Organic Nitrogen-containing Material Patents (Class 106/14.42)
  • Publication number: 20040011252
    Abstract: Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems.
    Type: Application
    Filed: January 13, 2003
    Publication date: January 22, 2004
    Inventors: Jeffrey A. Sturgill, Andrew Wells Phelps
  • Publication number: 20030221590
    Abstract: Corrosion-inhibiting pigments based on manganese are described that contain a heptavalent (permanganate), hexavalent (manganate), or pentavalent (manganate) compound. An inorganic or organic material is used with the heptavalent, hexavalent, or pentavalent manganese ion to form a compound that is sparingly soluble in water. Specific solubility control cations are chosen to control the release rate of heptavalent, hexavalent, or pentavalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Solubility control agents may also modify the processing and handling characteristics of the formed powders. Many permanganate or manganate compounds are presented that can equal the performance of conventional hexavalent chromium systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure.
    Type: Application
    Filed: January 13, 2003
    Publication date: December 4, 2003
    Inventors: Jeffrey A. Sturgill, Andrew Wells Phelps
  • Patent number: 6579353
    Abstract: A transparent coating for protecting wood, brick, stucco, glass, steel and other materials from graffiti, paint, ink, mildew, rust and salt air. The protective coating of the present invention comprises: water, paraffin wax, a corrosion inhibitor, an organic amine, and an emulsifying agent. Preferably each gallon of the transparent protective coating contains: 2308.0 g water, 621.4 g paraffin wax, 15.8 g triethanolamine, 6.5 g diethanolamine, and 85.6 g glycerine monostearate. The present invention also comprises methods for preparing the protective coating and methods of protecting surfaces from being marred by graffiti and the like using these protective coatings.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: June 17, 2003
    Inventors: Michael DeLaMater, Donal Dallas Coleman
  • Publication number: 20030101898
    Abstract: An organosilane- and/or organosiloxane-containing composition reduces active corrosion of steel reinforcement in concrete.
    Type: Application
    Filed: November 5, 2002
    Publication date: June 5, 2003
    Applicant: DEGUSSA AG
    Inventors: Burkhard Standke, Edward McGettigan
  • Patent number: 6540943
    Abstract: The corrosion of metal equipment which is cleaned with an inorganic acid is inhibited by treating the equipment with a corrosion inhibitor composition containing at least one quaternary ammonium compound, a sulfur-containing compound and a nonionic surfactant in a solvent.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: April 1, 2003
    Assignee: Ondeo Nadco Company
    Inventors: Duane S. Treybig, Dennis A. Williams
  • Patent number: 6540934
    Abstract: The present provides novel deicing and anti-icing compositions which are especially adapted for and are highly useful as deicing and anti-corrosion products, especially on many surfaces which require protection against icing and corrosion, such as airport runways.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: April 1, 2003
    Assignee: Metss Corporation
    Inventors: Richard Sapienza, William Ricks, Joseph Sanders
  • Patent number: 6524376
    Abstract: An anticorrosive agent containing, as essential components, (a) urea or a urea derivative and (b) a hydroxy aromatic compound.
    Type: Grant
    Filed: January 25, 2001
    Date of Patent: February 25, 2003
    Assignee: NEC Corporation
    Inventors: Hidemitsu Aoki, Tatsuya Koito, Kenichi Nakabeppu
  • Patent number: 6521028
    Abstract: The present invention is directed to methods for preparing quaternary ammonium salts, particularly pyridinium and quinolinium salts. By preparing these salts in a solvent selected from the group consisting of propylene glycols, propylene glycol ethers and mixtures thereof, the production of undesirable by-products and contamination of the product with undesirable solvents are minimized, if not eliminated. Using the preparation methods of the present invention low hazard corrosion inhibitors and aqueous cleaning solutions using these inhibitors may be prepared. In fact, by preparing dodecyl pyridinium bromide in dipropylene glycol methyl ether as the solvent, a particularly desirable corrosion inhibitor characterized by a low toxicity and a high flash point has been prepared. The present invention thus provides the safer corrosion inhibitors and cleaning solutions long sought by industrial cleaning services.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: February 18, 2003
    Assignee: HydroChem Industrial Services, Inc.
