FIELD OF THE INVENTION The present invention relates to delivery systems comprising malodor reduction compositions, methods of making such delivery systems and consumer products made with such delivery systems.
BACKGROUND OF THE INVENTION Unscented or scented products are desired by consumers as they may be considered more natural and discreet than scented products. Manufacturers of unscented or scented products for controlling malodors rely on malodor reduction ingredients or other technologies (e.g. filters) to reduce malodors. However, effectively controlling malodors, for example, amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C2-C12 carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g. fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g. mold/mildew) may be difficult, and the time required for a product to noticeably reduce malodors may create consumer doubt as to the product's efficacy on malodors. Often times, manufacturers incorporate scented perfumes to help mask these difficult malodors.
Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is extremely constraining. Thus what is needed is a broader palette of malodor control technologies so the perfume community can deliver the desired level of character in a greater number of situations/applications. Surprisingly, Applicants recognized that in addition to blocking a malodor's access to a sensory cell, in order to achieve the desired goal, a malodor control technology must leave such sensor cell open to other molecules, for example scent molecules. As a result of such recognition, Applicants developed delivery systems comprising malodor reduction compositions that do not unduely interfere with the scent of the perfumed or unperfumed delivery system, perfumed or unperfumed products comprising such delivery systems and any perfumed or unperfumed situs that is treated with such products. Such delivery systems are disclosed herein.
SUMMARY OF THE INVENTION The present invention relates to delivery systems comprising malodor reduction compositions, methods of making such delivery systems and consumer products made with such delivery systems. Such delivery systems do not unduely interfere with the scent of the perfumed or unperfumed delivery system, perfumed or unperfumed products comprising such delivery systems and any perfumed or unperfumed situs that is treated with such products.
DETAILED DESCRIPTION OF THE INVENTION As used herein “MORV” is the calculated malodor reduction value for a subject material. A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.
As used herein, the term “perfume” does not include malodor reduction materials. Thus, the perfume portion of a composition does not include, when determining the perfume's composition, any malodor reduction materials found in the composition as such malodor reduction materials are described herein. In short, if a material has a malodor reduction value “MORV” that is within the range of the MORV recited in the subject claim, such material is a malodor reduction material for purposes of such claim.
As used herein “cleaning and/or treatment products” means products comprising fluid laundry detergents, fabric enhancers, laundry and/or rinse additives, fluid dishwashing detergents, fluid hard surface cleaning and/or treatment compositions, fluid toilet bowl cleaners that may or may not be contained in a unit dose delivery product all for consumer, agricultural, industrial or institutional use.
As used herein, “malodor” refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.
As used herein, “odor blocking” refers to the ability of a compound to dull the human sense of smell.
As used herein, the terms “a” and “an” mean “at least one”.
As used herein, the terms “include”, “includes” and “including” are meant to be non-limiting.
Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.
All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.
It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.
Malodor Reduction Materials A non-limiting set of suitable malodor reduction materials are provided in the tables below. For ease of use, each material in Tables 1-3 is assigned a numerical indentifier which is found in the column for each table that is designated Number. Table 4 is a subset of Table 1, Table 5 is a subset of Table 2 and Table 6 is a subset of Table 3 and there for Tables 4, 5 and 6 each use the same numerical identifier as found, respectively, in Tables 1-3.
Codes
A = Vapor Pressure >0.1 torr
B = Vapor Pressure is between 0.01 torr and 0.1 torr
C = Calculated logP <3
D = Calculated logP >3
E = Probability of Ingredient Color Instability = 0%
F = Probability of Ingredient Color Instability <71%
G = Odor Detection Threshold less than p.ol = 8
H = Odor Detection Threshold greater than p.ol = 8
I = Melamine formaldehyde PMC Headspace Response Ratio greater
than or equal to 10
J = Melamine formaldehyde PMC leakage less than or equal to 5%
K = Log of liquid dish neat product liquid-air partition coefficient greater
than or equal to −7
L = Log of liquid dish neat product liquid-air partition coefficient greater
than or equal to −5
TABLE 1
List of materials with at least one MORV from 1 to 5
Number Material Name CAS Number Comment Code
1 2-ethylhexyl (Z)-3-(4- 5466-77-3 DEFHJ
methoxyphenyl)acrylate
2 2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ
5,6,7,8-tetrahydronaphthalen-2-yl)-
1,3-dioxolane
3 1,1-dimethoxynon-2-yne 13257-44-8 ACEFHJK
4 para-Cymen-8-ol 1197-01-9 BCGIJK
7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK
methylenebicyclo[4.3.1]decane
9 Methoxycyclododecane 2986-54-1 DEFHJK
10 1,1-dimethoxycyclododecane 950-33-4 DEFHJK
11 (Z)-tridec-2-enenitrile 22629-49-8 DEFHJK
13 Oxybenzone 131-57-7 DEFGJ
14 Oxyoctaline formate 65405-72-3 DFHJK
16 4-methyl-1-oxaspiro[5.5]undecan-4- 57094-40-3 CFGIJK
ol
17 7-methyl-2H-benzo[b][1,4]dioxepin- 28940-11-6 CGIK
3(4H)-one
18 1,8-dioxacycloheptadecan-9-one 1725-01-5 DGJ
21 4-(tert-pentyl)cyclohexan-1-one 16587-71-6 ADFGIJKL
22 o-Phenyl anisol 86-26-0 DEFHJK
23 3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK
2,2,6,6,7,8,8-heptamethyl-4H-
indeno(4,5-d)-1,3-dioxole
25 7-isopropyl-8,8-dimethyl-6,10- 62406-73-9 BDEFHIJK
dioxaspiro[4.5]decane
28 Octyl 2-furoate 39251-88-2 DEFHJK
29 Octyl acetate 112-14-1 BDEFHJKL
30 octanal propylene glycol acetal 74094-61-4 BDEFHJKL
31 Octanal 124-13-0 ACHIKL
32 Octanal dimethyl acetal 10022-28-3 ACEFGJKL
33 Myrcene 123-35-3 ADEFGIKL
34 Myrcenol 543-39-5 BCEFGIJK
35 Myrcenyl acetate 1118-39-4 ADEFGJK
36 Myristaldehyde 124-25-4 DFHJK
37 Myristicine 607-91-0 CGJK
38 Myristyl nitrile 629-63-0 DEFHJK
39 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJK
octahydronaphthalen-1-ol
42 Ocimenol 5986-38-9 BCHIJK
43 Ocimenol 28977-58-4 BCHIJK
47 Nopyl acetate 128-51-8 DEFHJK
48 Nootkatone 4674-50-4 DHJK
49 Nonyl alcohol 143-08-8 BDEFGIJKL
50 Nonaldehyde 124-19-6 ADHIKL
52 12-methyl-14-tetradec-9-enolide 223104-61-8 DFHJK
57 N-ethyl-p-menthane-3-carboxamide 39711-79-0 DEFGIJK
61 1-(3-methylbenzofuran-2-yl)ethan-1- 23911-56-0 CEFHIK
one
62 2-methoxynaphthalene 93-04-9 BDEFHK
63 Nerolidol 7212-44-4 DEFHJK
64 Nerol 106-25-2 BCHIK
65 1-ethyl-3- 31996-78-8 ACEFHIJKL
methoxytricyclo[2.2.1.02,6]heptane
67 Methyl (E)-non-2-enoate 111-79-5 ADEFHJKL
68 10-isopropyl-2,7-dimethyl-1- 89079-92-5 BDEFHIJK
oxaspiro[4.5]deca-3,6-diene
69 2-(2-(4-methylcyclohex-3-en-1- 95962-14-4 DHJK
yl)propyl)cyclopentan-1-one
70 Myrtenal 564-94-3 ACFHIJKL
71 (E)-4-(2,2,3,6- 54992-90-4 BDEFHIJK
tetramethylcyclohexyl)but-3-en-2-
one
74 Myraldyl acetate 53889-39-7 DHJK
75 Musk tibetine 145-39-1 DHIJ
76 1,7-dioxacycloheptadecan-8-one 3391-83-1 DGJ
77 Musk ketone 81-14-1 DHJ
78 Musk ambrette 83-66-9 DHIJ
79 3-methylcyclopentadecan-1-one 541-91-3 DEFHJK
80 (E)-3-methylcyclopentadec-4-en-1- 82356-51-2 DHJK
one
82 3-methyl-4-phenylbutan-2-ol 56836-93-2 BCEFHIK
83 1-(4-isopropylcyclohexyl)ethan-1-ol 63767-86-2 BDEFHIJK
85 Milk Lactone 72881-27-7 DEFHJK
91 Methyl octine carbonate 111-80-8 BDEFHKL
92 Methyl octyl acetaldehyde 19009-56-4 ADFHJKL
93 6,6-dimethoxy-2,5,5-trimethylhex-2- 67674-46-8 ACHIJKL
ene
98 Methyl phenylethyl carbinol 2344-70-9 BCEFHIK
100 Methyl stearate 112-61-8 DEFHJ
101 Methyl nonyl acetaldehyde dimethyl 68141-17-3 BDEFHJK
acetal
102 Methyl nonyl ketone 112-12-9 BDFHJKL
103 Methyl nonyl acetaldehyde 110-41-8 BDFHJK
104 Methyl myristate 124-10-7 DEFHJK
105 Methyl linoleate 112-63-0 DEFHJ
106 Methyl lavender ketone 67633-95-8 CFHJK
108 Methyl isoeugenol 93-16-3 ACEFHK
109 Methyl hexadecanoate 112-39-0 DEFHJK
110 Methyl eugenol 93-15-2 ACEFHK
112 Methyl epijasmonate 1211-29-6 CHJK
113 Methyl dihydrojasmonate 24851-98-7 DFHJK
114 Methyl diphenyl ether 3586-14-9 DEFHJK
117 Methyl cinnamate 103-26-4 BCEFHK
119 Methyl chavicol 140-67-0 ADEFHK
120 Methyl beta-naphthyl ketone 93-08-3 CEFHK
122 Methyl 2-octynoate 111-12-6 ACEFHKL
123 Methyl alpha-cyclogeranate 28043-10-9 ACHIJKL
126 Methoxycitronellal 3613-30-7 ACFGIJK
128 Menthone 1,2-glycerol ketal 67785-70-0 CEFHJ
(racemic)
130 Octahydro-1H-4,7-methanoindene-1- 30772-79-3 BCFHIJKL
carbaldehyde
134 3-(3-(tert-butyl)phenyl)-2- 62518-65-4 BDHJK
methylpropanal
135 (E)-4-(4,8-dimethylnona-3,7-dien-1- 38462-23-6 DEFHJK
yl)pyridine
137 (E)-trideca-3,12-dienenitrile 134769-33-8 DEFHJK
140 2,2-dimethyl-3-(m-tolyl)propan-1-ol 103694-68-4 CEFHIJK
141 2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK
tetrahydroindeno[1,2-d][1,3]dioxine
142 Maceal 67845-30-1 BDFHJK
143 4-(4-hydroxy-4- 31906-04-4 CHJ
methylpentyl)cyclohex-3-ene-1-
carbaldehyde
145 1-Limonene 5989-54-8 ADEFGIJKL
146 (Z)-3-hexen-1-yl-2-cyclopenten-1- 53253-09-1 BDHK
one
148 Linalyl octanoate 10024-64-3 DEFHJ
149 Linalyl isobutyrate 78-35-3 BDHJK
152 Linalyl benzoate 126-64-7 DFHJ
153 Linalyl anthranilate 7149-26-0 DFHJ
155 Linalool oxide (furanoid) 60047-17-8 BCHIJK
156 linalool oxide 1365-19-1 CGIJK
158 (2Z,6E)-3,7-dimethylnona-2,6- 61792-11-8 BDEFHJK
dienenitrile
159 3-(4-methylcyclohex-3-en-1- 6784-13-0 ACFHIJK
yl)butanal
161 (2,5-dimethyl-1,3-dihydroinden-2- 285977-85-7 CEFHJK
yl)methanol
162 3-(4-(tert-butyl)phenyl)-2- 80-54-6 BDHJK
methylpropanal
167 (E)-1-(1-methoxypropoxy)hex-3-ene 97358-54-8 ACEFGJKL
168 Leaf acetal 88683-94-7 ACEFGJKL
170 1-Carveol 2102-58-1 BCHIJK
174 Lauryl alcohol 112-53-8 DEFGJK
175 Lauryl acetate 112-66-3 DEFHJK
176 Lauric acid 143-07-7 DEFHJ
177 Lactojasmone 7011-83-8 BDEFHIJKL
178 Lauraldehyde 112-54-9 BDFHJK
179 3,6-dimethylhexahydrobenzofuran- 92015-65-1 BCEFHIJKL
2(3H)-one
182 4-(1-ethoxyvinyl)-3,3,5,5- 36306-87-3 BDFHIJK
tetramethylcyclohexan-1-one
183 Khusimol 16223-63-5 CEFHJK
184 5-(sec-butyl)-2-(2,4- 117933-89-8 DEFHJ
dimethylcyclohex-3-en-1-yl)-5-
methyl-1,3-dioxane
185 (1-methyl-2-((1,2,2- 198404-98-7 DEFHJK
trimethylbicyclo[3.1.0]hexan-3-
yl)methyl)cyclopropyl)methanol
186 2-propylheptanenitrile 208041-98-9 ADEFHIJKL
187 (E)-6-(pent-3-en-1-yl)tetrahydro-2H- 32764-98-0 BCFHIKL
pyran-2-one
189 2-hexylcyclopentan-1-one 13074-65-2 BDFHJKL
190 2-methyl-4-phenyl-1,3-dioxolane 33941-99-0 BCEFGIK
192 2,6,9,10-tetramethyl-1- 71078-31-4 BDEFHIJK
oxaspiro(4.5)deca-3,6-diene
193 Isopulegol 89-79-2 BCEFHIJKL
195 Isopropyl palmitate 142-91-6 DEFHJ
196 Isopropyl myristate 110-27-0 DEFHJK
197 Isopropyl dodecanoate 10233-13-3 DEFHJK
199 Isopimpinellin 482-27-9 CFGJ
206 Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK
208 Isomenthone 491-07-6 ADEFGIJKL
209 Isojasmone 95-41-0 BDFHJKL
210 Isomenthone 36977-92-1 ADEFGIJKL
211 Isohexenyl cyclohexenyl 37677-14-8 DFHJK
carboxaldehyde
212 Isoeugenyl benzyl ether 120-11-6 DFHJ
215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK
1,2,3,4,5,6,7,8-octahydronaphthalen-
2-yl)ethan-1-one
218 Isocyclocitral 1335-66-6 ACFHIJKL
221 Isobutyl quinoline 65442-31-1 DEFHJK
227 Isobornylcyclohexanol 68877-29-2 DEFHJK
228 Isobornyl propionate 2756-56-1 BDEFHIJK
229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK
230 Isobornyl cyclohexanol 66072-32-0 DEFHJK
231 Isobornyl acetate 125-12-2 ADEFHIJKL
233 Isobergamate 68683-20-5 DEFHJK
234 Isoamyl undecylenate 12262-03-2 DEFHJK
238 Isoamyl laurate 6309-51-9 DEFHJK
242 Isoambrettolide 28645-51-4 DGJ
243 Irisnitrile 29127-83-1 ADEFHKL
244 Indolene 68527-79-7 DEFHJ
246 Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ
247 4,4a,5,9b-tetrahydroindeno[1,2- 18096-62-3 BCEFGJK
d][1,3]dioxine
249 Hydroxy-citronellol 107-74-4 CEFGIJK
252 2-cyclododecylpropan-1-ol 118562-73-5 DEFHJK
253 Hydrocitronitrile 54089-83-7 CEFHJK
254 Hydrocinnamyl alcohol 122-97-4 BCEFHIK
256 Hydratropaldehyde dimethyl acetal 90-87-9 ACEFHJK
259 5-ethyl-4-hydroxy-2-methylfuran- 27538-09-6 CFGIK
3(2H)-one
260 2,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK
5-propanal
261 3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK
inden-5-yl)propanal
263 Hexyl octanoate 1117-55-1 DEFHJK
267 Hexyl hexanoate 6378-65-0 DEFHJKL
269 Hexyl cinnamic aldehyde 101-86-0 DHJ
271 Hexyl benzoate 6789-88-4 DEFHJK
274 Hexenyl tiglate 84060-80-0 BDEFHJK
276 (E)-3,7-dimethylocta-2,6-dien-1-yl 3681-73-0 DEFHJ
palmitate
277 Hexadecanolide 109-29-5 DEFGJK
278 2-butyl-4,4,6-trimethyl-1,3-dioxane 54546-26-8 ADEFHIJKL
280 Ethyl (1R,2R,3R,4R)-3- 116126-82-0 BDEFHIJK
isopropylbicyclo[2.2.1]hept-5-ene-2-
carboxylate
281 3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK
methanoinden-6-yl acetate
285 2-(1-(3,3- 141773-73-1 DEFHJ
dimethylcyclohexyl)ethoxy)-2-
methylpropyl propionate
286 Heliotropine diethyl acetal 40527-42-2 CEFGJ
288 Helional 1205-17-0 CHJK
289 (E)-oxacyclohexadec-13-en-2-one 111879-80-2 DGJK
290 Gyrane 24237-00-1 ADEFHIJKL
292 Guaiol 489-86-1 DEFHJK
293 1-(2,6,6-trimethylcyclohex-2-en-1- 68611-23-4 DHJK
yl)pentan-3-one
294 Ethyl 2-ethyl-6,6-dimethylcyclohex- 57934-97-1 BDEFHIJK
2-ene-1-carboxylate
295 Germacrene B 15423-57-1 DEFHJK
296 Germacrene D 23986-74-5 DEFHJK
300 Geranyl phenylacetate 102-22-7 DFHJ
301 Geranyl phenyl acetate 71648-43-6 DFHJ
303 Geranyl linalool 1113-21-9 DFHJ
307 Geranyl cyclopentanone 68133-79-9 DHJK
316 gamma-Undecalactone (racemic) 104-67-6 DEFHJKL
317 gamma-Terpinyl acetate 10235-63-9 BDHJK
318 gamma-Terpineol 586-81-2 BCGIJK
321 gamma-Nonalactone 104-61-0 BCEFHIKL
322 gamma-Muurolene 30021-74-0 DEFHJKL
323 gamma-(E)-6-(pent-3-en-1- 63095-33-0 BCEFHKL
yl)tetrahydro-2H-pyran-2-one
324 gamma-Ionone 79-76-5 BDEFHIJK
325 gamma-Himachalene 53111-25-4 BDEFHJKL
328 gamma-Gurjunene 22567-17-5 DEFHJKL
329 gamma-Eudesmol 1209-71-8 DFHJK
330 gamma-Dodecalactone 2305-05-7 DEFHJK
331 gamma-Damascone 35087-49-1 BDEFHIJK
332 gamma-Decalactone 706-14-9 BDEFHIJKL
333 gamma-Cadinene 39029-41-9 DEFHJKL
334 1-(3,3-dimethylcyclohexyl)pent-4- 56973-87-6 BDEFHJK
en-1-one
335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJK
hexahydrocyclopenta[g]isochromene
336 Furfuryl octanoate 39252-03-4 DEFHJK
338 Furfuryl hexanoate 39252-02-3 CEFHJK
339 Furfuryl heptanoate 39481-28-2 CEFHJK
342 2-methyldecanenitrile 69300-15-8 BDEFHJKL
343 8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK
hexahydro-1H-4,7-methanoinden-6-
yl propionate
344 Ethyl (3aR,4S,7R,7aR)-octahydro- 80657-64-3 DEFHIJK
3aH-4,7-methanoindene-3a-
carboxylate
347 Diethyl cyclohexane-1,4- 72903-27-6 CEFHJK
dicarboxylate
349 (6-isopropyl-9-methyl-1,4- 63187-91-7 CEFHJ
dioxaspiro[4.5]decan-2-yl)methanol
350 2-isobutyl-4-methyltetrahydro-2H- 63500-71-0 BCEFHIJK
pyran-4-ol
352 Undec-10-enenitrile 53179-04-7 BDEFHJK
353 (Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK
methanochromen-2-one
356 3-(2-ethylphenyl)-2,2- 67634-15-5 BDHJK
dimethylpropanal
358 (E)-4,8-dimethyldeca-4,9-dienal 71077-31-1 BDFHJK
359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK
1,3a,4,6,7,7a-hexahydro-5H-4,7-
methanoinden-5-ylidene)-3-
methylbutan-2-ol
360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJK
hexahydro-1H-4,7-methanoinden-6-
yl acetate
361 3-(4-ethylphenyl)-2,2- 134123-93-6 DEFHJK
dimethylpropanenitrile
362 2-heptylcyclopentan-1-one 137-03-1 DFHJKL
363 1-ethoxyethoxy Cyclododecane 389083-83-4 DEFHJK
364 3-cyclohexene-1-carboxylic acid, 815580-59-7 ACHIJKL
2,6,6-trimethyl-, methyl ester
368 Farnesyl acetate 29548-30-9 DEFHJK
369 Farnesol 4602-84-0 DEFHJK
370 Oxacyclohexadecan-2-one 106-02-5 DEFGJK
371 1-cyclopentadec-4-en-1-one 14595-54-1 DEFGJK
372 1-cyclopentadec-4-en-1-one 35720-57-1 DEFGJK
373 2-methoxy-4-(4- 128489-04-3 CGJ
methylenetetrahydro-2H-pyran-2-
yl)phenol
374 Eugenyl acetate 93-28-7 CFHJK
375 Eugenol 97-53-0 CHIK
377 Ethylmethylphenylglycidate 77-83-8 CFHJK
378 Ethylene brassylate 105-95-3 DFGJ
381 Ethyl undecylenate 692-86-4 DEFHJK
385 Ethyl palmitate 628-97-7 DEFHJ
386 Ethyl nonanoate 123-29-5 BDEFHJKL
388 Ethyl myristate 124-06-1 DEFHJK
390 Ethyl linalool 10339-55-6 BCEFHJK
391 Ethyl laurate 106-33-2 DEFHJK
394 Ethyl hexyl ketone 925-78-0 ADFHIKL
397 Ethyl decanoate 110-38-3 BDEFHJK
398 Ethyl gamma-Safranate 35044-57-6 ADHIJK
407 Ethyl 3-phenylglycidate 121-39-1 CGJK
413 6-ethyl-2,10,10-trimethyl-1- 79893-63-3 BDEFHIJK
oxaspiro[4.5]deca-3,6-diene
414 Elemol 639-99-6 DEFHJK
415 (2-(1-ethoxyethoxy)ethyl)benzene 2556-10-7 BCEFHJK
416 (E)-3-methyl-5-(2,2,3- 67801-20-1 DHJK
trimethylcyclopent-3-en-1-yl)pent-4-
en-2-ol
417 d-xylose 58-86-6 CGIJ
418 (E)-4-((3aS,7aS)-octahydro-5H-4,7- 30168-23-1 DFHJK
methanoinden-5-ylidene)butanal
421 Dodecanal dimethyl acetal 14620-52-1 DEFHJK
424 d-Limonene 5989-27-5 ADEFGIJKL
425 Dipropylene Glycol 25265-71-8 CEFGIK
426 Dispirone 83863-64-3 BDEFHJK
428 Diphenyloxide 101-84-8 BDEFHK
429 Diphenylmethane 101-81-5 DEFGK
432 Dimethyl benzyl carbinyl butyrate 10094-34-5 DEFHJK
436 2,6-dimethyloct-7-en-4-one 1879-00-1 ADEFHIJKL
441 Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL
yl acetate
444 Dihydrocarveol acetate 20777-49-5 BDEFHIJK
445 Dihydrocarveol 619-01-2 BCEFHIJKL
449 Dihydro Linalool 18479-51-1 BCEFGIJKL
450 Dihydro Isojasmonate 37172-53-5 DHJK
453 Dibutyl sulfide 544-40-1 ADEFHIKL
457 Dibenzyl 103-29-7 DEFGJK
459 delta-Undecalactone 710-04-3 DEFHJKL
461 delta-Elemene 20307-84-0 BDEFHJK
462 delta-Guaiene 3691-11-0 DEFHJKL
463 delta-Dodecalactone 713-95-1 DEFHJK
464 delta-Decalactone 705-86-2 BDEFHIJKL
465 delta-Cadinene 483-76-1 DEFHJKL
466 delta-damascone 57378-68-4 ADHIJK
467 delta-Amorphene 189165-79-5 DEFHJKL
468 delta-3-Carene 13466-78-9 ADEFGIJKL
470 Decylenic alcohol 13019-22-2 BDEFHJK
471 Decyl propionate 5454-19-3 DEFHJK
473 Decanal diethyl acetal 34764-02-8 DEFHJK
474 Decahydro-beta-naphthol 825-51-4 BCEFGIK
