MULTIPURPOSE CONSUMER SCRUBBING CLOTHS AND METHODS OF MAKING SAME
A scrubbing cloth having opposed first and second surfaces formed to have different properties relative to one another and a texture layer formed on at least one of the first and second surfaces to provide a multipurpose scrubbing cloth having enhanced surface treating capabilities.
The present disclosure relates to scrubbing articles having a textured surface or surfaces. More particularly, the present disclosure relates to a scrubbing cloth having opposed first and second surfaces formed to have different properties relative to one another and a texture layer formed on at least one of the first and second surfaces to provide a multipurpose scrubbing cloth having enhanced surface treating capabilities. The differently formed surfaces can provide one relatively more absorbent side of the scrubbing cloth and/or one relatively higher, fluffier, loftier, less dense side of the scrubbing cloth, either temporarily or permanently.
A variety of cleaning articles in the form of pads, wipes and cloths have been developed and made commercially available for household and industrial use. Consumers oftentimes desire to use the articles for cleaning or surface treating tasks requiring scrubbing which in turn may include various degrees of wiping, abrading and/or scouring. For example, it can be difficult, if not impossible, to remove dried food from a countertop using an inherently soft article. Conversely, however, consumers strongly prefer that the article not be overly rigid. In some cases, consumers thus desire that the article be drapable for ease of use. Furthermore, consumers often desire a scrubbing cloth that is reusable and that is not overly abrasive on relatively soft or easily scratched surfaces. In addition, consumers are often faced with cleaning tasks requiring both an abrasive-type scrubbing action as well as a non-abrasive wiping action. Finally, consumers often find cleaning articles that are pre-loaded with a cleaning/disinfecting/sanitizing chemical or chemicals to be useful and convenient.
Scrubbing articles have been developed to address some of the above-identified desires and concerns. For example, U.S. Pat. No. 7,829,478 to Johnson et al., describes a scrubbing wipe article including a nonwoven substrate and a texture layer. The texture layer is a non-crosslinked, abrasive resin-based material that is printed onto at least one surface of the nonwoven substrate. Johnson et al. teach that the texture layer composition is printed onto the substrate and then caused to coalesce to bond the composition to the substrate. Johnson et al. further describe that the resin constituent does not crosslink as part of the coalescing step and that coalescing represents a distinct advantage over other scrubbing wipe article forming techniques in which a lengthy curing period is required to achieve a sufficient hardness value. The scrubbing wipe article of Johnson et al. can be used “dry” or can be loaded with a chemical solution.
U.S. Patent App. Pub. No 2006/0286884 to Thioliere et al. describes a wiping article comprising a liquid-absorbent web material and abrasive areas comprising cured particulate binder material disposed on a surface of the web. The web material may include woven, knitted and non-woven materials. Non-woven materials may include dry-laid, wet-laid and spun-bonded materials. Suitable binder materials are disclosed that can be cured by heating, cooling or ultraviolet light.
U.S. Patent App. Pub. No. 2007/0212965 to Smith et al. describes a flexible scrubbing material that combines at least two discrete components, one being a continuous flexible substrate and one a discontinuous abrasive layer affixed to the flexible substrate. The abrasive layer is a set of plates formed from a material different than the continuous flexible substrate. The plate material is a printable material that subsequently solidifies, such as epoxy. Smith et al. teach that the abrasive plates can be formed from a solidified material such as ultraviolet or thermally curable polymeric materials with or without abrasive particles embedded inside. Smith et al. further describe a technique for printing the plates onto the substrates such as conventional screen-printing, UV etching and roller-printing. An adhesive is sprayed on the fabric prior to application of the plates. Smith et al. teaches an embodiment having two surfaces with different abrasion levels where the abrasion levels are provided on two separate substrates that may be assembled together or laminated to another substrate to form a scrub pad. Alternately, a single printed fabric can be stitched to an intermediate layer to form a composite (multiple-layer substrate) scrubbing cloth.
Other cleaning wipe constructions include or incorporate mildly abrasive particles within or at a surface of the base substrate. For example, U.S. Pat. No. 5,213,588 to Wong et al. describes an abrasive wipe consisting of a paper towel-like base substrate having printed thereon a mixture containing irregularly-shaped polymeric particles.
U.S. Pat. No. 4,142,334 to Kirsch et al. describes a scouring and cleaning cloth having a coating of a solid binding agent on at least a portion of each surface in an open pattern applied by a printing process. Kirsch et al. teach a consolidated nonwoven fabric having a pattern printed on its surface such that the pattern can be pressed down into the nonwoven fabric so as to produce an even surface. However, Kirsch et al. do not describe opposed, differently formed surfaces of the fabric prior to printing the described patterns, nor a fabric having only one consolidated side or surface.
