Foam cleaning compositions
The present invention relates to a foam composition for killing dust mites comprising an acaricidal agent, polymer, ether solvent, perfume, surfactant and water.
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This invention relates to a foam compositions which are used for treating textile surfaces of interior furnishings such as carpets, mattresses and chairs for the purpose of killing dust mites.
BACKGROUND OF THE INVENTIONA major problem existing in households is the presence of house dust mites which release allergens. Dust mites flourish in textile materials such as carpets, upholstered chairs and mattresses.
U.S. Pat. No. 4,666,940 teaches a textile cleaning composition containing benzyl benzoate as an acaricidal agent, a surfactant and a polymeric material.
European Patent No. 17,315 has disclosed that normal insecticides, such as pyrethrins or DDT, are relatively ineffective against house dust mites. According to this patent specification, benzyl benzoate is regarded as a suitable active substance, and the aim of that patent is to diminish a disadvantage of this compound, namely the relatively high vapor pressure, in order to achieve longer retention of the substance. For this purpose, combinations of benzyl benzoate with fatty acid esters and a fungicidal agent in a nonaqueous preparation are proposed therein.
According to British Patent No. 1,368,657, teaches the adding of nonvolatile polyalkylene glycols or nonvolatile ethers or esters to benzyl benzoate. However, this has caused considerable disadvantages in the use of the beds, and these are documented in detail in European Patent No. 17,315. In both literature references, the carrier substances used are volatile organic solvents.
SUMMARY OF THE INVENTIONThe present invention relates to a foam composition which is effective in killing dust mites. The foam cleaning composition contains a polyacrylate polymer, a hydrocarbon propellant, an ether type solvent, an acaricidal agent a surfactant, a hydrotrope, perfume, an anticorrision agent and water, wherein the composition does not contain benzyl benzoate.
An object of the instant composition is to provide a foam composition which is effective in killing dust mites and that the treating foam composition be readily removed from the treated surface by post vacuuming.
DETAILED DESCRIPTION OF THE INVENTIONThe present invention relates to a foam composition for killing dust mites which comprises approximately by weight:
(a) 0.5% to 10%, more preferably 1% to 8% of a polyacrylate polymer having a molecular weight of about 100,000 to about 900,000;
(b) 2% to 10%, more preferably 3% to 8% of a hydrocarbon propellant which can be a mixture of butaine, isobutane and/or propane;
(c) 0.5% to 5%, more preferably 0.75% to 3% of an alkali metal builder such selected from the group consisting of pentasodium triphosphate, potassium, pyrophosphate, sodium pyrophosphate, sodium citrate, potassium citrate, sodium carbonate, potassium carbonate, sodium bicarbonate and potassium bicarbonate and mixtures thereof;
(d) 0.5% to 3%, more preferably 0.75% to 2% of an ether solvent a C.sub.2 -C.sub.5 alkanol such as methanol, ethanol, isopropanol, propanol, butanol, isobutanol and pentanol;
(e) 0.1% to 5%, more preferably 0.5% to 4% of an acaricidal agent;
(f) 0.1% to 5%, more preferably 0.25% to 2% of at least one surfactant;
(g) 0.1% to 3%, more preferably 0.25% to 2% of a hydrotrope;
(h) 0.1% to 1%, more preferably 0.2% to 0.8% of a perfume;
(i) 0.01% to 5%, more preferably 0.02% to 3% of an anticorrosion agent;
(j) 0 to 3%, more preferably 0.1% to 2.5% of a hydrocarbon solvent such as limonene, terpene, perfume and/or essential oil; and
(k) the balance being water, wherein the foam composition does not contain benzyl benzoate.
The polyacrylate polymer useful in the instant invention has a molecular weight of about 100,000 to about 900,000, more preferably about 400,000 to about 700,000. A preferred polymer is Ubatol VTR455 which is manufactured by Cray Valley and is an aqueous emulsion of a polyacrylate polymer which contains 24 wt. % of polyacrylate polymer, 10 wt. % of a paraffin sulfonate surfactant and the balance being water.
The propellant gas mixture can be any conventionally employed propellant gas but a preferred mixture is isobutane and propane in a weight ratio of about 6:1 to 1:1.