475 1-cyclohexylethyl (E)-but-2-enoate 68039-69-0 BDFHJK
478 3-(4-isopropylphenyl)-2- 103-95-7 BDFHJK
methylpropanal
479 Cyclotetradecane 295-17-0 DEFGJKL
480 Cyclopentadecanone 502-72-7 DEFGJK
482 Cyclohexyl salicylate 25485-88-5 DFGJ
484 3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK
methanoinden-6-yl butyrate
485 Cyclic ethylene dodecanedioate 54982-83-1 DFGJ
486 8,8-dimethyl-1,2,3,4,5,6,7,8- 68991-97-9 DHJK
octahydronaphthalene-2-
carbaldehyde
487 3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJK
methanoinden-5-yl isobutyrate
488 Curzerene 17910-09-7 DHJK
491 Cumic alcohol 536-60-7 CHIJK
493 Coumarone 1646-26-0 BCEFHIK
497 2-(3-phenylpropyl)pyridine 2110-18-1 CEFHJK
498 Dodecanenitrile 2437-25-4 DEFHJK
501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ
502 Citryl acetate 6819-19-8 DFHJK
503 Citrus Propanol 15760-18-6 CEFHIJK
505 Citronitrile 93893-89-1 CEFHJK
519 Citral propylene glycol acetal 10444-50-5 CEFHJK
520 Citral dimethyl acetal 7549-37-3 BCEFHJK
521 Citral diethyl acetal 7492-66-2 BDEFHJK
524 cis-Ocimene 3338-55-4 ADGIKL
527 cis-Limonene oxide 13837-75-7 ADEFGIJKL
529 Cis-iso-ambrettolide 36508-31-3 DGJ
530 cis-6-nonenol 35854-86-5 BCEFHIKL
531 cis-carveol 1197-06-4 BCHIJK
532 cis-4-Decen-1-al 21662-09-9 ADHKL
534 cis-3-hexenyl-cis-3-hexenoate 61444-38-0 BDEFHJK
537 cis-3-Hexenyl salicylate 65405-77-8 DEFGJ
541 Cis-3-hexenyl Benzoate 25152-85-6 DEFHJK
544 cis-3-Hexenyl 2-methylbutyrate 53398-85-9 ADEFHJKL
546 cis-3, cis-6-nonadienol 53046-97-2 ACEFHK
548 Cinnamyl propionate 103-56-0 DEFHJK
550 Cinnamyl isobutyrate 103-59-3 DEFHJK
551 Cinnamyl formate 104-65-4 BCEFHK
552 Cinnamyl cinnamate 122-69-0 DHJ
553 Cinnamyl acetate 103-54-8 BCEFHK
555 Cinnamic alcohol 104-54-1 BCEFHIK
558 Cetyl alcohol 36653-82-4 DEFHJ
559 (E)-1-(2,6,6-trimethylcyclohex-2-en- 79-78-7 DHJK
1-yl)hepta-1,6-dien-3-one
560 2-methyl-4-(2,6,6-trimethylcyclohex- 65405-84-7 DFHJK
1-en-1-yl)butanal
561 (3aR,5aR,9aR,9bR)-3a,6,6,9a- 3738-00-9 DEFHJK
tetramethyldodecahydronaphtho[2,1-
b]furan
562 1,6-dioxacycloheptadecan-7-one 6707-60-4 DGJ
563 1-(6-(tert-butyl)-1,1-dimethyl-2,3- 13171-00-1 DEFHJK
dihydro-1H-inden-4-yl)ethan-1-one
565 Cedryl methyl ether 19870-74-7 ADEFHJK
566 Cedryl formate 39900-38-4 BDEFHJK
567 Cedryl acetate 77-54-3 DEFHJK
568 (4Z,8Z)-1,5,9-trimethyl-13- 71735-79-0 DFHJK
oxabicyclo[10.1.0]trideca-4,8-diene
569 Cedrol 77-53-2 DEFHJK
570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK
trimethylcyclopent-3-en-1-yl)-6-
oxabicyclo[3.2.1]octane
571 5-methyl-1-(2,2,3- 426218-78-2 DFHJ
trimethylcyclopent-3-en-1-yl)-6-
oxabicyclo[3.2.1]octane
572 1,1,2,3,3-pentamethyl-1,2,3,5,6,7- 33704-61-9 BDEFHIJK
hexahydro-4H-inden-4-one
573 Caryophyllene alcohol acetate 32214-91-8 DEFHJK
574 Caryolan-1-ol 472-97-9 DEFHJK
577 Carvyl acetate 97-42-7 BDHIJK
578 Caprylnitrile 124-12-9 ACEFGIKL
580 Caprylic alcohol 111-87-5 ACEFGIKL
581 Caprylic acid 124-07-2 BCEFHIK
582 Capric acid 334-48-5 DEFHJK
584 Capraldehyde 112-31-2 ADHKL
586 3-(4-methoxyphenyl)-2- 5462-06-6 BCHJK
methylpropanal
587 Camphorquinone 10373-78-1 ACEFGIJK
589 Camphene 79-92-5 ADEFGIJKL
591 Ethyl 2-methyl-4-oxo-6- 59151-19-8 DHJ
pentylcyclohex-2-ene-1-carboxylate
592 Butylated hydroxytoluene 128-37-0 DEFGIJK
594 Butyl stearate 123-95-5 DEFHJ
595 Butyl butyryl lactate 7492-70-8 CEFGJK
599 Butyl 10-undecenoate 109-42-2 DEFHJK
600 2-methyl-4-(2,2,3- 72089-08-8 DEFHJK
trimethylcyclopent-3-en-1-yl)butan-
1-ol
601 3-(4-(tert-butyl)phenyl)propanal 18127-01-0 BDHJK
603 Bornyl isobutyrate 24717-86-0 BDEFHIJK
604 Bornyl acetate 76-49-3 ADEFHIJKL
606 2-ethoxy-2,6,6-trimethyl-9- 68845-00-1 BDEFHJK
methylenebicyclo[3.3.1]nonane
607 (ethoxymethoxy)cyclododecane 58567-11-6 DEFHJK
608 Bisabolene 495-62-5 DEFHJK
609 Bigarade oxide 72429-08-4 ADEFHJKL
610 beta-Vetivone 18444-79-6 DHJK
611 beta-Terpinyl acetate 10198-23-9 BDHJK
612 beta-Terpineol 138-87-4 BCGIJK
613 beta-Sinensal 60066-88-8 DHJK
614 beta-Sesquiphellandrene 20307-83-9 DEFHJK
615 beta-Selinene 17066-67-0 BDEFGJK
616 beta-Santalol 77-42-9 DEFHJK
618 beta-Pinene 127-91-3 ADEFGIJKL
620 beta-Naphthyl ethyl ether 93-18-5 BDEFHJK
621 beta-Patchoulline 514-51-2 BDEFGJKL
624 beta-Himachalene Oxide 57819-73-5 BDFHJK
625 beta-Himachalene 1461-03-6 DEFHJKL
626 beta-Guaiene 88-84-6 DEFHJKL
627 (2,2-dimethoxyethyl)benzene 101-48-4 DHJK
628 beta-Farnesene 18794-84-8 DEFHJK
631 beta-Copaene 18252-44-3 BDEFHJKL
632 beta-Cedrene 546-28-1 BDEFGJKL
633 beta-Caryophyllene 87-44-5 DEFHJKL
635 beta-Bisabolol 15352-77-9 DFHJK
636 Beta ionone epoxide 23267-57-4 BDEFHIJK
638 Bergaptene 484-20-8 CGJ
639 Benzyl-tert-butanol 103-05-9 CEFGJK
644 Benzyl laurate 140-25-0 DEFHJ
649 Benzyl dimethyl carbinol 100-86-7 BCEFGIK
650 Benzyl cinnamate 103-41-3 DHJ
653 Benzyl benzoate 120-51-4 DHJ
655 Benzophenone 119-61-9 DEFHK
658 7-isopentyl-2H- 362467-67-2 DHJ
benzo[b][1,4]dioxepin-3(4H)-one
659 2′-isopropyl-1,7,7- 188199-50-0 DEFHJK
trimethylspiro[bicyclo[2.2.1]heptane-
2,4′-[1,3]dioxane]
660 4-(4-methylpent-3-en-1-yl)cyclohex- 21690-43-7 DEFHJK
3-ene-1-carbonitrile
661 Aurantiol 89-43-0 DEFHJ
663 Anisyl phenylacetate 102-17-0 DFHJ
668 Methyl (E)-octa-4,7-dienoate 189440-77-5 ACEFHKL
671 Amyl Cinnamate 3487-99-8 DEFHJK
673 (3aR,5aS,9aS,9bR)-3a,6,6,9a- 6790-58-5 DEFHJK
tetramethyldodecahydronaphtho[2,1-
b]furan
674 (4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJK
hexamethyloctahydro-4H-4a,9-
methanoazuleno[5,6-d][1,3]dioxole
675 2,5,5-trimethyl-1,2,3,4,5,6,7,8- 71832-76-3 DEFHJK
octahydronaphthalen-2-ol
676 2,5,5-trimethyl-1,2,3,4,5,6,7,8- 41199-19-3 DEFHJK
octahydronaphthalen-2-ol
677 1-((2-(tert- 139504-68-0 DEFHJK
butyl)cyclohexyl)oxy)butan-2-ol
678 (3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ
tetramethyldodecahydro-5H-3,5a-
epoxynaphtho[2,1-c]oxepine
679 2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 ADEFHJK
2H-indeno[4,5-b]furan
680 2,2,6,6,7,8,8-heptamethyldecahydro- 647828-16-8 ADEFHJK
2H-indeno[4,5-b]furan
681 Amber acetate 37172-02-4 BDEFHJK
682 Alpinofix ® 811436-82-5 DEFHJ
683 alpha-Thujone 546-80-5 ADEFGIJKL
684 alpha-Vetivone 15764-04-2 DHJK
686 alpha-Terpinyl propionate 80-27-3 BDEFHJK
691 alpha-Sinensal 17909-77-2 DHJK
692 alpha-Selinene 473-13-2 BDEFHJK
693 alpha-Santalene 512-61-8 ADEFHJKL
694 alpha-Santalol 115-71-9 DEFHJK
696 alpha-Patchoulene 560-32-7 ADEFHJKL
697 alpha-neobutenone 56973-85-4 BDHJK
698 alpha-Muurolene 10208-80-7 DEFHJKL
700 alpha-methyl ionone 127-42-4 BDHJK
702 alpha-Limonene 138-86-3 ADEFGIJKL
704 alpha-Irone 79-69-6 BDHJK
706 alpha-Humulene 6753-98-6 DEFHJK
707 alpha-Himachalene 186538-22-7 BDEFHJK
708 alpha-Gurjunene 489-40-7 BDEFHJKL
709 alpha-Guaiene 3691-12-1 DEFHJKL
710 alpha-Farnesene 502-61-4 DEFHJK
711 alpha-Fenchene 471-84-1 ADEFGIJKL
712 alpha-Eudesmol 473-16-5 DEFHJK
713 alpha-Curcumene 4176-17-4 DEFHJK
714 alpha-Cubebene 17699-14-8 ADEFHJKL
715 alpha-Cedrene epoxide 13567-39-0 ADEFHJK
716 alpha-Cadinol 481-34-5 DEFHJK
717 alpha-Cadinene 24406-05-1 DEFHJKL
718 alpha-Bisabolol 515-69-5 DFHJK
719 alpha-bisabolene 17627-44-0 DEFHJK
720 alpha-Bergamotene 17699-05-7 BDEFHJKL
721 alpha-Amylcinnamyl alcohol 101-85-9 DEFHJ
722 alpha-Amylcinnamyl acetate 7493-78-9 DEFHJ
723 alpha-Amylcinnamaldehyde diethyl 60763-41-9 DEFHJ
acetal
724 alpha-Amylcinnamaldehyde 122-40-7 DHJK
725 alpha-Amorphene 23515-88-0 DEFHJKL
726 alpha-Agarofuran 5956-12-7 BDEFHJK
727 1-methyl-4-(4-methyl-3-penten-1- 52475-86-2 DFHJK
yl)-3-Cyclohexene-1-carboxaldehyde
730 1-Phenyl-2-pentanol 705-73-7 CEFHK
731 1-Phenyl-3-methyl-3-pentanol 10415-87-9 CEFHJK
733 2,3,4-trimethoxy-benzaldehyde 2103-57-3 BCGI
735 2,4,5-trimethoxy-benzaldehyde 4460-86-0 BCG
736 2,4,6-trimethoxybenzaldehyde 830-79-5 BCGI
738 2,4-Nonadienal 6750-03-4 ACHKL
741 2,6,10-Trimethylundecanal 105-88-4 BDFGJK
742 alpha,4-Dimethyl benzenepropanal 41496-43-9 ACHJK
746 Allyl cyclohexyl propionate 2705-87-5 BDEFHJK
748 Allyl amyl glycolate 67634-00-8 BCEFGJK
750 Allo-aromadendrene 25246-27-9 BDEFHJKL
752 Aldehyde C-11 143-14-6 ADHJK
754 Methyl (E)-2-(((3,5- 94022-83-0 DEFHJ
dimethylcyclohex-3-en-1-
yl)methylene)amino)benzoate
757 2,6,10-trimethylundec-9-enal 141-13-9 BDFHJK
758 Acetoxymethyl-isolongifolene 59056-62-1 BDEFHJK
(isomers)
763 Acetate C9 143-13-5 BDEFHJKL
764 Acetarolle ® 744266-61-3 DFHJK
766 Acetaldehyde phenylethyl propyl 7493-57-4 CEFHJK
acetal
767 Acetaldehyde dipropyl acetal 105-82-8 ACEFGIKL
768 Acetaldehyde benzyl 2-methoxyethyl 7492-39-9 BCEFHJK
acetal
769 (Z)-2-(4-methylbenzylidene)heptanal 84697-09-6 DHJ
770 9-decenal 39770-05-3 ADHKL
771 8-Hexadecenolide 123-69-3 DGJ
772 7-Methoxycoumarin 531-59-9 CHK
774 7-epi-alpha-Selinene 123123-37-5 BDEFHJK
775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK
776 7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ
hexamethyltetralin
778 6-Isopropylquinoline 135-79-5 CEFHJK
781 6,6-dimethyl-2-norpinene-2- 33885-51-7 BCFHJK
propionaldehyde
782 6,10,14-trimethyl-2-Pentadecanone 502-69-2 DEFHJK
786 5-Isopropenyl-2-methyl-2- 13679-86-2 ACGIJKL
vinyltetrahydrofuran
788 5-Cyclohexadecenone 37609-25-9 DEFGJK
791 4-Terpinenol 562-74-3 BCHIJK
792 4-Pentenophenone 3240-29-7 BCEFHIK
800 4-Carvomenthenol 28219-82-1 BCHIJK
802 4,5,6,7-Tetrahydro-3,6- 494-90-6 BCEFHIJKL
dimethylbenzofuran
803 4-(p-Methoxyphenyl)-2-butanone 104-20-1 BCEFHJK
804 3-Thujopsanone 25966-79-4 BDEFHJK
805 3-Propylidenephthalide 17369-59-4 CEFHK
806 3-Nonylacrolein 20407-84-5 BDFHJK
807 3-Methyl-5-phenyl-1-pentanal 55066-49-4 BDFHJK
814 3-Hexenyl isovalerate 10032-11-8 ADEFHJKL
821 3,6-Dimethyl-3-octanyl acetate 60763-42-0 ADEFHIJKL
824 3,4,5-trimethoxybenzaldehyde 86-81-7 BCGIK
826 3-(p- 7775-00-0 BDFHJK
Isopropylphenyl)propionaldehyde
827 2-Undecenenitrile 22629-48-7 BDEFHJK
828 2-Undecenal 2463-77-6 ADHJK
829 2-trans-6-trans-Nonadienal 17587-33-6 ACHKL
831 2-Phenylethyl butyrate 103-52-6 DEFHJK
833 2-Phenyl-3-(2-furyl)prop-2-enal 57568-60-2 CHJ
834 2-Phenoxyethanol 122-99-6 BCEFGIK
837 2-Nonen-1-al 2463-53-8 ADHKL
839 2-Nonanol 628-99-9 BDEFGIKL
840 2-Nonanone 821-55-6 ADFHIKL
849 2-Isobutyl quinoline 93-19-6 CEFHJK
850 2-Hexylidene cyclopentanone 17373-89-6 DFHJKL
852 2-Heptyl tetrahydrofuran 2435-16-7 BDEFHJKL
856 2-Decenal 3913-71-1 ADHKL
864 2,6-Nonadienal 26370-28-5 ACHKL
865 2,6-Nonadien-1-ol 7786-44-9 ACEFHK
866 2,6-dimethyl-octanal 7779-07-9 ADFGIJKL
868 1-Decanol 112-30-1 BDEFGJK
869 1-Hepten-1-ol, 1-acetate 35468-97-4 ACEFHKL
870 10-Undecen-1-ol 112-43-6 DEFHJK
871 10-Undecenal 112-45-8 ADHJK
872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK
873 1,8-Thiocineol 68391-28-6 ADEFHIJKL
876 1,3,5-undecatriene 16356-11-9 ADEFHJKL
877 1,2-Dihydrolinalool 2270-57-7 BCEFGIJKL
878 1,3,3-trimethyl-2-norbornanyl 13851-11-1 ADEFHIJKL
acetate
879 1,1,2,3,3-Pentamethylindan 1203-17-4 ADHIJKL
881 (Z)-6,10-dimethylundeca-5,9-dien-2- 3239-37-0 DEFHJK
yl acetate
884 (Z)-3-Dodecenal 68141-15-1 BCFHJK
885 (S)-gamma-Undecalactone 74568-05-1 DEFHJKL
886 (R)-gamma-Undecalactone 74568-06-2 DEFHJKL
890 (E)-6,10-dimethylundeca-5,9-dien-2- 3239-35-8 DEFHJK
yl acetate
892 (2Z)-3-methyl-5-phenyl-2- 53243-59-7 DEFHJK
Pentenenitrile
893 (2S,5S,6S)-2,6,10,10-tetramethyl-1- 65620-50-0 DFHIJK
oxaspiro[4_5]decan-6-ol
894 (2E)-3-methyl-5-phenyl-2- 53243-60-0 CEFHJK
pentenenitrile
897 (+)-Dihydrocarveol 22567-21-1 BCEFHIJKL
905 Menthone 89-80-5 ADEFGIJKL
908 (R,E)-2-methyl-4-(2,2,3- 185068-69-3 CHJK
trimethylcyclopent-3-en-1-yl)but-2-
en-1-ol
912 2-(8-isopropyl-6- 68901-32-6 DEFHJK
methylbicyclo[2.2.2]oct-5-en-2-yl)-
1,3-dioxolane
913 gamma-methyl ionone 7388-22-9 BDHIJK
914 3-(3-isopropylphenyl)butanal 125109-85-5 BDHJK
916 3-(1-ethoxyethoxy)-3,7- 40910-49-4 BDEFHJK
dimethylocta-1,6-diene
919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJK
methanoinden-6-yl propionate
920 Bulnesol 22451-73-6 DEFHJK
922 Benzyl phenylacetate 102-16-9 DHJ
923 Benzoin 119-53-9 CEFHJ
924 (E)-1,2,4-trimethoxy-5-(prop-1-en-1- 2883-98-9 BCFGJK
yl)benzene
925 alpha,alpha,6,6-tetramethyl 33885-52-8 BDFHJK
bicyclo[3.1.1]hept-2-ene-propanal
926 7-epi-sesquithujene 159407-35-9 DEFHJKL
927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK
hexamethylindan
928 3-Methylphenethyl alcohol 1875-89-4 BCEFHIK
929 3,6-Nonadien-1-ol 76649-25-7 ACEFHK
930 2-Tridecenal 7774-82-5 BDFHJK
933 Patchouli alcohol 5986-55-0 DEFHIJK
937 p-Cresyl isobutyrate 103-93-5 BDHJK
939 p-Cresyl n-hexanoate 68141-11-7 DEFHJK
941 5-hexyl-4-methyldihydrofuran- 67663-01-8 BDEFHIJKL
2(3H)-one
942 Ethyl (2Z,4E)-deca-2,4-dienoate 3025-30-7 BDEFHJK
943 Pelargene 68039-40-7 DEFHJK
945 2-cyclohexylidene-2- 10461-98-0 DFHJK
phenylacetonitrile
946 Perillaldehyde 2111-75-3 ACHIJK
947 Perillyl acetate 15111-96-3 DFHJK
948 Perillyl alcohol 536-59-4 CHIJK
950 (2-isopropoxyethyl)benzene 68039-47-4 ACEFHJKL
951 Ethyl (2Z,4E)-deca-2,4-dienoate 313973-37-4 BDEFHJK
953 (2-(cyclohexyloxy)ethyl)benzene 80858-47-5 DEFHJK
954 Phenethyl 2-methylbutyrate 24817-51-4 DEFHJK
955 Phenethyl alcohol 60-12-8 BCEFGIK
959 Phenethyl phenylacetate 102-20-5 DHJ
962 Phenoxanol 55066-48-3 DEFHJK
965 Phenyl benzoate 93-99-2 DFHJK
967 Phenyl ethyl benzoate 94-47-3 DHJ
969 Phenylacetaldehyde ethyleneglycol 101-49-5 BCEFGIK
acetal
973 2-(6,6-dimethylbicyclo[3.1.1]hept-2- 30897-75-7 ACFHIJKL
en-2-yl)acetaldehyde
974 Pinocarveol 5947-36-4 BCEFGIJKL
976 Piperonyl acetone 55418-52-5 CEFGJ
978 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK
methanoinden-6-yl pivalate
980 (4aR,8aS)-7-methyloctahydro-1,4- 41724-19-0 CEFGJKL
methanonaphthalen-6(2H)-one
982 p-Menth-3-en-1-ol 586-82-3 BCGIJK
985 (E)-3,3-dimethyl-5-(2,2,3- 107898-54-4 DHJK
trimethylcyclopent-3-en-1-yl)pent-4-
en-2-ol
988 1-methyl-4-(4-methylpent-3-en-1- 52474-60-9 DFHJK
yl)cyclohex-3-ene-1-carbaldehyde
993 Propylene glycol 57-55-6 ACEFGIKL
998 p-Tolyl phenylacetate 101-94-0 DFHJ
1000 Ethyl 2,4,7-decatrienoate 78417-28-4 BDEFHJK
1003 2-benzyl-4,4,6-trimethyl-1,3-dioxane 67633-94-7 DEFHJK
1006 2,4-dimethyl-4- 82461-14-1 BDEFHJK
phenyltetrahydrofuran
1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK
3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-
spiro[oxirane-2,2′-
[1,4]methanonaphthalene]
1008 (Z)-6-ethylideneoctahydro-2H-5,8- 93939-86-7 BCEFHJKL
methanochromene
1009 2-((S)-1-((S)-3,3- 236391-76-7 DFHJ
dimethylcyclohexyl)ethoxy)-2-
oxoethyl propionate
1010 Methyl 2,2-dimethyl-6- 81752-87-6 ADHIJKL
methylenecyclohexane-1-carboxylate
1012 2-methyl-5-phenylpentan-1-ol 25634-93-9 DEFHJK
1016 4-methyl-2-phenyl-3,6-dihydro-2H- 60335-71-9 BCEFGJK
pyran
1020 Sabinol 471-16-9 BCEFHIJKL
1021 Safrole 94-59-7 BCEFHK
1022 2,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK
8-en-1-one
1023 3-methyl-5-(2,2,3- 65113-99-7 DEFHJK
trimethylcyclopent-3-en-1-yl)pentan-
2-ol
1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6 DEFHJK
trimethylcyclopent-3-en-1-yl)but-2-
en-1-ol
1025 (E)-2-methyl-4-(2,2,3- 28219-60-5 CHJK
trimethylcyclopent-3-en-1-yl)but-2-
en-1-ol
1026 5-methoxyoctahydro-1H-4,7- 86803-90-9 CHJK
methanoindene-2-carbaldehyde
1027 5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK
methanoindene-2-carbaldehyde
1028 Sclareol 515-03-7 DEFHJ
1029 Sclareol oxide 5153-92-4 DEFHJK
1031 Selina-3,7(11)-diene 6813-21-4 DEFHJKL
1032 2-(1-(3,3- 477218-42-1 DEFHJ
dimethylcyclohexyl)ethoxy)-2-
methylpropyl
cyclopropanecarboxylate
1033 3-(4-isobutylphenyl)-2- 6658-48-6 DHJK
methylpropanal
1035 Spathulenol 6750-60-3 DEFHJK
1036 Spirambrene 533925-08-5 BCEFHJK
1037 Spirodecane 6413-26-9 BCEFGIJKL
1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK
1-one
1042 2-(4-methylthiazol-5-yl)ethan-1-ol 137-00-8 CGIKL
1043 2-(heptan-3-yl)-1,3-dioxolane 4359-47-1 ACEFHIJKL
1045 (Z)-dodec-4-enal 21944-98-9 BDFHJK
1046 tau-Cadinol 5937-11-1 DEFHJK
1047 tau-Muurolol 19912-62-0 DEFHJK
1053 Tetrahydrojasmone 13074-63-0 BDFHIJKL
1057 2,6,10,10-tetramethyl-1- 36431-72-8 BDFHIJKL
oxaspiro[4.5]dec-6-ene
1059 Thiomenthone 38462-22-5 BDEFHIJKL
1060 Thujopsene 470-40-6 BDEFGJKL
1062 Thymol methyl ether 1076-56-8 ADHIJKL
1063 1-(2,2,6-trimethylcyclohexyl)hexan- 70788-30-6 DEFHJK
3-ol
1064 trans,trans-2,4-Nonadienal 5910-87-2 ACHKL
1065 trans,trans-Farnesol 106-28-5 DEFHJK
1066 trans-2,cis-6-Nonadienal 557-48-2 ACHKL
1067 trans-2-Decenal 3913-81-3 ADHKL
1070 trans-2-Nonen-1-al 18829-56-6 ADHKL
1072 trans-3, cis-6-nonadienol 56805-23-3 ACEFHK
1073 trans-4-Decen-1-al 65405-70-1 ADHKL
1075 trans-ambrettolide 51155-12-5 DGJ
1077 trans-beta-ocimene 13877-91-3 ADGIKL
1078 trans-beta-Ocimene 3779-61-1 ADGIKL
1082 trans-Geraniol 106-24-1 BCHIK
1083 trans-Hedione 2570-03-8 DFHJK
1085 7-(1,1-Dimethylethyl)-2H-1,5- 195251-91-3 CEFHJ
benzodioxepin-3(4H)-one
1089 Tricyclone 68433-81-8 DEFHJK
1090 Tridecyl alcohol 112-70-9 DEFGJK
1091 Triethyl citrate 77-93-0 CEFGJ
1093 Methyl 2-((1-hydroxy-3- 144761-91-1 DFHJ
phenylbutyl)amino)benzoate
1095 1-((2E,5Z,9Z)-2,6,10- 28371-99-5 DHJK
trimethylcyclododeca-2,5,9-trien-1-
yl)ethan-1-one
1097 Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 BDEFHJK
2h-indeno(4,5-b)furan
1099 13-methyl oxacyclopentadec-10-en- 365411-50-3 DEFHJK
2-one
1102 Undecanal 112-44-7 BDHJK
1104 (E)-4-methyldec-3-en-5-ol 81782-77-6 BDEFHIJK
1105 Valencene 4630-07-3 BDEFHJK
1107 Valerianol 20489-45-6 DEFHJK
1111 Vanillin isobutyrate 20665-85-4 CHJ
1113 Vaniwhite ® 5533-03-9 CGIK
1116 (Z)-2-methyl-4-(2,6,6- 68555-62-4 BDFHJK
trimethylcyclohex-2-en-1-yl)but-2-
enal
1117 Methyl 2,4-dihydroxy-3,6- 4707-47-5 CGIJ
dimethylbenzoate
1120 1-methoxy-3a,4,5,6,7,7a-hexahydro- 27135-90-6 ACEFHJKL
1H-4,7-methanoindene
1121 Methyl (Z)-2-((3-(4-(tert- 91-51-0 DFHJ
butyl)phenyl)-2-
methylpropylidene)amino)benzoate
1125 (Z)-hex-3-en-1-yl isobutyrate 41519-23-7 ADEFHJKL
1126 Vertacetal 5182-36-5 BCFHJK
1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9 DHJK
tetramethyl-2,3,4,7,8,8a-hexahydro-
1H-3a,7-methanoazulen-5-yl)ethan-
1-one
1131 Methyl (Z)-2-(((2,4- 68738-99-8 DEFHJ
dimethylcyclohex-3-en-1-
yl)methylene)amino)benzoate
1135 Vetiverol 89-88-3 CEFHIJK
1136 Vetivert Acetate 117-98-6 DEFHJK
1137 Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL
[4,7]methanoindene]
1138 (2Z,6E)-nona-2,6-dienenitrile 67019-89-0 ACEFHKL
1139 (Z)-cyclooct-4-en-1-yl methyl 87731-18-8 BCHJKL
carbonate
1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJK
tetramethyldecahydro-1H-
cyclopropa[e]azulen-4-ol
1142 3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ
tetrahydronaphthalene-2-carbonitrile
1143 (1S,2S,3S,5R)-2,6,6- 133636-82-5 DEFHJK
trimethylspiro[bicyclo[3.1.1]heptane-
3,1′-cyclohexan]-2′-en-4′-one
