.8 is shown in
Grain-size-distribution measurement (micro track: a laser diffracting and scattering method) was performed on the raw material powders and the product. The result is shown in
The grain size distribution of the raw material powder has a peak at approximately 1 μm, whereas the grain-size-distribution of the product has a peak at approximately 4 μm, in the case in which the oxygen ratio is 0.6, revealing that it is larger than the grain size of the raw material powder. On the other hand, in the case in which the oxygen ratio is 0.8, it shows a distribution which has a peak at approximately 0.15 μm, and this reveals that grain size could be controlled by changing the oxygen ratio.
It should be noted that in this example, although nickel oxide was used as the raw material, the invention is applicable to other metallic compounds, such as nickel hydroxide.
Example 2An experimentation of forming spherical fine powder of metallic nickel was performed, using powdery nickel oxide and nickel hydroxide as raw materials, the burner tip part 20 having the shape shown in
It was confirmed that spherical ultra-fine powder of metallic nickel could be formed within the range of the experimental conditions shown in Table 2. Moreover, it is revealed that the grain size can be controlled by changing the oxygen ratio in the furnace, the primary/the secondary oxygen ratio, the oxygen concentration in the burning-assist gas, the ratio of the fuel to the raw material, the jetting rate of the gaseous mixture of the raw material and the fuel, the jetting rate of oxygen, the swirling strength of the primary oxygen, the temperature of atmosphere in the furnace, etc.
An example of a scanning electron microscope photograph (SEM (Scanning Electron Microscope) picture) of the spherical fine powder obtained using nickel hydroxide having an average grain size of 10 μm as a raw material is shown.
The influence on the grain size of the spherical fine powder which is given by the temperature in the furnace is shown. In the apparatus for producing metallic ultra-fine powder shown in
When nitrogen gas was not supplied, the temperature in the furnace became approximately 1600° C., and spherical fine powder having an average grain size of 0.4 μm was obtained. When nitrogen gas was supplied at a flow rate of 288 Nm3/h, the temperature in the furnace decreased to approximately 500° C., and spherical fine powder having an average grain size of 0.2 μm was obtained. An SEM image of the spherical fine powder obtained in the case in which nitrogen gas was not supplied is shown in
The relationship between the oxygen ratio of the burner (i.e. the ratio of supplied quantity of oxygen to the quantity of oxygen which is equivalent to the quantity required for burning a fuel perfectly) and the metallization percentage was investigated, using nickel oxide and nickel hydroxide as raw materials. The relationship between the oxygen ratio of the burner and the metallization percentage is shown in
Moreover, although a hydrocarbon type fuel was used as a fuel in this example, in the case in which it will become a problem for soot to remain in the produced fine powder, the problem can be easily resolved by using hydrogen as a fuel.
Example 5An experiment for obtaining ultra-fine grains of metallic nickel was performed, using an aqueous solution raw material in which nickel nitrate was dissolved in water, an organic solution of raw material in which nickel nitrate was dissolved in an organic solvent such as methanol, etc.
Examples of the structure of the burner tip part used when using liquid raw materials, such as an aqueous solution raw material or an organic solution of raw material, are shown in
In the burner tip part 210 shown in
The secondary oxygen jetting orifice 218 formed at the end of the secondary oxygen channel 217 is aslant formed to the center line of the burner tip part 210, and the plural secondary oxygen jetting orifices 218 are formed inclined to the direction toward a point on a line extended from the center line of the burner tip part 210.
In the burner shown in
As shown in
On the other hand, the secondary oxygen jetting orifice 228 formed at the end of the secondary oxygen channel 227 is aslant formed to the center line of the burner tip part 220, and the plural secondary oxygen jetting orifices 228 are formed inclined to the direction toward a point on a line extended from the center line of the burner tip part 220.
Although the above liquid raw material is atomized into a mist by compressing atomization, it is also possible to perform atomization by double fluid atomization using compressed air or steam or an ultrasonic nebulizer, instead of using compressing atomization.
In the case of an aqueous solution a raw material, by the flame which is formed outer periphery thereof, whereas in the case of an organic solvent raw material, by the flame derived from the raw material fluid itself, the atomized raw material is thermally treated rapidly. Although the way of jetting a burning-assist gas (in this case, oxygen) and a fuel is almost the same as in the case of using powdery raw material above, it is possible to adopt various jetting forms in order to form a flame which is capable of involving the raw material.
An experiment was performed, using two kinds of burners each consisting of the apparatus shown in
An SEM image of the formed metallic ultra-fine powder is shown in
Also when using a liquid raw material, as described in Example 3, grain size can be controlled freely by controlling the temperature in the furnace. Furthermore, nickel element concentration and the diameter of atomized grain can also serve as a grain-size-controlling factor.
Moreover, it is also possible to increase nickel concentration in a solution to increase productivity by heating an aqueous solution raw material and an organic solvent raw material. Moreover, the solute is not limited to nitrate, and what is required for the solute is that it be soluble in water or an organic solvent, and contain the target metallic element.
