Plural Acyclic Azo Group Component Containing Patents (Class 106/31.52)
  • Patent number: 6852154
    Abstract: The invention provides: an ink set comprising a yellow ink composition, a magenta ink composition, and a cyan ink composition, wherein the magenta ink composition contains as a colorant at least one member selected from compounds represented by the following formula (1) and salts thereof; and an ink set comprising two magenta ink compositions differing in color density, wherein the magenta ink composition having a lower color density contains as a colorant at least one member selected from compounds represented by the following formula (1) and salts thereof. Also disclosed are: an ink cartridge housing the ink set; a process for recording with the ink set; and recorded matter obtained by recording with the ink set.
    Type: Grant
    Filed: April 21, 2003
    Date of Patent: February 8, 2005
    Assignee: Seiko Epson Corporation
    Inventors: Kazuhiko Kitamura, Hiroko Hayashi, Kyoichi Oka
  • Patent number: 6835239
    Abstract: A novel fluorescent ink is provided which contains at least a coloring material and an aqueous liquid medium for dissolving the coloring material, wherein the coloring material comprises C.I. Acid Red 52 and at least one direct dye, the content of the C.I. Acid Red 52 ranging from 0.1 to 0.4% by weight based on the total amount of the ink, and the content of the direct dye ranging from 0.15 to 0.4% by weight based on the total amount of the ink, and the weight ratio of the direct dye to the C.I. Acid Red 52 is not higher than 1.6. This fluorescent ink is capable of forming prints with fluorescence of high intensity and with high water resistance.
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: December 28, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shinichi Hakamada, Shoji Koike, Akira Nagashima
  • Publication number: 20040244642
    Abstract: An ink for use in ink jet recording which contains a dye and a pigment as colorants.
    Type: Application
    Filed: April 23, 2004
    Publication date: December 9, 2004
    Applicant: Canon Kabushiki Kaisha
    Inventors: Ayako Uji, Noribumi Koitabashi, Yoshihisa Yamashita, Ryota Kato, Takeshi Miyazaki, Yasunori Fujimoto
  • Patent number: 6824598
    Abstract: An ink set for ink-jet printing, having at least one ink of the ink set comprising a light dye load and a dark dye load with both the light dye load and the dark dye load being one color. The one color is selected from magenta, cyan, yellow and black; and the light dye load being at least one of air fade resistant, light fade resistant and humid color migration resistant. The invention also relates to a method of inkjet printing with such a method.
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: November 30, 2004
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Matthew Thornberry, Eric L Burch, John L Stoffel
  • Publication number: 20040187734
    Abstract: An inkjet recording ink set comprising at least two inks, wherein each of the inks contains at least one dye having an anionic group, and even when any two inks in the ink set are mixed, precipitation of the dye does not occur.
    Type: Application
    Filed: March 23, 2004
    Publication date: September 30, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Takashi Ozawa, Toshiki Taguchi
  • Publication number: 20040187738
    Abstract: An ink obtained by dissolving at least one specific dye in an aqueous medium, wherein the dyes contained in the ink all have a solubility of 15 g or more in 100 g of water at 25° C. under atmospheric pressure; and an ink set formed from the ink. The dye is preferably a dye having an oxidation potential of 1.0 V (vs SCE) or more, more preferably a specific azo dye having a heterocyclic group of a specific structure or an aromatic group which is bound directly to an azo group, or a specific phthalocyanine dye having a water-soluble group as a substitunet. According to the present invention, an ink, specifically an inkjet ink, and an ink set, which can print an image without disorder or beading due to ejection failure and ensure excellent ejection stability and durability, is provided.
    Type: Application
    Filed: March 26, 2004
    Publication date: September 30, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Toshiki Taguchi, Naotaka Wachi
  • Publication number: 20040182279
    Abstract: A lightfast colorant and a lightfast ink composition include a lightfast colorant that is derived by covalently binding a benzophenone derivative and a conventional colorant and that imparts effective lightfastness and long-term storage stability to an ink composition that is prepared with the same.