Various materials and material compositions may be used to form scrubbing articles having textured surfaces. However, a cleaning or scrubbing cloth formed of a single layer substrate having one surface treated to form a relatively more absorbent side and a texture layer formed on at least one surface is not presently available. Likewise, a scrubbing cloth formed of a single layer substrate having a fluffy, lofty, less dense or relatively higher surface (i.e., fibers of the substrate project a distance from a mid-plane of the substrate) and an opposed relatively flat, less lofty, more dense, lower surface with a texture layer provided on at least one of the surfaces, is not presently available. Such multipurpose cloths would advantageously allow for both non-abrasive wiping and/or liquid absorption as well as scouring/abrading actions to be accomplished with a single scrubbing article simply by reversing the side of the cloth being applied to the surface to be treated.
As described above, improvements in the properties and manufacture of a scrubbing cloth may be beneficial and desirable. A need therefore exists for a multipurpose scrubbing cloth that includes the benefits and advantages of a single-layer substrate having different, opposed surfaces, for example, where one surface/side is more absorbent, fluffier, loftier, less dense and/or has higher projecting fibers than an opposed less absorbent, flatter, less lofty, denser and/or smoother surface (at least temporarily) and a texture layer on at least one of the surfaces. A need also exists for such a scrubbing cloth that is likewise reusable.
SUMMARYAspects of the present disclosure relate to a scrubbing cloth. Scrubbing cloths of the present disclosure may take a variety of forms that include opposed, differing surfaces (e.g., differing relative loft, height, fluff, absorptive properties etc.) and a texture layer formed on at least one of the surfaces. In some embodiments, the scrubbing cloth includes a substrate having a first surface and a second surface opposite the first surface where the first surface has a first degree of loftiness and the second surface has a second degree of loftiness and the first degree of loftiness is greater than the second degree of loftiness. In other embodiments, the scrubbing cloth includes a substrate having a substrate having first and second surface opposed surfaces where at least one of the first and second surfaces is more absorptive than the other. At least one of the first and second surfaces of the various disclosed substrates include a texture layer formed thereon. Formation of the texture layer can be accomplished via various techniques and the texture layer composition may be formed of various materials. In some embodiments, the first surface of the cloth can have a first height greater than a second height of the second surface and the second surface can have a density greater than a density of the first surface.
According to some embodiments, the scrubbing cloth has a first, lofty or fluffy surface and an opposed, second, less lofty or flat surface while according to alternative embodiments, the relative loft, density and height of opposed surfaces of a scrubbing cloth are equal and the substrate forming the scrubbing cloth is treated on one side to form a side or surface having different absorptive properties relative to the opposed side or surface. Scrubbing cloths described may form multipurpose and/or reusable scrubbing cloths. Scrubbing cloths according to the disclosure comprise a single-layer substrate made of various fabrics including any of a woven, knitted, and non-woven material or combinations thereof.
In some embodiments, a texture layer may be formed on the relatively flatter surface while the flatter surface remains permanently flattened. Alternatively, the flatter surface may be formed to only temporarily be flatter such that the texture layer may be formed thereon more readily while the surface is in a flattened configuration. As a further alternative, a texture layer may be formed on the relatively loftier (fluffier) surface while the flatter surface remains permanently in a relatively flat, less lofty configuration. As yet a further alternative, a texture layer may be formed on both a loftier surface as well as on an opposed relative flat surface and still result in a cleaning article that provides multipurpose cleaning actions (given the relative differences in the surface portions that are not textured). In yet further embodiments, a texture layer may be formed on a surface of a substrate having one side that is more absorbent than an opposed side.
Methods according to the present disclosure include formation of a scrubbing cloth having a textured layer formed thereon including treating one side of a substrate to form a treated surface having surface characteristics differing from that of an opposed side of the substrate. The opposed side of the substrate may be untreated or may be left undisturbed by the treatment of the treated side. The opposed side may form a first, lofty surface and the treated side may form a second, flattened or less lofty surface. In some embodiments, the treated side forms a more absorptive surface and the opposed side forms a less absorptive surface. Treatment can be achieved via various processing methods including calendaring, heat compression, flame treating, melting, cutting, removing fiber height, plasma treatment, spraying, flame treatment or electrical discharge. A texture layer is formed on at least one surface of the substrate to form a scrubbing cloth.