1144 1′,1′,5′,5′-tetramethylhexahydro- 154171-76-3 DEFHJK
2′H,5′H-spiro[[1,3]dioxolane-2,8′-
[2,4a]methanonaphthalene]
1145 1′,1′,5′,5′-tetramethylhexahydro- 154171-77-4 DEFHJK
2′H,5′H-spiro[[1,3]dioxolane-2,8′-
[2,4a]methanonaphthalene] K
1146 4-(4-hydroxy-3- 122-48-5 CEFGJ
methoxyphenyl)butan-2-one
1147 (1R,8aR)-4-isopropyl-1,6-dimethyl- 41929-05-9 DEFHJKL
1,2,3,7,8,8a-hexahydronaphthalene
1148 4,5-epoxy-4,11,11-trimethyl-8- 1139-30-6 DEFHJK
methylenebicyclo(7.2.0)undecane
1149 1,3,4,6,7,8alpha-hexahydro-1,1,5,5- 23787-90-8 DEFHIJK
tetramethyl-2H-2,4alpha-
methanophthalen-8(5H)-one
TABLE 2
List of materials with at least one MORV greater than 5 to 10
Num- CAS Comment
ber Material Name Number Code
2 2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ
5,6,7,8-tetrahydronaphthalen-2-yl)-
1,3-dioxolane
23 3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK
2,2,6,6,7,8,8-heptamethyl-4H-
indeno(4,5-d)-1,3-dioxole
141 2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK
tetrahydroindeno[1,2-d][1,3]dioxine
185 (1-methyl-2-((1,2,2- 198404-98-7 DEFHJK
trimethylbicyclo[3.1.0]hexan-3-
yl)methyl)cyclopropyl)methanol
227 Isobornylcyclohexanol 68877-29-2 DEFHJK
230 Isobornyl cyclohexanol 66072-32-0 DEFHJK
246 Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ
248 Hydroxymethyl isolongifolene 59056-64-3 DEFHJK
343 8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK
hexahydro-1H-4,7-methanoinden-6-
yl propionate
359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK
1,3a,4,6,7,7a-hexahydro-5H-4,7-
methanoinden-5-ylidene)-3-
methylbutan-2-ol
565 Cedryl methyl ether 19870-74-7 BDEFHJK
631 beta-Copaene 18252-44-3 BDEFHJKL
659 2′-isopropyl-1,7,7- 869292-93-3 BDEFHJK
trimethylspiro[bicyclo[2.2.1]heptane-
2,4′-[1,3]dioxane]
674 (4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJK
hexamethyloctahydro-4H-4a,9-
methanoazuleno[5,6-d][1,3]dioxole
678 (3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ
tetramethyldodecahydro-5H-3,5a-
epoxynaphtho[2,1-c]oxepine
679 2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 DEFHJK
2H-indeno[4,5-b]furan
715 alpha-Cedrene epoxide 13567-39-0 BDEFHJK
758 Acetoxymethyl-isolongifolene 59056-62-1 DEFHJK
(isomers)
1028 Sclareol 515-03-7 DEFHJ
1097 Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 DEFHJK
2h-indeno(4,5-b)furan
TABLE 3
List of materials with at least one MORV from 0.5 to less than 1
Num- CAS Comment
ber Material Name Number Code
12 1-ethoxy-4-(tert- 181258-89-9 ADEFHJK
pentyl)cyclohexane
19 (3Z)-1-(2-buten-1-yloxy)-3- 888744-18-1 ADEFHJKL
hexene
20 4-(2-methoxypropan-2-yl)-1- 14576-08-0 ADHIJKL
methylcyclohex-1-ene
24 O-Methyl linalool 60763-44-2 ADHIJKL
26 o-Methoxycinnamaldehyde 1504-74-1 ACHK
27 Octanal, 3,7-dimethyl- 25795-46-4 ADGIJKL
53 3,3-Dimethyl-5(2,2,3- 329925-33-9 CEFHJ
Trimethyl-3-Cyclopenten-
1yl)-4-Penten-2-ol
54 n-Hexyl salicylate 6259-76-3 DEFHJ
55 n-Hexyl 2-butenoate 19089-92-0 ADEFHJKL
59 Neryl Formate 2142-94-1 BCEFHJK
72 Methyl-beta-ionone 127-43-5 DHJK
73 Myroxide 28977-57-3 ADGIJKL
81 (E)-3,7-dimethylocta-4,6- 18479-54-4 BCEFGIJK
dien-3-ol
84 (Z)-hex-3-en-1-yl 188570-78-7 BCEFHIKL
cyclopropanecarboxylate
96 Methyl phenyl carbinyl 120-45-6 BCHJK
propionate
97 Methyl phenylacetate 101-41-7 ACEFHIKL
107 2-methyl-6- 91069-37-3 BCEFGIKL
oxaspiro[4.5]decan-7-one
111 Methyl geraniate 2349-14-6 BCHJKL
115 2-ethoxy-4- 5595-79-9 CFGK
(methoxymethyl)phenol
116 Methyl 40203-73-4 ACEFHIKL
cyclopentylideneacetate
125 Methoxymelonal 62439-41-2 ACGIJK
133 ((1s,4s)-4- 13828-37-0 BDEFHIJK
isopropylcyclohexyl)methanol
147 Linalyl propionate 144-39-8 BDFHJK
150 Linalyl formate 115-99-1 ACFHJK
151 Linalyl butyrate 78-36-4 BDEFHJK
154 Linalyl acetate 115-95-7 BDHJK
157 Linalool 78-70-6 BCEFGIJK
163 (Z)-hex-3-en-1-yl methyl 67633-96-9 ACEFGKL
carbonate
166 Lepidine 491-35-0 BCEFHIKL
169 L-Carvone 6485-40-1 ACGIJKL
181 Khusinil 75490-39-0 DHJK
191 Isoraldeine 1335-46-2 BDHIJK
194 Isopropylvinylcarbinol 4798-45-2 ACGIKL
198 Isopropyl 2-methylbutyrate 66576-71-4 ACEFGIJKL
201 Isopentyrate 80118-06-5 ADEFGIJKL
204 Isononyl acetate 40379-24-6 BDEFHJKL
205 Isononanol 27458-94-2 BDEFGIKL
213 Isoeugenyl acetate 93-29-8 CFHJK
214 Isoeugenol 97-54-1 CEFHIK
232 Isoborneol 124-76-5 ACEFHIJKL
237 Isoamyl octanoate 2035-99-6 DEFHJK
239 Isoamyl isobutyrate 2050-01-3 ACEFGIJKL
255 Hydrocinnamic acid 501-52-0 CEFHIK
258 Hydratopic alcohol 1123-85-9 BCEFHIK
264 Hexyl propanoate 2445-76-3 ADEFHIKL
270 Hexyl butyrate 2639-63-6 BDEFHJKL
273 Hexyl 2-methylbutanoate 10032-15-2 BDEFHJKL
275 Hexyl 2-furoate 39251-86-0 DEFHJK
282 Heptyl alcohol 111-70-6 ACEFGIKL
283 Heptyl acetate 112-06-1 ADEFHKL
284 Heptaldehyde 111-71-7 ACHIKL
287 Heliotropin 120-57-0 BCGIK
302 Geranyl nitrile 5146-66-7 BCEFHKL
306 Geranyl formate 105-86-2 BCEFHJK
308 Geranyl caprylate 51532-26-4 DEFHJ
310 Geranyl benzoate 94-48-4 DFHJ
312 Geranial 141-27-5 ACHIKL
314 N,2-dimethyl-N- 84434-18-4 BCEFHJK
phenylbutanamide
319 gamma-Terpinene 99-85-4 ADEFGIJKL
346 2-(sec-butyl)cyclohexan-1- 14765-30-1 ADFHIKL
one
354 3-(2-ethylphenyl)-2,2- 67634-14-4 BDHJK
dimethylpropanal
355 2-(tert-butyl)cyclohexyl ethyl 67801-64-3 BDFHJK
carbonate
365 2-(tert-butyl)cyclohexyl ethyl 81925-81-7 ACFHIKL
carbonate
366 Fenchyl alcohol 1632-73-1 ACGIJKL
376 Eucalyptol 470-82-6 ADEFGIJKL
379 Ethyl vanillin acetate 72207-94-4 CHJ
387 Ethyl octanoate 106-32-1 BDEFHJKL
400 Ethyl cinnamate 103-36-6 BCEFHK
412 Ethyl 2- 2511-00-4 BDFHIJKL
(cyclohexyl)propionate
419 d-p-8(9)-Menthen-2-one 5524-05-0 ACGIJKL
420 4-methyl-2-phenyltetrahydro- 94201-73-7 BDEFHJK
2H-pyran
437 Dihydromyrcenol 18479-58-8 ADEFGIJK
438 Dihydrojasmone 1128-08-1 BCFHIJKL
439 Dihydroisophorone 873-94-9 ACEFGIJKL
440 Dihydroeugenol 2785-87-7 CEFHIJK
442 Dihydrocoumarin 119-84-6 BCGIKL
443 Dihydrocarvone 7764-50-3 ACGIJKL
447 Dihydro-alpha-terpinyl 80-25-1 BDEFHIJKL
acetate
448 Dihydro-alpha-ionone 31499-72-6 BDHIJK
454 Dibenzyl ether 103-50-4 DEFHJK
455 Dibutyl o-phthalate 84-74-2 DEFHJ
469 2-pentylcyclopentan-1-one 4819-67-4 BDFHIKL
472 Decyl anthranilate 18189-07-6 DEFHJ
477 Methyl (1s,4s)-1,4- 23059-38-3 ADEFHIJKL
dimethylcyclohexane-1-
carboxylate
481 Cyclohexylethyl acetate 21722-83-8 BDEFHJKL
492 Creosol 93-51-6 BCHIK
495 Cosmene 460-01-5 ADEFGIKL
496 4-cyclohexyl-2-methylbutan- 83926-73-2 BDEFGIJK
2-ol
504 2-benzyl-2-methylbut-3- 97384-48-0 BDHJK
enenitrile
509 Citronellyl nitrile 51566-62-2 BCEFGIKL
510 Citronellyl phenylacetate 139-70-8 DFHJ
512 Citronellyl formate 105-85-1 BCEFGJKL
515 Citronellyl benzoate 10482-77-6 DFHJ
517 Citronellol 106-22-9 BCHIJKL
518 Citronellal 106-23-0 ACHIJKL
522 Citral 5392-40-5 ACHIKL
525 cis-Pinane 6876-13-7 ADEFGIJKL
526 (Z)-3-methyl-2-(pent-2-en-1- 488-10-8 BCHIJKL
yl)cyclopent-2-en-1-one
528 cis-iso-Eugenol 5912-86-7 CEFHIK
535 cis-3-Hexenyl valerate 35852-46-1 BDEFHJKL
536 cis-3-Hexenyl tiglate 67883-79-8 BDEFHJK
538 cis-3-Hexenyl propionate 33467-74-2 ACEFHIKL
540 cis-3-Hexenyl butyrate 16491-36-4 ADEFHJKL
542 cis-3-Hexen-1-ol 928-96-1 ACEFHIKL
547 cis-2-Hexenol 928-94-9 ACEFHIKL
549 Cinnamyl nitrile 4360-47-8 ACEFGIK
554 Cinnamic aldehyde 104-55-2 ACHIK
556 Cinnamyl nitrile 1885-38-7 ACEFGIK
557 Chloroxylenol 88-04-0 BCHIJK
575 Carvacrol 499-75-2 DHIJK
576 Carvone 99-49-0 ACGIJKL
579 Carbitol 111-90-0 BCEFGIK
583 Caproyl alcohol 111-27-3 ACEFGIKL
585 2-(2,2,3-trimethylcyclopent-3- 15373-31-6 ACGIJKL
en-1-yl)acetonitrile
588 Camphor 76-22-2 ACEFGIJKL
602 (E)-2-methyl-4-(2,6,6- 3155-71-3 DHJK
trimethylcyclohex-1-en-1-
yl)but-2-enal
605 Borneol 507-70-0 ACEFHIJKL
617 beta-Pinene epoxide 6931-54-0 ACEFGIJKL
619 beta-Phellandrene 555-10-2 ADEFGIJKL
640 Benzylacetone 2550-26-7 ACEFGIK
641 Benzyl salicylate 118-58-1 DFGJ
645 Benzyl isovalerate 103-38-8 BDEFHJK
647 Benzyl isobutyrate 103-28-6 BCHJK
651 Benzyl butyrate 103-37-7 BCEFHJK
652 Benzyl alcohol 100-51-6 ACEFGIKL
662 1-(3,3- 25225-08-5 ADEFHIJKL
dimethylcyclohexyl)ethyl
formate
664 Anisyl acetate 104-21-2 BCEFGK
665 Anisyl formate 122-91-8 BCEFGK
667 Anethole 104-46-1 ACEFHK
672 Amyl benzoate 2049-96-9 DEFHJK
687 alpha-Terpinyl acetate 80-26-2 BDHJK
699 alpha-methyl- 10528-67-3 BDEFHIK
cyclohexanepropanol
701 alpha-methyl cinnamaldehyde 101-39-3 ACHIK
703 alpha-Isomethylionone 127-51-5 BDHIJK
740 2,5-Dimethyl-4-methoxy- 4077-47-8 ACEFGIJKL
3(2H)-furanone
743 Allyl phenoxyacetate 7493-74-5 BCGK
744 Allyl Phenethyl ether 14289-65-7 ACEFHK
745 Allyl heptanoate 142-19-8 ADEFHJKL
755 N-ethyl-N-(m- 179911-08-1 CEFHJK
tolyl)propionamide
760 3-hydroxybutan-2-one 513-86-0 ACEFGIKL
761 Acetoanisole 100-06-1 BCEFHIK
777 6-Methylquinoline 91-62-3 BCEFHIKL
779 6,8-Diethyl-2-nonanol 70214-77-6 BDEFGIJKL
784 5-Methyl-3-heptanone 541-85-5 ACFGIKL
789 4-Vinylphenol 2628-17-3 BCHIK
796 4-hydroxy-3-methoxy- 458-36-6 CH
cinnamaldehyde
797 4-Ethylguaiacol 2785-89-9 CEFHIK
799 4-Damascol 4927-36-0 BDFHJK
808 3-methyl-4-phenylpyrazole 13788-84-6 CEFHK
810 3-Methyl-1,2- 765-70-8 ACEFGIKL
cyclopentanedione
811 3-Methoxy-5-methylphenol 3209-13-0 BCHIK
812 3-Methoxy-3-Methyl Butanol 56539-66-3 ACGIKL
817 3-Hexenol 544-12-7 ACEFHIKL
819 3,7-dimethyl-2-methylene-6- 22418-66-2 ADFHIJK
octenal
820 3,7-dimethyl-1-octanol 106-21-8 BDEFGIJKL
832 2-Phenylethyl acetate 103-45-7 BCEFHK
835 2-Phenethyl propionate 122-70-3 BCEFHJK
836 2-Pentylcyclopentan-1-ol 84560-00-9 DEFHIKL
838 2-nonanone propylene glycol 165191-91-3 BDEFHJK
acetal
845 2-Methoxy-3-(1- 24168-70-5 BCEFGIK
methylpropyl)pyrazine
846 2-isopropyl-N,2,3- 51115-67-4 ACEFGIJK
trimethylbutyramide
847 2-Isopropyl-5-methyl-2- 35158-25-9 ADFGIJKL
hexenal
848 2-Isopropyl-4-methylthiazole 15679-13-7 ACHIJKL
851 2-Hexen-1-ol 2305-21-7 ACEFHIKL
858 2-Butoxyethanol 111-76-2 ACEFGIKL
875 1,4-Cineole 470-67-7 ADGIJKL
880 1-(2,6,6-Trimethyl-2- 43052-87-5 BDHIJK
cyclohexen-1-yl)-2-buten-1-one
882 (Z)-3-hepten-1-yl acetate 1576-78-9 ACEFHKL
883 (S)-(1R,5R)-4,6,6- 1196-01-6 ACEFGIJKL
trimethylbicyclo[3.1.1]hept-3-
en-2-one
888 (R)-(−)-Linalool 126-91-0 BCEFGIJK
889 (l)-Citronellal 5949-05-3 ACHIJKL
891 (d)-Citronellal 2385-77-5 ACHIJKL
899 (+)-Citronellol 1117-61-9 BCHIJKL
900 (−)-Citronellol 7540-51-4 BCHIJKL
901 (+)-alpha-Pinene 7785-70-8 ADEFGIJKL
902 (+)-Carvone 2244-16-8 ACGIJKL
903 (−)-alpha-Pinene 7785-26-4 ADEFGIJKL
904 Methyl 2-methylbutyrate 868-57-5 ACEFGIKL
909 Hexyl tiglate 16930-96-4 BDEFHJKL
918 Allyl 2- 68901-15-5 CHJK
(cyclohexyloxy)acetate
921 1,5- 75147-23-8 CFHIJK
dimethylbicyclo[3.2.1]octan-
8-one oxime
931 alpha-acetoxystyrene 2206-94-2 ACEFHIK
940 p-Cymene 99-87-6 ADGIJKL
956 Phenethyl formate 104-62-1 ACEFHK
958 Phenethyl isobutyrate 103-48-0 DHJK
960 Phenethyl tiglate 55719-85-2 DHJK
971 Phenylethyl methacrylate 3683-12-3 DHJK
977 p- 4395-92-0 BDFHK
Isopropylphenylacetaldehyde
981 1,2-dimethyl-3-(prop-1-en-2- 72402-00-7 BCEFGIJKL
yl)cyclopentan-1-ol
983 p-Methoxyphenylacetone 122-84-9 BCEFHK
986 (2Z,5Z)-5,6,7-trimethylocta- 358331-95-0 ADHIJKL
2,5-dien-4-one
987 p-Propyl anisole 104-45-0 ADEFHKL
994 p-t-butyl phenyl acetaldehyde 109347-45-7 BDHJK
995 p-tert-Amyl cyclohexanol 5349-51-9 BDEFHIJK
1001 Racemic alpha-Pinene 80-56-8 ADEFGIJKL
1002 4-(4-hydroxyphenyl)butan-2- 5471-51-2 CEFGIK
one
1004 Rhodinol 141-25-3 BCHIJKL
1005 Ethyl (2,3,6- 93981-50-1 BDEFHJKL
trimethylcyclohexyl)
carbonate
1011 1-(3,3- 25225-10-9 ADHIJKL
dimethylcyclohexyl)ethyl
acetate
1017 S)-(+)-Linalool 126-90-9 BCEFGIJK
1018 Sabinene 3387-41-5 ADEFGIJKL
1019 Sabinene hydrate 546-79-2 ADEFGIJKL
1030 Propyl (S)-2-(tert- 319002-92-1 BDEFHJK
pentyloxy)propanoate
1039 Spirolide 699-61-6 BCGIKL
1040 (Z)-5-methylheptan-3-one 22457-23-4 BCEFGIJKL
oxime
1041 1-phenylethyl acetate 93-92-5 ACEFHIK
1051 Tetrahydrogeranial 5988-91-0 ADGIJKL
1052 Tetrahydroionol 4361-23-3 BDEFHIJK
1054 Tetrahydrolinalool 78-69-3 BDEFGIJKL
1055 Tetrahydrolinalyl acetate 20780-48-7 ADEFHJKL
1058 Ethyl (1R,6S)-2,2,6- 22471-55-2 ADEFHIJKL
trimethylcyclohexane-1-
carboxylate
1061 Thymol 89-83-8 BDHIJK
1069 trans-2-Hexenol 928-95-0 ACEFHIKL
1071 trans-2-tert- 5448-22-6 ACGIJKL
Butylcyclohexanol
1074 trans-alpha-Damascone 24720-09-0 BDHIJK
1076 trans-Anethole 4180-23-8 ACEFHK
1079 trans-Cinnamic acid 140-10-3 CEFHK
1081 trans-Dihydrocarvone 5948-04-9 ACGIJKL
1084 trans-Isoeugenol 5932-68-3 CEFHIK
1088 Trichloromethyl phenyl 90-17-5 BDEFGJ
carbinyl acetate
1098 2-mercapto-2-methylpentan- 258823-39-1 ACEFHIJKL
1-ol
1110 Vanillin acetate 881-68-5 CH
1112 Vanitrope 94-86-0 CEFHK
1115 2,2,5-trimethyl-5- 65443-14-3 BDFGIJKL
pentylcyclopentan-1-one
1118 Veratraldehyde 120-14-9 BCGIK
1119 (1R,5R)-4,6,6- 18309-32-5 ACEFGIJKL
trimethylbicyclo[3.1.1]hept-3-
en-2-one
1122 Verdol 13491-79-7 ACGIJKL
1127 4-(tert-butyl)cyclohexyl 10411-92-4 BDEFHJK
acetate
1128 4-(tert-butyl)cyclohexyl 32210-23-4 BDEFHJK
acetate
1133 Vethymine 7193-87-5 CEFGK
1134 4-methyl-4-phenylpentan-2-yl 68083-58-9 BDFHJK
acetate
1141 (Z)-1-((2- 292605-05-1 ADEFHKL
methylallyl)oxy)hex-3-ene
TABLE 4
List of materials with ALL MORVs from 1 to 5
Num- CAS Comment
ber Material Name Number Code
7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK
methylenebicyclo[4.3.1]decane
14 Oxyoctaline formate 65405-72-3 DFHJK
39 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJK
octahydronaphthalen-1-ol
48 Nootkatone 4674-50-4 DHJK
183 Khusimol 16223-63-5 CEFHJK
199 Isopimpinellin 482-27-9 CFGJ
206 Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK
212 Isoeugenyl benzyl ether 120-11-6 DFHJ
215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK
1,2,3,4,5,6,7,8-octahydronaphthalen-
2-yl)ethan-1-one
229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK
260 2,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK
5-propanal
261 3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK
inden-5-yl)propanal
281 3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK
methanoinden-6-yl acetate
329 gamma-Eudesmol 1209-71-8 DFHJK
335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJK
hexahydrocyclopenta[g]isochromene
353 (Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK
methanochromen-2-one
360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJK
hexahydro-1H-4,7-methanoinden-6-
yl acetate
441 Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL
yl acetate
484 3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK
methanoinden-6-yl butyrate
487 3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJK
methanoinden-5-yl isobutyrate
488 Curzerene 17910-09-7 DHJK
501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ
566 Cedryl formate 39900-38-4 BDEFHJK
567 Cedryl acetate 77-54-3 DEFHJK
569 Cedrol 77-53-2 DEFHJK
570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK
trimethylcyclopent-3-en-1-yl)-6-
oxabicyclo[3.2.1]octane
573 Caryophyllene alcohol acetate 32214-91-8 DEFHJK
574 Caryolan-1-ol 472-97-9 DEFHJK
603 Bornyl isobutyrate 24717-86-0 BDEFHIJK
616 beta-Santalol 77-42-9 DEFHJK
621 beta-Patchoulline 514-51-2 BDEFGJKL
624 beta-Himachalene Oxide 57819-73-5 BDFHJK
627 (2,2-dimethoxyethyl)benzene 101-48-4 DHJK
632 beta-Cedrene 546-28-1 BDEFGJKL
663 Anisyl phenylacetate 102-17-0 DFHJ
680 2,2,6,6,7,8,8-heptamethyldecahydro- 647828-16-8 ADEFHJK
2H-indeno[4,5-b]furan
684 alpha-Vetivone 15764-04-2 DHJK
694 alpha-Santalol 115-71-9 DEFHJK
696 alpha-Patchoulene 560-32-7 ADEFHJKL
708 alpha-Gurjunene 489-40-7 BDEFHJKL
712 alpha-Eudesmol 473-16-5 DEFHJK
714 alpha-Cubebene 17699-14-8 ADEFHJKL
726 alpha-Agarofuran 5956-12-7 BDEFHJK
750 Allo-aromadendrene 25246-27-9 BDEFHJKL
764 Acetarolle ® 744266-61-3 DFHJK
775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK
776 7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ
hexamethyltetralin
788 5-Cyclohexadecenone 37609-25-9 DEFGJK
804 3-Thujopsanone 25966-79-4 BDEFHJK
872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK
919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJK
methanoinden-6-yl propionate
927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK
hexamethylindan
933 Patchouli alcohol 5986-55-0 DEFHIJK
978 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK
methanoinden-6-yl pivalate
1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK
3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-
spiro[oxirane-2,2′-
[1,4]methanonaphthalene]
1022 2,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK
8-en-1-one
1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6 DEFHJK
trimethylcyclopent-3-en-1-yl)but-2-
en-1-ol
1027 5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK
methanoindene-2-carbaldehyde
1029 Sclareol oxide 5153-92-4 DEFHJK
1035 Spathulenol 6750-60-3 DEFHJK
1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK
1-one
1060 Thujopsene 470-40-6 BDEFGJKL
1089 Tricyclone 68433-81-8 DEFHJK
1107 Valerianol 20489-45-6 DEFHJK
1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9 DHJK
tetramethyl-2,3,4,7,8,8a-hexahydro-
1H-3a,7-methanoazulen-5-yl)ethan-
1-one
1131 Methyl (Z)-2-(((2,4- 68738-99-8 DEFHJ
dimethylcyclohex-3-en-1-
yl)methylene)amino)benzoate
1136 Vetivert Acetate 117-98-6 DEFHJK
1137 Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL
[4,7]methanoindene]
1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJK
tetramethyldecahydro-1H-
cyclopropa[e]azulen-4-ol
1142 3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ
tetrahydronaphthalene-2-carbonitrile
1143 (1S,2S,3S,5R)-2,6,6- 133636-82-5 DEFHJK
trimethylspiro[bicyclo[3.1.1]heptane-
3,1′-cyclohexan]-2′-en-4′-one
1144 1′,1′,5′,5′-tetramethylhexahydro- 154171-76-3 DEFHJK
2′H,5′H-spiro[[1,3]dioxolane-2,8′-
[2,4a]methanonaphthalene]
1145 1′,1′,5′,5′-tetramethylhexahydro- 154171-77-4 DEFHJK
2′H,5′H-spiro[[1,3]dioxolane-2,8′-
[2,4a]methanonaphthalene] K
1148 4,5-epoxy-4,11,11-trimethyl-8- 1139-30-6 DEFHJK
methylenebicyclo(7.2.0)undecane
1149 1,3,4,6,7,8alpha-hexahydro-1,1,5,5- 23787-90-8 DEFHIJK
tetramethyl-2H-2,4alpha-
methanophtalen-8(5H)-one
TABLE 5
List of materials with ALL MORVs greater than 5 to 10
Num- CAS Comment
ber Material Name Number Code
248 Hydroxymethyl isolongifolene 59056-64-3 BDEFHJK
TABLE 6
List of materials with ALL MORVs from 0.5 to less than 1
Num- CAS Comment
ber Material Name Number Code
472 Decyl anthranilate 18189-07-6 DEFHJ
526 (Z)-3-methyl-2-(pent-2-en- 488-10-8 BCHIJKL
1-yl)cyclopent-2-en-1-one
The materials in Tables 1-6 can be supplied by one or more of the following: Firmenich Inc. of Plainsboro N.J. USA; International Flavor and Fragrance Inc. New York, N.Y. USA; Takasago Corp. Teterboro, N.J. USA; Symrise Inc. Teterboro, N.J. USA; Sigma-Aldrich/SAFC Inc. Carlsbad, Calif. USA; and Bedoukian Research Inc. Danbury, Conn. USA.