    Type: Application
    Filed: March 18, 2004
    Publication date: September 23, 2004
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Kyung-hoon Lee, Seung-min Ryu, Yeon-kyoung Jung
  • Patent number: 6793722
    Abstract: Inkjet ink composition with high chroma. The inkjet ink composition includes 0.1 to 15 weight % of Acid Red 92; at least one red colorant other than Acid Red 92; and an aqueous solution medium. By means of the addition of Acid Red 92, the chroma of magenta color of the ink composition is increased.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: September 21, 2004
    Assignee: Benq Corporation
    Inventors: Chia-Hsin Chien, In-Shan Sir, Yu-Ting Lin
  • Publication number: 20040154496
    Abstract: The invention provides an inkjet black ink ensuring excellent image durability capable of satisfactorily maintaining the image quality such as non-loosening of black and gradation even when the image is stored for a long period of time, which is a inkjet black ink having a discoloration rate constant (kvis) of 5.0×10−2 [hour−1] or less, which is measured by using an ozone gas, the ink comprising an aqueous medium having dissolved or dispersed therein at least one dye selected from (1) an azo dye having a specific structure where a heterocyclic group is bonded to both of two N atoms, (2) a phthalocyanine dye having a specific structure, (3) an azo dye having a specific structure where a 5-membered heterocyclic group is bonded to one of two N atoms and a 6-membered 2-amino heterocyclic group is bonded to the other, and (4) a bisazo dye constituted by a specific aromatic or heterocyclic group and an azo group.
    Type: Application
    Filed: November 18, 2003
    Publication date: August 12, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Toshiki Taguchi
  • Patent number: 6764541
    Abstract: Disclosed is a colorant composition of the formula wherein R is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and wherein R can be joined to the phenyl moiety to form a ring, R′ is an aromatic- or heteroaromatic-containing group, each Ra, independently of the others, is a halogen atom, an alkyl group, an alkoxy group, a nitrile group, a nitro group, an amide group, or a sulfonamide group, w is an integer of 0, 1, 2, 3, or 4, n is an integer representing the number of carbon atoms in each repeat alkylene oxide unit, and x is an integer representing the number of repeat alkylene oxide units, wherein said colorant has no more than one —OH, —SH, or primary or secondary amino group per molecule.
    Type: Grant
    Filed: April 24, 2003
    Date of Patent: July 20, 2004
    Assignee: Xerox Corporation
    Inventors: Jeffery H. Banning, Donald R. Titterington, Clifford R. King
  • Publication number: 20040138335
    Abstract: The present invention provides an aqueous ink composition including a hydrophilic organic solvent, a surfactant, and a colored fine particle dispersion which contains an oil-soluble dye, and exhibiting a dynamic surface tension of 25 to 35 mN/m, as well as an ink-jet recording method including a step of carrying out recording using the aqueous ink composition.
    Type: Application
    Filed: July 21, 2003
    Publication date: July 15, 2004
    Inventors: Kenji Ikeda, Takahiro Ishizuka
  • Publication number: 20040128775
    Abstract: The invention relates to a dye mixture essentially consisting of one dye of formula (4) and a dye of formula (5). The black dye mixture is advantageously used for ink jet printing and provides high light-resisting and neutral black ink formulations.
    Type: Application
    Filed: November 21, 2003
    Publication date: July 8, 2004
    Inventors: Andreas Wuzik, Josef Geisenberger, Heidemarie Menzel
  • Publication number: 20040129172
    Abstract: An ink, which contains at least one dye of formula (1):
    Type: Application
    Filed: August 1, 2003
    Publication date: July 8, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Toru Harada, Naotaka Wachi
  • Publication number: 20040123773
    Abstract: An ink composition comprising: a self-dispersing carbon black, a binder, a stabilizing dye comprising at least as many groups comprising CO2H or COSH as groups comprising SO3H, and an aqueous vehicle. The stabilizing dye can improve the reliability and performance of the ink composition. The addition of the stabilizing dye can reduce or prevent the formation of material that blocks the printhead vias and throats as a result of the presence of a binder in the ink. The ink composition can reduce the amount of maintenance needed to retain all of a printhead's nozzles through the life of the printhead.
