Organic Material Or Silicon Containing Patents (Class 106/465)
  • Patent number: 6572694
    Abstract: A pigment composition for use as a substrate to produce ink, paints, and pigment compounds, the composition being made from an aqueous slurry containing about 17 to 40% calcium carbonate, based on the weight of said aqueous slurry, and an inorganic pigment from group comprising titanium dioxide, in which the amount of calcium carbonate is higher than that found in standard pigment compositions and the amount of amount of pigment is lower than that found in standard pigment compositions, yet there is not an appreciable degradation of the color, coating, and other qualities of the pigment composition.
    Type: Grant
    Filed: May 15, 2001
    Date of Patent: June 3, 2003
    Inventor: Michael Towe
  • Publication number: 20030056693
    Abstract: A colorant for ink-jet printing ink of the present invention, has an average particle diameter of 0.001 to 0.15 &mgr;m, and comprises: extender pigments as core particles; a gluing agent coating layer formed on at least a part of surface of said core particle; and an organic pigment coat uniformly formed on at least a part of said gluing agent coating layer. The colorant for ink-jet printing ink exhibits not only a high tinting strength and a clear hue, but also excellent dispersibility and light resistance in spite of fine particles.
    Type: Application
    Filed: June 4, 2002
    Publication date: March 27, 2003
    Inventors: Kazuyuki Hayashi, Hiroko Morii, Keisuke Iwasaki
  • Publication number: 20030055207
    Abstract: A method for preparing a surface-modified calcium carbonate useful in the synthesis of polyesters such as polyethylene terephthalate, polybutylene terephthalate, etc. to improve the polymer's friction coefficient, which method comprises the step of forming a dispersion comprising calcium carbonate particles and a bi-functional reagent having two functional linking substituents consisting of a first substituent linking to the calcium carbonate particles and a second substituent which can link to the polyester, thereby bonding the calcium carbonate to the polyester through the bifunctional linking reagent; and surface-modified calcium carbonate and polyesters containing same.
    Type: Application
    Filed: August 12, 2002
    Publication date: March 20, 2003
    Applicant: NYACOL NANO TECHNOLOGIES, INC.
    Inventors: Peter W.Q. Xu, Robert J. Nehring, Raymond F. Woodman
  • Patent number: 6531514
    Abstract: A dispersant slurry for making spandex, based on phosphated block poly(alkylsiloxane)-poly(alkyleneether) alcohol or aromatic- or alkylaromatic-terminated phosphated poly(alkyleneether) alcohol dispersants, is provided.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: March 11, 2003
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Thomas Edward Carney, Oliver Gutsche, Kai-Volker Schubert
  • Publication number: 20030033962
    Abstract: A number of stable mixtures are disclosed containing specific combinations and levels of extender pigments and thickeners. These stable mixtures may be employed, inter alia, as a mixture in a method of making paints using prepaints or as a conventional component in a coating, such as a paint, or other end-use where opacifying pigments are employed.
    Type: Application
    Filed: August 8, 2002
    Publication date: February 20, 2003
    Inventors: Edwin Hugh Nungesser, Jerry William Washel, John Michael Friel
  • Publication number: 20030029590
    Abstract: Silica-calcium carbonate composition particles having the characteristics of both synthetic silica and calcium carbonate without a lowering thereof are described along with paper internally filling the particles and a method for making the particles.
    Type: Application
    Filed: August 20, 2002
    Publication date: February 13, 2003
    Inventors: Katsuyuki Tanabe, Kouhei Mitsuhashi
  • Patent number: 6511536
    Abstract: Pigments of flake substrate coated with calcium carbonate wherein the surface of the flake substrate is coated with fine particles of calcium carbonate. The pigment may be manufactured by a method where calcium carbonate in fine particles is separated out and coated on the surface of the flaky substrate by the reaction of a calcium salt with a carbonate in a suspension of the flake substrate. It can be used as an extender particularly for cosmetics exhibiting appropriate adhesion to skin, low luster and excellent wrinkle-hiding effect, prevention of unpleasant feel due to perspiration, sebum absorbing property, etc.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: January 28, 2003
    Assignee: Merck Patent Gesellschaft
    Inventors: Tamio Noguchi, Yukitaka Watanabe
  • Publication number: 20030017271
    Abstract: The invention relates to an aqueous slurry or dispersion of pigment particles comprising as dispersant an amphiphilic polymer at least partly adsorbed to the pigment particles, wherein the slurry or dispersion exhibits a temperature dependent viscosity in such way that the viscosity increases at least with a factor of about 2 when the temperature is raised from about 20 up to about 100° C. The invention further relates to a the preparation of the slurry or dispersion, a coating color composition, a process for its preparation, and a process for preparing coated paper or board.