    Inventor: Wayne W. Frenier
  • Patent number: 6517617
    Abstract: The present invention relates to the application of a coating to a pipeline, FPS (Fire Protection System) or to pipe stock from which a pipeline is fabricated. A composition which when applied to the inside surface of the pipe prevents either chemical corrosion or microbiologically influenced corrosion is disclosed. Also disclosed is a method for utilizing this material to protect both existing pipelines and the raw stock used to construct pipelines and various apparatus for applying a coating of the composition, cleaning, and maintenance of the passive coating. Also disclosed is a method to recycle the composition to be used in other industrial pacification processes.
    Type: Grant
    Filed: September 20, 2001
    Date of Patent: February 11, 2003
    Assignee: WHI USA, Inc.
    Inventors: Douglas M. Chartier, Calvin L. Reid
  • Publication number: 20030026912
    Abstract: A method, a composition and a method for making the composition for increasing the corrosion resistance of a magnesium or magnesium alloy surface is disclosed. The composition is a water/organic solution of one or more hydrolyzed silanes. By binding silane moieties to the magnesium surface, an anti-corrosion coating on a magnesium workpiece is produced. A complementary method, composition and method for preparing the composition for treating a metal surface to increase corrosion resistance is disclosed. The composition is an aqueous hydrogen fluoride solution with a non-ionic surfactant.
    Type: Application
    Filed: June 26, 2002
    Publication date: February 6, 2003
    Applicant: ALGAT SHERUTEY GIMUR TEUFATI-KIBBUTZ ALONIM
    Inventor: Ilya Ostrovsky
  • Publication number: 20030015685
    Abstract: The present provides novel deicing and anti-icing compositions which are especially adapted for and are highly useful as deicing and anti-corrosion products, especially on many surfaces which require protection against icing and corrosion, such as airport runways.
    Type: Application
    Filed: July 13, 2001
    Publication date: January 23, 2003
    Inventors: Richard Sapienza, William Ricks, Joseph Sanders
  • Patent number: 6488749
    Abstract: An object of the present invention is to provide an aquarous rust inhibitor having low toxicity and excellent rust resistance, which contains saturated fatty acid, saturated dicarboxylic acid and salt thereof, derivatives of ethylenediamine tetraacetic acid, tolyltriazole or benzotriazole, fatty acid metal salt, and water.
    Type: Grant
    Filed: July 10, 2001
    Date of Patent: December 3, 2002
    Inventors: Yasuo Fukutani, Kikuko Fukutani, Yukio Wada, Yoshiki Ueno, Shinya Fukushima, Eiichiro Nakayama
  • Patent number: 6485549
    Abstract: A corrosion resistant coating to protect metallic and polymeric composite surfaces from corrosion and water promoted deterioration that is environmentally safe and non-toxic and is applied in one coat without the use of a primer is provided. The coating comprises a tough, flexible polyurethane binder and a corrosion inhibiting pigment selected from the group consisting of zinc hydroxy phosphite, zinc phosphate, calcium ion-exchanged silica, calcium strontium zinc phosphosilicate. The coating is effective in protecting both aluminum and steel surfaces against corrosion in salt spray environments and in protecting polymeric composite materials such as ablative coatings used in aerospace against deterioration after exposure to water.
    Type: Grant
    Filed: August 2, 2000
    Date of Patent: November 26, 2002
    Assignee: USBI
    Inventors: Howard L. Novak, James M. Klotz
  • Patent number: 6482274
    Abstract: A nonchromate metallic surface treating agent comprising (a) a silane coupling agent and/or a hydrolytic condensation product thereof, (b) water-dispersible silica, and (c) a zirconium compound and/or a titanium compound is disclosed. The present invention also discloses a method for treating a surface of a PCM steel panel, a method of producing a PCM steel panel, and a PCM steel panel as produced by the method.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: November 19, 2002
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Toshiaki Shimakura, Motohiro Sasaki, Katsuyoshi Yamasoe, Christian Jung
  • Patent number: 6475299
    Abstract: Disclosed are a conversion coating composition for use in the surface treatment of a PCB and a conversion coating method using the same. The composition comprises 0.1-30 vol % of sulfuric acid; 0.1-15 vol % of hydrogen peroxide; 0.01-10 wt % of an organic acid; 0.1-30 wt % of a nitrogen compound; 0.01-10 wt % of an organic silicate and/or organic titanate; and 0.1-20 wt % of a film forming auxiliary, 0.1-30 wt % of an etching rate controller, 0.1-20 wt % of a reaction promoter and/or 0.1-20 g/l of a stabilizer. This composition is applied to a PCB at 10-60° C. for 1-10 min. The conversion coating film is superb in adhesive strength, acid resistance, and adhesion and can be formed with ease.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: November 5, 2002
    Assignees: Samsung Electro-Mechanics Co., Ltd., SD Chemical Co., Ltd.