    Type: Application
    Filed: December 30, 2002
    Publication date: July 1, 2004
    Inventors: Susan Butler, Meagan Winkler
  • Patent number: 6749674
    Abstract: Disclosed are metal complexes of trisazo dyes of the general formula 4 wherein R1 through R6 are as defined in the specification. The dyes are useful for dyeing and printing natural and synthetic fiber materials, recording fluids, especially for the inkjet process, liquid formulations for paper pulp dyeing, and also as colorants for electrophotographic toners, powder coatings and color filters including the dyes of the invention.
    Type: Grant
    Filed: March 23, 2001
    Date of Patent: June 15, 2004
    Assignee: Clariant GmbH
    Inventors: Josef Geisenberger, Andreas Wuzik
  • Patent number: 6746526
    Abstract: 1. A compound of Formula (1) and salts thereof: wherein: A is a substituted phenyl group carrying a group of the formula —NR3R4 and an ortho group selected from sulpho, phosphonato and phosphinato; n is 0 or 1; L1 and L2 are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or L1 and L2 together with the N atom to which they are attached form an optionally substituted 5- or 6-membered ring; R1 and R2 are each independently optionally substituted alkyl or optionally substituted alkoxy; and R3 and R4 are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or R3 and R4 together with the nitrogen atom to which they are attached form an optionally substituted 5- or 6-membered ring; or R3 is H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl and R4 is an acyl group.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: June 8, 2004
    Assignee: Avecia Limited
    Inventor: Prahalad Manibhai Mistry
  • Patent number: 6746525
    Abstract: A compound comprising a disazo chromaphore and an optionally substituted acyl group linked together through a —SO2—NH— group, inks comprising these compounds, ink jet printer cartridges containing these inks and their use in ink jet printing.
    Type: Grant
    Filed: March 18, 2002
    Date of Patent: June 8, 2004
    Assignee: Avecia Limited
    Inventor: Mark Robert James
  • Patent number: 6737517
    Abstract: A metal chelated azo dyestuff containing at least one hydrophilic group and having formula (1): wherein M is a metal; A, B and C are each independently a substituted or unsubstituted aromatic ring; D is an aromatic ring optionally substituted by a group other than an azo group; m is 0 or 1; n is an integer from 0 to 3; p is an integer from 0 to 2; q is an integer from 1 to 3; with the proviso that in the event of a plurality of B's, they are the same or different; R1 and R2 are each independently hydrogen or a substituent group; M is tridentate or of higher coordination; and optionally a metal ion coordinated to A and B, B and B in the event of plural B's separated by azo or B and C, in the form of the structure: —O—M—O—.
    Type: Grant
    Filed: August 12, 2002
    Date of Patent: May 18, 2004
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Wataru Shimizu
  • Publication number: 20040089198
    Abstract: A process for coloration of a substrate comprising applying thereto by means of an ink jet printer a composition comprising a medium and a compound of Formula (1): 1
    Type: Application
    Filed: September 11, 2003
    Publication date: May 13, 2004
    Inventors: Christine Millard, Clive Edwin Foster, Peter Gregory
  • Publication number: 20040083560
    Abstract: A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) a capped diazonium compound and b) a water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
    Type: Application
    Filed: September 3, 2003
    Publication date: May 6, 2004
    Inventors: Jean-Marie Adam, Taher Yousaf, Beate Frhling
  • Publication number: 20040083924
    Abstract: Compouns of formula (I) 1
    Type: Application
    Filed: August 1, 2003
    Publication date: May 6, 2004
    Inventor: Martin Oberholzer
  • Patent number: 6712893
    Abstract: A compound of Formula (1) and salts thereof: In the formula, m is 1, 2 or 3; X is H or SO3H; R1 and R2 are each independently selected from optionally substituted alkyl and optionally substituted alkoxy; and R4 and R5 are each independently H, optionally substituted alkyl or optionally substituted aryl. When (i) at least one of R1 and R2 carries an —OH group; and (ii) when X is H at least one of R1 and R2 is optionally substituted alkyl. The compounds are useful as dyes for ink jet printing inks.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: March 30, 2004
    Assignee: Avecia Limited
    Inventors: Prahalad Manibhai Mistry, Roy Bradbury
  • Patent number: 6706104
    Abstract: An ink set which comprises a black ink containing an aqueous medium and a pigment dispersed in the aqueous medium by an action of an ionic group, and at least two color inks each containing a coloring material and an aqueous medium, wherein (i) respective images formed with the respective color inks have the same &Dgr;E or have the difference in &Dgr;E that is 10 or less in a CIELAB color space display system in a fading test under conditions that cause fading corresponding to pseudo-indoor sunlight fading through a window for 3 years or more, and (ii) at least one of the color inks contains at least one of a coloring material and an additive that destabilize dispersion stability of the pigment in the black ink. The ink set can provide a high quality multicolor image keeping color balance after long preservation and showing less bleeding between black and color regions.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: March 16, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroyuki Takuhara, Yoshihisa Takizawa, Kumiko Mafune, Hisashi Teraoka, Yoichi Takada, Noriyasu Asaki, Yuko Takada, Tsuyoshi Kanke
  • Publication number: 20040040466
    Abstract: To provide a black aqueous ink composition for excellent light and gas fastness, an ink set including the ink composition, and an ink jet recording process using the same, the black aqueous ink composition contains at least a trisazo dye represented by Chemical Formula 31.