Actual MORV values for each material listed in Tables 1-6 above are as follows:
MORV MORV MORV MORV
Material value for Value for Value for value for
No. Equation a.) Equation b.) Equation c.) Equation d.)
1 0.548223914 0.876283261 1.22018588 −0.41901144
2 1.520311929 3.493450446 2.70657265 5.11342862
3 2.267801995 −0.81712657 0.43218875 1.595983683
4 −0.591063369 −0.48283571 0.16199804 1.210497701
7 1.437444636 2.131822996 3.81633465 1.318339345
9 2.151445882 −0.46189495 0.56090469 1.206360803
10 2.5733592 −0.58780849 1.39751471 1.258361951
11 3.052627325 1.008519135 −0.30475953 0.076323462
12 0.683776599 −0.01157903 0.82853231 0.326169402
13 1.549643217 1.809183231 0.70864531 2.22799611
14 2.82111224 2.339505033 1.240818 2.502429355
16 −0.31551128 −0.06816599 −0.04371934 2.76742389
17 −1.334904153 −0.5773313 1.75644798 1.898455724
18 −1.34154226 −2.63596666 0.06885109 1.001431671
19 0.15532384 0.09866097 0.64214585 −0.33330779
20 0.640261783 0.693213268 0.54637273 −0.97556029
21 0.936895364 −0.01521118 1.1697513 −0.63510809
22 1.158981042 1.115900089 −0.25859776 1.318200884
23 3.702361074 1.399942641 5.23954766 7.089933671
24 0.773874141 0.146848137 −1.05705847 −0.36193173
25 −1.016103969 −1.18967936 0.78064625 2.944710012
25 −1.016103969 −1.18967936 0.78064625 2.944710012
26 0.615085491 −0.00096877 −0.35697252 −0.18121401
27 0.70261974 −0.22197386 0.19710806 −2.37196477
28 1.366472597 −0.42546942 −0.59394241 −0.01417395
29 1.096043453 −1.02972898 −1.42167356 −0.63817943
30 1.143415203 −0.85945441 −0.41416913 2.499807942
31 1.138642907 −0.19595476 −0.54547769 −0.98828898
32 1.914414495 −0.64487788 0.63212987 1.166699371
33 0.314847366 1.848003955 −1.3905032 −0.62848261
34 −0.113542761 0.981530917 0.32824239 1.126524277
35 0.472382903 1.494882467 −0.07201236 −0.64589543
36 3.158513795 1.084094934 −0.00328981 −0.17786385
37 −1.055631982 2.240172964 0.92596118 2.105391988
38 3.158513795 0.592820874 −0.49326241 0.212867212
39 1.083800659 2.069727985 2.48170879 3.205630609
42 −0.103134861 0.267726008 −0.65350189 1.125952363
43 0.323961628 1.469295081 −0.52991193 0.797908251
47 1.703678841 1.348737095 2.00634162 −0.16505407
48 2.370955056 2.783472865 2.68240273 1.221864405
49 1.670680003 −0.41866107 −0.9173849 1.181929544
50 1.670680003 0.076369374 −0.49915943 −0.85392575
52 0.464485039 0.057512869 1.31230219 −0.11170276
53 0.626671823 −0.46954947 −0.33383736 0.277079201
54 0.666149043 0.009549925 −0.36226343 0.197224432
55 0.723473579 −1.50916383 −0.3848989 −0.71458778
57 0.381273227 1.192994109 1.65593321 −1.65739236
59 0.561360663 −0.17793966 −1.63250554 −0.7564969
61 0.146473611 −0.01535544 −0.16339658 1.738656146
62 1.20162032 −0.3576095 −0.10695443 1.322155191
63 1.084291915 2.258720158 −1.01245416 1.688283974
64 0.744770665 0.155243763 −1.8029919 1.023503542
65 0.972835178 2.797151284 1.53453579 0.857051645
67 2.069410561 0.021831924 0.37855159 −0.67235457
68 0.527636614 0.590831983 1.02843762 2.208655795
69 2.133965691 2.088998449 2.05751412 −0.9433713
70 0.327378959 0.996844599 1.23648533 −1.25138371
71 1.40093669 0.778222691 0.70401172 −0.24075444
72 0.617697349 −0.29503359 0.52404847 0.816184656
73 0.617792473 0.888976061 −0.45289639 0.615659244
74 1.437359024 1.548292147 0.10314807 −0.48982286
75 −1.970885622 3.398008325 4.08025266 −0.89948156
76 −1.32746934 −2.65365233 0.10272816 1.001614125
77 −2.541686116 3.295534192 3.75284227 0.404837808
78 −2.110794 2.109874746 3.13350902 −0.3880285
79 1.641162056 −0.28533994 1.53676145 0.652696023
80 1.594400214 0.283682865 2.23140233 1.111682021
81 0.176566806 −2.0786518 −2.13986952 0.981126964
82 0.980373758 −0.28813159 0.19404501 1.252564677
83 0.941833098 0.317310013 1.17606727 0.72992237
84 0.774237336 −0.27140727 0.72461427 −1.56415746
85 2.092976965 0.810644229 0.82999192 −0.62861806
91 2.061595915 −0.79930338 −0.18285395 −0.66898499
92 2.068748434 −0.24299896 0.07214682 −1.11758276
93 −0.08984279 −1.06025959 −0.05068694 1.560050105
96 0.927758203 −0.44129515 0.89190422 0.744284978
97 0.658667572 −0.68771072 0.46051026 −0.53120883
98 0.853222693 −0.2037738 −0.21414441 1.119784962
100 1.654535066 0.995056228 2.35139085 0.543654824
101 2.173663649 −0.11491477 1.48285148 1.698527571
102 2.066679492 −0.16785146 −0.84780149 0.12159477
103 2.335152618 −0.02866585 0.16993375 −0.98254522
104 2.760588276 0.459513599 1.35310241 0.000336976
105 1.654535066 3.654489674 3.13033965 0.544225478
106 1.750588169 −0.55853348 0.50257773 1.630011313
107 0.896789863 0.73615897 0.53011623 −0.54697747
108 0.532375207 0.826537134 1.21040312 0.690230716
109 2.407655187 0.742651426 1.80322099 0.271832856
110 0.54830833 2.916795026 1.40126098 0.690230716
111 0.939597126 −0.3750368 −1.23479972 −0.89366351
112 1.398518854 1.265740274 4.19618377 −0.12762692
113 1.415726941 0.086297006 3.43559555 −0.12964168
115 −1.557729423 −0.44113526 0.86330536 0.590708892
116 0.193562268 −1.58091165 0.83247813 −0.70978039
117 1.353510875 −0.59062398 −0.31776345 −0.3050158
119 0.830052725 2.28725579 0.38409695 0.219336109
120 1.261997955 −0.22622961 −1.04772194 2.028504137
122 1.505653628 −1.14748206 −0.19760084 −0.81373045
123 −0.658721962 −0.21299878 1.01439841 −0.76731016
125 0.749676998 −1.0761601 0.99563924 −1.15409002
126 0.931054384 −0.35067079 1.06050832 −1.62171794
128 −1.344832644 −0.09451199 1.19145467 1.621274257
130 1.153249538 1.605070708 2.38047907 −0.93842293
133 0.840066046 0.2323025 0.19054023 −0.26588341
134 0.522267541 0.824106618 1.83479545 0.364403434
135 2.142817887 2.142411243 −0.93830995 0.696522652
137 3.052627325 3.606270166 0.50445208 0.076323462
140 −0.153437637 0.246303216 0.76565758 1.800968868
141 2.067620311 1.424830396 2.33536931 7.644025075
142 0.98353103 1.950251373 2.50851828 −0.24499521
143 1.736969725 0.991537809 2.5691601 1.227191656
145 −0.211768579 1.46336231 −0.93580247 −1.48749449
146 1.912710035 0.926306508 1.81253333 0.494121361
147 0.675736703 0.99202385 −0.66034472 −0.66302669
148 0.757176542 1.83006252 0.16210659 0.243674851
149 0.438772371 1.091438092 −0.1560319 −0.61711642
150 0.84399938 0.675302022 −1.69771411 −0.73841711
151 0.633570539 0.988413715 −0.54991825 −0.43550324
152 0.911582356 1.974700218 −0.92267786 0.628660087
153 0.319053885 2.531735341 −0.39139184 0.734629224
154 0.714814512 0.690769753 −2.06588692 −0.73356628
155 −0.161798388 0.032135767 −0.13802086 1.734928461
156 −0.571799976 −1.32834264 −1.65346017 1.856689553
157 0.131224024 0.21510779 −1.70996346 0.964902175
158 1.201616145 −0.21158932 −0.8501176 −0.33330779
159 0.811289908 1.606645397 0.25352447 −1.83775117
159 0.811289908 1.606645397 0.25352447 −1.83775117
161 0.475184006 1.99305646 1.90910177 3.288337059
162 0.833030517 0.487189028 1.76798642 0.104378164
163 0.58993703 −0.46431772 0.74883588 −0.81090824
166 −0.121286831 −0.84664528 −0.32625341 0.778055656
167 0.846400186 −0.25922232 0.69248774 1.183696217
168 −0.310930833 −0.81048493 0.08527131 1.61831109
169 −0.2346025 0.890438419 −0.13206526 −0.83961838
170 −0.169223695 1.172917966 −0.11306441 0.099121666
174 2.863652137 0.236674094 −0.69038707 1.610215283
175 1.789769228 −0.31740428 −0.89529921 −0.09686469
176 2.625947334 0.083548191 0.30634559 −0.35925728
177 1.674319352 −0.22179044 0.42093738 −0.23683577
178 2.863652137 0.727069168 −0.26724686 −0.44888613
179 0.070511885 0.365852864 1.35327505 −0.03748038
181 0.976254543 0.691638796 0.51371978 −0.02503945
182 −1.842503751 −0.12688474 2.56277877 0.111744488
183 3.195758563 3.886545621 4.29482769 3.829845293
184 0.333889534 −0.67236766 2.21605977 4.254612125
185 5.61162203 1.40458529 2.86231343 1.035135749
186 1.068190511 −0.65969343 −0.63104765 −1.36962992
187 1.396358739 0.249705611 0.81449499 −0.15353102
189 1.544466636 −0.33742685 0.8096674 −0.44483677
190 −0.210918777 −1.04086063 0.02614862 3.362615492
191 0.715897301 0.666316436 −0.41719538 0.400723176
192 0.65612864 1.231196814 0.75462061 1.514581532
193 −0.394884432 1.129269425 −0.3157071 −0.61478944
194 −2.111794245 −0.71010521 0.53077207 0.59302222
195 1.18880856 0.704463775 1.99312777 1.419709023
196 1.885714606 0.436434665 1.44657532 1.145809063
197 2.174580668 0.133070149 0.99814905 0.871658496
198 −0.533922573 −2.16213117 0.5812107 −0.92280453
199 1.493919434 1.45125612 1.95141371 4.403441058
201 −0.005520296 −0.83362523 0.65480762 −0.38894276
204 0.732981164 −0.97494758 −0.91192246 −1.00034323
205 0.991838899 −0.60053505 −0.49983634 0.674468753
206 2.147983695 1.291351958 1.64553247 1.626455601
208 −0.386224123 −0.24799559 1.19406353 −1.61243489
209 1.447075297 0.122626462 1.08021156 0.473154634
210 −0.386224123 −0.24799559 1.19406353 −1.61243489
211 2.186118467 1.873949371 0.64852028 −0.59205851
212 1.367811201 1.689658923 1.8017376 2.525531645
213 0.925016223 0.875610609 0.31462609 0.847028648
214 −0.239873321 1.808823425 −0.36105512 −0.07650286
215 2.264275088 1.360001278 3.25759951 2.147928282
218 −0.509585598 −0.93428643 1.63030386 −0.79436377
221 1.876297063 0.026873469 0.45442758 1.538486988
227 5.317676982 2.824566654 1.73360625 3.103310061
228 3.323728685 1.554268023 1.8883835 0.957527434
229 3.218950175 1.464118271 2.47512497 1.214429025
230 5.242356467 3.482206715 3.50441556 1.614847073
230 5.242356467 3.482206715 3.50441556 1.614847073
231 2.710087358 1.517756148 0.35088855 0.603171932
231 2.710087358 1.517756148 0.35088855 0.603171932
232 0.703604481 0.42129186 0.39567696 0.41729786
233 1.312921486 0.816597603 2.17066283 0.472801294
234 0.874145958 0.741410502 1.71105733 −0.47289415
237 0.778921491 −1.02119303 0.4612164 −0.8881184
238 0.681403734 −0.342052 1.27750286 −0.3383341
239 −0.870637933 −2.58292907 0.79173772 −1.27888846
242 0.910211214 0.374558101 1.01712685 1.001043471
243 1.670680003 0.104780951 −0.6545574 −0.46985154
244 1.140332181 0.116513028 1.61110902 3.713305291
246 −0.634992987 0.548746912 4.62542427 7.660969857
247 −1.739729444 −0.91508372 1.18693162 3.108631198
248 5.81821686 6.320330665 6.14379552 5.214046447
249 0.348188924 −0.95333461 −0.08432225 1.866717393
252 2.456287983 −0.02516176 0.76814124 1.756087132
253 1.76915226 0.226389981 −0.18115009 −0.62385199
254 0.658956861 −0.39322197 −0.67153044 1.416053304
255 0.892122738 −0.46985097 0.42813903 −0.46752753
256 0.625043963 −0.65111806 1.4319541 2.110656697
258 −0.187789327 −0.85870492 −0.21766971 0.931521178
259 −1.261365139 −2.33099427 1.33595129 0.43644676
260 2.4020693 2.669351733 2.36395771 1.910609499
261 1.978618006 2.732613301 2.19594212 1.683156477
263 1.350274014 −0.59210334 0.14780643 −0.13113746
264 0.526085484 −1.54983116 −0.17497208 −0.8204696
267 1.175997006 −1.03507906 −0.11004734 −0.50564806
269 2.367197222 0.457286256 0.02211231 0.497925297
270 0.711734628 −1.45058685 −0.17018094 −0.71795736
271 1.073564668 −0.47951936 −0.80269361 0.136837431
273 0.663835001 −1.5674675 0.28509522 −1.12959038
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1072 1.670680003 1.94609957 0.19633838 1.14825764
1073 2.237616041 1.438074134 0.31117554 −0.71786492
1074 −0.192632911 0.142411101 0.79310676 0.125548041
1075 0.909356011 0.368597887 1.03689838 1.001198751
1076 0.812238101 0.195908668 0.21564664 0.219336109
1077 0.325255266 1.131242708 −2.79377204 −0.62848261
1078 0.325255266 1.131242708 −2.79377204 −0.62848261
1079 0.85330799 −0.6855194 −0.90046979 −0.46415796
1081 −0.131519393 0.731836014 0.81604919 −1.29993979
1082 0.744770665 0.155243763 −1.8029919 1.023503542
1083 1.415726941 0.086297223 3.43559555 −0.12964168
1084 0.161304111 0.66712144 0.58401752 0.373809692
1085 −0.72863532 −0.2873027 2.21251376 3.003873022
1088 −1.1773616 −0.23258175 0.40529195 0.994988969
1089 2.769817302 1.661618789 3.97585272 1.059236597
1090 3.052627325 0.420821685 −0.57080756 1.751222205
1091 −3.379896722 −3.71174986 2.53586709 0.644702886
1093 0.72304265 1.667011476 2.53982093 2.7903213
1095 0.744219765 1.372184572 0.15852396 1.126053442
1097 4.407270402 2.670641491 5.02636153 5.361271976
1098 −1.85804837 −2.59071226 −0.46522239 0.655734646
1099 0.745797788 −0.20547378 4.27836342 4.646390386
1102 2.068748434 −0.24299896 0.07214682 −1.11758276
1104 1.018876287 0.025163067 −0.1106021 0.838914654
1105 2.387326861 3.865456674 2.2251199 0.728667998
1107 2.352582059 2.595496601 3.20492728 2.844590737
1110 0.302703712 0.599942142 −0.25637571 −0.03195517
1111 0.750930333 0.656784751 1.68326413 0.329846578
1112 −0.205527848 0.287622624 −0.00340777 0.59203719
1115 0.999825037 0.662221152 0.43571192 0.342558518
1116 0.873381263 1.544324176 0.13703728 −0.38172701
1117 −0.682983903 1.798204302 2.42110319 −0.39173951
1118 0.069769623 0.496895599 0.67857133 −0.14954441
1119 −0.671908804 −0.65984824 0.5238174 −0.85314111
1120 0.953790113 1.106552668 3.00006904 1.585038764
1121 −1.184630973 2.476138312 4.80971952 2.450646806
1122 −1.02687397 −0.36244273 0.13010074 0.535909448
1125 0.387315524 −0.36101406 1.14153708 −0.75303953
1126 1.021783831 −0.0070257 −0.14327539 3.954381426
1127 0.990592079 0.305612583 0.14155512 −0.29526854
1128 0.990592079 0.305612583 0.14155512 −0.29526854
1129 3.18966648 3.284362987 4.49398568 3.950809104
1131 1.650621055 1.545704806 2.37535081 1.259373143
1133 −1.519747805 −0.60804324 0.02746106 0.590708892
1134 0.815942067 −0.16126019 −0.54117238 0.613093526
1135 0.626973385 1.998305877 2.61706075 1.570404253
1136 2.812199484 1.353198146 2.05618426 1.869204406
1137 2.208307057 1.387136198 3.21521374 2.069795393
1138 1.670680003 1.316442078 0.14822999 −0.46985154
1139 1.408517438 0.890457374 1.24524408 0.685687797
1140 2.765860952 2.525539595 4.12464228 3.833744077
1141 −0.484394663 0.677713073 −0.22783646 −0.37267608
1142 2.54335679 4.298105601 3.36234238 2.684404542
1143 4.204367611 3.062126931 3.4234313 2.072899554
1144 2.479165229 3.226545885 4.65897152 4.952127235
1145 2.479158921 3.226545885 4.65897152 4.952127235
1146 0.774334025 1.075800774 1.06893156 1.011113116
1147 0.844648531 1.21935371 2.59138595 0.805938034
1148 2.906236436 1.550674121 3.56959167 2.832126896
1149 2.837627443 3.707154326 4.53384262 2.625871865
Delivery Systems and Methods Non-limiting examples of suitable delivery systems, methods of making delivery systems and the uses of such delivery systems are disclosed in USPA 2007/0275866 A1. Such delivery systems include:
Polymer Assisted Delivery (PAD): This delivery technology uses polymeric materials to deliver materials. Classical coacervation, water soluble or partly soluble to insoluble charged or neutral polymers, liquid crystals, hot melts, hydrogels, perfumed plastics, microcapsules, nano- and micro-latexes, polymeric film formers, and polymeric absorbents, polymeric adsorbents, etc. are some examples. PAD includes but is not limited to:
-
- Matrix Systems: The fragrance is dissolved or dispersed in a polymer matrix or particle. Perfumes, for example, may be 1) dispersed into the polymer prior to formulating into the product or 2) added separately from the polymer during or after formulation of the product. Diffusion of perfume from the polymer is a common trigger that allows or increases the rate of perfume release from a polymeric matrix system that is deposited or applied to the desired surface (situs), although many other triggers are known that may control perfume release. Absorption and/or adsorption into or onto polymeric particles, films, solutions, and the like are aspects of this technology. Nano- or micro-particles composed of organic materials (e.g., latexes) are examples. Suitable particles include a wide range of materials including, but not limited to polyacetal, polyacrylate, polyacrylic, polyacrylonitrile, polyamide, polyaryletherketone, polybutadiene, polybutylene, polybutylene terephthalate, polychloroprene, polyethylene, polyethylene terephthalate, polycyclohexylene dimethylene terephthalate, polycarbonate, polychloroprene, polyhydroxyalkanoate, polyketone, polyester, polyetherimide, polyethersulfone, polyethylenechlorinates, polyimide, polyisoprene, polylactic acid, polymethylpentene, polyphenylene oxide, polyphenylene sulfide, polyphthalamide, polypropylene, polystyrene, polysulfone, polyvinyl acetate, polyvinyl chloride, as well as polymers or copolymers based on acrylonitrile-butadiene, cellulose acetate, ethylene-vinyl acetate, ethylene vinyl alcohol, styrene-butadiene, vinyl acetate-ethylene, and mixtures thereof.