The ether solvents used in the instant compositions are glycol ethers such as ethylene glycol monobutyl ether(butyl cellosolve), diethylene glycol monobutyl ether(butyl carbitol), triethylene glycol monobutyl ether, mono, di, tri propylene glycol monobutyl ether, tetraethylene glycol monobutyl ether, mono, di, tripropylene glycol monomethyl ether, propylene glycol monomethyl ether, ethylene glycol monohexyl ether, diethylene glycol monohexyl ether, propylene glycol tertiary butyl ether, ethylene glycol monoethyl ether, ethylene glycol monomethyl ether, ethylene glycol monopropyl ether, ethylene glycol monopentyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monopentyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monopropyl ether, triethylene glycol monopentyl ether, triethylene glycol monohexyl ether, mono, di, tripropylene glycol monoethyl ether, mono, di tripropylene glycol monopropyl ether, mono, di, tripropylene glycol monopentyl ether, mono, di, tripropylene glycol monohexyl ether, mono, di, tributylene glycol mono methyl ether, mono, di, tributylene glycol monoethyl ether, mono, di, tributylene glycol monopropyl ether, mono, di, tributylene glycol monobutyl ether, mono, di, tributylene glycol monopentyl ether and mono, di, tributylene glycol monohexyl ether, ethylene glycol monoacetate and dipropylene glycol propionate.
The surfactants can be anionic sulfonate surfactants which may be used in the compositions of this invention are water soluble and include the sodium, potassium, ammonium and ethanolammonium salts of linear C.sub.8 -C.sub.16 alkyl benzene sulfonates; C.sub.10 -C.sub.20 paraffin sulfonates, alpha olefin sulfonates containing about 10-24 carbon atoms and C.sub.8 -C.sub.18 alkyl sulfates and mixtures thereof. The preferred anionic sulfonate surfactants are a paraffin sulfonate or alkyl benzene sulfonate.
The paraffin sulfonates may be monosulfonates or di-sulfonates and usually are mixtures thereof, obtained by sulfonating paraffins of 10 to 20 carbon atoms. Preferred paraffin sulfonates are those of C.sub.12-18 carbon atoms chains, and more preferably they are of C.sub.14-17 chains. Paraffin sulfonates that have the sulfonate group(s) distributed along the paraffin chain are described in U.S. Pat. Nos. 2,503,280; 2,507,088; 3,260,744; and 3,372,188; and also in German Patent 735,096. Such compounds may be made to specifications and desirably the content of paraffin sulfonates outside the C.sub.14-17 range will be minor and will be minimized, as will be any contents of di- or poly-sulfonates.
Examples of suitable other sulfonated anionic detergents are the well known higher alkyl mononuclear aromatic sulfonates, such as the higher alkylbenzene sulfonates containing 9 to 18 or preferably 9 to 16 carbon atoms in the higher alkyl group in a straight or branched chain, or C.sub.8-15 alkyl toluene sulfonates. A preferred alkylbenzene sulfonate is a linear alkylbenzene sulfonate having a higher content of 3-phenyl (or higher) isomers and a correspondingly lower content (well below 50%) of 2-phenyl (or lower) isomers, such as those sulfonates wherein the benzene ring is attached mostly at the 3 or higher (for example 4, 5, 6 or 7) position of the alkyl group and the content of the isomers in which the benzene ring is attached in the 2 or 1 position is correspondingly low. Preferred materials are set forth in U.S. Pat. No. 3,320,174, especially those in which the alkyls are of 10 to 13 carbon atoms.
The C.sub.8-18 ethoxylated alkyl ether sulfate surfactants have the structure
R--(OCHCH.sub.2).sub.n OSO.sub.3.sup.- M.sup.+
wherein n is about 1 to about 22 more preferably 1 to 3 and R is an alkyl group having about 8 to about 18 carbon atoms, more preferably 12 to 15 and natural cuts, for example, C.sub.12-14 or C.sub.12-16 and M is an ammonium cation or a metal cation, most preferably sodium. The ethoxylated alkyl ether sulfate is present in the composition at a concentration of about 8 to about 20 wt. %, more preferably about 10 to 18 wt. %.