With reference to
Compositions of the substrate 12 and the texture layer 14, as well as processing thereof, are provided below. In general terms, the scrubbing cloth 10 may be described as a multipurpose scrubbing cloth formed to have a lofty, fluffy surface on one side (e.g., 16) and a relatively less lofty, flat or smooth surface on an opposed side/surface (e.g., 18). The loftier side or surface 16 of scrubbing cloth 10 has an average fiber height that is higher than an average fiber height of the less lofty or flat side/surface 18 of the scrubbing cloth 10 (where height is in reference to a mid-plane M,
The term “flat” when used to describe a surface of cloth 10 (or of substrate 12) is intended to define surface characteristics including: generally uniform, uniform, completely flat, substantially flat, smooth, consolidated, more dense, less lofty (i.e., having a lesser degree of loftiness), less fluffy, shorter, lower height and/or having fibers of the surface that lie generally in the same plane, where the terms “more” and “less” are relative to an opposed side/surface. In addition, the term “fluff” or “fluffy” as used herein to describe an opposed surface of cloth 10 (or substrate 12) is intended to define surface characteristics including: open, lofty (i.e., having a greater degree of loftiness, less dense, non-consolidated, non-compacted, higher, or greater height, where the terms “more” and “less” are relative to an opposed side/surface. When using the term “flat” or “fluff” alone or in conjunction with other terms such as “smooth”, “less lofty”, “open, lofty” etc., it is to be understood that any one or all of the characteristics may be used to define the surface characteristics, whether or not the terms “and”/“or” are used to denote the various features.
The terms “absorbent”, “absorptive” and “absorbing” as used to describe scrubbing cloths according to embodiments of the present disclosure are defined as having the ability to absorb a material (e.g., a liquid) reversibly, at least to some degree. Stated otherwise, an absorbent material can be defined as one that a liquid can penetrate into and, rather than trap and irreversibly hold the liquid, the material may release the liquid either by evaporation (drying) or physical force (e.g., hand pressure/wringing). Thus, a more absorbent side or surface of a substrate may more readily or to a greater degree absorb a liquid than an opposed side of the substrate and the liquid absorbed is able to at least partially be removed from the substrate, for example, by hand (e.g., wringing) or by drying.
Further, in general terms, the scrubbing cloth 10 may be described as providing a “scrubbiness” or abrasive attribute that is given by the texture layer 14 formed on at least one side or surface of the substrate 12. Conversely, the scrubbing cloth 10 provides a wiping or non-abrasive attribute on a side opposing the abrasive surface/side. The term “scrubbiness” is in reference to an ability to abrade or remove a relatively small, undesirable item otherwise affixed to a surface as the cloth is moved back and forth over the item, as described more fully below. A substrate can be given a scrubbiness characteristic not only by forming a hardened scrubbing material (i.e., texture layer) on the substrate's surface that may be at least as hard as or harder than the substrate itself, but also via the extent to which the so-formed material extends from or beyond the substrate surfaces or fibers, in conjunction with side-to-side spacing between individual sections of the scrubbing material.
In the embodiment of
To better illustrate the loftiness characteristics associated with the first and second surfaces 16, 18, reference is made to
With reference to the above conventions, the first degree of loftiness (i.e., the degree of loftiness associated with the first surface 16) is greater than the second degree of loftiness (i.e., the degree of loftiness associated with the second surface 18). Similarly, the first height h1 (i.e., the height associated with the first surface 16) is greater than the second height h2 (i.e., the height associated with the second surface 18). With specific reference to
Regardless, in one embodiment, the bulk density of the first surface 16 is at least 100% less than the bulk density of the second surface 18, more preferably at least 200% less than, and even more preferably at least 300% less than. It will be understood that by having a lesser bulk density, the first degree of loftiness (of the first surface 16) is thus greater than the second degree of loftiness (of the second surface 18) as bulk density has an inverse relationship with loftiness.
As further evidenced by
Regardless, and in one embodiment, the height of the first surface 16 is at least 120% of the height of the second surface 18, more preferably at least 150%, and even more preferably at least 200%. Alternatively stated, relative to the mid-plane the first surface 16 extends higher or farther beyond the mid-plane M than does the second surface 18.
Alternatively, the degree of loftiness and height of opposed sides 16, 18 of substrate 10 may be substantially equal. However, one side (e.g., 16) may be treated to form a side having a greater (or lesser) degree of absorptiveness than an opposed side (e.g., 18).