- “Standard” systems refer to those that are “pre-loaded” with the intent of keeping the pre-loaded perfume associated with the polymer until the moment or moments of perfume release. Such polymers may also suppress the neat product odor and provide a bloom and/or longevity benefit depending on the rate of perfume release. One challenge with such systems is to achieve the ideal balance between 1) in-product stability (keeping perfume inside carrier until you need it) and 2) timely release (during use or from dry situs). Achieving such stability is particularly important during in-product storage and product aging. This challenge is particularly apparent for aqueous-based, surfactant-containing products, such as heavy duty liquid laundry detergents. Many “Standard” matrix systems available effectively become “Equilibrium” systems when formulated into aqueous-based products. One may select an “Equilibrium” system or a Reservoir system, which has acceptable in-product diffusion stability and available triggers for release (e.g., friction). “Equilibrium” systems are those in which the perfume and polymer may be added separately to the product, and the equilibrium interaction between perfume and polymer leads to a benefit at one or more consumer touch points (versus a free perfume control that has no polymer-assisted delivery technology). The polymer may also be pre-loaded with perfume; however, part or all of the perfume may diffuse during in-product storage reaching an equilibrium that includes having desired perfume raw materials (PRMs) associated with the polymer. The polymer then carries the perfume to the surface, and releases it typically via perfume diffusion. The use of such equilibrium system polymers has the potential to decrease the odor intensity of the neat product (usually more so in the case of pre-loaded standard systems). Deposition of such polymers may serve to “flatten” the release profile and provide increased longevity. As indicated above, such longevity would be achieved by suppressing the initial intensity and may enable the formulator to use more high impact or low odor detection threshold (ODT) or low Kovats Index (KI) PRMs to achieve FMOT benefits without initial intensity that is too strong or distorted. It is important that perfume release occurs within the time frame of the application to impact the desired consumer touch point or touch points. Matrix systems also include hot melt adhesives and perfume plastics. In addition, hydrophobically modified polysaccharides may be formulated into the perfumed product to increase perfume deposition and/or modify perfume release. All such matrix systems, including for example polysaccarides and nanolatexes may be combined with other PDTs, including other PAD systems such as PAD reservoir systems in the form of a perfume microcapsule (PMC).
- Silicones are also examples of polymers that may be used as PDT, and can provide perfume benefits in a manner similar to the polymer-assisted delivery “matrix system”. Such a PDT is referred to as silicone-assisted delivery (SAD). One may pre-load silicones with perfume, or use them as an equilibrium system as described for PAD. Examples of silicones include polydimethylsiloxane and polyalkyldimethylsiloxanes. Other examples include those with amine functionality, which may be used to provide benefits associated with amine-assisted delivery (AAD) and/or polymer-assisted delivery (PAD) and/or amine-reaction products (ARP).
Reservoir Systems: Reservoir systems are also known as a core-shell type technology, or one in which the material that will be delivered is surrounded by a release controlling membrane, which may serve as a protective shell. The material inside the microcapsule is referred to as the core, internal phase, or fill, whereas the wall is sometimes called a shell, coating, or membrane. Microparticles or pressure sensitive capsules or microcapsules are examples of this technology. Microcapsules of the current invention are formed by a variety of procedures that include, but are not limited to, coating, extrusion, spray-drying, interfacial, in-situ and matrix polymerization. The possible shell materials vary widely in their stability toward water. Among the most stable are polyoxymethyleneurea (PMU)-based materials, which may hold certain PRMs for even long periods of time in aqueous solution (or product). Such systems include but are not limited to urea-formaldehyde and/or melamine-formaldehyde. Gelatin-based microcapsules may be prepared so that they dissolve quickly or slowly in water, depending for example on the degree of cross-linking. Many other capsule wall materials are available and vary in the degree of perfume diffusion stability observed. Without wishing to be bound by theory, the rate of release of perfume from a capsule, for example, once deposited on a surface is typically in reverse order of in-product perfume diffusion stability. As such, urea-formaldehyde and melamine-formaldehyde microcapsules for example, typically require a release mechanism other than, or in addition to, diffusion for release, such as mechanical force (e.g., friction, pressure, shear stress) that serves to break the capsule and increase the rate of perfume (fragrance) release. Other triggers include melting, dissolution, hydrolysis or other chemical reaction, electromagnetic radiation, and the like. The use of pre-loaded microcapsules requires the proper ratio of in-product stability and in-use and/or on-surface (on-situs) release, as well as proper selection of PRMs. Microcapsules that are based on urea-formaldehyde and/or melamine-formaldehyde are relatively stable, especially in near neutral aqueous-based solutions. These materials may require a friction trigger which may not be applicable to all product applications. Other microcapsule materials (e.g., gelatin) may be unstable in aqueous-based products and may even provide reduced benefit (versus free perfume control) when in-product aged. Scratch and sniff technologies are yet another example of PAD.
Molecule-Assisted Delivery (MAD): Non-polymer materials or molecules may also serve to improve the delivery of materials. Without wishing to be bound by theory, perfume may non-covalently interact with organic materials, resulting in altered deposition and/or release. Non-limiting examples of such organic materials include but are not limited to hydrophobic materials such as organic oils, waxes, mineral oils, petrolatum, fatty acids or esters, sugars, surfactants, liposomes and even other perfume raw material (perfume oils), as well as natural oils, including body and/or other soils. Perfume fixatives are yet another example. In one aspect, non-polymeric materials or molecules have a Log P greater than about 2.
Cyclodextrin (CD): This technology approach uses a cyclic oligosaccharide or cyclodextrin to improve the delivery of materials. Typically a perfume and cyclodextrin (CD) complex is formed. Such complexes may be preformed, formed in-situ, or formed on or in the situs. Without wishing to be bound by theory, loss of water may serve to shift the equilibrium toward the CD-Perfume complex, especially if other adjunct ingredients (e.g., surfactant) are not present at high concentration to compete with the perfume for the cyclodextrin cavity. A bloom benefit may be achieved if water exposure or an increase in moisture content occurs at a later time point. In addition, cyclodextrin allows the perfume formulator increased flexibility in selection of PRMs. Cyclodextrin may be pre-loaded with perfume or added separately from perfume to obtain the desired perfume stability, deposition or release benefit.
Starch Encapsulated Accord (SEA): The use of a starch encapsulated accord (SEA) technology allows one to modify the properties of the material that will be delivered, for example, by converting a liquid perfume into a solid by adding ingredients such as starch. The benefit includes increased perfume retention during product storage, especially under non-aqueous conditions. Upon exposure to moisture, a perfume bloom may be triggered. Benefits at other moments of truth may also be achieved because the starch allows the product formulator to select PRMs or PRM concentrations that normally cannot be used without the presence of SEA. Another technology example includes the use of other organic and inorganic materials, such as silica to convert perfume from liquid to solid.
Zeolite & Inorganic Carrier (ZIC): This technology relates to the use of porous zeolites or other inorganic materials to deliver materials. By way of example, perfume-loaded zeolite may be used with or without adjunct ingredients used for example to coat the perfume-loaded zeolite (PLZ) to change its perfume release properties during product storage or during use or from the dry situs. Silica is another form of ZIC. Another example of a suitable inorganic carrier includes inorganic tubules, where the perfume or other active material is contained within the lumen of the nano- or micro-tubules. Preferably, the perfume-loaded inorganic tubule (or Perfume-Loaded Tubule or PLT) is a mineral nano- or micro-tubule, such as halloysite or mixtures of halloysite with other inorganic materials, including other clays. The PLT technology may also comprise additional ingredients on the inside and/or outside of the tubule for the purpose of improving in-product diffusion stability, deposition on the desired situs or for controlling the release rate of the loaded perfume. Monomeric and/or polymeric materials, including starch encapsulation, may be used to coat, plug, cap, or otherwise encapsulate the PLT.
A delivery system comprising, based on total delivery system weight, a sum total of from about 0.00025% to about 30%, preferably from about 0.0025% to about 10%, more preferably from about 0.005% to about 5%, most preferably from about 0.01% to about 4% of a benefit agent that comprises one or more malodor reduction materials, preferably 1 to about 20 malodor reduction materials, more preferably 1 to about 15 malodor reduction materials, most preferably 1 to about 10 malodor reduction materials, each of said malodor reduction materials having a MORV of at least 0.5, preferably from 0.5 to 10, more preferably from 1 to 10, most preferably from 1 to 5, and preferably each of said malodor reduction materials having a Universal MORV, said sum total of malodor reduction materials having a Blocker Index of less than 3, more preferable less than about 2.5 even more preferably less than about 2 and still more preferably less than about 1 and most preferably 0 and/or a Blocker Index average of 3 to about 0.001; and optionally an additional benefit agent, is disclosed.
In one aspect of said delivery system each of said malodor reduction materials may have an MORV of 1 or greater, 2 or greater, 3 or greater, 4 or greater, 5 or greater, 6 or greater, 7 or greater, 8 or greater, 9 or greater, preferably for each of such ranges, the upper limit is about 10. In one aspect of said delivery system, said malodor reduction materials have a Fragrance Fidelity Index of less than 3, preferably less than 2, more preferably less than 1 and most preferably 0 and/or a Fragrance Fidelity Index average of 3 to about 0.001 Fragrance Fidelity Index.
In one aspect of said delivery system, said one or more malodor reduction materials is selected from the group consisting of about 0.01 to about 80% malodor reduction composition, preferably from about 0.1 to 70% malodor reduction composition, more preferably from about 0.5 to 60% malodor reduction composition, most preferably from about 1.0 to 40% malodor reduction composition.
In one aspect of said delivery system, said delivery system is selected from the group consisting of:
a) a Polymer Assisted Delivery (PAD) system comprising, based on total benefit agent weight, from about 0.1 to about 50% Malodor reducing composition
b) a Molecule-Assisted Delivery (MAD) system, comprising, based on total benefit agent weight, from about 0.1 to about 75% Malodor reducing composition.
c) a Cyclodextrin (CD) system comprising, based on total benefit agent weight, from about 0.1 to about 20% Malodor reducing composition.
d) a Starch Encapsulated Accord (SEA) system comprising, based on total benefit agent weight, from about 0.1 to about 80% Malodor reducing composition.
e) a Zeolite & Inorganic Carrier (ZIC) system comprising, based on total benefit agent weight, from about 0.1 to about 30% Malodor reducing composition.
In one aspect of said delivery system, said Polymer Assisted Delivery (PAD) system comprises a Polymer Assisted Delivery (PAD) Reservoir system.
In one aspect of said delivery system, said Polymer Assisted Delivery (PAD) Reservoir system is a perfume delivery particle that comprises a shell material and a core material, said shell material encapsulating said core material, said core material comprising a malodor reduction material according to claims 1 and said shell comprising a material selected from the group consisting of polyethylenes; polyamides; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyacrylates; aminoplasts, in one aspect said aminoplast comprises a polyureas, polyurethane, and/or polyureaurethane, in one aspect said polyurea comprises polyoxymethyleneurea and/or melamine formaldehyde; polyvinylamine, polyvinyl formamide, polyolefins; polyvinyl alcohol, polysaccharides, in one aspect alginate and/or chitosan; gelatin; shellac; epoxy resins; vinyl polymers; water insoluble inorganics; silicone; and mixtures thereof, preferably said perfume delivery particle have a volume weighted mean particle size from about, from about 5 microns to about 45 microns more preferably from about 8 microns to about 25 microns, or alternatively a volume weighted mean particle size from about, from about 25 microns to about 60 microns, more preferably from about 25 microns to about 60 microns.
In one aspect of said delivery system, said shell comprises melamine formaldehyde and/or cross linked melamine formaldehyde.
In one aspect of said delivery system, said shell is coated by a water-soluble cationic polymer selected from the group that consists of polysaccharides, cationically modified starch and cationically modified guar, polysiloxanes, dimethyldiallylammonium polyhalogenides, copolymers of dimethyldiallylammonium polychloride and vinyl pyrrolidone, acrylamides, imidazoles, imidazolinium halogenides and imidazolium halogenides and polyvinyl amine and its copolymers with N-vinyl formamide.
In one aspect of said delivery system, said coating that coats said shell, comprises a cationic polymer and an anionic polymer.
In one aspect of said delivery system, said cationic polymer comprises hydroxyl ethyl cellulose; and said anionic polymer comprises carboxyl methyl cellulose.
In one aspect of said delivery system, said reduction materials are selected from the group consisting of Table 1 materials and mixtures thereof; preferably said material is selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 17, 18, 21, 22, 23, 25, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 50, 52, 57, 61, 62, 63, 64, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 82, 83, 85, 91, 92, 93, 98, 100, 101, 102, 103, 104, 105, 106, 108, 109, 110, 112, 113, 114, 117, 119, 120, 122, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 146, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 187, 189, 190, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 243, 244, 246, 247, 249, 252, 253, 254, 256, 259, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 321, 322, 323, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 375, 377, 378, 381, 385, 386, 388, 390, 391, 394, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 425, 426, 428, 429, 432, 436, 441, 444, 445, 449, 450, 453, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 474, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 493, 497, 498, 501, 502, 503, 505, 519, 520, 521, 524, 527, 529, 530, 531, 532, 534, 537, 541, 544, 546, 548, 550, 551, 552, 553, 555, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 578, 580, 581, 582, 584, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 649, 650, 653, 655, 658, 659, 660, 661, 663, 668, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 682, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 730, 731, 733, 735, 736, 738, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 764, 766, 767, 768, 769, 770, 771, 772, 774, 775, 776, 778, 781, 782, 786, 788, 791, 792, 800, 802, 803, 804, 805, 806, 807, 814, 821, 824, 826, 827, 828, 829, 831, 833, 834, 837, 839, 840, 849, 850, 852, 856, 864, 865, 866, 868, 869, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 928, 929, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 955, 959, 962, 965, 967, 969, 973, 974, 976, 978, 980, 982, 985, 988, 993, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1021, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1042, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1064, 1065, 1066, 1067, 1070, 1072, 1073, 1075, 1077, 1078, 1082, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1113, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1138, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149, Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097, Table 3 materials 12, 19, 20, 24, 26, 27, 53, 54, 55, 59, 72, 73, 81, 84, 96, 97, 107, 111, 115, 116, 125, 133, 147, 150, 151, 154, 157, 163, 166, 169, 181, 191, 194, 198, 201, 204, 205, 213, 214, 232, 237, 239, 255, 258, 264, 270, 273, 275, 282, 283, 284, 287, 302, 306, 308, 310, 312, 314, 319, 346, 354, 355, 365, 366, 376, 379, 387, 400, 412, 419, 420, 437, 438, 439, 440, 442, 443, 447, 448, 454, 455, 469, 472, 477, 481, 492, 495, 496, 504, 509, 510, 512, 515, 517, 518, 522, 525, 526, 528, 535, 536, 538, 540, 542, 547, 549, 554, 556, 557, 575, 576, 579, 583, 585, 588, 602, 605, 617, 619, 640, 641, 645, 647, 651, 652, 662, 664, 665, 667, 672, 687, 699, 701, 703, 740, 743, 744, 745, 755, 760, 761, 777, 779, 784, 789, 796, 797, 799, 808, 810, 811, 812, 817, 819, 820, 832, 835, 836, 838, 845, 846, 847, 848, 851, 858, 875, 880, 882, 883, 888, 889, 891, 899, 900, 901, 902, 903, 904, 909, 918, 921, 931, 940, 956, 958, 960, 971, 977, 981, 983, 986, 987, 994, 995, 1001, 1002, 1004, 1005, 1011, 1017, 1018, 1019, 1030, 1039, 1040, 1041, 1051, 1052, 1054, 1055, 1058, 1061, 1069, 1071, 1074, 1076, 1079, 1081, 1084, 1088, 1098, 1110, 1112, 1115, 1118, 1119, 1122, 1127, 1128, 1133, 1134, 1141 and mixtures thereof; preferably said malodor reduction materials are selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 17, 18, 21, 22, 23, 25, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 50, 52, 57, 61, 62, 63, 64, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 82, 83, 85, 91, 92, 93, 98, 100, 101, 102, 103, 104, 105, 106, 108, 109, 110, 112, 113, 114, 117, 119, 120, 122, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 146, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 187, 189, 190, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 243, 244, 246, 247, 249, 252, 253, 254, 256, 259, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 321, 322, 323, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 375, 377, 378, 381, 385, 386, 388, 390, 391, 394, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 425, 426, 428, 429, 432, 436, 441, 444, 445, 449, 450, 453, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 474, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 493, 497, 498, 501, 502, 503, 505, 519, 520, 521, 524, 527, 529, 530, 531, 532, 534, 537, 541, 544, 546, 548, 550, 551, 552, 553, 555, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 578, 580, 581, 582, 584, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 649, 650, 653, 655, 658, 659, 660, 661, 663, 668, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 682, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 730, 731, 733, 735, 736, 738, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 764, 766, 767, 768, 769, 770, 771, 772, 774, 775, 776, 778, 781, 782, 786, 788, 791, 792, 800, 802, 803, 804, 805, 806, 807, 814, 821, 824, 826, 827, 828, 829, 831, 833, 834, 837, 839, 840, 849, 850, 852, 856, 864, 865, 866, 868, 869, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 928, 929, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 955, 959, 962, 965, 967, 969, 973, 974, 976, 978, 980, 982, 985, 988, 993, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1021, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1042, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1064, 1065, 1066, 1067, 1070, 1072, 1073, 1075, 1077, 1078, 1082, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1113, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1138, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149, Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097 and mixtures thereof, more preferably said malodor reduction materials are selected from the group consisting of Table 4 materials 7, 14, 39, 48, 183, 199, 206, 212, 215, 229, 260, 261, 281, 329, 335, 353, 360, 441, 484, 487, 488, 501, 566, 567, 569, 570, 573, 574, 603, 616, 621, 624, 627, 632, 663, 680, 684, 694, 696, 708, 712, 714, 726, 750, 764, 775, 776, 788, 804, 872, 919, 927, 933, 978, 1007, 1022, 1024, 1027, 1029, 1035, 1038, 1060, 1089, 1107, 1129, 1131, 1136, 1137, 1140, 1142, 1143, 1144, 1145, 1148, 1149, Table 5 material 248 and mixtures thereof, most preferably said malodor reduction materials are selected from the group consisting of Table 4 materials 261, 680, 788, 1129, 1148, 1149 and mixtures thereof.
In one aspect of said delivery system, said delivery system is a perfume delivery particle that comprises a shell material and a core material, said shell material encapsulating said core material, said core material comprising a malodor reduction material selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 18, 21, 22, 23, 25, 28, 29, 30, 32, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 52, 57, 63, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 83, 85, 92, 93, 100, 101, 102, 103, 104, 105, 106, 109, 112, 113, 114, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 189, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 244, 246, 247, 249, 252, 253, 256, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 322, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 377, 378, 381, 385, 386, 388, 390, 391, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 426, 432, 436, 441, 444, 445, 449, 450, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 497, 498, 501, 502, 503, 505, 519, 520, 521, 527, 529, 531, 534, 537, 541, 544, 548, 550, 552, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 582, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 650, 653, 658, 659, 660, 661, 663, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 731, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 766, 768, 769, 771, 774, 775, 776, 778, 781, 782, 786, 788, 791, 800, 802, 803, 804, 806, 807, 814, 821, 826, 827, 828, 831, 833, 849, 850, 852, 866, 868, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 959, 962, 965, 967, 973, 974, 976, 978, 980, 982, 985, 988, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1065, 1075, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149; Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097; Table 3 materials 1, 9, 12, 13, 19, 20, 21, 24, 25, 27, 32, 34, 37, 38, 43, 53, 54, 55, 59, 65, 68, 70, 71, 72, 73, 79, 81, 83, 85, 96, 100, 105, 106, 109, 111, 114, 125, 126, 133, 134, 135, 137, 140, 142, 143, 147, 148, 150, 151, 152, 153, 154, 157, 159, 162, 167, 169, 178, 181, 189, 191, 192, 195, 197, 198, 201, 204, 211, 213, 228, 231, 232, 233, 234, 237, 238, 239, 242, 246, 252, 256, 270, 273, 275, 277, 285, 286, 288, 289, 290, 292, 293, 295, 300, 301, 306, 308, 310, 314, 319, 322, 325, 331, 333, 334, 336, 338, 339, 344, 354, 355, 356, 358, 361, 362, 363, 366, 370, 371, 372, 374, 376, 377, 378, 379, 381, 385, 387, 388, 390, 407, 412, 413, 417, 418, 419, 420, 432, 437, 438, 439, 440, 443, 444, 447, 448, 454, 455, 457, 461, 465, 467, 472, 477, 478, 479, 480, 481, 482, 485, 491, 496, 497, 502, 503, 504, 510, 512, 515, 517, 518, 525, 526, 529, 535, 536, 537, 540, 541, 544, 550, 557, 558, 559, 560, 561, 568, 571, 572, 575, 576, 585, 588, 589, 592, 594, 599, 600, 602, 604, 605, 609, 617, 619, 620, 625, 626, 633, 636, 638, 641, 644, 645, 647, 650, 651, 653, 662, 672, 673, 675, 676, 681, 683, 686, 687, 693, 697, 698, 700, 703, 704, 706, 707, 716, 717, 718, 722, 725, 740, 742, 745, 746, 755, 757, 769, 771, 779, 782, 799, 803, 806, 807, 819, 820, 827, 828, 833, 835, 838, 846, 847, 848, 850, 875, 878, 879, 880, 881, 883, 888, 889, 890, 891, 893, 899, 900, 901, 902, 903, 909, 912, 914, 918, 920, 921, 922, 923, 930, 937, 939, 940, 941, 945, 946, 947, 948, 953, 954, 958, 959, 960, 965, 967, 971, 981, 986, 994, 995, 998, 1000, 1001, 1003, 1004, 1005, 1008, 1009, 1010, 1011, 1017, 1018, 1019, 1020, 1023, 1026, 1030, 1031, 1032, 1036, 1040, 1046, 1047, 1051, 1052, 1053, 1054, 1055, 1057, 1058, 1061, 1062, 1063, 1071, 1074, 1075, 1081, 1088, 1091, 1093, 1095, 1098, 1099, 1102, 1104, 1105, 1111, 1115, 1116, 1119, 1120, 1122, 1127, 1128, 1134, 1135, 1139, 1146, 1147 and mixtures thereof, preferably said malodor reduction material is selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 18, 21, 22, 23, 25, 28, 29, 30, 32, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 52, 57, 63, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 83, 85, 92, 93, 100, 101, 102, 103, 104, 105, 106, 109, 112, 113, 114, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 189, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 244, 246, 247, 249, 252, 253, 256, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 322, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 377, 378, 381, 385, 386, 388, 390, 391, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 426, 432, 436, 441, 444, 445, 449, 450, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 497, 498, 501, 502, 503, 505, 519, 520, 521, 527, 529, 531, 534, 537, 541, 544, 548, 550, 552, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 582, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 650, 653, 658, 659, 660, 661, 663, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 731, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 766, 768, 769, 771, 774, 775, 776, 778, 781, 782, 786, 788, 791, 800, 802, 803, 804, 806, 807, 814, 821, 826, 827, 828, 831, 833, 849, 850, 852, 866, 868, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 959, 962, 965, 967, 973, 974, 976, 978, 980, 982, 985, 988, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1065, 1075, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149; Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097, and mixtures thereof, most preferably said malodor reduction materials are selected from the group consisting of Table 4 materials 7, 14, 39, 48, 183, 199, 206, 212, 215, 229, 260, 261, 281, 329, 335, 353, 360, 441, 484, 487, 488, 501, 566, 567, 569, 570, 573, 574, 603, 616, 621, 624, 627, 632, 663, 680, 684, 694, 696, 708, 712, 714, 726, 750, 775, 776, 788, 804, 872, 919, 927, 933, 978, 1007, 1022, 1024, 1027, 1029, 1035, 1038, 1060, 1089, 1107, 1129, 1131, 1136, 1137, 1140, 1142, 1143, 1144, 1145, 1148, 1149, Table 5 material 248 and mixtures thereof. These are materials that are stable in perfume microcapsules and do not leak so they will deposit and be available to counteract the malodor.