The ethoxylated alkyl ether sulfate may be made by sulfating the condensation product of ethylene oxide and C.sub.8-10 alkanol, and neutralizing the resultant product. The ethoxylated alkyl ether sulfates differ from one another in the number of carbon atoms in the alcohols and in the number of moles of ethylene oxide reacted with one mole of such alcohol. Preferred ethoxylated alkyl ether polyethenoxy sulfates contain 12 to 15 carbon atoms in the alcohols and in the alkyl groups thereof.
Ethoxylated C.sub.8-18 alkylphenyl ether sulfates containing from 1 to 6 moles of ethylene oxide in the molecule are also suitable for use in the invention compositions. These detergents can be prepared by reacting an alkyl phenol with 1 to 6 moles of ethylene oxide and sulfating and neutralizing the resultant ethoxylated alkylphenol. The concentration of the ethoxylated alkyl ether sulfate surfactant is about 8 to about 20 wt. %. Other surfactants which can be used are disodium cocfatty ethanol amido sulfosuccinates and sarcosinates.
The instant composition can also contain a zwitterionic surfactant and/or an amine oxide surfactant at a concentration of 0 to 5 wt. %, more preferably 0.5 to 2.0 wt %.
The zwitterionic surfactants are water soluble betaine having the general formula: ##STR1## wherein X.sup.- is selected from the group consisting of SO.sub.3.sup.- and CO.sub.2.sup.- and R.sub.1 is an alkyl group having 10 to about 20 carbon atoms, preferably 12 to 16 carbon atoms, or the amido radical: ##STR2## wherein R.sub.5 is an alkyl group having about 9 to 19 carbon atoms and a is the integer 1 to 4; R.sub.2 and R.sub.3 are each alkyl groups having 1 to 3 carbons and preferably 1 carbon; R.sub.4 is an alkylene or hydroxyalkylene group having from 1 to 4 carbon atoms and, optionally, one hydroxyl group. Typical alkyldimethyl betaines include decyl dimethyl betaine or 2-(N-decyl-N,N-dimethyl-ammonia)acetate, coco dimethyl betaine or 2-(N-coco N,N-dimethylammonia)acetate, myristyl dimethyl betaine, palmityl dimethyl betaine, lauryl dimethyl betaine, cetyl dimethyl betaine, stearyl dimethyl betaine, etc. The amidobetaines similarly include cocoamidoethylbetaine, cocoamidopropyl betaine and the like. Preferred betaines are coco (C.sub.8 -C.sub.18) amidopropyl dimethyl betaine and lauryl dimethyl betaine.
Other acaricidal agents are alpha pinene; citronellol dextro; hedione; linalool; eucalyptus globulus; thyme white; lavandin oil grosso; a C.sub.6 to C.sub.14 aldehyde such as methyl nonyl aldehyde, hexylcinnamic aldehyde; litsea cubebaoil; terpineol and verdox. Especially preferred acaricidal agents are benzyl alcohol, benzyl salicylate, piperonyl butoxide, D-phenothrin, benzophenone, acetophenone, isobutyl benzoate, phenyl ethyl acetate or benzoate, benzaldehyde, carvone, methyl salicylate, and citral lemarome and mixtures thereof.
Examples of the component (a) cationic germicides useful in the practice of the present invention at a concentration of 0 to 10 wt. %, more preferably 0.1 to 5 wt. % include cationic surfactant-type germicides such as benzethonium chloride, benzalkonium chloride, dialkyldimethylammonium halides, monoalkyltrimethylammonium halides and their variants having the counter ions thereof changed to other anions; biguanide type germicides such as chlorhexidine and chlorhexidine gluconate; amino acid surfactants such as alkyldiamino ethylglycines and alkylpolyamino ethylglycines; and the like. The cationic germicides carry a positive charge and are typically ion-paired with a counter anion so as to provide a neutral salt when in the solid phase. Other useful cationic germicides are described in the The Merck Index, Merck & Co., Inc., Rahway, N.J. 1989 incorporated herein by reference. Mixtures of cationic germicides can be used.