    Type: Application
    Filed: June 26, 2002
    Publication date: January 23, 2003
    Applicant: AKZO NOBEL N.V.
    Inventors: Rein Sikkar, Olof Eriksson, Michael Persson
  • Publication number: 20030010459
    Abstract: Cationically modified white pigments (W) in particulate form, essentially consisting of a particulate inorganic white pigment (M) of a particle size in the range of 0, 1 to 40 &mgr;m and an applied water soluble, cationic, crosslinked polymer (PA) containing quaternary ammonium groups in salt form, obtainable by reaction of epichlorohydrin or of epichlorohydrin derivatives or precursors with amines, under conditions leading to at least partial crosslinking, optionally in combination with an anionic optical brightener (B) and where the molar ratio of (B) to (PA) is such that the number of cationic charges of the total polymer (PA) is higher than the number of anionic charges of the total anionic optical brightener (B), are surprisingly useful as cationic white pigments in various fields of technique, especially in papermaking.
    Type: Application
    Filed: June 17, 2002
    Publication date: January 16, 2003
    Inventors: John Martin Farrar, Andrew Clive Jackson, Alec Stewart Tindal
  • Publication number: 20020144797
    Abstract: A method of dispersing a solid particulate material in an aqueous medium by addition to the aqueous medium of a dispersing agent wherein the solid particulate material is to be used as a filler or pigment in a sheet material which is required to come into contact with foodstuffs, wherein the dispersing agent is a composition comprising:
    Type: Application
    Filed: November 13, 2001
    Publication date: October 10, 2002
    Applicant: ECC INTERNATIONAL, LTD.
    Inventors: David Robert Skuse, Shih-Ruey Thomas Chen, William Leonard Garforth, Gary F. Matz
  • Patent number: 6416868
    Abstract: Alkaline earth-manganese oxides are used as pigments. The alkaline earth-manganese oxide pigments are preferably of the formula MexMnOy, where Me is at least one metal selected from Ca, Sr, Ba and Mg, x is from 0.01 to 99, and y is greater than or equal to x+1 and less than or equal to x+2. The pigments are useful as colorants, and also possess improved reflectance characteristics, particularly in the IR region, and may reduce IR-induced heat buildup. These colorants can be used to form colored objects, or coat objects when they are either added into or applied onto materials such as paints, inks, plastics, glasses, ceramics and the like. The patent also covers the production of these pigments.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: July 9, 2002
    Assignee: DMC2 Degussa Metals Catalysts Cerdec AG
    Inventors: Robert Michael Sullivan, Terry James Detrie, Daniel Russell Swiler
  • Patent number: 6402824
    Abstract: Processes for making high quality PCC compositions, and the resulting PCC products thereof. A precipitated calcium carbonate (PCC) composition is prepared by a process comprising the step of wet media mill grinding an aqueous slurry of PCC made by carbonation of lime milk, with the grinding being done at a low solids content in a plurality of separate grinding stages, which can done while essentially free of the presence of organic dispersant. After the multi-stage wet grinding step, the ground PCC slurry is partially dewatered in the presence of an organic dispersant in a solid bowl centrifuge. Then, the partially dewatered PCC slurry is subjected, in the presence of an organic dispersant, to fluid shearing forces created in a rotor/stator type mixer. While these three steps are advantageously used together within a single PCC process flow for optimal effect, the individual steps also can be incorporated singly or in lesser combinations thereof into different PCC manufacturing schemes to beneficial effect.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: June 11, 2002
    Assignee: J. M. Huber Corporation
    Inventors: Gary M. Freeman, Randal A. Moritz, William J. Jones, Kurt H. Moller
  • Patent number: 6387500
    Abstract: A multi-layered coating for use preferably on paperboard or paper is disclosed wherein the coating contains at least two layers. The first layer contains at least one dark colorant, at least one white or near white pigment, and at least one binder, and the second layer contains at least one pigment other than a dark colorant, such as a white or near white pigment, and at least one binder. Slurries and dry mixtures containing these ingredients are also disclosed. A multi-layered coated paperboard or paper comprising paperboard or paper and the multi-layered coating is also disclosed. A method to reduce the amount of a white or near white pigment like titania is also disclosed which involves using one or more of the above-described multi-layered coatings on paperboard or paper.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: May 14, 2002
    Assignee: Cabot Corporation
    Inventor: Sanjay Behl
  • Patent number: 6372832
    Abstract: A glycol dispersion of an inorganic powder is provided, which comprises glycol and an inorganic powder dispersed therein, said inorganic powder being surface-treated with a dispersant having a solubility of not less than 5 (g/100 g-water) in water of 20° C., and which contains water and/or methanol in the specific amounts. According to the present invention, it is not required to transport a slurry of water, methanol or glycol, but possible to transport in the form of powder, so that efficiency in transportation is not only enhanced, but a drastic simplification in the production steps and a cost reduction are attainable because neither a distillation apparatus for replacing a solvent such as water and methanol with glycol nor a step of wet-pulverizing is required. Moreover, a glycol dispersion of the present invention is able to reproduce the excellent shape and size of the inorganic particles before drying or in the initial state and therefore has an excellent dispersibility.