A delivery system according to any of claims 6 through 9, wherein said core comprises one or more malodor reduction materials having a vapor pressure of greater than 0.01 torr, preferably, greater than 0.01 torr to 10 torr, preferably said one or more malodor materials are selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 32; 34; 35; 42; 49; 65; 67; 70; 92; 93; 101; 102; 103; 114; 123; 126; 130; 142; 145; 149; 155; 159; 167; 168; 170; 178; 186; 189; 192; 193; 208; 209; 210; 218; 228; 229; 231; 256; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 386; 397; 398; 415; 421; 424; 436; 441; 444; 445; 449; 461; 466; 468; 471; 473; 475; 491; 519; 520; 527; 531; 534; 544; 565; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 659; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 742; 748; 750; 752; 763; 766; 768; 774; 778; 781; 786; 791; 800; 802; 806; 814; 821; 826; 827; 828; 850; 852; 866; 868; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 937; 946; 947; 950; 973; 974; 982; 1006; 1008; 1010; 1016; 1020; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1102; 1104; 1105; 1120; 1125; 1137; 1144; 1145, Table 2 materials 565: 631; 659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34; 53; 55; 59; 65; 70; 73; 81; 96; 111; 114; 125; 126; 133; 142; 147; 150; 154; 157; 159; 167; 169; 178; 189; 192; 198; 201; 204; 228; 231; 232; 237; 239; 256; 270; 273; 290; 306; 319; 322; 325; 333; 338; 344; 354; 358; 362; 366; 376; 387; 412; 419; 420; 437; 438; 439; 443; 444; 447; 448; 461; 477; 481; 491; 496; 512; 517; 518; 525; 535; 536; 540; 544; 557; 575; 576; 585; 588; 589; 604; 605; 609; 617; 619; 633; 645; 647; 651; 662; 683; 686; 687; 693; 698; 717; 725; 740; 742; 745; 779; 806; 819; 820; 827; 828; 835; 838; 846; 847; 848; 850; 875; 878; 879; 883; 888; 889; 891; 899; 900; 901; 902; 903; 909; 914; 937; 940; 946; 947; 981; 986; 994; 995; 1001; 1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1040; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1071; 1081; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128 and mixtures thereof, preferably said malodor reduction material is selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 32; 34; 35; 42; 49; 65; 67; 70; 92; 93; 101; 102; 103; 114; 123; 126; 130; 142; 145; 149; 155; 159; 167; 168; 170; 178; 186; 189; 192; 193; 208; 209; 210; 218; 228; 229; 231; 256; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 386; 397; 398; 415; 421; 424; 436; 441; 444; 445; 449; 461; 466; 468; 471; 473; 475; 491; 519; 520; 527; 531; 534; 544; 565; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 659; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 742; 748; 750; 752; 763; 766; 768; 774; 778; 781; 786; 791; 800; 802; 806; 814; 821; 826; 827; 828; 850; 852; 866; 868; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 937; 946; 947; 950; 973; 974; 982; 1006; 1008; 1010; 1016; 1020; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1102; 1104; 1105; 1120; 1125; 1137; 1144; 1145 and Table 2 materials 565: 631; 659; 715 and mixtures thereof, preferably said malodor reduction material is selected from the group consisting of Table 4 materials 7; 229; 281; 441; 603; 621; 627; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145, Table 5 material 526 and mixtures thereof. These are materials that are stable in perfume particles as they do not leak and will volatilize more quickly into the air because they are lower VP when the delivery system releases them thus being able to block the perception of the malodor better on the substrate the delivery system is near to or in contact with.
A consumer product comprising delivery system disclosed by Applicants herein and a consumer product ingredient is disclosed.
A method of treating and/or cleaning a situs, said method comprising
-
- a) optionally washing, rinsing and/or drying said situs;
- b) contacting said situs with a delivery system according to claims 1-12 and/or a consumer product according to claim 13; and
- c) optionally washing, rinsing and/or drying said situs
is disclosed.
A situs treated with a delivery system disclosed herein and/or a consumer product disclosed herein is disclosed.
Process of Making Encapsulates In one aspect, a process that may comprise:
-
- a.) preparing a first solution that may comprise, based on total solution weight from about 20% to about 90%, from about 40% to about 80%, or even from about 60% to about 80% water, of a first emulsifier and a first resin, the ratio of said first emulsifier and said first resin being from about 0.1:0 to about 10:0, from about 0.1:1 to about 10:1, from about 0.5:1 to about 3:1, or even from about 0.8:1 to about 1.1:1;
- b.) preparing a second solution that may comprise based on total solution weight from about 20% to about 95% water, of a second emulsifier and a second resin, the ratio of said second emulsifier and said second resin being from about 0:1 to about 3:1, from about 0.04:1 to about 0.2:1, or even from about 0.05:1 to about 0.15:1;
- c.) combining a core material that may comprise a perfume disclosed in the present specification and said first solution to form a first composition;
- d.) emulsifying said first composition;
- e.) combining said first composition and said second solution to form a second composition and optionally combining any processing aids and said second composition—said first composition and said second solution may be combined in any order but in one aspect said second solution is added to said first composition or said second solution and said first composition are combined simultaneously;
- f.) mixing said second composition for at least 15 minutes, at least 1 hour or even from about 4 hours to about 100 hours at a temperature of from about 25° C. to about 100° C., from about 45° C. to about 90° C., or even from about 50° C. to about 80° C. heat and optionally combining any processing aids to said second composition;
- g.) optionally combining any scavenger material, structurant, and/or anti-agglomeration agent with said second composition during step f.) or thereafter—such materials may be combined in any order but in one aspect the scavenger material is combined first, any structurant second, and then anti-agglomeration agent is combined; and
- h.) optionally spray drying said second composition
is disclosed.
In one or more aspects of the process, said first and second resins may comprise the reaction product of an aldehyde and an amine, suitable aldehydes include, formaldehyde. Suitable amines include melamine, urea, benzoguanamine, glycoluril, and mixtures thereof. Suitable melamines include, methylol melamine, methylated methylol melamine, imino melamine and mixtures thereof. Suitable ureas include, dimethylol urea, methylated dimethylol urea, urea-resorcinol, and mixtures thereof.
In one or more aspects of the process, said first and second emulsifiers may comprise a moiety selected from the group consisting of carboxy, hydroxyl, thiol, amine, amide and combinations thereof. In one aspect, said emulsifier may have a pKa of less than 5, preferably greater than 0 but less than 5. Emulsifiers include acrylic acid-alkyl acrylate copolymer, poly(acrylic acid), polyoxyalkylene sorbitan fatty esters, polyalkylene co-carboxy anhydrides, polyalkylene co-maleic anhydrides, poly(methyl vinyl ether-co-maleic anhydride), poly(propylene-co-maleic anhydride), poly(butadiene co-maleic anhydride), and poly(vinyl acetate-co-maleic anhydride), polyvinyl alcohols, polyalkylene glycols, polyoxyalkylene glycols, and mixtures thereof.
In one or more aspects of the process, the pH of the first and second solutions may be controlled such that the pH of said first and second solution is from about 3.0 to 7.0.
In one or more aspects of the process, during step f.), from about 0% to about 10%, from about 1% to about 5% or even from about 2% to about 4%, based on total second composition weight, of a salt comprising an anion and cation, said anion being selected from the group consisting of chloride, sulfate, phosphate, nitrate, polyphosphate, citrate, maleate, fumarate and mixtures thereof; and said cation being selected from the group consisting of a Periodic Group IA element, Periodic Group IIA element, ammonium cation and mixtures thereof, preferably sodium sulfate, may be combined with said second composition.
In one or more aspects of the process, any of the aforementioned processing parameters may be combined.
Supplemental teachings of making suitable encapsulates as well as suitable shell materials are described in U.S. Pat. No. 6,869,923 B1 and US Published Patent Applications Nos. 2005/0276831 A1 and 2007/020263 A1. Suitable equipment for use in the processes disclosed herein may include continuous stirred tank reactors, homogenizers, turbine agitators, recirculating pumps, paddle mixers, ploughshear mixers, ribbon blenders, vertical axis granulators and drum mixers, both in batch and, where available, in continuous process configurations, spray dryers, and extruders. Such equipment can be obtained from Lodige GmbH (Paderborn, Germany), Littleford Day, Inc. (Florence, Ky., U.S.A.), Forberg AS (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex Corp. (Minneapolis, Minn., U.S.A.), Arde Barinco (New Jersey, U.S.A.).
Compositions In one aspect, a composition that may comprise any aspect of the perfume delivery systems and/or perfumes disclosed in the present specification is disclosed.
In one aspect, said composition may be a consumer product.
In one aspect, such composition may be a consumer product that may comprise, based on total composition weight, from about 0.001% to about 50%, from about 0.01% to about 10%, or even from about 0.1% to about 5%, of a perfume disclosed in the present specification—from about 0.001% to about 90%, from about 0.01% to about 50%, or even from about 0.1% to about 10%, of said perfume, based on said perfume's weight, may be provided by a perfume delivery system according to the present specification.
In one aspect, said composition may comprise an encapsulate wherein said encapsulate's density may be such that the density ratio of said encapsulate to one or more fluids of the composition's fluids may be from about 0.9:1 to about 1.1:1; from about 0.98:1 to about 1.02:1; from about 0.99:1 to about 1.01:1 or even 1:1.
In one aspect, any of the aforementioned compositions may comprise a cleaning and/or treatment ingredient.
In one aspect, any of the aforementioned compositions' encapsulates may be a perfume microcapsule.
In one aspect, any of the aforementioned compositions may comprise one or more cleaning and/or treatment agents selected from the adjunct ingredients listed in the present specification.
While the precise level of encapsulate that is employed depends on the type and end use of the consumer product, in one aspect a consumer product may comprise, based on total composition weight, at least about 0.01%, from about 0.01% to about 80%, or even from about 0.02% to about 10% wt % of a encapsulate disclosed herein.
In one aspect, a consumer product that is compact is disclosed.
In one aspect, a consumer products including liquid detergents having a water content, based on total consumer product formulation weight, of from about 0% to about 15%, from about 0.01% to about 15%, from about 0.5% to about 10% or even from about 1% to about 8% water are disclosed.
In one aspect, the consumer product is a cleaning and/or treatment composition or fabric care composition that may comprise an encapsulate disclosed in the present specification and at least one cleaning and/or treatment composition or fabric care adjunct ingredient.
In one aspect, a cleaning composition may comprise, from about 0.005% to about 5% weight % of such encapsulate based on total cleaning composition weight of such encapsulate. In one aspect, a fabric treatment composition may comprise, based on total fabric treatment composition weight from about 0.005% to about 20% of such encapsulate.
Aspects of the invention include the use of the encapsulates of the present invention in detergent compositions (e.g., TIDE™), hard surface cleaners (e.g., MR CLEAN™), automatic dishwashing liquids (e.g., CASCADE™), dishwashing liquids (e.g., DAWN™), and floor cleaners (e.g., SWIFFER™). The cleaning compositions disclosed herein may be formulated such that, during use in aqueous cleaning operations, the wash water will have a pH of between about 6.5 and about 12, or between about 7.5 and 10.5. Liquid dishwashing product formulations typically have a pH between about 6.8 and about 9.0. Cleaning products are typically formulated to have a pH of from about 2 to about 11. Techniques for controlling pH at recommended usage levels include the use of buffers, alkalis, acids, etc., and are well known to those skilled in the art.
Fabric treatment compositions disclosed herein typically comprise a fabric softening active (“FSA”). Suitable fabric softening actives, include, but are not limited to, materials selected from the group consisting of quats, amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, clays, polysaccharides, fatty oils, polymer latexes and mixtures thereof.
Formaldehyde Scavenger In one aspect, the perfume delivery system disclosed herein may be combined with a formaldehyde scavenger. In one aspect, such perfume delivery system may comprise the encapsulates of the present invention. Suitable formaldehyde scavengers include materials selected from the group consisting of sodium bisulfite, melamine, urea, ethylene urea, cysteine, cysteamine, lysine, glycine, serine, carnosine, histidine, glutathione, 3,4-diaminobenzoic acid, allantoin, glycouril, anthranilic acid, methyl anthranilate, methyl 4-aminobenzoate, ethyl acetoacetate, acetoacetamide, malonamide, ascorbic acid, 1,3-dihydroxyacetone dimer, biuret, oxamide, benzoguanamine, pyroglutamic acid, pyrogallol, methyl gallate, ethyl gallate, propyl gallate, triethanol amine, succinamide, thiabendazole, benzotriazol, triazole, indoline, sulfanilic acid, oxamide, sorbitol, glucose, cellulose, poly(vinyl alcohol), partially hydrolyzed poly(vinylformamide), poly(vinyl amine), poly(ethylene imine), poly(oxyalkyleneamine), poly(vinyl alcohol)-co-poly(vinyl amine), poly(4-aminostyrene), poly(l-lysine), chitosan, hexane diol, ethylenediamine-N,N′-bisacetoacetamide, N-(2-ethylhexyl)acetoacetamide, 2-benzoylacetoacetamide, N-(3-phenylpropyl)acetoacetamide, helional, melonal, Triplal®, 5,5-dimethyl-1,3-cyclohexanedione, 2,4-dimethyl-3-cyclohexenecarboxaldehyde, 2,2-dimethyl-1,3-dioxan-4,6-dione, 2-pentanone, dibutyl amine, triethylenetetramine, ammonium hydroxide, benzylamine, hydroxycitronellol, cyclohexanone, 2-butanone, pentane dione, dehydroacetic acid, or a mixture thereof. These formaldehyde scavengers may be obtained from Sigma/Aldrich/Fluka of St. Louis, Mo. U.S.A. or PolySciences, Inc. of Warrington, Pa., U.S.A.
Such formaldehyde scavengers are typically combined with a slurry containing said benefit agent containing delivery particle, at a level, based on total slurry weight, of from about 2 wt. % to about 18 wt. %, from about 3.5 wt. % to about 14 wt. % or even from about 5 wt. % to about 13 wt. %.
In one aspect, such formaldehyde scavengers may be combined with a product containing a benefit agent containing delivery particle, said scavengers being combined with said product at a level, based on total product weight, of from about 0.005% to about 0.8%, alternatively from about 0.03% to about 0.5%, alternatively from about 0.065% to about 0.25% of the product formulation.
Consumer Product Ingredients While not essential for each consumer product embodiment of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the instant consumer products and may be desirably incorporated in certain embodiments of the invention, for example to assist or enhance performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the operation for which it is to be used. Such adjunct are in addition to the perfumes and/or perfume delivery systems previously disclosed herein. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, additional perfume and perfume delivery systems, structure elasticizing agents, thickeners/structurants, fabric softeners, carriers, hydrotropes, processing aids and/or pigments.
As stated, the adjunct ingredients are not essential for each consumer product embodiment of the present invention. Thus, certain embodiments of Applicants' compositions do not contain one or more of the following adjuncts materials: bleach activators, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, additional perfumes and perfume delivery systems, structure elasticizing agents, thickeners/structurants, fabric softeners, carriers, hydrotropes, processing aids and/or pigments. However, when one or more adjuncts are present, such one or more adjuncts may be present as detailed below:
Surfactants—The compositions according to the present invention can comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic and/or anionic and/or cationic surfactants and/or ampholytic and/or zwitterionic and/or semi-polar nonionic surfactants. The surfactant is typically present at a level of from about 0.1%, from about 1%, or even from about 5% by weight of the cleaning compositions to about 99.9%, to about 80%, to about 35%, or even to about 30% by weight of the cleaning compositions.
Builders—The compositions of the present invention can comprise one or more detergent builders or builder systems. When present, the compositions will typically comprise at least about 1% builder, or from about 5% or 10% to about 80%, 50%, or even 30% by weight, of said builder. Builders include, but are not limited to, the alkali metal, ammonium and alkanolammonium salts of polyphosphates, alkali metal silicates, alkaline earth and alkali metal carbonates, aluminosilicate builders, polycarboxylate compounds, ether hydroxypolycarboxylates, copolymers of maleic anhydride with ethylene or vinyl methyl ether, 1,3,5-trihydroxybenzene-2,4,6-trisulphonic acid, and carboxymethyl-oxysuccinic acid, the various alkali metal, ammonium and substituted ammonium salts of polyacetic acids such as ethylenediamine tetraacetic acid and nitrilotriacetic acid, as well as polycarboxylates such as mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic acid, carboxymethyloxysuccinic acid, and soluble salts thereof.
Chelating Agents—The compositions herein may also optionally contain one or more copper, iron and/or manganese chelating agents. If utilized, chelating agents will generally comprise from about 0.1% by weight of the compositions herein to about 15%, or even from about 3.0% to about 15% by weight of the compositions herein.
Dye Transfer Inhibiting Agents—The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof. When present in the compositions herein, the dye transfer inhibiting agents are present at levels from about 0.0001%, from about 0.01%, from about 0.05% by weight of the cleaning compositions to about 10%, about 2%, or even about 1% by weight of the cleaning compositions.
Dispersants—The compositions of the present invention can also contain dispersants. Suitable water-soluble organic materials are the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid may comprise at least two carboxyl radicals separated from each other by not more than two carbon atoms.
Enzymes—The compositions can comprise one or more detergent enzymes which provide cleaning performance and/or fabric care benefits. Examples of suitable enzymes include, but are not limited to, hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, keratanases, reductases, oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases, pentosanases, malanases, β-glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase, and amylases, or mixtures thereof. A typical combination is a cocktail of conventional applicable enzymes like protease, lipase, cutinase and/or cellulase in conjunction with amylase.
Enzyme Stabilizers—Enzymes for use in compositions, for example, detergents can be stabilized by various techniques. The enzymes employed herein can be stabilized by the presence of water-soluble sources of calcium and/or magnesium ions in the finished compositions that provide such ions to the enzymes.
Catalytic Metal Complexes—Applicants' compositions may include catalytic metal complexes. One type of metal-containing bleach catalyst is a catalyst system comprising a transition metal cation of defined bleach catalytic activity, such as copper, iron, titanium, ruthenium, tungsten, molybdenum, or manganese cations, an auxiliary metal cation having little or no bleach catalytic activity, such as zinc or aluminum cations, and a sequestrate having defined stability constants for the catalytic and auxiliary metal cations, particularly ethylenediaminetetraacetic acid, ethylenediaminetetra (methyl-enephosphonic acid) and water-soluble salts thereof.
If desired, the compositions herein can be catalyzed by means of a manganese compound. Such compounds and levels of use are well known in the art.
Compositions herein may also suitably include a transition metal complex of a macropolycyclic rigid ligand—abbreviated as “MRL”. As a practical matter, and not by way of limitation, the compositions and cleaning processes herein can be adjusted to provide on the order of at least one part per hundred million of the benefit agent MRL species in the aqueous washing medium, and may provide from about 0.005 ppm to about 25 ppm, from about 0.05 ppm to about 10 ppm, or even from about 0.1 ppm to about 5 ppm, of the MRL in the wash liquor.
Preferred transition-metals in the instant transition-metal bleach catalyst include manganese, iron and chromium. Preferred MRL's herein are a special type of ultra-rigid ligand that is cross-bridged such as 5,12-diethyl-1,5,8,12-tetraazabicyclo[6.6.2]hexa-decane.
Rheology Modifier
The liquid compositions of the present invention may comprise a rheology modifier. The rheology modifier may be selected from the group consisting of non-polymeric crystalline, hydroxy-functional materials, polymeric rheology modifiers which impart shear thinning characteristics to the aqueous liquid matrix of the composition. In one aspect, such rheology modifiers impart to the aqueous liquid composition a high shear viscosity, at 20 sec−1 shear rate and at 21° C., of from 1 to 7000 mPa·s and a viscosity at low shear (0.5 sec−1 shear rate at 21° C.) of greater than 1000 mPa·s, or even 1000 mPa·s to 200,000 mPa·s. In one aspect, for cleaning and treatment compositions, such rheology modifiers impart to the aqueous liquid composition a high shear viscosity, at 20 sec−1 and at 21° C., of from 50 to 3000 mPa·s and a viscosity at low shear (0.5 sec−1 shear rate at 21° C.) of greater than 1000 mPa·s, or even 1000 mPa·s to 200,000 mPa·s. Viscosity according to the present invention is measured using an AR 2000 rheometer from TA instruments using a plate steel spindle having a plate diameter of 40 mm and a gap size of 500 μm. The high shear viscosity at 20 sec−1 and low shear viscosity at 0.5 sec−1 can be obtained from a logarithmic shear rate sweep from 0.1 sec−1 to 25 sec−1 in 3 minutes time at 21° C. Crystalline hydroxyl functional materials are rheology modifiers which form thread-like structuring systems throughout the matrix of the composition upon in situ crystallization in the matrix. Polymeric rheology modifiers are preferably selected from polyacrylates, polymeric gums, other non-gum polysaccharides, and combinations of these polymeric materials.
Generally the rheology modifier will comprise from 0.01% to 1% by weight, preferably from 0.05% to 0.75% by weight, more preferably from 0.1% to 0.5% by weight, of the compositions herein.
Structuring agents which are especially useful in the compositions of the present invention may comprise non-polymeric (except for conventional alkoxylation), crystalline hydroxy-functional materials which can form thread-like structuring systems throughout the liquid matrix when they are crystallized within the matrix in situ. Such materials can be generally characterized as crystalline, hydroxyl-containing fatty acids, fatty esters or fatty waxes. In one aspect, rheology modifiers include crystalline, hydroxyl-containing rheology modifiers include castor oil and its derivatives. In one aspect, rheology modifiers include hydrogenated castor oil derivatives such as hydrogenated castor oil and hydrogenated castor wax. Commercially available, castor oil-based, crystalline, hydroxyl-containing rheology modifiers include THIXCIN™ from Rheox, Inc. (now Elementis).
Other types of rheology modifiers, besides the non-polymeric, crystalline, hydroxyl-containing rheology modifiers described heretofore, may be utilized in the liquid detergent compositions herein. Polymeric materials which provide shear-thinning characteristics to the aqueous liquid matrix may also be employed.
Suitable polymeric rheology modifiers include those of the polyacrylate, polysaccharide or polysaccharide derivative type. Polysaccharide derivatives typically used as rheology modifiers comprise polymeric gum materials. Such gums include pectine, alginate, arabinogalactan (gum Arabic), carrageenan, gellan gum, xanthan gum and guar gum.
If polymeric rheology modifiers are employed herein, a preferred material of this type is gellan gum. Gellan gum is a heteropolysaccharide prepared by fermentation of Pseudomonaselodea ATCC 31461. Gellan gum is commercially marketed by CP Kelco U.S., Inc. under the KELCOGEL tradename.
A further alternative and suitable rheology modifier include a combination of a solvent and a polycarboxylate polymer. More specifically the solvent may be an alkylene glycol. In one aspect, the solvent may comprise dipropylene glycol. In one aspect, the polycarboxylate polymer may comprise a polyacrylate, polymethacrylate or mixtures thereof. In one aspect, solvent may be present, based on total composition weight, at a level of from 0.5% to 15%, or from 2% to 9% of the composition. In one aspect, polycarboxylate polymer may be present, based on total composition weight, at a level of from 0.1% to 10%, or from 2% to 5%. In one aspect, the solvent component may comprise mixture of dipropylene glycol and 1,2-propanediol. In one aspect, the ratio of dipropylene glycol to 1,2-propanediol may be 3:1 to 1:3, or even 1:1. In one aspect, the polyacrylate may comprise a copolymer of unsaturated mono- or di-carbonic acid and C1-C30 alkyl ester of the (meth) acrylic acid. In another aspect, the rheology modifier may comprise a polyacrylate of unsaturated mono- or di-carbonic acid and C1-C30 alkyl ester of the (meth) acrylic acid. Such copolymers are available from Noveon Inc. under the tradename Carbopol Aqua 30®.
In the absence of rheology modifier and in order to impart the desired shear thinning characteristics to the liquid composition, the liquid composition can be internally structured through surfactant phase chemistry or gel phases.
Processes of Making and Using Consumer Products The embodiments of consumer products of the present invention can be formulated into any suitable form and prepared by any process chosen by the formulator, non-limiting examples of which are described in U.S. Pat. No. 5,879,584; which is incorporated herein by reference.
In one aspect, the perfumes and/or delivery systems comprising same that are disclosed herein may be incorporated into solid particles, particularly polymeric based particles. Preferably said perfume delivery system is a microcapsule that comprises said perfume one or more of said perfumes. Examples of such polymeric particles may include particles comprising polyethylene glycol, starches and polysaccharides, polyvinyl alcohol, celluloses. Such particles may additionally comprise additional components such as other benefit agents, inorganic fillers such as carbonate, silicate, clay, metal oxides. Particularly useful particles include particles based on polyethylene glycol.