The cationic surfactant which can be used in the present invention at a concentration of 0 to 10 wt. %, more preferably 0.1 to 5 wt. % can be any cationic surfactant with a sanitizing action well known in the art. Examples of such cationic detergent surfactants are the quaternary ammonium compounds, such as the mono- or di(long chain alkyl) tri- or di(short chain)alkyl quaternary ammonium salts; mono- or di(long chain alkyl)imidazolinium compounds; substituted long chain alkyl polyamine salts; alkyl pyridinium salts and so on. Further suitable examples can be found in Schwartz, Perry and Berch, Vol. II (1958), "Surface-active Agents and Detergents" under the heading "Cationic Surface Active Agents". The water soluble cationic surfactants which can be utilized in this invention are iso alkyl quaternary ammonium halides such as a decyl isononyl dimethyl ammonium chloride (Bardac 2170 ex Lonza) and benzyl dimethyl ammonium chloride (Protectol D50 ex BASF).
The amine oxides are semi-polar nonionic surfactants which comprise compounds and mixtures of compounds having the formula: ##STR3## wherein R.sub.6 is an alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl, or 3-alkoxy-2-hydroxypropyl radical in which the alkyl and alkoxy, respectively, contain from 8 to 18 carbon atoms, R.sub.7 and R.sub.8 are each methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, or 3-hydroxypropyl, and n is from 0 to 10. Particularly preferred are amine oxides of the formula: ##STR4## wherein R.sub.9 is a C.sub.12-16 alkyl group or amido radical: ##STR5## wherein R.sub.12 is an alkyl group having about 9 to 19 carbon atoms and a is an integer 1 to 4 and R.sub.10 and R.sub.11 are methyl or ethyl. The above ethylene oxide condensates, amides, and amine oxides are more fully described in U.S. Pat. No. 4,316,824 which is hereby incorporated herein by reference.
Ethoxylated nonionic surfactants or lauryl myristyl monoethanolamide can be used at a concentration of 0 to 5 wt. %, more preferably 0.5 to 2 wt. % in the instant compositions.
According to the present invention, the role of the hydrocarbon can be provided by a non-water-soluble perfume. Typically, in aqueous based compositions the presence of a solubilizers, such as alkali metal lower alkyl aryl sulfonate hydrotrope, triethanolamine, urea, etc., is required for perfume dissolution, especially at perfume levels of 0.1% and higher, since perfumes are generally a mixture of fragrant essential oils and aromatic compounds which are generally not water-soluble. Therefore, by incorporating the perfume into the aqueous cleaning composition as the oil (hydrocarbon) phase of the ultimate o/w microemulsion composition, several different important advantages are achieved.
As used herein and in the appended claims the term "perfume" is used in its ordinary sense to refer to and include any non-water soluble fragrant substance or mixture of substances including natural (i.e., obtained by extraction of flower, herb, blossom or plant), artificial (i.e., mixture of natural oils or oil constituents) and synthetically produced substance) odoriferous substances. Typically, perfumes are complex mixtures of blends of various organic compounds such as alcohols, aldehydes, ethers, aromatic compounds and varying amounts of essential oils (e.g., terpenes) such as from 0% to 80%, usually from 10% to 70% by weight, the essential oils themselves being volatile odoriferous compounds and also serving to dissolve the other components of the perfume, wherein the solvent of the perfume which can be 50 to 70 wt. % of the perfume can exhibit acaricidal activity.
In the present invention the precise composition of the perfume is of no particular consequence to cleaning performance so long as it meets the criteria of water immiscibility and having a pleasing odor. Naturally, of course, especially for cleaning compositions intended for use in the home, the perfume, as well as all other ingredients, should be cosmetically acceptable, i.e., non-toxic, hypoallergenic, etc. The instant compositions show a marked improvement in ecotoxocity as compared to existing commercial products. The perfume is present in the sprayable cleaning composition in an amount of from 0.01% to 5% by weight, preferably from 0.05% to 3% by weight.