The substrate 12 may be formed from a variety of materials and in a variety of forms. Any substrate material or combination of materials suitable for use as a consumer scrubbing cloth can be used including, without limitation, various woven, knitted, and non-woven materials. The materials and forms of the substrate 12 can be selected to provide varying ranges of desired properties, such as extensibility, elasticity, durability, flexibility, etc., that are particularly suited to a given scrubbing task and/or are particularly suited to depositing or forming of a texture composition thereon. The durability of materials suitable for use in scrubbing cloths is often categorized as “disposable” (meaning that an cloth formed from the material is intended to be discarded immediately after use), “semi-disposable” (meaning that an article formed from the material can be washed and re-used a limited number of times), or “reusable” (meaning that an article formed from the material is intended to be washed and re-used). Materials useful for substrate 12 may be selected to have durability properties in a wide range (i.e., disposable, semi-disposable or reusable), but may be particularly chosen to have reusable properties.
Also as indicated above, materials may be selected based upon their flexibility. In applications where a relatively more flexible, supple scrubbing article is preferred (e.g., drapable), providing a more flexible substrate 12 allows the user to readily fold, squeeze, or otherwise manipulate the scrubbing article 10 in a manner most appropriate for the particular scrubbing task. The desired suppleness of the substrate 12 is best described with reference to a dry basis weight thereof. As one non-limiting example, in an embodiment, a nonwoven substrate 12 of the present disclosure has a dry basis weight of less than about 300 g/m2, but preferably greater than about 30 g/m2. In other embodiments, the nonwoven substrate 12 has a dry basis weight of less than about 200 g/m2. Alternatively, the suppleness of the nonwoven substrate 12 can be expressed in terms of drapability. “Drapability” is defined as the inherent ability to conform to an irregular or non-flat surface. Drapability or “drape” is measured using INDA standard for “Handle-O-Meter Stiffness of Nonwoven Fabrics” IST 90.3 (95). With this in mind, the nonwoven substrate 12 preferably has a drapability value of less than about 250.
Some exemplary substrates 12 used to form the fabric of the present disclosure will now be described, however, a wide variety of materials may be used for substrate 12, as noted above. Exemplary fabrics useful with the present disclosure include a knitted fabric prepared from 82% poly(ethylene terephthalate) and 18% polyamide 6 fibers having a thickness in a range of 0.45-0.75 mm and a unit weight of 160 grams per square meter.
Nonwovens likewise may be used and can be formed from a variety of materials and in a variety of fashions selected to provide desired properties, such as extensibility, elasticity, etc., in addition to the requisite suppleness. In most general terms, a nonwoven is comprised of individual fibers (e.g., 50,
In some embodiments, the substrate 12 is spunlaced utilizing a fiber sized in accordance with known spunlace processing techniques. With this manufacturing technique, one construction of a nonwoven substrate 12 is a blend of 50/50 wt. % 1.5 denier polyester and 1.5 denier rayon at 50-60 g/m2. The substrate 12 is first carded and then entangled via high-pressure water jets as is known in the art. The spunlace technique eliminates the need for a thermal resin bonding component, so that the resulting nonwoven substrate is amenable to being loaded with virtually any type of chemical solution (i.e., anionic, cationic, or neutral). An exemplary nonwoven includes a thermally point-bonded spunbond poly(ethylene terephthalate) nonwoven.
Other knits, wovens and nonwovens are likewise contemplated and these examples are not meant to be limiting. Regardless of the exact construction, however, the substrate 12 is highly flexible and drapable and conducive to use and handling by a user otherwise using the article 10 for scrubbing purposes and is selected having regard to the intended use of the scrubbing cloth 10. Further embodiments, can include one or more additional layers on the surface 16, 18 of the substrate 12 such as an adhesion promoter layer or a tie layer, for example.
Substrate FormationAs described above, substrate 12 may be formed to have differing degrees of loft, height and relative “flatness”/“fluff” on opposed sides 16, 18. In addition, as described above, forming the substrate 12 to include these features may be accomplished in a variety of ways. In general, the substrate 12 can be formed in the first instance, or upon manufacturing of the fabric 12, such that the opposed sides 16, 18 include the varying (different) features immediately after manufacture of the fabric 12, without undergoing any further processing. Alternatively, and as described in further detail below, a substrate 12 may be first formed into a fabric and subsequently one side (e.g., 18,
In embodiments where the substrate 12 is formed initially to provide the relative flat/fluffy surfaces 16, 18, various methods may be used to achieve the fabric formation. For example, the fabric/substrate 12 may be knitted or woven in a manner whereby the knit stitch or weave is configured such that one side of the fabric forms a lower plane of the fabric having a relatively flat surface 18 while the opposed side 16 of the fabric 12 includes fibers (e.g., 50) projecting in a direction outwardly opposed to the flat surface 18 to form a relatively fluffy, loftier surface 16.