Method of Use Compositions, such as consumer products, containing the encapsulate disclosed herein can be used to clean or treat a situs inter alia a surface or fabric. Typically at least a portion of the situs is contacted with an embodiment of Applicants' composition, in neat form or diluted in a liquor, for example, a wash liquor and then the situs may be optionally washed and/or rinsed. In one aspect, a situs is optionally washed and/or rinsed, contacted with an encapsulate according to the present invention or composition comprising said encapsulate and then optionally washed and/or rinsed. For purposes of the present invention, washing includes but is not limited to, scrubbing, and mechanical agitation. The situs may comprise most any material, for example a fabric, fabric capable of being laundered or treated in normal consumer use conditions. Liquors that may comprise the disclosed compositions may have a pH of from about 3 to about 11.5. Such compositions are typically employed at concentrations of from about 500 ppm to about 15,000 ppm in solution. When the wash solvent is water, the water temperature typically ranges from about 5° C. to about 90° C. and, when the situs comprises a fabric, the water to fabric ratio is typically from about 1:1 to about 30:1.
Test Methods Malodor reduction materials may be separated from mixtures, including but not limited to finished products such as consumer products and indentified, by analytical methods that include GC-MS and/or NMR.
Test for Volume Weighted Mean Particle Size
-
- Particle size is measured using an Accusizer 780A, made by Particle Sizing Systems, Santa Barbara Calif. The instrument is calibrated from 0 to 300μ using Duke particle size standards. Samples for particle size evaluation are prepared by diluting about 1 g emulsion, if the volume weighted mean particle size of the emulsion is to be determined, or 1 g of capsule slurry, if the finished capsule volume weighted mean particle size is to be determined, in about 5 g of de-ionized water and further diluting about 1 g of this solution in about 25 g of water.
- About 1 g of the most dilute sample is added to the Accusizer and the testing initiated, using the autodilution feature. The Accusizer should be reading in excess of 9200 counts/second. If the counts are less than 9200 additional sample should be added. The accusizer will dilute the test sample until 9200 counts/second and initiate the evaluation. After 2 minutes of testing the Accusizer will display the results, including volume-weighted median size.
The broadness index can be calculated by determining the particle size at which 95% of the cumulative particle volume is exceeded (95% size), the particle size at which 5% of the cumulative particle volume is exceeded (5% size), and the median volume-weighted particle size (50% size−50% of the particle volume both above and below this size). Broadness Index (5)=((95% size)−(5% size)/50% size).
Test Method for Determining Saturation Vapour Pressure (VP) The saturation Vapour Pressure (VP) values are computed for each PRM in the perfume mixture being tested. The VP of an individual PRM is calculated using the VP Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the VP value at 25° C. expressed in units of torr. The ACD/Labs' Vapor Pressure model is part of the ACD/Labs model suite.
Test Method for Determining the Logarithm of the Octanol/Water Partition Coefficient (log P) The value of the log of the Octanol/Water Partition Coefficient (log P) is computed for each PRM in the perfume mixture being tested. The log P of an individual PRM is calculated using the Consensus log P Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the unitless log P value. The ACD/Labs' Consensus log P Computational Model is part of the ACD/Labs model suite.
Test Method for the Generation of Molecular Descriptors In order to conduct the calculations involved in the computed-value test methods described herein, the starting information required includes the identity, weight percent, and molar percent of each PRM in the perfume being tested, as a proportion of that perfume, wherein all PRMs in the perfume composition are included in the calculations. Additionally for each of those PRMs, the molecular structure, and the values of various computationally-derived molecular descriptors are also required, as determined in accordance with the Test Method for the Generation of Molecular Descriptors described herein.
For each PRM in a perfume mixture or composition, its molecular structure is used to compute various molecular descriptors. The molecular structure is determined by the graphic molecular structure representations provided by the Chemical Abstract Service (“CAS”), a division of the American Chemical Society, Columbus, Ohio, U.S.A. These molecular structures may be obtained from the CAS Chemical Registry System database by looking up the index name or CAS number of each PRM. For PRMs, which at the time of their testing are not yet listed in the CAS Chemical Registry System database, other databases or information sources may be used to determine their structures. For a PRM which has potentially more than one isomer present, the molecular descriptor computations are conducted using the molecular structure of only one of the isomers, which is selected to represent that PRM. The selection of isomer is determined by the relative amount of extension in the molecular structures of the isomers. Of all the isomers of a given PRM, it is the isomer whose molecular structure that is the most prevalent which is the one that is selected to represent that PRM. The structures for other potential isomers of that PRM are excluded from the computations. The molecular structure of the isomer that is the most prevalent is paired with the concentration of that PRM, where the concentration reflects the presence of all the isomers of that PRM that are present.
A molecule editor or molecular sketching software program, such as ChemDraw (CambridgeSoft/PerkinElmer Inc., Waltham, Mass., U.S.A.), is used to duplicate the 2-dimensional molecular structure representing each PRM. Molecular structures should be represented as neutral species (quaternary nitrogen atoms are allowed) with no disconnected fragments (e.g., single structures with no counter ions). The winMolconn program described below can convert any deprotonated functional groups to the neutral form by adding the appropriate number of hydrogen atoms and will discard the counter ion.
For each PRM, the molecular sketching software is used to generate a file which describes the molecular structure of the PRM. The file(s) describing the molecular structures of the PRMs is subsequently submitted to the computer software program winMolconn, version 1.0.1.3 (Hall Associates Consulting, Quincy, Mass., U.S.A., www.molconn.com), in order to derive various molecular descriptors for each PRM. As such, it is the winMolconn software program which dictates the structure notations and file formats that are acceptable options. These options include either a MACCS SDF formatted file (i.e., a Structure-Data File); or a Simplified Molecular Input Line Entry Specification (i.e., a SMILES string structure line notation) which is commonly used within a simple text file, often with a “.smi” or “.txt” file name extension. The SDF file represents each molecular structure in the format of a multi-line record, while the syntax for a SMILES structure is a single line of text with no white space. A structure name or identifier can be added to the SMILES string by including it on the same line following the SMILES string and separated by a space, e.g.: C1=CC=CC=C1 benzene.
The winMolconn software program is used to generate numerous molecular descriptors for each PRM, which are then output in a table format. Specific molecular descriptors derived by winMolconn are subsequently used as inputs (i.e., as variable terms in mathematical equations) for a variety of computer model test methods in order to calculate values such as: saturation Vapour Pressure (VP); Boiling Point (BP); logarithm of the Octanol/Water Partition Coefficient (log P); Odour Detection Threshold (ODT); Malodour Reduction Value (MORV); and/or Universal Malodour Reduction Value (Universal MORV) for each PRM. The molecular descriptor labels used in the models' test method computations are the same labels reported by the winMolconn program, and their descriptions and definitions can be found listed in the winMolconn documentation. The following is a generic description of how to execute the winMolconn software program and generate the required molecular structure descriptors for each PRM in a composition.
-
- Computing Molecular Structure Descriptors using winMolconn:
- 1) Assemble the molecular structure for one or more perfume ingredients in the form of a MACCS Structure-Data File, also called an SDF file, or as a SMILES file.
- 2) Using version 1.0.1.3 of the winMolconn program, running on an appropriate computer, compute the full complement of molecular descriptors that are available from the program, using the SDF or SMILES file described above as input.
- a. The output of winMolconn is in the form of an ASCII text file, typically space delimited, containing the structure identifiers in the first column and respective molecular descriptors in the remaining columns for each structure in the input file.
- 3) Parse the text file into columns using a spreadsheet software program or some other appropriate technique. The molecular descriptor labels are found on the first row of the resulting table.
- 4) Find and extract the descriptor columns, identified by the molecular descriptor label, corresponding to the inputs required for each model.
- a. Note that the winMolconn molecular descriptor labels are case-sensitive.
MORV and Universal MORV Calculation
- 1.) Input Molecular Descriptor values as determined via the method above into the following four equations:
MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22) a)
MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(e1C2C2d)−0.6202×(c1C2O2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129×(idcbar) b)
MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C1O2)+0.00403×(idc)−0.23286×(nd2). c)
MORV=−0.9926−0.03882×(Sd0)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C302)−0.45767×(c1C2C3)+0.7684×(CKetone) d)
Equation a) relates a material's effectiveness in reducing the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based malodors)
Equation b) relates a material's effectiveness in reducing the malodor trimethylamine (amine based malodors)
Equation c) relates a material's effectiveness in reducing the malodor 3-mercapto-3-methylhexan-1-ol (thiol based malodors)
Equation d) relates a material's effectiveness in reducing the malodor skatole (indole based malodors)
- 2.) For purpose of the present application, a material's MORV is the highest MORV value from equations 1.)a) through 1.)d).
- 3.) If all MORV values from equations 1.)a) through 1.)d) above are greater than 0.5, the subject material has a Universal MORV.
Method for Assigning Fragrance Fidelity Index (FFI) and the Blocker Index (BI) for a Malodor Reduction Compound Blocker materials suitable for use in consumer products of the present invention are chosen for their ability to decrease malodor, while not interfering with perception of a fragrance. Material selection is done by assigning two indices to a test sample material from two reference scales in order to rank odor strengths. The two reference scales are the Fragrance Fidelity Index (FFI) scale and the Blocker Index (BI) scale. The FFI ranks the ability of the test sample material to impart a perceivable odor which could cause interference when combined with another fragrance and the BI ranks the ability of the test sample material to reduce malodor perception. The two methods for assigning the indices to a test sample on the FFI and the BI reference scales are given below.
Method for Assigning the FFI to Test Samples The first step in the method for assigning an FFI to the test samples on the FFI reference scale is to create the FFI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known concentration of an ethyl vanillin solution. Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.
Making the FFI Reference Swatches Make three solutions of ethyl vanillin using a 50%/50% EtOH/water as the diluent at the following concentrations: 25 ppm, 120 ppm and 1000 ppm. Pipette 13 μL of each of the three solutions into the middle of a clean swatch resulting in about a 1 cm diameter of the solution in the middle of the swatch. This will create a sensory scale of three swatches with three different odor levels based on the concentration of the solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for odor strength on the FPI scale. The FFI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Fragrance Fidelity Index (FFI) as show in Table 7.
At least four perfumers/expert graders are used to rank the ethyl vanillin swatches in the FFI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert panel is asked to rank order swatches according to a scale between 0 and 3. The panel must demonstrate statistical differences between the swatches as seen in Table 7.
TABLE 7
Results FFI of reference swatches
from six perfumers/expert graders.
Expert Grader Std
FFI Swatch 1 2 3 4 5 6 Ave Dev.
0 Control: stripped 0 0 0.5 0 0 0 0.08 0.2
swatch NIL ethyl
vanillin
1 Stripped swatch with 0.5 0.5 0.5 1.5 0.5 1.0 0.75 0.4
13 μL 25 ppm ethyl
vanillin
2 Stripped swatch with 2.0 1.5 1.5 2.0 2.0 2.0 1.8 0.2
13 μL 120 ppm ethyl
vanillin
3 Stripped swatch with 3.0 2.0 3.0 3.0 3.0 3.0 2.8 0.4
13 μL 1000 ppm
ethyl vanillin
The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. Grader 2 in table 1 has a range of only 2 and is eliminated from the panel. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale.
TABLE 8
This table demonstrates acceptable expert graders
with an acceptable range and the panel meets the
requirement for discriminating statistics.
Expert Grader Std
FFI Swatch 1 3 4 5 6 Ave Dev.
0 Control: stripped swatch 0 0.5 0 0 0 0.08 0.2
NIL ethyl vanillin
1 Stripped swatch with 13 0.5 0.5 1.5 0.5 1.0 0.80 0.4
μL 25 ppm ethyl vanillin
2 Stripped swatch with 13 2.0 1.5 2.0 2.0 2.0 1.9 0.2
μL 120 ppm ethyl vanillin
3 Stripped swatch with 13 3.0 3.0 3.0 3.0 3.0 3.0 0.0
μL 1000 ppm ethyl vanillin
The reference swatches represent the 0, 1, 2, and 3 FFIs on the FFI reference scale, Table 9. The expert grader should familiarize them self with the strength of the odor on the FFI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the test sample material treated swatch.
TABLE 9
Swatch treatments comprising the Fragrance
Fidelity Index (FFI) reference scale
Swatch treatment Conc. of ethyl vanillin FFI
Clean fabric swatch 1000 ppm ethyl vanillin 3
w/13 μL ethyl vanillin
Clean fabric swatch 120 ppm ethyl vanillin 2
w/13 μL ethyl vanillin
Clean fabric swatch 25 ppm ethyl vanillin 1
w/13 μL ethyl vanillin
Clean fabric swatch NIL ethyl vanillin NIL ethyl vanillin 0
Making Swatches Treated with the Test Material
A clean swatch is treated with 13 μL of a known concentration of a test sample material resulting in an about 1 cm of the solution on the clean swatch. Just like the reference swatches, the test sample material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The test material swatches and the FFI reference swatches should be made within 2 hrs of each other. The test material swatch must be used within 0.5 to 12 hours and discarded after 12 hours.
Assigning the FFI to the Test Material At least two perfumers/expert graders are used to assign an FFI grade to a test sample. The perfumer/expert grader smells the test sample swatch by holding that swatch 1 inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the test sample an FFI grade using the FFI reference scale anchor swatches as references. The test sample swatch is assigned an FPI grade at or between numbers on the FFI scale shown in Table 9. In cases where the test sample material is graded greater than 3, the test material is not a blocker material or the concentration of the material needs to be lowered and reevaluated to determine if a lower level has a malodor blocker functionality.
Method for Assigning the BI to Test Sample The first step in the method for assigning a BI to a test sample material on the BI reference scale is to create the BI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known volume of isovaleric acid solution at a known concentration. Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.
Making the BI Reference Swatches Make one solution of 0.08% isovaleric acid using 50%/50% EtOH/water as the diluent. The BI scale contains one clean swatch with no malodor applied. Three other swatches each have a different volume of the 0.08% isovaleric acid applied. Pipette 2 μL of the 0.08% isovaleric acid solution to one clean swatch, 5 μL of the 0.08% isovaleric acid solution to the next swatch and 20 μL of isovaleric acid to the final clean swatch. These solutions are pipetted to the middle of the swatches. This will create a sensory scale of three swatches with three different odor levels based on the volume of the 0.08% isovaleric acid solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for malodor strength on the BI scale. The BI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Blocker Index (BI) as show in Table 12.
At least four perfumers/expert graders are used to rank the isovaleric acid swatches in the BI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert grader is asked to rank order swatches according to a scale between 0 and 3. The panel of graders must demonstrate statistical differences between the swatches as seen in Table 10.
TABLE 10
Results from six perfumers/expert graders to create the BI scale.
Expert Grader Std
BI Swatch 1 2 3 4 5 Ave Dev.
0 Control: stripped swatch 0 0 0 0 0 0 0
NIL isovaleric acid
1 Stripped swatch with 2 0.5 2.0 1.0 1.0 0.5 1.0 0.5
μL 0.08% isovaleric acid
2 Stripped swatch with 5 2.0 2.5 2.0 2.0 2.0 2.1 0.2
μL 0.08% isovaleric acid
3 Stripped swatch with 20 3.0 3.0 3.0 3.0 2.5 2.8 0.2
μL 0.08% isovaleric acid
The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale. Expert grader #2 did not demonstrate the ability to discriminate between the swatches and is eliminated from the panel, see Table 11.
TABLE 11
This table demonstrates acceptable expert graders
with an acceptable range and the panel meets the
requirement for discriminating statistics.
Expert Grader Std
BI Swatch 1 3 4 5 Ave Dev.
0 Control: stripped swatch 0 0 0 0 0 0
NIL isovaleric acid
1 Stripped swatch with 2 0.5 1.0 1.0 0.5 0.8 0.3
μL 0.08% isovaleric acid
2 Stripped swatch with 5 2.0 2.0 2.0 2.0 2.0 0
μL 0.08% isovaleric acid
3 Stripped swatch with 20 3.0 3.0 3.0 2.5 2.9 0.2
μL 0.08% isovaleric acid
The reference swatches represent the 0, 1, 2, and 3 BIs on the BI reference scale, Table 12. The expert grader should familiarizes him/herself with the strength of the odor on the BI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the swatch treated with the test material.
TABLE 12
Swatch treatments comprising the Blocker
Index (BI) reference scale.
Swatch/treatment Wt of isovaleric acid BI
Clean fabric swatch w/20 μL 16 mg isovaleric acid 3
0.08% isovaleric acid
Clean fabric swatch w/5 μL 4 mg isovaleric acid 2
0.08% isovaleric acid
Clean fabric swatch w/2 μL 1.6 mg isovaleric acid 1
0.08% isovaleric acid
Clean fabric swatch NIL isovaleric acid NIL isovaleric acid 0
Making the Malodorous Swatch and Treating it with a Test Material
To evaluate the BI, the test material is applied to a malodorous swatch to determine how well the test material blocks the malodor. The malodorous swatch is made by treating a clean swatch with 20 μL of a 0.08% solution of isovaleric acid. Dry the malodorous swatch treated with isovaleric acid in a vented hood for 30 minutes. After drying the malodorous swatch a known concentration of test material solution, between 1 ppm and 100 ppm is pipetted onto the malodorous swatch. Apply the test material solution right on top of the spot where the isovaleric acid solution was applied making an about 1 cm diameter spot. Just like the BI reference swatches, the isovaleric acid+test material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The isovaleric acid+test material swatches and the BI reference swatches should be made within 2 hrs of each other. The isovaleric acid+test material swatch must be used between 1-12 hours just like the reference swatches. It is sometimes necessary to evaluate several levels of the test material between about 1 and about 100 ppm to determine the BI.
Assigning the BI to the Test Material At least two perfumers/expert graders are used to assign the BI to the test sample. The expert grader smells the isovaleric acid+test material swatch by holding that swatch one inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the isovaleric acid+test material swatch a BI based on ranking its odor strength against the odor strength of the swatches in the BI reference scale. The test sample swatch is assigned a BI at or between numbers on the BI in table. In cases where the isovaleric acid+test material swatch odor is greater than 3 on the BI reference scale, this indicates the material is not a blocker or the concentration of the test material needs to be lowered to achieve its blocker functionality.
Malodor Reduction Compounds with FFI and BI Grades Based on the Aforementioned
Table
Ref # CAS# log P Name Conc FFI BI
281 54830-99-8 3.11 3a,4,5,6,7,7a-hexahydro-4,7- 10 ppm 0 2.0
methano-1H-indenyl acetate 50 ppm 0.5 2.0
677 139504-68-0 3.75 1-((2-(tert- 10 ppm 0 2.3
butyl)cyclohexyl)oxy)butan-2-ol 50 ppm 1.8 2.0
962 55066-48-3 3.17 3-methyl-5-phenylpentan-1-ol 10 ppm 0 2.3
50 ppm 0.5 1.7
261 173445-65-3 3.29 3-(3,3-dimethyl-2,3-dihydro-1H- 10 ppm 0 1.8
inden-5-yl)propanal 50 ppm 1.3 1.3
1139 87731-18-8 2.11 (Z)-cyclooct-4-en-1-yl methyl 10 ppm 0 2.0
carbonate 50 ppm 1.0 2.7
4430-31-3 1.43 3,4,4a,5,6,7,8,8a-octahydrochromen- 10 ppm 0 2.0
2-one 50 ppm 0 2.0
204 40379-24-6 3.89 7-methyloctyl acetate 10 ppm 0 2.0
50 ppm 0 2.7
1005 93981-50-1 5.59 ethyl (2,3,6-trimethylcyclohexyl) 50 ppm 0.5 2.6
carbonate
391 106-33-2 5.73 Ethyl laurate 50 ppm 0.3 2.2
1148 1139-30-6 4.06 Caryophyllene Oxide 50 ppm 0.5 2.3
524 13877-91-3 4.31 3,7-Dimethyl-1,3,6-Octatriene(cis-β 50 ppm 0 2.8
3338-55-4 ocimene 70%)
1149 23787-90-8 4 1,3,4,6,7,8alpha-hexahydro- 10 ppm 0 1.5
1,1,5,5-tetramethyl-2H-2,4alpha- 50 ppm 0.8 2.3
methanophtalen-8(5H)-one
112-42-5 4.62 Undecanol 50 ppm 0.8 2.3
174 112-53-8 5.17 1-dodecanol 50 ppm 0.5 2.3
98-52-2 2.78 4-tert-butyl cyclohexane 10 ppm 0 2.0
50 ppm 0.3 2.0
109 112-39-0 6.41 Methyl palmitate 10 ppm 2.0
Malodor Control Compounds with Improved Performance at Lower Levels.
Below are some non-limiting examples of preferred behavior by which the malodor control compound gives improved malodor control at lower concentration. These nonlimiting data provide additional compelling data that malodor is being blocked, not masked.
Table
Ref # CAS# Name Conc FFI BI
N/A 68912-13-0 8,8-dimethyl-3a,4,5,6,7,7a- 10 ppm 0 1.5
hexahydro-1H-4,7- 50 ppm 0 2.2
methanoinden-
6-yl propionate
N/A NA 4,8-dimethyl-1-(methylethyl)- 10 ppm 2.0
7-oxybiciclo [4.3.0]nonane 50 ppm 0.3 2.2
Retesting Malodor Reduction Compounds at Lower Levels. The example below demonstrates that while a malodor control compound could fail to demonstrate odor blocking (BI>2.5) at a higher concentration it should be retested at a lower concentration to determine if it passes.
Table
Ref # CAS # Name Conc FFI BI
N/A 173445-65-3 1H-Indene-5-propanal, 10 ppm 0 1.5
2,3-dihydro-3,3-dimethyl- 50 ppm 0.5 2.7
Example 1 Compositions Comprising Malodor Reduction Compounds In the present invention blends enable more potent malodor reduction because blends are useful at a higher % of the product composition before becoming olfactively noticeable. Below are non-limiting examples of malodor reduction compounds.