Moreover, it is also possible to use an organic metallic compound which contains the target metallic element. Furthermore, the target metallic elements are not restricted to nickel, and it is possible to include any appropriate metal such as copper, cobalt, etc.
While preferred embodiments of the present invention have been described and illustrated above, it should be understood that these are exemplary of the invention and are not to be considered as limiting. Additions, omissions, substitutions, and other modifications can be made without departing from the spirit or scope of the present invention. Accordingly, the invention is not to be considered as being limited by the foregoing description, and is only limited by the scope of the appended claims.
The present invention can be applied to the production of metallic ultra-fine powder, and is capable of using a wide spread raw material, and controlling freely the grain size of metallic powder to be formed, with low cost and excellent safety.
INDUSTRIAL APPLICABILITYThe present invention is applicable to a process for producing metallic ultra-fine powder, for obtaining metallic ultra-fine powder having controlled grain size from a metallic compound in a high temperature reductive atmosphere using a burner, a burner for producing metallic ultra-fine powder, and an apparatus for producing metallic ultra-fine powder.
Claims
1.-11. (canceled)
12. A burner which generates a high temperature reductive airflow from a fuel fluid and oxygen or oxygen-enriched air to reduce a metallic compound, thereby producing metallic ultra-fine powder having a particle size smaller than a particle size of a raw material, comprising:
- a raw material jetting hole for jetting the metallic compound as the raw material in a direction, with a fuel fluid as a carrier gas,
- plural primary oxygen jetting orifices disposed circularly around a center of said raw material jetting hole, for jetting oxygen or oxygen-enriched air parallel to said direction of jetting of said raw material, and
- plural secondary oxygen jetting orifices disposed circularly around a center of said raw material jetting hole and outward from said primary oxygen jetting orifices, for jetting oxygen or oxygen-enriched air toward a point on a line extended from said raw material jetting hole and parallel to said direction of jetting of said raw material.
13. The burner as set forth in claim 12, further comprising a fuel jetting orifice for supplying a fuel separately, in the case in which said carrier gas is air, oxygen, oxygen-enriched air, or an inert gas.
14. A burner which generates a high temperature reductive airflow from an organic solvent and oxygen or oxygen-enriched air to reduce a metallic compound, thereby producing metallic ultra-fine powder, comprising:
- a raw material atomizing hole for atomizing a liquid raw material containing a metallic compound dissolved in an organic solvent,
- plural primary oxygen jetting orifices disposed circularly around a center of said raw material atomizing hole, for jetting oxygen or oxygen-enriched air parallel to a center line of said raw material atomizing hole, and
- plural secondary oxygen jetting orifices disposed circularly around a center of said raw material atomizing hole and outward from said primary oxygen jetting orifices, for jetting oxygen or oxygen-enriched air toward a point on a line extended from said raw material atomizing hole and parallel to said center line of said raw material atomizing hole.
15. A burner which generates a high temperature reductive airflow from a fuel and oxygen or oxygen-enriched air to reduce a metallic compound, thereby producing metallic ultra-fine powder, comprising:
- a raw material atomizing hole for atomizing a liquid fuel which contains a metallic compound,
- plural fuel jetting orifices disposed circularly around a center of said raw material atomizing hole, for jetting said fuel parallel to a center line of said raw material atomizing hole,
- plural primary oxygen jetting orifices disposed circularly around a center of said raw material atomizing hole and outward from said fuel jetting orifices, for jetting oxygen or oxygen-enriched air parallel to a center line of said raw material atomizing hole, and
- plural secondary oxygen jetting orifices disposed circularly around a center of said raw material atomizing hole and outward from said primary oxygen jetting orifices, for jetting oxygen or oxygen-enriched air toward a point on a line extended from said raw material atomizing hole and parallel to said center line of said raw material atomizing hole.
16. An apparatus for producing metallic ultra-fine powder comprising:
- a furnace part, for performing heat treatment of a raw material in an oxidation-reduction atmosphere,
- the burner as set forth in claim 12, disposed in said furnace part, for jetting a fuel, oxygen or oxygen-enriched air, with a raw material toward said furnace part,
- a fuel supply system for supplying a fuel to said burner,
- a raw material supply system for supplying a raw material to said burner, and
- a cooling gas supply system for supplying a cooling gas to said furnace part.
17. The apparatus for producing metallic ultra-fine powder as set forth in claim 16, wherein said cooling gas supply system further comprises a gas supplying apparatus for controlling temperature.
Type: Application
Filed: Jun 27, 2011
Publication Date: Oct 20, 2011
Applicant: TAIYO NIPPON SANSO CORPORATION (Tokyo)
Inventors: Hiroshi Igarashi (Kai-shi), Takayuki Matsumura (Kai-shi), Shinichi Miyake (Tokyo)
Application Number: 13/067,780
International Classification: B22F 9/02 (20060101); F23C 99/00 (20060101);