In other embodiments, one side of substrate 12 may be treated to temporarily or permanently create a less lofty, flatmore dense surface, or at least portions thereof 16. Treatment of a surface can include various processing methods including but not limited to: calendaring, heat compression, flame treating, ultrasound treating, melting, cutting, and removing fiber height. These processing methods in turn can take on various forms and may be accomplished in a variety of ways. Some of these methods can create only a permanent or only a temporarily flatter/denser/consolidated surface (or at least portions of the surface) whereas some of these methods can create either a permanent or a temporarily flatter/denser/consolidated surface or portions of the surface), depending upon processing parameters. As described above, a temporarily flattened (compressed, consolidated etc.) surface is one having at least portions that are allowed to revert to a first, original (uncompressed, lofty etc.) state. Conversely, a permanently flattened surface is one that remains in the flattened state throughout the life of the cloth 10 despite use and/or washing etc. of the cloth 10.
In some embodiments, one side 18 of substrate 12 is only temporarily flattened (consolidated, compressed, etc.) and a texture layer 14 is formed on the temporarily flattened surface. The temporarily flattened surface, having texture layer 14, includes surface portions that do not have a texture composition deposited thereon and these portions are allowed to return to an unflattened state. As illustrated in
The texture layer 14 defines a plurality of discrete portions (e.g., the various dot-like portions shown in
Regardless of the pattern design and/or extension distance of portions (e.g., 20a, 20b) from the surface 18, during a scrubbing application, a user may position the scrubbing cloth 10 such that one or the other of surfaces 16, 18 is facing the surface to be scrubbed.
Alternatively, in use, the scrubbing cloth 10 may be positioned such that the non-textured surface (e.g., 16,
As discussed above, the texture layer 14 is an abrasive composition that is imparted to substrate 12. The exact composition of the texture layer 14 can vary depending upon desired end performance characteristics. To this end, a texture layer composition is initially formulated and then deposited or formed on the substrate 12. The texture layer 14 of the present disclosure is distinguished from a thin layer of print applied to a surface of a cloth via heat transfer printing. Heat transfer printing of a thin layer of print results in a printed layer that is not ideal for scrubbing or scouring functions as described herein. Compositions of the texture layer 14 according to the disclosure will include a selected resin and may include additional constituents such as mineral(s), filler(s), colorant(s), thickener(s), defoaming agent(s), surfactant(s), soaps, or other cleaning/disinfecting/sanitizing agents etc. The texture layer 14 may optionally be e-beam treatable/treated and may include compositions such as described U.S. Provisional Patent Application Ser. No. 62/121,766, entitled “Scrubbing Article and Method of Making Same” filed on Feb. 27, 2015 and incorporated by reference herein in its entirety. Alternately, the texture layer 14 may be UV treatable/treated or crosslinked and may include compositions such as described in U.S. Provisional Patent Application Ser. No. 62/121,705, entitled, “UV Treated Scrubbing Articles and Methods of Making Same” filed on Feb. 27, 2015 and incorporated by reference herein in its entirety.
Various materials are suitable for forming the texture layer 14. As described above, texture layer 14 comprises a resin composition and may comprise various polymers and/or monomers. Some acceptable resins include those resins selected from the group consisting of polyolefins, styrene-butadiene resin, acrylic resin, phenolic resin, nitrile resin, ethylene vinyl acetate resin, polyurethane resin, styrene-acrylic resin, vinyl acrylic resin and combinations thereof. Other non-limiting examples of binder resins useful with the present disclosure include amino resins, alkylated urea-formaldehyde resins, melamine-formaldehyde resins, acrylic resins (including acrylates and methacrylates) such as vinyl acrylates, acrylated epoxies, acrylated urethanes, acrylated polyesters, acrylated acrylics, acrylated polyethers, vinyl ethers, acrylated oils, and acrylated silicones, alkyd resins such as urethane alkyd resins, polyester resins, reactive urethane resins, phenolic resins such as resole and novolac resins, phenolic/latex resins, epoxy resins, and the like. The resins may be provided as monomers, oligomers, polymers, or combination thereof. Monomers may include multifunctional monomers capable of forming a crosslinked structure, such as epoxy monomers, olefins, styrene, butadiene, acrylic monomers, phenolic monomers, substituted phenolic monomers, nitrile monomers, ethylene vinyl acetate monomer, isocyanates, acrylic monomers, vinyl acrylic monomer and combinations thereof. Other non-limiting examples of binder resins useful with the present disclosure include amino acids, alkylated urea monomers, melamines, acrylic monomers (including acrylates and methacrylates) such as vinyl acrylates, acrylated epoxies, acrylated urethanes, acrylated polyesters, acrylated acrylics, acrylated ethers, vinyl ethers, acrylated oils, and acrylated silicones, alkyd monomers such as urethane alkyd monomers, and esters.