    Type: Application
    Filed: October 24, 2002
    Publication date: March 4, 2004
    Applicants: SEIKO EPSON CORPORATION, ORIENT CHEMICAL INDUSTRIES, LTD.
    Inventors: Tetsuya Aoyama, Kazuhiko Kitamura, Hiroshi Fukumoto, Yoshihiro Sawatari, Shuji Sugawara, Makiko Matsui
  • Patent number: 6695899
    Abstract: A compound of Formula (1) and salts thereof: wherein: A is a substituted phenyl group carrying a group of the formula —NR3R4 and an ortho carboxy group; n is 0 or 1; L1 and L2 are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or L1 and L2 together with the N atom to which they are attached form an optionally substituted 5- or 6-membered ring; R1 and R2 are each independently optionally substituted alkyl or optionally substituted alkoxy; and R3 and R4 are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or R3 and R4 together with the N atom to which they are attached form an optionally substituted 5- or 6-membered ring; or R3 is H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl; and R4 is an acyl group.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: February 24, 2004
    Assignee: Avecia Limited
    Inventor: Prahalad Manibhai Mistry
  • Patent number: 6689201
    Abstract: A compound of Formula (1) and salts thereof are useful as dyes for ink jet printing inks. In the formula (1), A is optionally substituted phenyl (other than carboxyl substituted); R1 and R2 are each independently optionally substituted alkyl or optionally substituted alkoxy; and R4 and R5 are each independently H, alkyl or optionally substituted aryl. In formula (1) at least one of R1 and R2 carries an —OH group.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: February 10, 2004
    Assignee: Avecia Limited
    Inventors: Prahalad Manibhai Mistry, Roy Bradbury
  • Publication number: 20040020404
    Abstract: A process for printing an image on a substrate comprising applying thereto a composition comprising a liquid medium and a compound of Formula (1):
    Type: Application
    Filed: April 11, 2003
    Publication date: February 5, 2004
    Applicant: Avecia Limited
    Inventors: Ajay Haridas Popat, Alan Dickinson, Maria Soteri Hadjisoteriou, Neil James Thompson, Paul Wight, Peter Gregory, Roy Bradbury, Philip John Double, Thomas Paul
  • Patent number: 6673140
    Abstract: The present invention is drawn to ink-jet inks that can be used with cyan, magenta, and yellow ink set systems for improved image gamut and lightfastness while maintaining good chroma in the case of color ink and lightness in the case of black ink. More specifically, in an embodiment of the invention, ink sets can comprise specific ink-jet inks having low dye load dyes for use in six-ink systems, for example.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: January 6, 2004
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Paul Tyrell, Patricia A Wang, Charles G. Dupuy
  • Patent number: 6652637
    Abstract: A compound of Formula (1) and salts thereof are useful as dyes for ink jet printing inks. In Formula (I) m is 1, 2 or 3; R1 and R2 are each independently optionally substituted alkoxy; and R4 and R5 are each independently H, optionally substituted alkyl or optionally substituted aryl; provided that at least one of R1 and R2 carries an —OH group.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: November 25, 2003
    Assignee: Avecia Limited
    Inventors: Prahalad Manibhai Mistry, Roy Bradbury
  • Publication number: 20030172839
    Abstract: The present invention is drawn to ink-jet inks that can be used with cyan, magenta, and yellow ink set systems for improved image gamut and lightfastness while maintaining good chroma in the case of color ink and lightness in the case of black ink. More specifically, in an embodiment of the invention, ink sets can comprise specific ink-jet inks having low dye load dyes for use in six-ink systems, for example.