    Type: Grant
    Filed: January 13, 2000
    Date of Patent: April 16, 2002
    Assignee: Maruo Calcium Company Limited
    Inventors: Naofumi Saito, Seiya Shimizu, Kazunori Ohide, Shiro Minayoshi
  • Publication number: 20020020328
    Abstract: A plaster-like coating composition particularly adapted for the do-it-yourselfer or those not trained in the art of plastering or painting, containing both a binder for coating (with texture or the appearance of texture) and a colorant. The composition is applied to walls constructed of various substrates (i.e., sheetrock, plaster, wood, brick, metal, cement, or various composite structures.) to create a decorative surface which has texture or the appearance of texture and also has color. The coating composition is applied in a two to three coat process using a flat metal or plastic trowel, or one which is padded.
    Type: Application
    Filed: March 26, 2001
    Publication date: February 21, 2002
    Inventor: Kristen Amanda Krenz
  • Publication number: 20020011187
    Abstract: A coating system for in-situ coating of a surface formed by a plurality of plasterboard sections comprises a dry powder composition which is dispersible in an aqueous applicator medium and provides a very high quality surface finish to which gloss or matt paint may be applied directly without joint photographing or show-through of fasteners. The coating composition may be applied by a spray coating technique or a roller technique. The dry powder composition comprises calcium carbonate and, by weight, relative to calcium carbonate, from 4% to 11% of a polymeric binder, from 0.60% to 1.5% of a thickening agent and from 0.10% to 0.35% of a surfactant.
    Type: Application
    Filed: August 15, 2001
    Publication date: January 31, 2002
    Inventor: Fergus Rupert Fitzgerald
  • Patent number: 6342100
    Abstract: Bimolecular coated calcium carbonate and a process for controlled surface treatment of calcium carbonate according to which an amount of coating determined from the mean particle diameter (dp) of the calcium carbonate is contacted with the calcium carbonate particles. The way in which the amount of coating agent is determined enables purposeful control of the properties of the coated calcium carbonate particles to adapt them for use as functional filling materials in different technical applications.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: January 29, 2002
    Assignee: Solvay Soda Deutschland GmbH
    Inventors: Christoph Nover, Helmut Dillenburg
  • Publication number: 20010042494
    Abstract: A manufactured granular substrate composition suitable for use as a carrier for active chemical agents. The composition includes one or more mineral components having a bulk density greater than about 70 pounds per cubic foot. The composition also contains about one or more light weight additives and one or more water soluble binders. The resulting manufactured granular substrate has a bulk density of less than about 55 pounds per cubic foot with a size guide number of about 75 to about 300.
    Type: Application
    Filed: May 14, 2001
    Publication date: November 22, 2001
    Inventors: James W. Welshimer, Nadine C. Dunn, Timothy D. Birthisel
  • Patent number: 6315867
    Abstract: A method of dispersing a solid particulate material in an aqueous medium by addition to the aqueous medium of a dispersing agent wherein the solid particulate material is to be used as a filler or pigment in a sheet material which is required to come into contact with foodstuffs, wherein the dispersing agent is a composition comprising: (1) up to 0.25% by weight, based on the dry weight of the particulate solid material, of a water-soluble salt of a poly(acrylic acid) having a weight average molecular weight not greater than 20,000, and (2) from 0.02% to 1.5% by weight, based on the dry weight of the particulate solid material, of either (a) an anionic polyelectrolyte which comprises a water-soluble salt of a copolymer of acrylic acid with acrylamide; or (b) a water-soluble condensed phosphate salt.