Other desirable features of texture layer 14 compositions include compositions having a molecular weight and/or viscosity that allows for the texture layer 14 to have sufficient (e.g., minimum level of) adhesion to the substrate 12 to which it is applied such that it does not readily wipe off of or shift along the substrate surface 16 (i.e., such that the texture layer 14 stays on the substrate surface 16 after transfer of the texture layer 14 to the substrate 16 and prior and/or subsequent to further treatment). Further, the texture layer 14 desirably has a molecular weight resulting in qualities (e.g., hardiness, stability etc.) at room temperature such that, after application to a substrate (e.g., 12) it does not stick to itself or deform readily when contacted, for example if the substrate is wound upon itself to be further processed (e.g., e-beam treated) offline at a location different from the texture forming location. To this end, suitable materials for the texture layer 14 composition may also be selected to have molecular weights and/or viscosities resulting in desired material flow properties. Specifically, materials may be selected to have molecular weights or viscosities allowing the texture layer 14 composition to be flowable in a manner that will fill the holes or voids of stencil pattern during transfer or printing of the composition to a substrate 12, sufficiently adhere to, and perhaps penetrate, the substrate 12 and to hold the desired pattern shape upon removal of the stencil from the substrate 12, even prior to (though especially subsequent to) additional processing such as rest or wait periods, heat treatment (evaporation) or optional e-beam or UV treatment. Regardless, the viscosity of a texture layer 14 composition may be selected to provide a sharp pattern. Lower viscosity mixtures may have a tendency to result in printed (or coated) droplets of mixture that almost immediately coalesce on a substrate and form a continuous film rather than discreet droplets, as often desirable for obtaining a sharp pattern.
In addition, an initiator, a promoter, or a retardant can optionally be provided as part of the formulation or composition of texture layer 14, according to some embodiments of the present disclosure, as described in detail in Provisional Patent Application Ser. No. 62/121,766, incorporated by reference herein above.
In some embodiments, the texture layer 14 optionally further includes a particulate additive for enhanced hardness. To this end, the scrubbing article 10 of the present disclosure is useful in a wide variety of potential applications having different scrubbing requirements. For some applications, it is desirable that the scrubbing article 10, and in particular the texture layer 14, be more or less abrasive than others. While the above-described resin component of the texture layer 14 independently imparts a scrubbiness feature to the article 10 greater than other available scrubbing articles, this scrubbiness characteristic can be further enhanced via the addition of a particulate component. With this in mind, a wide variety of minerals or fillers as known in the art can be employed. Useful minerals include Al2O3, “Minex” (available from The Cary Co. of Addison, Ill.), SiO2, TiO2, etc. Exemplary fillers include CaCO3, talc, etc. Where employed, the particulate component additive comprises less than 70% by weight of the texture layer 14, more preferably less than 50% by weight, most preferably less than 30% by weight. Further, the particulate component may consist of inorganic, hard, and small particles. For example, the “Minex” mineral particulate component has a median particle size of 2 microns and a Knoop hardness of about 560. Of course, other particle size and hardness values may also be useful. The inorganic nature of the particulate component, in conjunction with the non-ionic resin component, renders the resulting texture layer 14 amenable for use with any type of chemical solution.
The texture layer 14 can further include a colorant or pigment additive to provide a desired aesthetic appeal to the wiping article 10. Appropriate pigments are well known in the art, and include, for example, products sold under the trade name SUNSPERSE, available from Sun Chemical Corp. of Amelia, Ohio. Other coloring agents as known in the art are equally acceptable and in some embodiments comprise less than 10% of the texture layer composition by weight.
Additionally, the texture layer composition can include a thickening agent or agents to achieve a viscosity most desirable for the particular printing technique employed and speed of the manufacturing line. In this regard, appropriate thickening agents are known in the art and include, for example, methylcellulose and a material available under the trade name “RHEOLATE 255” from Rheox, Inc. of Hightstown, N.J. Another acceptable thickening agent is available from Huntsman International LLC, High Point, N.C., USA under the trade designation of LYOPRINT PT-XN. A thickening agent may be unnecessary depending upon the selected resin and printing technique; however, where employed, the thickening agent preferably comprises less than approximately 40% by weight of the texture layer composition. In other embodiments, a salt component may be provided in the composition to aid in causing an ionic reaction between components of an emulsion and thereby likewise generate an increase in the viscosity of the composition, as is known in the art. Notwithstanding the above, the composition of texture layer 14 may be non-ionic, according to some embodiments.