    Inventors: Byong Ho Lee, Dek Gin Yang, Yang Je Lee, Myong Gun Chong, Jae Ok Lim, Sung Wook Chun, Min Eui Hong, Kyu Hong An
  • Patent number: 6475300
    Abstract: A non-chromate metallic surface treating agent comprising (a) a silane coupling agent and/or a hydrolytic condensation product thereof, (b) water-dispersible silica, and (c) a zirconium compound and/or a titanium compound, and further comprising (d) a thiocarbonyl-containing compound and/or (e) a water-soluble acrylic resin is disclosed.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: November 5, 2002
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Toshiaki Shimakura, Motohiro Sasaki, Katsuyoshi Yamasoe, Hiromasa Nomura, Hiroshi Kanai, Kouhei Ueda
  • Patent number: 6464763
    Abstract: A composition for use in forming a dry film coating on metal surfaces to at least temporarily protect the surfaces from oxidation comprises at least 20% by weight of a combination of at least one saturated linear carboxylic monoacid with at least one unsaturated linear carboxylic monoacid. The monoacids are in the form of alkaline, alkaline-earth or amine salts. The carbon chain of each acid comprises an uneven number of carbon atoms varying from 5 to 21. At least 0.5% by weight of a triazole derivative can be added to enhance the anti-corrosion effect. The composition is water-soluble and the dry protective film can be formed by diluting the composition in water, applying the diluted composition to a metal surface and then air drying it.
    Type: Grant
    Filed: May 22, 2001
    Date of Patent: October 15, 2002
    Assignee: Elf Antar France
    Inventors: Pierre Steinmetz, Jacques Cotteret, Corinne Chauvineau
  • Publication number: 20020124768
    Abstract: A composition and process are described which are useful in treating metal surfaces, which composition comprises an oxidizer, an acid, a corrosion inhibitor, an organic nitro compound and, optionally, a benzotriazole with an electron withdrawing group in the I-position which electron withdrawing group is a stronger electron withdrawer than a hydrogen group, optionally, a source of adhesion enhancing species selected from the group consisting of molybdates, tungstates, tantalates, niobates, vanadates, isopoly or heteropoly acids of molybdenum, tungsten, tantalum, niobium, vanadium, and combinations of any of the foregoing and optionally but preferably a source of halide ions. The composition and process are useful in increasing the adhesion of metal surfaces to polymeric substances and in preserving said adhesion through temperature variation.
    Type: Application
    Filed: February 27, 2002
    Publication date: September 12, 2002
    Applicant: MacDermid, Inc.
    Inventor: Donald Ferrier
  • Patent number: 6447590
    Abstract: An aqueous composition containing at least 2% by weight of pregelatinized starch and, as an emulsion, at least 1% or vegetable wax or oil, preferably chosen from carnauba wax, jojoba oil and candelilla wax. Also a process for applying a layer of this composition and in drying it so as to obtain a dry film having; a surface density of between 1 and 2.5 g/m2. Treating a metal surface with the composition provides temporary corrosion protection and prelubrication.
    Type: Grant
    Filed: August 25, 2000
    Date of Patent: September 10, 2002
    Assignee: Usinor
    Inventors: Ronald Kefferstein, Lothaire Scherer
  • Patent number: 6423126
    Abstract: There is provided an anticorrosive composition for a memory unit bearing so as to control outgas generation which would cause magnetic head crushing or memory error. The anticorrosive composition for a memory unit bearing contains a carbonic ester represented by the following formula: wherein R and R′ are branched alkyl groups of 13 to 15 carbon atoms and may either be the same or different.