    Type: Application
    Filed: March 11, 2002
    Publication date: September 18, 2003
    Inventors: Paul Tyrell, Patricia A. Wang, Charles G. Dupuy
  • Publication number: 20030149251
    Abstract: The present invention provides a black dyestuff for inkjet recording which exhibits a good achromaticity as well as a good light-resistance and a recording liquid containing the black dyestuff.
    Type: Application
    Filed: August 12, 2002
    Publication date: August 7, 2003
    Applicant: Mitsubishi Chemical Corporation
    Inventor: Wataru Shimizu
  • Publication number: 20030127017
    Abstract: A dye for ink-jet printing on both hydrophilic and hydrophobic papers. The dye includes a chromophore ionically coupled to a counterion. One of the chromophore and the counterion includes a hydrophilic moiety. The other includes a hydrophobic moiety.
    Type: Application
    Filed: October 31, 2001
    Publication date: July 10, 2003
    Inventors: David M. Schut, Christian Schmid
  • Publication number: 20030110980
    Abstract: An ink set for ink-jet printing, having at least one ink of the ink set comprising a light dye load and a dark dye load with both the light dye load and the dark dye load being one color. The one color is selected from magenta, cyan, yellow and black; and the light dye load being at least one of air fade resistant, light fade resistant and humid color migration resistant. The invention also relates to a method of inkjet printing with such a method.
    Type: Application
    Filed: December 3, 2002
    Publication date: June 19, 2003
    Inventors: Matthew Thornberry, Eric L. Burch, John L. Stoffel
  • Patent number: 6558459
    Abstract: An inkjet ink is provided that employs one or more water-soluble colorants or water-insoluble colorants, such as solvent dyes, disperse dyes, or pigments. The colorant, whether water-soluble or water-insoluble, is derivatized with one or more crown ethers to render the water-insoluble colorants soluble in water and in water-miscible organic solvents commonly employed in inkjet printing, particularly thermal inkjet printing, and to impart improved properties to the colorants, such as lightfastness, smearfastness, and waterfastness. The inkjet ink comprises a vehicle and at least one crown ether derivatized colorant. The resulting inkjet ink evidences improved print quality properties, compared to inkjet inks containing colorants that are not so derivatized.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: May 6, 2003
    Assignee: Hewlett-Packard Development Company
    Inventor: David M. Schut
  • Patent number: 6559292
    Abstract: Compounds of Formula (1) and salts thereof: wherein: A is optionally substituted phenyl; R1 and R2 are each independently optionally substituted alkyl or optionally substituted alkoxy; and R4 and R5 are each independently H, optionally substituted alkyl or optionally substituted aryl; provided that (i) at least one of R1 and R2 carries an —OH group; and (ii) A is not of the formula:  wherein m is 1, 2 or 3. The compounds are useful as dyes for ink jet printing inks.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: May 6, 2003
    Assignee: Avecia Limited
    Inventors: Prahalad Manibhai Mistry, Roy Bradbury
  • Patent number: 6551390
    Abstract: Compositions comprising (a) a dye of the Formula (1) or a salt thereof; and (b) a dye of the Formula (2) or a salt thereof:  wherein R1 to R10, a and b are as defined in the description. Also claimed are liquid compositions and inks containing the dyes, an ink jet printing process using the inks, an ink jet printer cartridge containing the ink and an ink jet printer containing the cartridge.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: April 22, 2003
    Assignee: Avecia Limited
    Inventors: Aidan Joseph Lavery, Janette Watkinson, Paul Francis Mahon
  • Patent number: 6521030
    Abstract: A set of inkjet inks with at least one of light magenta ink having high lightfastness magenta dye, a light cyan ink having high lightfastness cyan dye, light yellow ink having high lightfastness yellow dye and light black having high lightfastness black dye.