As indicated above, anti-foaming agents may be included in the composition to provide defoaming or emulsification of the composition. As described in Ullmann's Encyclopedia of Industrial Chemistry (section “Foams and Foam Control”), some anti-foaming materials are carrier oils; such as water-insoluble paraffinic and naphthenic mineral oils, vegetable oils, tall oil, castor oil, soybean oil, peanut oil; silicone oils, such as dimethylpolysiloxanes; hydrophobic silica; Hydrophobic fat derivatives and waxes, such as fatty acid esters of monofunctional and polyfunctional alcohols, fatty acid amides and sulfonamides, paraffinic hydrocarbon waxes, ozokerite, and montan wax, phosphoric acid mono-, di-, and triesters of short- and long-chain fatty alcohols, short- and long-chain natural or synthetic fatty alcohols, water-insoluble soaps of long-chain fatty acids, including aluminum stearate, calcium stearate, and calcium behenate, perfluorinated fatty alcohols; water-insoluble polymers, such as low molecular mass, fatty acid modified alkyd resins, low molecular mass novolaks, copolymers of vinyl acetate and long-chain maleic and fumaric acid diesters, and methyl methacrylate-vinylpyrrolidone copolymers, poly(propyleneglycols) and high molecular mass propylene oxide adducts to glycerol, trimethylol, propane (1,1,1-tris(hydroxymethyl)propane), pentaerythritol, triethanolamine, dipentaerythritol, polyglycerol, addition products of butylene oxide or long-chain a-epoxides with polyvalent alcohols. An example anti-foaming agent is a silicone emulsion commercially available under the trade designation of XIAMETER AFE-1520, manufactured by Dow Corning Corporation of Midland, Mich., USA.
In some embodiments, the composition of the texture layer 14 may include binder resins, ceramic microparticles or processing agents as described in U.S. Provisional Patent Application Ser. No. 62/121,644, entitled, “Consumer Scrubbing Article with Ceramic Microparticles and Method of Making Same” filed on Feb. 27, 2015 and incorporated by referenced herein in its entirety.
Finally, and as previously described, the scrubbing cloth 10 of the present disclosure can be used “dry” or can be loaded with a chemical (solution or solid) for disinfecting, sanitizing or cleaning (e.g., a soap). The term “loaded” is in reference to a chemical solution being absorbed by the substrate 12 prior to being delivered to a user. In addition or alternatively, the chemical may be sprayed onto a surface of the cloth. In still further embodiments, a chemical may be provided in or as part of the texture layer composition 14. Thus, deposited (e.g., printed) texture layer 14 may comprise printed soap scrubbing dots having similar or varying heights (e.g., 20a, 20b,
Prior to forming a texture layer 14 on a substrate 12, depending upon the type of substrate, the surface (16, 18) of the substrate 12 may be primed. Priming may involve mechanical, chemical, physical and material application methods beyond the fabric treatments described above in relation to formation of a flat, less lofty surface 18. Alternatively, priming may include application of a chemical primer such as an adhesive. Notably, however, for many substrates 12, no primer is necessary prior to transfer of the texture layer 14 composition onto the substrate 12 and achieve adequate adhesion.
The texture layer 14 composition can be formed on the substrate 12 using a variety of known techniques such as printing, (e.g., screen printing, gravure printing, flexographic printing, etc.), coating (e.g., roll, spray, electrostatic), etching, laser etching, injection molding, micro-replication and embossing such as described in U.S. Provisional Patent Application Ser. No. 62/121,644 and 62/121,766, each incorporated by reference herein above.
Examples
All ingredients from TABLE 1 were weighed out to the nearest 0.1 grams in separate plastic containers in desired quantities. A mixture was prepared by placing all ingredients in a rigid plastic container. A plastic lid was secured on the container before starting the mixing. The mixture was mixed for 30 seconds in a laboratory centrifugal mixer commercially available from Flaktek, Inc., Landrum, S.C., USA under the trade designation of SPEEDMIXER DAC 400.1 VAC-P. After 30 seconds, the mixer was stopped, and the plastic container which had the mixture in it was removed the mixer. The container was left undisturbed on a laboratory bench for 24 hours. The composition of the resultant texture layer (printing abrasive) mixture is presented in TABLE 2.