    Type: Grant
    Filed: March 29, 2000
    Date of Patent: July 23, 2002
    Assignee: Minebea Co., Ltd.
    Inventor: Motoharu Akiyama
  • Patent number: 6402990
    Abstract: The present invention provides methods and compositions for the reduction of the corrosion rate of already corroding steel reinforcements embedded in a hardened concrete structure as well as for the protective corrosion inhibition of uncorroded steel reinforcements embedded in a hardened concrete structure exposed to aggressive environments. The inventive new compositions employed for the novel method are essentially based on one or more amino- and/or hydroxyalkylamino compound(s), which are partially or completely neutralized with one or more inorganic acid(s) and/or derivatives thereof and/or aliphatic carboxylic- and/or aromatic carboxylic acid(s), one or more surfactant(s) and one or more water-based or water-thinnable water repellent agent(s) selected from the group of organosilicones.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: June 11, 2002
    Assignee: Sika AG, Vorm, Kaspar Winkler & Co.
    Inventors: Beat Marazzani, Theodor A. Bürge, Urs Mäder
  • Patent number: 6383271
    Abstract: An anti-corrosive coating composition suitable for providing corrosion protection for a sheet metal substrate includes from 20 to 97 wt. % of a filler dispersed in a polymeric base or matrix material. The filler includes at least one filler material having a hollow cellular structure, of which the hollow cells are loaded with organic and/or inorganic inhibitors and/or antioxidants. The hollow cellular structure material may be diatomaceous earth, zeolite, or carbon. The inhibitors and/or antioxidants may be selected from carbonic acids, amines, ketones, aldehydes, heterocyclic compounds, phosphates, benzoates, silicates, vanadates, tungstates, zirconates, borates, molybdates, benzaldehyde, vitamin C, vitamin E, or the like. A long term durable corrosion protection is achieved because the inhibitors and/or antioxidants are released from the hollow cells of the filler material in a dosed time-release manner over the operating lifetime of the anti-corrosive coating.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: May 7, 2002
    Assignee: DaimlerChrysler AG
    Inventor: Christina Schmidt
  • Patent number: 6383272
    Abstract: A composition and process are described which are useful in treating metal surfaces, which composition comprises an oxidizer, an acid, a corrosion inhibitor, an organic nitro compound and, optionally, a benzotriazole with an electron withdrawing group in the 1-position which electron withdrawing group is a stronger electron withdrawer than a hydrogen group, optionally, a source of adhesion enhancing species selected from the group consisting of molybdates, tungstates, tantalates, niobates, vanadates, isopoly or heteropoly acids of molybdenum, tungsten, tantalum, niobium, vanadium, and combinations of any of the foregoing and optionally but preferably a source of halide ions. The composition and process are useful in increasing the adhesion of metal surfaces to polymeric substances and in preserving said adhesion through temperature variation.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: May 7, 2002
    Inventor: Donald Ferrier
  • Patent number: 6372027
    Abstract: The invention relates to a process, and compositions for its implementation, to promote adhesion between an inorganic substrate and an organic polymer, especially between the copper surfaces of printed circuits for electronic use and a polymer resin, in which an organometallic layer of a dark brown colour, which is very uniform and compact, is deposited on the inorganic substrate by means of treatment in a composition which comprises: a) a silane or a mixture of functional organic silanes with a structure represented by the following general formula: Y—(CH2)n—Si(OR)3 where: Y represents a functional organic group, n is a number which has a value between 0 and 3, and R represents a hydrogen atom or any easily hydrolysable group which is capable of releasing an atom of hydrogen b) an azole compound; c) an oxygen carrier; d) an organic or inorganic acid; and preferably e) a zinc compound.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: April 16, 2002
    Assignee: Alfachimici S.p.A.
    Inventors: Francesco Tomaiuolo, Riccardo Ottria
  • Patent number: 6340438
    Abstract: A corrosion inhibiting admixture for concrete is disclosed comprising a combination of organic (amines) and inorganic (nitrites) fractions that provide a synergistic effect when present at a specific ratio. Such a synergistic effect occurs when the amine:nitrite ratio (% by weight) is between 1.5 to 2.5 resulting in the admixture providing excellent corrosion inhibiting capabilities.