    Type: Grant
    Filed: October 30, 1997
    Date of Patent: November 13, 2001
    Assignee: Imerys Minerals Limited
    Inventors: David Robert Skuse, Shih-Ruey Thomas Chen, William Leonard Garforth, Gary F Matz
  • Patent number: 6270564
    Abstract: The invention relates to a process for the bleaching of a mineral pigment or a synthetic pigment, in which process the pigment to be bleached is contacted with a solution which contains peracetic acid in order to obtain a pigment with a raised degree of brightness.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: August 7, 2001
    Assignee: Kemira Chemicals Oy
    Inventor: Pentti Hukkanen
  • Patent number: 6235105
    Abstract: Optical coating compositions containing thin film particulates or pigments that are capable of imparting to the coating preselected optical characteristics or properties, such as selective reflectance, transmission and absorptance of light energy, are comprised of film forming binder and improved high volume pigment particles dispersed in the binder. Each pigment particle is a high volume flake comprised of an inorganic or polymer core having two sides and a thin film optical structure deposited onto each of the two sides of the core. The core occupies a large volume of the coating composition and dramatically reduces the number of flakes and the amount of thin film structures required to produce a coating of given thickness and desired optical properties. The core may also be fabricated to have diffuse and irregular side surfaces in order to render the applied coating visually diffuse and nonspecular. Methods of making the pigment particles are disclosed.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: May 22, 2001
    Assignee: General Atomics
    Inventors: Ronald N. Hubbard, Terry D. Gulden, Michael T. Martin
  • Patent number: 6228161
    Abstract: The present invention relates to an acid-stabilized calcium carbonate slurry having a pH of less than 7, preferably between about 6 and about 7, containing water, calcium carbonate, preferably precipitated calcium carbonate, and an acid-stabilizer of a water soluble calcium salt, a weak acid, a chelating agent, a weak acid capable of chelating calcium ion, or a mixture thereof. The acid-stabilizer is present in an amount sufficient to provide an aqueous calcium carbonate slurry having an increased calcium ion concentration and an acidic pH. In a typical acid-stabilized calcium carbonate slurry of the invention, the acid-stabilizer is present in an amount sufficient to provide a calcium ion concentration of about 1 millimolar to about 5 molar, preferably from about 1 to about 120 millimolar.
    Type: Grant
    Filed: December 30, 1996
    Date of Patent: May 8, 2001
    Assignee: Minerals Technologies Inc.
    Inventor: Donald Kendall Drummond
  • Patent number: 6221146
    Abstract: A method of producing a precipitated calcium carbonate (pcc) product which has a coarse crystalline form which comprises the steps of: (a) preparing a suspension in an aqueous medium of calcium hydroxide particles which partially dissolve as calcium ions in the aqueous medium, the aqueous medium also incorporating an agent which promotes release into solution in the aqueous medium of calcium ions from the calcium hydroxide; (b) adding carbon dioxide to the aqueous medium to react with the calcium ions therein to produce a suspension in the aqueous medium of a precipitate of calcium carbonate crystals; (c) concentrating the suspension of the precipitate by a dewatering process; and (d) adding to the suspension of the precipitate a dispersing agent for the precipitate; wherein in step (a) the calcium hydroxide particles of the suspension of calcium hydroxide particles have a specific surface area measured by the BET nitrogen method of less than 33 m2/g and the said agent comprises a water soluble organic c
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: April 24, 2001
    Assignee: Imerys Pigments, Inc.
    Inventors: Steven M. Fortier, William B. Jackson, Peter B. O'Rorke, Ricardo Perez, David P. Bryan
  • Patent number: 6180128
    Abstract: A material for use in children's sand boxes, play sets and play areas that is not hazardous to the health of humans and comprises calcium carbonate or calcium magnesium carbonate.
    Type: Grant
    Filed: January 27, 1997
    Date of Patent: January 30, 2001
    Assignee: C-Cure Corp.