The SAMPLE 2 substrate was treated via consolidating one side via heated steel rolls with a nip. The steel rolls were heated, starting at room temperature and increased to greater than 204° C. It was observed that the roll speed has an impact on the heat dwell time, which can impact the amount of the consolidation present on the cloth. One of the rolls was heated to a higher temperature than the other, providing consolidation on one side while the opposed side remained undisturbed. It was likewise observed that the lower temperature roll would not necessarily need to be heated. A gap was also set between the rolls in order to not compress SAMPLE 2 completely flat. The initial thickness of the substrate was 3.2 mm prior to consolidating one surface. After consolidating, an approximate thickness of the same cloth was found to be 2.0 mm.
For each of SAMPLES 1 and 2 a rectangular cloth specimen with approximate dimensions of 30 cm×20 cm was secured on a flat laboratory bench by applying adhesive tape on its edges for subsequent printing of the prepared composition (described in TABLE 2) thereon.
Printing the Prepared Compositions onto the Prepared Substrates
For each of the prepared SAMPLES, a metal stencil was placed on top of the substrate specimen. For SAMPLE 1, the metal stencil included the texture pattern shown in
Scrubbing cloths according to the present disclosure may uniquely satisfy various cleaning or scrubbing requirements in a singular cleaning article. In this manner, scrubbing cloths according to the disclosure may be considered multipurpose scrubbing cloths.
Although the present disclosure has been described with reference to preferred embodiments, workers skilled in the art will recognize that changes can be made in form and detail without departing from the spirit and scope of the present disclosure.
Claims
1. A scrubbing cloth comprising:
- a substrate having a first surface and a second surface opposite the first surface;
- wherein the first surface has a first degree of loftiness and the second surface has a second degree of loftiness; and
- wherein the first degree of loftiness is greater than the second degree of loftiness; and
- wherein at least one of the first and second surfaces include a texture layer formed thereon.
2. The scrubbing cloth of claim 1, wherein the first surface has a first height and a first density and the second surface has a second height and a second density and wherein the first height is greater than the second height and the second density is greater than the first density.
3. The scrubbing cloth of claim 1, wherein the substrate consists essentially of a single layer of material.
4. The scrubbing cloth of claim 1, wherein each of the first and second surfaces comprise a texture layer.
5. The scrubbing cloth of claim 1, wherein the second surface comprises a consolidated surface.
6. The scrubbing cloth of claim 5, wherein the consolidated surface is formed by application of heat and pressure to the second surface.
7. The scrubbing cloth of claim 1, wherein the substrate comprises a fabric selected from the group consisting of a woven, a nonwoven, and a knit.
8. The scrubbing cloth of claim 1, wherein the substrate comprises a knit fabric formed by a knit stitch having loops configured such that the loops project from a plane of the fabric at the first surface and the loops lie substantially in a plane of the fabric at the second surface.
9. The scrubbing cloth of claim 1, wherein the texture layer defines a pattern.
10. The scrubbing cloth of claim 9, wherein the pattern includes a plurality of discrete segments.
11. The scrubbing cloth of claim 10, wherein the discrete segments include at least one of series of unconnected lines, dots or images.
12. The scrubbing cloth of claim 1, wherein the texture layer includes a multiplicity of ceramic microparticles.
13. The scrubbing cloth of claim 1, wherein the texture layer includes a plurality of randomly distributed texturings.
14. The scrubbing cloth of claim 1, wherein the texture layer comprises one of an e-beam or UV treated texture layer.
15. The scrubbing cloth of claim 1, further wherein at least one of the texture layer and substrate comprise a chemical solution for cleaning.
16. The scrubbing cloth of claim 1, wherein the texture layer comprises a hardness that is equal or greater than a hardness of the substrate.
17. A scrubbing cloth comprising:
- a substrate having first and second surface opposed surfaces;
- wherein at least one of the first and second surfaces is more absorptive than the other; and
- wherein at least one of the first and second surfaces include a texture layer formed thereon.
18. A method of manufacturing a scrubbing cloth having a textured surface, the method comprising:
- providing a scrubbing cloth having a first surface and a second surface opposite the first surface;
- treating at least one surface of the cloth such that at least one of the surfaces includes at least one of an absorption, density, loftiness or height greater than the opposed surface;
- allowing the first surface to remain undisturbed during the treating step; and
- forming a texture layer on at least one of the first and second surfaces.
19. The method of claim 18, wherein the texture layer comprises a soap solution.
Type: Application
Filed: Feb 4, 2016
Publication Date: Dec 22, 2016
Inventors: Paul N. Daveloose (Maplewood, MN), Matthew S. Cole (Eagan, MN), Ibrahim S. Gunes (Minneapolis, MN), Irem Bolukbasi (St. Paul, MN), Ann M. Gilman (Woodbury, MN), Matthew Richard Dillon Smith (Woodbury, MN), David C. Raithel (Hudson, WI)
Application Number: 15/021,902