The water insoluble saturated or unsaturated organic compounds contain 4 to 20 carbon atoms and up to 4 different or identical functional groups. Examples of acceptable water insoluble saturated or unsaturated organic compound include (but are not limited to) water insoluble hydrocarbons containing 0 to 4 different or identical functional groups, water insoluble aromatic hydrocarbons containing 0 to 4 different or identical functional groups, water insoluble heterocyclic compounds containing 0 to 4 different or identical functional groups, water insoluble ethers containing 0 to 3 different or identical functional groups, water insoluble alcohols containing 0 to 3 different or identical functional groups, water insoluble amines containing 0 to 3 different or identical functional groups, water insoluble esters containing 0 to 3 different or identical functional groups, water insoluble carboxylic acids containing 0 to 3 different or identical functional groups, water insoluble amides containing 0 to 3 different or identical functional groups, water insoluble nitriles containing 0 to 3 different or identical functional group, water insoluble aldehydes containing 0 to 3 different or identical functional groups, water insoluble ketones containing 0 to 3 different or identical functional groups, water insoluble phenols containing 0 to 3 different or identical functional groups, water insoluble nitro compounds containing 0 to 3 different or identical functional groups, water insoluble halogens containing 0 to 3 different or identical functional groups, water insoluble sulfates or sulfonates containing 0 to 3 different or identical functional groups, limonene, dipentene, terpineol, essential oils, perfumes, water insoluble organic compounds containing up to 4 different or identical functional groups such as an alkyl cyclohexane having both three hydroxys and one ester group and mixture thereof.
Typical heterocyclic compounds are 2,5-dimethylhydrofuran, 2-methyl-1,3-dioxolane, 2-ethyl 2-methyl 1,3 dioxolane, 3-ethyl 4-propyl tetrahydropyran, 3-morpholino-1,2-propanediol and N-isopropyl morpholine. A typical amine is alphamethyl benzyldimethylamine. Typical halogens are 4-bromotoluene, butyl chloroform and methyl perchloropropane. Typical hydrocarbons are 1,3-dimethylcyclohexane, cyclohexyl-1 decane, methyl-3 cyclohexyl-9 nonane, methyl-3 cyclohexyl-6 nonane, dimethyl cycloheptane, trimethyl cyclopentane, ethyl-2 isopropyl-4 cyclohexane. Typical aromatic hydrocarbons are bromotoluene, diethyl benzene, cyclohexyl bromoxylene, ethyl-3 pentyl-4 toluene, tetrahydronaphthalene, nitrobenzene and methyl naphthalene. Typical water insoluble esters are benzyl acetate, dicyclopentadienylacetate, isononyl acetate, isobornyl acetate and isobutyl isobutyrate. (Typical water insoluble ethers are di(alphamethyl benzyl)ether and diphenyl ether. Typical alcohols are phenoxyethanol and 3-morpholino-1,2-propanediol. Typical water insoluble nitro derivatives are nitro butane and nitrobenzene.
Suitable essential oils are selected from the group consisting of: Anethole 20/21 natural, Aniseed oil china star, Aniseed oil globe brand, Balsam (Peru), Basil oil (India), Black pepper oil, Black pepper oleoresin 40/20, Bois de Rose (Brazil) FOB, Borneol Flakes (China), Camphor oil, White, Camphor powder synthetic technical, Cananga oil (Java), Cardamom oil, Cassia oil (China), Cedarwood oil (China) BP, Cinnamon bark oil, Cinnamon leaf oil, Citronella oil, Clove bud oil, Clove leaf, Coriander (Russia), Coumarin 69.degree. C. (China), Cyclamen Aldehyde, Diphenyl oxide, Ethyl vanilin, Eucalyptol, Eucalyptus oil, Eucalyptus citriodora, Fennel