    Type: Grant
    Filed: June 20, 2000
    Date of Patent: February 18, 2003
    Assignee: Hewlett-Packard Company
    Inventor: John L Stoffel
  • Publication number: 20030024435
    Abstract: Black-dyeing aqueous inks comprising
    Type: Application
    Filed: January 29, 2002
    Publication date: February 6, 2003
    Inventors: Urs Lehmann, Athanassios Tzikas, Marcel Frick
  • Patent number: 6511535
    Abstract: The invention relates to a method for printing fibrous textile materials using the ink-jet printing technique, wherein the fibrous materials are printed with an aqueous ink that comprises at least one acid dye according to claim 1 and that has a viscosity of from 1 to 40 mPa·s.
    Type: Grant
    Filed: January 3, 2001
    Date of Patent: January 28, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Roger Lacroix, Peter Scheibli, Mickael Mheidle
  • Patent number: 6503308
    Abstract: The present invention provides black ink compositions for use in inkjet printing, which exhibit improved neutral color, light fastness, and gray scale properties. The black ink compositions generally include a mixture of two or more black dyes in balanced concentrations to obtain black ink having the improved properties while retaining good print-ability in an inkjet pen. In one aspect, a black ink composition may include a mixture of pacified Reactive Black 31 and Direct Black 168.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: January 7, 2003
    Assignee: Hewlett-Packard Company
    Inventors: Rodney D. Stramel, Kai Kong Iu
  • Patent number: 6500247
    Abstract: Black-dyeing aqueous inks having good black shades without a shade change in artificial light and outstanding lightfastness comprising 20 to 95% by weight of at least one dye (A), together with 5 to 80% by weight of at least one dye chosen from the group consisting of (B) and (C), based on the total weight of the dyes (A), (B) and (C) in the ink, and 1 to 40% by weight of a water-miscible organic solvent, based on the total weight of the ink, the dye (A) containing, as the colouring part of the molecule, one or more radicals of the formula (I), (II), (III) or (IV) the dye (B) containing, as the colouring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formula (V), (VI), (VII) or (VIII) and the dye (C) containing, as the colouring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formulae (V), (VI), (VII) or (VII) and one or more radicals of the f
    Type: Grant
    Filed: February 1, 2000
    Date of Patent: December 31, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Althanassios Tzikas, Marcel Frick
  • Patent number: 6482256
    Abstract: An ink set is provided which can realize images having excellent lightfastness and color reproduction. The ink set comprises magenta ink compositions, the magenta ink compositions containing specific compounds as colorants.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: November 19, 2002
    Assignee: Seiko Epson Corporation
    Inventors: Miharu Kanaya, Jun Ito, Hiroshi Fukumoto
  • Patent number: 6471757
    Abstract: An ink of the present invention has a dye and a pigment. The pigment is a self-dispersant type pigment and an anionic dye in which at least one anionic group is bound on a surface of the pigment directly or through another atomic group and having a Ka value of less than 1 ml·m−2·msec−½ according to a Bristow method. An image having an excellent image quality is formed by using such an ink in the process of ink jet recording.
    Type: Grant
    Filed: October 26, 1998
    Date of Patent: October 29, 2002
    Assignee: Canon Kabushiki Kaisha
    Inventors: Noribumi Koitabashi, Yoshihisa Takizawa, Yutaka Kurabayashi, Takeo Eguchi
  • Patent number: 6464768
    Abstract: The invention relates to a dye in which R1 is hydrogen, alkyl of 1 to 4 carbon atoms, or alkoxy of 1 to 4 carbon atoms; R2 is hydrogen, carboxyl, chloro or nitro; R21 is hydrogen; or R2 and R21 together form a benzene ring which is fused on in positions 3 and 4 of the ring A and can carry 1, 2 or 3 sulfo groups; m is a number from 0 to 1; n is a number from 1 to 2; M+ is a cation or a mixture of different cations, at least one equivalent of the cations M+ per mole of the dye being lithium cations and/or cations of the formula (II) where p is a number from 1 to 30; X is CH2CH2, CH(CH3)CH2, CH2CH(CH3) or a combination thereof and R3, R4 and R5 independently of one another are hydrogen, a group of the formula (III) —(—X—O—)pH  (III) or an aliphatic radical of 1 to 18 carbon atoms. Dyes of the formula (I) are particularly suitable as colorants in inkjet inks.