    Type: Grant
    Filed: April 19, 1999
    Date of Patent: January 22, 2002
    Assignee: Tomahawk, Inc.
    Inventors: Donald R. Lane, Jose A. Melendez, Violeta F. Munteanu, Frederick D. Kinney
  • Patent number: 6331202
    Abstract: The invention relates to a paint and/or a coating composition comprising anti-corrosive composition comprises at least one oxyaminophosphate pigment and at least one oxynitrite, oxymetalphosphate, oxyborate or oxysilicate. A method for the oxyaminophosphate pigment is provided.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: December 18, 2001
    Assignee: Pigmentan Anticorrosive Pigments for Paints Ltd.
    Inventor: Gregory Pipko
  • Publication number: 20010011515
    Abstract: An anticorrosive agent containing, as essential components, (a) urea or a urea derivative and (b) a hydroxy aromatic compound.
    Type: Application
    Filed: January 25, 2001
    Publication date: August 9, 2001
    Applicant: NEC Corporation
    Inventors: Hidemitsu Aoki, Tatsuya Koito, Kenichi Nakabeppu
  • Patent number: 6261346
    Abstract: A process useful for protecting metal surfaces against corrosion in is presented involving: (a) forming a corrosion inhibitor having a compound corresponding to formula (I): where R1, R2 and R3 independently of one another represent an alkyl or hydroxyalkyl group containing 1 to 4 carbon atoms, an aryl or alkylaryl group or a group corresponding to formula (II): A− is an anion, n is the number 2 or 3, p is a number of 1 to 3 and R5 is an alkyl or alkenyl group containing 7 to 23 carbon atoms and 0, 1, 2 or 3 double bonds, and R4 is a group corresponding to formula (II) or (III): where R1, R2 and R3 are as defined above and Z is a group —(CH2)m— or a group corresponding to formula (IV):  m is an integer of 1 to 6, X is a group NH or an oxygen atom and D is a dimer fatty acid residue containing on average 36 to 54 carbon atoms; (b) combining the corrosion inhibitor with liquid aqueous, liquid non-aqueous or gaseous me
    Type: Grant
    Filed: July 29, 1999
    Date of Patent: July 17, 2001
    Assignee: Cognis Deutschland GmbH
    Inventors: Wolfgang Breuer, Robert Schuetz, Guenther Uphues, Claus-Peter Herold, Rafael Pi
  • Patent number: 6248701
    Abstract: A combination of sulfur-free azoles, preferably benzotriazole and tolyltriazole, with sulfur-containing azoles, preferably 2-mercaptobenzothiazole or mercaptobenzimidazole, prevents discoloration, staining, or corrosion of metal surfaces being coated with an organic protective coating from aqueous dispersion or solution.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: June 19, 2001
    Assignee: Henkel Corporation
    Inventor: Richard J. Church
  • Patent number: 6235394
    Abstract: A heat-expandable microcapsule comprising a polymer shell formed by polymerizing (I) acrylonitrile, a main monomer component, (II) a monomer having carboxyl and (III) a monomer having groups reactive with the carboxyl of the monomer (II) and of a liquid having a boiling point lower than the softening point of the polymer and being encapsulated in the polymer shell. The heat-expandable microcapsules expand within high temperature range, 240° C. or above, and have heat-resistance.
    Type: Grant
    Filed: August 24, 2000
    Date of Patent: May 22, 2001
    Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.
    Inventors: Toshiyuki Shimazawa, Ichiro Takahara
  • Patent number: 6174461
    Abstract: A concrete sealer material is provided containing a corrosion inhibitor which is free to migrate upon leeching from the concrete sealer. The inhibitor retards the rate of corrosion of reinforcements contained within the concrete, including metallic mesh, grid, rebar, and other metallic articles utilized for reinforcement. The sealer material is preferably a film forming component of silicate or silane modified siloxanes. The corrosion inhibitor is preferably an amine salt, an amino alcohol, alkalized salt of glucoheptonates, or, calcium nitrite and mixtures thereof. A compatibility enhancer of an aminoalkyl silane can be added to the blend.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: January 16, 2001
    Assignee: Cortec Corporation
    Inventors: Boris A. Miksic, Charles M. Suchy, Margarita Kharshan