oil, Geranium oil, Ginger oil, Ginger oleoresin (India), White grapefruit oil, Guaiacwood oil, Gurjun balsam, Heliotropin, Isobornyl acetate, Isolongifolene, Juniper berry oil, L-methyl acetate, Lavender oil, Lemon oil, Lemongrass oil, Lime oil distilled, Litsea Cubeba oil, Longifolene, Menthol crystals, Methyl cedryl ketone, Methyl chavicol, Methyl salicylate, Musk ambrette, Musk ketone, Musk xylol, Nutmeg oil, Orange oil, Patchouli oil, Peppermint oil, Phenyl ethyl alcohol, Pimento berry oil, Pimento leaf oil, Rosalin, Sandalwood oil, Sandenol, Sage oil, Clary sage, Sassafras oil, Spearmint oil, Spike lavender, Tagetes, Tea tree oil, Vanilin, Vetyver oil (Java), Wintergreen, Allocimene, Arbanex.TM., Arbanol.RTM., Bergamot oils, Camphene, Alpha-Campholenic aidehyde, I-Carvone, Cineoles, Citral, Citronellol Terpenes, Alpha-Citronellol, Citronellyl Acetate, Citronellyl Nitrile, Para-Cymene, Dihydroanethole, Dihydrocarveol, d-Dihydrocarvone, Dihydrolinalool, Dihydromyrcene, Dihydromyrcenol, Dihydromyrcenyl Acetate, Dihydroterpineol, Dimethyloctanal, Dimethyloctanol, Dimethyloctanyl Acetate, Estragole, Ethyl-2 Methylbutyrate, Fenchol, Fernlol.TM., Florilys.TM., Geraniol, Geranyl Acetate, Geranyl Nitrile, Glidmint.TM. Mint oils, Glidox.TM., Grapefruit oils, trans-2-Hexenal, trans-2-Hexenol, cis-3-Hexenyl Isovalerate, cis-3-Hexanyl-2-methylbutyrate, Hexyl Isovalerate, Hexyl-2-methylbutyrate, Hydroxycitronellal, Ionone, Isobornyl Methylether, Linalool, Linalool Oxide, Linalyl Acetate, Menthane Hydroperoxide, I-Methyl Acetate, Methyl Hexyl Ether, Methyl-2-methylbutyrate, 2-Methylbutyl Isovalerate, Myrcene, Nerol, Neryl Acetate, 3-Octanol, 3-Octyl Acetate, Phenyl Ethyl-2-methylbutyrate, Petitgrain oil, cis-Pinane, Pinane Hydroperoxide, Pinanol, Pine Ester, Pine Needle oils, Pine oil, alpha-Pinene, beta-Pinene, alpha-Pinene Oxide, Plinol, Plinyl Acetate, Pseudo Ionone, Rhodinol, Rhodinyl Acetate, Spice oils, alpha-Terpinene, gamma-Terpinene, Terpinene-4-OL, Terpineol, Terpinolene, Terpinyl Acetate, Tetrahydrolinalool, Tetrahydrolinalyl Acetate, Tetrahydromyrcenol, Tetralol.RTM., Tomato oils, Vitalizair, Zestoral.TM..
The amine oxides which can be optionally used in the instant formula are depicted by: ##STR6## wherein R.sub.6 is a C.sub.10 -C.sub.18 linear or branched chain alkyl group, R.sub.7 is a C.sub.1 -C.sub.16 linear alkyl group and R.sub.8 is a C.sub.1 -C.sub.16 linear alkyl group.
The hydrotropes useful in the instant invention are sodium xylene sulfonate or sodium cumene sulfonate.
The acaricidal agents which are useful in the instant invention are selected from the group consisting of benzaldehyde, benzophenone, methyl salicylate, citral lemarome, acetophenone, citral dimethyl acetal, benzyl acetate, benzyl propionate, phenyl ethyl acetate, phenyl ethyl benzoate, carvone, aubepine, litsea cubeba oil, geranyl acetate, benzyl isoeugenone, isobutyl benzoate, terpinolene, rosemary oil, amyl salicylate, phenyl ethyl alcohol, eucalyptus globulus, decyl aldehyde, benzyl acetone, linalool, terpineol, citronella, D-phenothrin and piperonyl butoxide and mixtures thereof.
The anticorrision agents are selected from the group consisting of sodium nitrate, sodium silicate, sodium sarcosinate, sodium sulfosuccinate, sodium phosphate and sodium borate.
The following examples illustrate foam cleaning compositions of the described invention. Unless otherwise specified, all percentages are by weight. The exemplified compositions are illustrative only and do not limit the scope of the invention. Unless otherwise specified, the proportions in the examples and elsewhere in the specification are by weight.