% wt Active
Component CAS# A B C D E
2,2,8,8-tetramethyl-octahydro-1H- 29461-14-1 35-45 15-25 5-20 10-30 15-25
2,4a-methanonapthalene-10-one
1H-Indene-ar-propanal,2,3- 300371-33-9 10-20 1-30 NIL 5-10 1-5
dihydro-1,1-dimethyl-
Hexadecanoic acid, (2E)-3,7- 3681-73-0 35-45 10-25 NIL 30-40 35-50
dimethyl-2,6-octadien-1-yl ester
1-Pentanol-3-methyl-5-phenyl 55066-48-3 10-20 10-25 2-10 5-17 10
4,7-Methano-1H-inden-5-ol, 171102-41-3 0-5 10-25 NIL 1-6 1-5
3a,4,5,6,7,7a-hexahydro-, 5-acetate
4,8-dimethyl-1-(methylethyl)-7- N/A 0-5 NIL NIL NIL 1-5
oxybiciclo [4.3.0]nonane
(3Z)-3,7-dimethylocta-1,3,6-triene 3338-55-4 NIL NIL 10-20 2-5 NIL
1H-Indene-5-propanal, 2,3- 173445-65-3 NIL NIL NIL 7.5-16 1-15
dihydro-3,3-dimethyl-
3,4,4a,5,6,7,8,8a- 4430-31-3 NIL NIL NIL 3-7 1-15
octahydrochromen-2-one
1-(2-tert- 139504-68-0 NIL NIL NIL 0.25-1.5 NIL
butylcyclohexyl)oxybutan-2-ol
ethyl (2,3,6-trimethylcyclohexyl) 93981-50-1 NIL NIL 15-30 NIL 2
carbonate
benzyl 2-hydroxypropanoate 2051-96-9 NIL NIL 2-5 NIL NIL
(3,5-dimethylcyclohex-3-en-1- 67634-16-6 NIL NIL 5-30 NIL NIL
yl)methanol
2-Dodecanol 10203-28-8 NIL 0.25-1 NIL 0.5-3 NIL
Example 2 Compositions Comprising Malodor Reduction Compounds
% wt Active
Ingredient CAS # A B C B D E
(E)-1-(2,6,6-trimethyl-1- 127-42-4 4 8 2 8 3 2
cyclohex-2-enyl)pent-1-en-3-
one
ethyl dodecanoate 106-33-2 NIL 1 NIL 3 NIL NIL
3a,4,5,6,7,7a-hexahydro-1H- 68912-13-0 8 30 1 4 1 3.5
4,7-methanoind3en-1-yl
propanoate
[1R-(1R*,4R*,6R*,10S*)]- 1139-30-6 NIL 0.3 2 0.5 NIL 0.5
4,12,12-trimethyl-9-
methylene-5-
oxatricyclo[8.2.0.04,6]dodecane
(8E)-cyclohexadec-8-en-1-one 3100-36-5 NIL 5 NIL 7 NIL NIL
3,5,5-trimethylhexyl acetate 58430-94-7 25 15 50 35 60 56
ethyl (2,3,6- 93981-50-1 NIL 1 NIL 5 NIL NIL
trimethylcyclohexyl)
carbonate
2,4-dimethyl-4,4a,5,9b- 27606-09-3 25 10 15 15 16 15
tetrahydroindeno[1,2-
d][1,3]dioxine
2,2,7,7- 23787-90-8 8 9 5 7 5 5
tetramethyltricyclo[6.2.1.01,6]
undecan-5-one
(3,5-dimethylcyclohex-3-en- 67634-16-6 NIL 0.7 NIL 0.5 NIL NIL
1-yl)methanol
3-(7,7-dimethyl-4- 33885-52-8 30 20 25 15 15 18
bicyclo[3.1.1]hept-3-enyl)-
2,2-dimethylpropanal
Total 100 100 100 100 100 100
Example 3 Malodor Reduction Composition
% wt Active
Ingredient CAS # A B C
5-Cyclohexadecen-1-One 37609-25-9 15.0 2.00 2.00
decahydro-2,2,7,7,8,9,9- 476332-65-7 0.005 0.01 0.01
heptamethylindeno(4,3a-b)furan
2,3-Dihydro-5,6-dimethoxy-2-(4- 33704-61-9 0.3 0.5 0.5
piperidinylmethylene)-1H-inden-1-one
Cedryl Methyl Ether 19870-74-7 6.0 10.0 4.0
Trans-4-Decenal 65405-70-1 0.005 0.002 0.002
Decyl Aldehyde 112-31-2 3.74 2.0 2.0
3-methyl cyclopentadecenone 63314-79-4 0.4 1.0 1.0
Diphenyl Oxide 101-84-8 0.5 1.0 1.0
3a,4,5,6,7,7a-hexahydro-4,7-methano- 54830-99-8 5.0 8.0 8.0
1H-indenyl acetate
3a,4,5,6,7,7a-hexahydro-1H-4,7- 68912-13-0 6.0 8.0 8.0
methanoinden-1-yl propanoate
2-(5-methyl-2-propan-2-yl-8- 68901-32-6 10.0 15.0 15.0
bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane
(E)-3,7-dimethyl-2,6- 3681-73-0 10.0 10.0 16.0
octadienylhexadecanoate
Iso Nonyl Acetate 58430-94-7 6.65 8.0 3.0
2,2,7,7- 23787-90-8 10.0 8.0 8.0
tetramethyltricyclo[6.2.1.01,6]undecan-5-
one
(1-Methyl-2-(1,2,2- 198404-98-7 0.1 0.3 0.3
trimethylbicyclo[3.1.0]-hex-3-
ylmethyl)cyclopropyl)methanol
Lauric Aldehyde 112-54-9 0.625 1.0 0.7
Methyl Iso Eugenol 93-16-3 18.000 10.0 13.0
Methyl hexadecanoate 112-39-0 3.000 10.0 12.0
2,3-dihydro-1,1-1H-dimethyl-indene-ar- 300371-33-9 0.400 0.0 0.3
propanal
4-tert-butylcyclohexanol 98-52-2 0.400 0.1 0.1
2-isobutyl-4-hydroxy-4- 63500-71-0 1.600 2.0 2.0
methyltetrahydropyran
Undecyl Aldehyde 112-44-7 1.725 2.888 1.888
Undecylenic Aldehyde 112-45-8 0.550 0.2 1.2
Total 100 100.0 100.0
Example 4 84 wt % Core/16 wt % Wall Melamine Formaldehyde (MF) Capsule 25 grams of butyl acrylate-acrylic acid copolymer emulsifier (Colloid C351, 25% solids, pKa 4.5-4.7, (Kemira Chemicals, Inc. Kennesaw, Ga. U.S.A.) is dissolved and mixed in 200 grams deionized water. The pH of the solution is adjusted to pH of 4.0 with sodium hydroxide solution. 8 grams of partially methylated methylol melamine resin (Cymel 385, 80% solids, (Cytec Industries West Paterson, N.J., U.S.A.)) is added to the emulsifier solution. 200 grams of perfume oil according to Table 1 or Table 2 is added to the previous mixture under mechanical agitation and the temperature is raised to 50° C. After mixing at higher speed until a stable emulsion is obtained, the second solution and 4 grams of sodium sulfate salt are added to the emulsion. This second solution contains 10 grams of butyl acrylate-acrylic acid copolymer emulsifier (Colloid C351, 25% solids, pKa 4.5-4.7, Kemira), 120 grams of distilled water, sodium hydroxide solution to adjust pH to 4.8, 25 grams of partially methylated methylol melamine resin (Cymel 385, 80% solids, Cytec). This mixture is heated to 70° C. and maintained overnight with continuous stirring to complete the encapsulation process. 23 grams of acetoacetamide (Sigma-Aldrich, Saint Louis, Mo., U.S.A.) is added to the suspension. An average capsule size of 30 um is obtained as analyzed by a Model 780 Accusizer.
Example 5 To demonstrate the benefit of the present invention, Applicants prepared liquid detergent matrix A, below.
Active Material in weight % A
C14-C15 alkyl poly ethoxylate 7 3.39
C12-C14 alkyl poly ethoxylate 7 1.13
C12-C14 alkyl poly ethoxylate 7.66
3 sulfate Na salt
Alkylbenzene sulfonic acid 1.17
Citric Acid 2.73
C12-18 fatty acid 5.06
Enzymes 0.2
Boric Acid 1.40
Trans-sulphated ethoxylated 0.81
hexamethylene diamine quat
Diethylene triamine penta 0.12
methylene phosphonic acid
Hydrogenated Castor Oil structurant 0.300
Ethanol 1.59
1,2 propanediol 0.07
Sodium hydroxide 3.48
Silicone PDMS emulsion 0.0025
Blue Dye 0.0006
Preservative Acticide MBS 2550 (ex Thor) 0.0135
Perfume (Neat) 0.3
Malodor reducing composition (Neat) 0.02
Perfume/Malodor reducing 0
composition in delivery system
Malodor reducing composition in Delivery System 0.04
Merquat 5300 polymer (1) 0.19
Water Balance to 100%
(1) Merquat 5300: terpolymer with mole ratio: 90% PAM/5% AA/5% MAPTAC produced by Nalco.
Examples 6-13 Laundry Detergent Compositions Comprising the Perfume Composition are Included Below
% w/w of laundry detergent compositions
Material 6 7 8 9 10 11 12 13
Linear alkyl benzene 7.1 6.7 11.0 10.6 6.9 4.5 10.1 8.9
sulphonate
Sodium C12-15 alkyl ethoxy 3.5 0.0 1.5 0.0 0.0 0.0 0.0 1.9
sulphate having a molar
average degree of
ethoxylation of 3
Acrylic Acid/Maleic Acid 3.6 1.8 4.9 2.0 1.0 1.6 3.9 2.3
Copolymer
Sodium Alumino Silicate 4.0 0.5 0.8 1.4 16.3 0.0 17.9 2.4
(Zeolite 4A)
Sodium Tripolyphosphate 0.0 17.5 0.0 15.8 0.0 23.3 0.0 0.0
Sodium Carbonate 23.2 16.8 30.2 17.3 18.4 9.0 20.8 30.0
Sodium Sulphate 31.4 29.4 35.5 7.2 26.3 42.8 33.2 28.3
Sodium Silicate 0.0 4.4 0.0 4.5 0.0 6.1 0.0 4.6
C14-15 alkyl ethoxylated 0.4 2.6 0.8 2.5 3.1 0.3 3.8 0.4
alcohol having a molar
average degree of
ethoxylation of 7
Sodium Percarbonate 16.0 0.0 8.4 20.4 13.1 3.6 0.0 7.0
Sodium Perborate 0.0 9.9 0.0 0.0 0.0 0.0 0.0 0.0
Tetraacetylethylenediamine 2.2 1.7 0.0 4.7 3.6 0.0 0.0 0.8
(TAED)
Calcium Bentonite 0.0 0.0 0.0 1.8 0.0 0.0 0.0 5.6
Citric acid 2.0 1.5 2.0 2.0 2.5 1.0 2.5 1.0
Protease (84 mg active/g) 0.14 0.12 0.0 0.12 0.09 0.08 0.10 0.08
Amylase (22 mg active/g) 0.10 0.11 0.0 0.10 0.10 0.0 0.14 0.08
Lipase (11 mg active/g) 0.70 0.50 0.0 0.70 0.50 0.0 0.0 0.0
Cellulase (2.3 mg active/g) 0.0 0.0 0.0 0.0 0.0 0.0 0.18 0.0
Free (Neat) Perfume 0.36 0.16 0.15 0.2 0.3 0.1 0.34 0.34
Free (Neat) malodor 0.04 0 0.03 .02 0 0 0.03 0.015
reducing composition
Perfume/malodor reducing 0.14 0.5 0 0.25 0 0.2 0.25 0.5
composition encapsulated5
Malodor reducing 0 0 0.2 0 0.02 0 0 0
composition encapsulated5
Water & Miscellaneous Balance to 100%
Examples 14-21 Granular Laundry Detergent Compositions Comprising the Perfume Composition are Included Below
% w/w of laundry detergent compositions
Material 14 15 16 17 18 19 20 21
Linear alkyl benzene 7.1 6.7 11.0 10.6 6.9 4.5 10.1 8.9
sulphonate
Sodium C12-15 alkyl ethoxy 3.5 0.0 1.5 0.0 0.0 0.0 0.0 1.9
sulphate having a molar
average degree of
ethoxylation of 3
Acrylic Acid/Maleic Acid 3.6 1.8 4.9 2.0 1.0 1.6 3.9 2.3
Copolymer
Sodium Alumino Silicate 4.0 0.5 0.8 1.4 16.3 0.0 17.9 2.4
(Zeolite 4A)
Sodium Tripolyphosphate 0.0 17.5 0.0 15.8 0.0 23.3 0.0 0.0
Sodium Carbonate 23.2 16.8 30.2 17.3 18.4 9.0 20.8 30.0
Sodium Sulphate 31.4 29.4 35.5 7.2 26.3 42.8 33.2 28.3
Sodium Silicate 0.0 4.4 0.0 4.5 0.0 6.1 0.0 4.6
C14-15 alkyl ethoxylated 0.4 2.6 0.8 2.5 3.1 0.3 3.8 0.4
alcohol having a molar
average degree of
ethoxylation of 7
Sodium Percarbonate 16.0 0.0 8.4 20.4 13.1 3.6 0.0 7.0
Sodium Perborate 0.0 9.9 0.0 0.0 0.0 0.0 0.0 0.0
Tetraacetylethylenediamine 2.2 1.7 0.0 4.7 3.6 0.0 0.0 0.8
(TAED)
Calcium Bentonite 0.0 0.0 0.0 1.8 0.0 0.0 0.0 5.6
Citric acid 2.0 1.5 2.0 2.0 2.5 1.0 2.5 1.0
Protease (84 mg active/g) 0.14 0.12 0.0 0.12 0.09 0.08 0.10 0.08
Amylase (22 mg active/g) 0.10 0.11 0.0 0.10 0.10 0.0 0.14 0.08
Lipase (11 mg active/g) 0.70 0.50 0.0 0.70 0.50 0.0 0.0 0.0
Cellulase (2.3 mg active/g) 0.0 0.0 0.0 0.0 0.0 0.0 0.18 0.0
Free (Neat) Perfume 0.36 0.16 0.15 0.2 0.3 0.1 0.34 0.34
Free (Neat) malodor 0.04 0 0.03 .02 0 0 0.03 0.015
reducing composition
Perfume/malodor reducing 0.14 0.5 0 0.25 0 0.2 0.25 0.5
composition encapsulated5
Malodor reducing 0 0 0.2 0 0.02 0 0 0
composition encapsulated5
Water & Miscellaneous Balance to 100%
The equipment and materials described in Examples 4 through to 21 can be obtained from the following: IKA Werke GmbH & Co. KG, Staufen, Germany; CP Kelco, Atlanta, United States; Forberg International AS, Larvik, Norway; Degussa GmbH, Dusseldorf, Germany; Niro A/S, Soeberg, Denmark; Baker Perkins Ltd, Peterborough, United Kingdom; Nippon Shokubai, Tokyo, Japan; BASF, Ludwigshafen, Germany; Braun, Kronberg, Germany; Industrial Chemicals Limited, Thurrock, United Kingdom; Primex ehf, Siglufjordur, Iceland; ISP World Headquarters; Polysciences, Inc. of Warrington, Pa., United States; Cytec Industries Inc., New Jersey, United States; International Specialty Products, Wayne, N.J., United States; P&G Chemicals Americas, Cincinnati, Ohio, United States; Sigma-Aldrich Corp., St. Louis, Mo., United States, Dow Chemical Company of Midland, Mich., USA
Examples 22-31 Fabric Conditioner Non-limiting examples of fabric conditioners containing the polymer coated perfume microcapsules disclosed in the present specification are summarized in the following table.
EXAMPLES
(% wt) 22 23 24 25 26 27 28 29 30 31
FSA a 14 16.47 14 12 12 16.47 — — 5 10
FSA b — 3.00 — — —
FSA c — — 6.5 — —
Ethanol 2.18 2.57 2.18 1.95 1.95 2.57 — — 0.81
Isopropyl — — — — — — 0.33 1.22 — 1.0—
Alcohol
Starch d 1.25 1.47 2.00 1.25 — 2.30 0.5 0.70 0.71 0.42
Phase 0.21 0.25 0.21 0.21 0.14 0.18 0.15 0.14 0.2 0.1
Stabilizing
Polymer f
Suds Suppressor g — — — — — — — 0.1 — —
Calcium Chloride 0.15 0.176 0.15 0.15 0.30 0.176 — 0.1-0.15 — 0025.
DTPA h 0.017 0.017 0.017 0.017 0.007 0.007 0.20 — 0.002 0.002
Preservative 5 5 5 5 5 5 — 250 j 5 5
(ppm) i, j
Antifoamk 0.015 0.018 0.015 0.015 0.015 0.015 — — 0.015 0.015
Dye (ppm) 40 40 40 40 40 40 11 30-300 30 30
Ammonium 0.100 0.118 0.100 0.100 0.115 0.115 — — — —
Chloride
HCl 0.012 0.014 0.012 0.012 0.028 0.028 0.016 0.025 0.011 0.011
Perfume 0.2 0.02 0.1 0.15 0.12 0.13 0.3 0.4 0.24 0.1
microcapsules
as disclosed in
Example 1
Malodor 0 0 0.2 0 0.02 0 0 0 0.5 0.02
reducing
composition
encapsulated5
Perfume/ 0.14 0.5 0 0.25 0 0.2 0.25 0.5 0 0
malodor
reducing
composition
encapsulated5
Additional Neat 0.8 0.7 0.9 0.5 1.2 0.5 1.1 0.6 1.0 0.9
Perfume
Free (Neat) 0.04 0 0.03 0.02 0 0 0.03 0.015 0.03 0.02
malodor
reducing
composition
Deionized † † † † † † † † † †
Water
a N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride.
b Methyl bis(tallow amidoethyl)2-hydroxyethyl ammonium methyl sulfate.
c Reaction product of Fatty acid with Methyldiethanolamine in a molar ratio 1.5:1, quaternized with Methylchloride, resulting in a 1:1 molar mixture of N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride and N-(stearoyl-oxy-ethyl) N,-hydroxyethyl N,N dimethyl ammonium chloride.
d Cationic high amylose maize starch available from National Starch under the trade name CATO ®.
f Rheovis DCE ex BASF.
g SE39 from Wacker
h Diethylenetriaminepentaacetic acid.
i KATHON ® CG available from Rohm and Haas Co. “PPM” is “parts per million.”
j Gluteraldehyde
kSilicone antifoam agent available from Dow Corning Corp. under the trade name DC2310.
† balance
Examples 32-37 Liquid Laundry Formulations (HDLs)
Ingredient 32 33 34 35 36 37
Alkyl Ether Sulphate 0.00 0.50 12.0 12.0 6.0 7.0
Dodecyl Benzene 8.0 8.0 1.0 1.0 2.0 3.0
Sulphonic Acid
Ethoxylated Alcohol 8.0 6.0 5.0 7.0 5.0 3.0
Citric Acid 5.0 3.0 3.0 5.0 2.0 3.0
Fatty Acid 3.0 5.0 5.0 3.0 6.0 5.0
Ethoxysulfated 1.9 1.2 1.5 2.0 1.0 1.0
hexamethylene diamine
quaternized
Diethylene triamine penta 0.3 0.2 0.2 0.3 0.1 0.2
methylene phosphonic acid
Enzymes 1.20 0.80 0 1.2 0 0.8
Brightener (disulphonated 0.14 0.09 0 0.14 0.01 0.09
diamino stilbene based
FWA)
Cationic hydroxyethyl 0 0 0.10 0 0.200 0.30
cellulose
Poly(acrylamide-co- 0 0 0 0.50 0.10 0
diallyldimethylammonium
chloride)
Hydrogenated Castor Oil 0.50 0.44 0.2 0.2 0.3 0.3
Structurant
Boric acid 2.4 1.5 1.0 2.4 1.0 1.5
Ethanol 0.50 1.0 2.0 2.0 1.0 1.0
1,2 propanediol 2.0 3.0 1.0 1.0 0.01 0.01
Glutaraldehyde 0 0 19 ppm 0 13 ppm 0
Diethyleneglycol (DEG) 1.6 0 0 0 0 0
2,3-Methyl-1,3- 1.0 1.0 0 0 0 0
propanediol (M pdiol)
Mono Ethanol Amine 1.0 0.5 0 0 0 0
NaOH Sufficient To pH 8 pH 8 pH 8 pH 8 pH 8 pH 8
Provide Formulation pH of:
Sodium Cumene 2.00 0 0 0 0 0
Sulphonate (NaCS)
Silicone (PDMS) emulsion 0.003 0.003 0.003 0.003 0.003 0.003
Perfume (neat) 0.2 0.15 0 0.2 0.2 0.1
Malodor reducing 0.01 0.002 0.08 0 0 0.001
composition (neat)
Malodor reducing 0.1 0.1 0 0.2 0 0
composition in delivery
system
Perfume/Malodor reducing 0 0 0.22 0 0.3 0.2
composition in delivery
system
Water Balance Balance Balance Balance Balance Balance
Examples 38-45: Liquid Unit Dose The following are examples of unit dose executions wherein the liquid composition is enclosed within a PVA film. The preferred film used in the present examples is Monosol M8630 76 μm thickness.
D E F
3 compartments 2 compartments 3 compartments
Compartment # 38 39 40 41 42 43 44 45
Dosage (g) 34.0 3.5 3.5 30.0 5.0 25.0 1.5 4.0
Ingredients Weight %
Alkylbenzene sulfonic 20.0 20.0 20.0 10.0 20.0 20.0 25 30
acid
Alkyl sulfate 2.0
C12-14 alkyl 7- 17.0 17.0 17.0 17.0 17.0 15 10
ethoxylate
C12-14 alkyl ethoxy 3 7.5 7.5 7.5 7.5 7.5
sulfate
Citric acid 0.5 2.0 1.0 2.0
Zeolite A 10.0
C12-18 Fatty acid 13.0 13.0 13.0 18.0 18.0 10 15
Sodium citrate 4.0 2.5
enzymes 0-3 0-3 0-3 0-3 0-3 0-3 0-3
Sodium Percarbonate 11.0
TAED 4.0
Polycarboxylate 1.0
Ethoxylated 2.2 2.2 2.2
Polyethylenimine1
Hydroxyethane 0.6 0.6 0.6 0.5 2.2
diphosphonic acid
Ethylene diamine 0.4
tetra(methylene
phosphonic) acid
Brightener 0.2 0.2 0.2 0.3 0.3
Perfume/Malodor 0.4 0 1.5 1.3 0 0 0.12 0
reducing composition
in delivery system
Malodor reducing 0 0.25 0 0 0.10 0.25 0 0.12
composition in
delivery system
Water 9 8.5 10 5 11 10 10 9
CaCl2 0.01
Perfume (neat) 1.7 1.7 0.6 0.2 1.5 0.5 0.1
Malodor reducing 0.015 0.002 0.02 0.06 0 0 0.002 0
composition (neat)
Minors (antioxidant, 2.0 2.0 2.0 4.0 1.5 2.2 2.2 2.0
sulfite, aesthetics, . . .)
Buffers (sodium To pH 8.0 for liquids
carbonate, To RA > 5.0 for powders
monoethanolamine) 3
Solvents (1,2 To 100 p
propanediol, ethanol),
Sulfate
Polyethylenimine (MW = 600) with 20 ethoxylate groups per —NH.
3 RA = Reserve Alkalinity (g NaOH/dose)
Example 46-47 Shampoo Formulation
Ingredient 46 47
Ammonium Laureth Sulfate (AE3S) 6.00 6.00
Ammonium Lauryl Sulfate (ALS) 10.00 10.00
Laureth-4 Alcohol 0.90 0.90
Trihydroxystearin 0.10 0.10
Perfume (neat) 0.15 0.15
Malodor reducing composition (neat) 0 0
Perfume/malodor delivery in 0.4 0.2
delivery system
Malodor reducing composition in 0 0.05
delivery system
Sodium Chloride 0.40 0.40
Citric Acid 0.04 0.04
Sodium Citrate 0.40 0.40
Sodium Benzoate 0.25 0.25
Ethylene Diamine Tetra Acetic Acid 0.10 0.10
Dimethicone 1.00 1.00
Water and Minors (QS to 100%) Balance Balance
Example 48-55: Free Flowing Particles Products Free flowing particles products that comprise perfume and/or microcapsules comprising such perfume are provided below. The table below also exemplifies combinations which comprise also perfume free and in microcapsules or combinations of these with aforementioned combinations with malodor reduction materials and/or compositions. The table also exemplifies compositions having only malodor reduction materials and/or compositions free, in microcapsules and combinations thereof that have little to no fragrance to provide a product that is essentially ‘fragrance free’
COMPOSITION
48 49 50 51
% Wt % Wt % Wt % Wt
Component Active Active Active Active
Polyethylene 70-99 0-20 0-29 0-40
glycol
Clay 0-29 0-20 0-20 0-10
NaCl 0-29 50-99 0-29 0-40
Na2SO4 0-10 0-10 0-10 0-5
Urea 0-29 0-29 0-99 0-40
Polysaccharide 0-29 0-29 0-29 0-5
Zeolite 0-29 0-29 0-29 0-5
Plasticizers/
Solvents
Starch/Zeolite 0-29 0-29 0-29 0-5
Silica 0-5 0-5 0-5 0-5
Metal oxide 0-29 0-29 0-29 0-29
Metal catalyst 0.001-0.5 0.001-0.5 0.001-0.5 0.001-0.5
Opacifier 0-5 0-5 0-1 0-1
Water 0-2 0-2 0-5 0-5
Perfume 0-5 0-5 0-5 0-5
Delivery 0.001-10 0.001-4.5 0.001-3 0.001-7.5
System
comprising
malodor
reduction
composition
COMPOSITION
52 53 54 55
% Wt % Wt % Wt % Wt
Component Active Active Active Active
Polyethylene 70-99 0-20 0-29 0-40
glycol
Clay 0-29 0-20 0-20 0-10
NaCl 0-29 50-99 0-29 0-40
Na2SO4 0-10 0-10 0-10 0-5
Urea 0-29 0-29 0-99 0-40
Polysaccharide 0-29 0-29 0-29 0-5
Zeolite 0-29 0-29 0-29 0-5
Plasticizers/
Solvents
Starch/Zeolite 0-29 0-29 0-29 0-5
Silica 0-5 0-5 0-5 0-5
Metal oxide 0-29 0-29 0-29 0-29
Metal catalyst 0.001-0.5 0.001-0.5 0.001-0.5 0.001-0.5
Opacifier 0-5 0-5 0-1 0-1
Water 0-2 0-2 0-5 0-5
Delivery 0.001-10 0.001-4.5 0.001-3 0.001-7.5
System
comprising
perfume/
malodor
reducing
composition
(1) PEG
(2) Clay
(3) Urea
(4) Polysaccharide, mostly starches, unmodified starches, starch derivatives, acid-modified starch and kappa carrageenan
(5) Zeolite
(6) Starch/Zeolite - SEA
(7) Metal oxides - non-limiting examples - TiO2, ZnO, MnO
(8) Metal catalysts
(9) Opacifier
Example 56-60 Aqueous Composition/Fabric Refresher or Air Freshening Composition
Ingredient 56 57 58 59 60
Deionized Water Balance Balance Balance Balance Balance
Ethanol 3.0 3.0 3.0 3.0 3.0
Lupasol HF1 0 0 0 0 0
Hydroxypropyl b-CD 0 0 0 0 0
Diethylene Glycol 0 0 0 0 0
Silwet L-7600 0.1 0.1 0.1 0.100 0.100
Basophor EL602 0 0.05 0.05 0.05 0.05
Maleic Acid and/or As needed As needed As needed As needed As needed
Citric Acid3
Koralone B-119 0.015 0.015 0.015 0.015 0.015
Hydroxypropyl β- 0 0 0 0 0
cyclodextrin
Sodium Hydroxide3 As needed As needed As needed As needed As needed
Malodor Reducing 0.03 0.05 0 0 .02
composition Ex. 1-3
Delivery System 0 0.2 0 .03
comprising
perfume/malodor
reducing composition
Delivery System 0 0.05 0 0.05% 0
comprising malodor
reducing composition
Perfume (neat) 0.04 0.01 0 0.05 0
Target pH 6.8 6.8 6.8 6.8 6.8
Total 100.000 100.000
The resulting fabric refreshing spray product when used to treat fabric surfaces is effective at reducing malodor on the treated fabric.
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
Every document cited herein, including any cross referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.