    Type: Grant
    Filed: July 12, 1999
    Date of Patent: October 15, 2002
    Assignee: Clariant GmbH
    Inventors: Wolfgang Bauer, Heidemarie Menzel, Josef Geisenberger, Reinhard Pedrazzi
  • Publication number: 20020144626
    Abstract: An inkjet ink is provided that employs one or more water-soluble colorants or water-insoluble colorants, such as solvent dyes, disperse dyes, or pigments. The colorant, whether water-soluble or water-insoluble, is derivatized with one or more crown ethers to render the water-insoluble colorants soluble in water and in water-miscible organic solvents commonly employed in inkjet printing, particularly thermal inkjet printing, and to impart improved properties to the colorants, such as lightfastness, smearfastness, and waterfastness. The inkjet ink comprises a vehicle and at least one crown ether derivatized colorant. The resulting inkjet ink evidences improved print quality properties, compared to inkjet inks containing colorants that are not so derivatized.
    Type: Application
    Filed: February 27, 2001
    Publication date: October 10, 2002
    Inventor: David M. Schut
  • Patent number: 6454844
    Abstract: An ink set is provided which can bring good lightfastness and can realize images having excellent color reproduction. The ink set comprises a yellow ink composition, two magenta ink compositions different from each other in color density, and two cyan ink compositions different from each other in color density. The ink compositions contain respective specific compounds as colorants.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: September 24, 2002
    Assignee: Seiko Epson Corporation
    Inventor: Miharu Kanaya
  • Patent number: 6451989
    Abstract: Provided are novel black azo dyes which are useful in ink compositions, especially ink jet ink compositions. The dyes and ink compositions of the present invention exhibit a good balance of optical density, print reliability, water fastness and light fastness.
    Type: Grant
    Filed: June 18, 2001
    Date of Patent: September 17, 2002
    Assignee: Lexmark International, Inc.
    Inventors: Bradley Leonard Beach, Ann P Holloway, James F Feeman
  • Patent number: 6395885
    Abstract: The use of lithium as a cation for an anionic dye to enhance the light-fastness of the dye. Also claimed are the lithium salts of certain anionic dyes as defined in the description; mixed lithium/sodium salts of an anionic dye wherein the molar ratio of lithium to sodium is from 1:4 to 99:1 and at least 20 mole % of the total counter ions in the dye are lithium cations; inks containing the dyes; a method of ink jet printing using the inks; a substrate printed with the inks; an ink jet printer cartridge containing the ink and a ink jet printer containing the ink jet printer cartridge.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: May 28, 2002
    Assignee: Avecia Limited
    Inventors: Aidan Joseph Lavery, Janette Watkinson, John Parker Meyers
  • Patent number: 6387168
    Abstract: Disclosed herein is an ink comprising a first pigment, a second pigment and a dispersant, both of the pigment being dispersed in an aqueous medium, wherein the first pigment is a self-dispersing pigment having an anionic group or a cationic group, the group being bonded directly or through an atomic group to a surface of the pigment, the second pigment is a pigment dispersible in an aqueous medium with the dispersant, and the dispersant is an ionic polymeric dispersant having a same polarity as that of the group bonded to the surface of the pigment or a nonionic polymeric dispersant.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: May 14, 2002
    Assignee: Canon Kabushiki Kaisha
    Inventors: Noribumi Koitabashi, Sadayuki Sugama, Yoshihisa Takizawa, Hitoshi Tsuboi
  • Patent number: 6379442
    Abstract: A composition comprising: (a) a water-soluble magenta dye; and (b) a dye of the Formula (1) or a salt thereof: wherein R1, R2, R3 are defined in the description.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: April 30, 2002
    Assignee: Avecia Limited
    Inventors: Aidan Joseph Lavery, Bachaspati Roy, Janette Watkinson, Mark Kenworthy