EXAMPLE 1The following compositions in wt. % were prepared at 25.degree. C. by simple mixing:
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A B C D E F G
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Polyacrylate polymer Ubatol VTR 455
3.84
3.84
3.84
3.84
3.84
3.84
3.84
Sodium C.sub.13- C.sub.17 paraffin sulfonate
1.6 1.6 1.6 1.6 1.6 1.6 1.6
Pentasodium triphosphate
2.2 2.2 2.2 2.2 2.2 2.2 2.2
Perfume 0.3 0.3 0.3 0.3 0.3 0.3 0.3
Sodium silicate 0.2 0.2 0.2 0.2 0.2 0.2 0.2
Lauryl myristyl monoethanol amide
0.5 0.5 0.5 0.5 0.5 0.5 0.5
Sodium xylene sulfonate
0.3 0.3 0.3 0.3 0.3 0.3 0.3
Water bal bal bal bal bal bal bal
Diethylene glycol monobutyl ether
1 1 1 2 1 1 0
Phenothrin 0.15
Piperonyl butoxide 0.75
Benzyl alcohol 2 1
Benzyl salicylate
1 0.5
Isobutane 4.63
4.63
4.63
4.63
4.63
4.63
4.63
Propane 0.87
0.87
0.87
0.87
0.87
0.87
0.87
Acaricidal tests: % dead dust mites
30 min contact time - neat product
100 100 100 l00 0 0 0
3 h after carpet treatment
89.9
49 34 81
24 h after carpet treatment
91 55 22 99
96 h after carpet treatment
92 98 65 100
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The acaricidal test for mites is done, first, in liquid medium in 24 wells plastic plates. About 30 living mites are placed in the well with the nourishing culture medium and then covered with either water (background values) or the neat foam for carpet (or any other liquid product to be tested) in water and left in contact for 30 minutes. The remaining living mites are counted by observation under the microscope after the envisaged contact time. Contact times with mites can be 5 minutes up to 3 hours. When the foam for carpet has been found an acaricidal activity, the test is repeated on carpet pieces. Carpet pieces are infested with a known amount (80-100) of dust mites and let to settle for 1 hour. Carpet pieces are then treated with the acaricidal foam and the remaining living mites are counted by visual observation after 3 hours, 24 hours and 96 hours. The examination can be extended up to 7 days after the treatment.
Claims
1. A foam composition comprising approximately by weight:
- (a) 0.5% to 10% of a polyacrylate polymer;
- (b) 2% to 10% of a hydrocarbon propellant;
- (c) 0.5% to 5% of pentasodium triphosphate;
- (d) 0.5% to 3% of a C.sub.2 -C.sub.5 alkanol solvent;
- (e) 0.1% to 5% of at least one acaricidal agent, wherein the acaricidal agent is selected from the group consisting of benzaldehyde, benzophenone, acetophenone, citral dimethyl acetal, carvone, litsea cubeba oil, terpinolene, rosemary oil, phenyl ethyl alcohol, eucalyptus globulus, decyl aldehyde, benzyl acetone, linalool, terpineol, citronella, D-phenothrin and piperonyl butuoxide and mixtures thereof;
- (f) 0.1% to 5% of a surfactant;
- (g) 0.1% to 3% of a hydrotrope;
- (h) 0.1% to 1% of a perfume; and
- (i) the balance being water, wherein the composition does not contain benzyl benzoate.
2. The composition according to claim 1 wherein said surfactant is an anionic surfactant.
3. The composition according to claim 2 further including a zwitterionic surfactant.
4. The composition according to claim 2 further including a nonionic surfactant.
5. The composition according to claim 1, wherein said hydrocarbon propellant is a mixture of propane and isobutane.
6. The composition of claim 1, further including an anticorrision agent.
| 4666940 | May 19, 1987 | Bischoff et al. |
| 8912673 | December 1989 | WOX |
Type: Grant
Filed: Sep 25, 1997
Date of Patent: Jun 27, 2000
Assignee: Colgate Palmolive Company (New York, NY)
Inventors: Germaine Zocchi (Villers-Aux-Tours), Pierre Fonsny (Fays)
Primary Examiner: John Pak
Attorney: Richard E. Nanfeldt
Application Number: 8/937,895
International Classification: A01N 3504; A01N 4330; A01N 2516; C11D 348;