    Inventors: Charles J. Johansen, Jr., Ernest D. Hollas
  • Patent number: 6156118
    Abstract: The invention relates to a filler for use in paper manufacture, said filler containing pigment and noil produced from cellulose fibre and/or mechanical pulp fibre by refining. According to the invention, the pigment has been mixed with noil fibrils, to be used as filler in paper manufacture.The invention also relates to a method for producing a filler for use in paper manufacture, said filler containing pigment and noil produced from cellulose fibre and/or mechanical pulp fibre by refining. According to the invention, the pigment is mixed with noil fibrils, to be used as filler in paper manufacture.
    Type: Grant
    Filed: November 17, 1998
    Date of Patent: December 5, 2000
    Assignee: Metsa-Serla Corporation
    Inventor: Petri Silenius
  • Patent number: 6156324
    Abstract: Cosmetic compositions and cosmetics which have good dispersibility, high UV protection effect that lasts for a long period and high stability with suppressed optical activity and catalytic activity. The cosmetic contains 10.5 weight % of a composition comprising fine-grain titanium oxide (mean particle size 0.9 .mu.m) treated with 5% methylhydrogenpolysiloxane, zinc oxide (mean particle size 2.5 .mu.m) treated in the same manner and talc (mean particle size 4 .mu.m) treated in the same manner.
    Type: Grant
    Filed: May 20, 1997
    Date of Patent: December 5, 2000
    Assignee: Miyoshi Kasei, Inc.
    Inventors: Masaakira Horino, Yukio Hasegawa
  • Patent number: 6136085
    Abstract: A method for forming a silica coating on at least a portion of the surface of alkaline earth metal carbonate particulates in aqueous suspension and the silica-coated alkaline earth metal carbonate so produced are claimed. The claimed method consists of allowing soluble silicate ions in the aqueous phase to slowly react with the alkaline earth metal carbonate surface to form silica micro-particulates on the surface. This silica coating confers upon the composition unique properties among which are pronounced thixotropic behavior when incorporated into an aqueous suspension and increased oil absorption when dry. The pigment produced by this method is especially suited for use as a filler in paper.
    Type: Grant
    Filed: October 29, 1998
    Date of Patent: October 24, 2000
    Assignee: Chemical Products Corporation
    Inventors: Charles Adams, Jr., Jerry Allen Cook
  • Patent number: 6126783
    Abstract: A hydrophobic filler material for neutral, alkaline and acidic papers is disclosed. The filler material comprises finely divided particles of an inorganic material, in admixture with a water miscible, butyl acrylate-acrylonitrile copolymer. A neutral or alkaline paper is disclosed. The neutral or alkaline paper comprises a hydrophobic filler material comprising inorganic material, in admixture with a water miscible, butyl acrylate-acrylonitrile copolymer. A method for improving sizing characteristics of neutral or alkaline paper is disclosed, comprising preparing a filler material and adding the same to cellulose fiber. The filler material is prepared by selecting particles of an inorganic material and admixing with a water miscible, butyl acrylate-acrylonitrile copolymer, forming a hydrophobic system.
    Type: Grant
    Filed: July 9, 1998
    Date of Patent: October 3, 2000
    Assignee: Minerals Technologies Inc.
    Inventor: Robert Anthony Gill
  • Patent number: 6087404
    Abstract: There is disclosed a process for preparing a concentrated aqueous suspension of a finely ground particular material, which process comprises (a) preparing an aqueous suspension comprising at least 20% by weight of the particulate material comprising calcium carbonate in coarse particular form; (b) grinding the suspension formed in step (a) in the presence of a polycarboxylate dispersing agent for the particular material in a grinding process where the pH is not less than 10 to produce an aqueous suspension wherein at least 90% by weight of the particles or the particulate material have an e.s.d. less than 2 .mu.m and 60% by weight have an e.s.d. less than 1 .mu.m; (c) adding an additive comprising an anionic polycarboxylate dispersing agent to the suspension of ground material formed in step (b). The process is characterized in that the aqueous suspension formed in step (c) has a pH which lies within the inclusive range 8.5 to 9.
    Type: Grant
    Filed: June 1, 1998
    Date of Patent: July 11, 2000
    Assignee: Imerys Minerals Limited
    Inventors: Richard Bown, David Robert Skuse
  • Patent number: 6083316
    Abstract: An adhesive-free, dry, free-flowing powder composition suitable for use in surface defect detection, where the powder composition comprises a physical mixture of particles of a colorant and particles of an extender, which mixture includes particles of colorant and particles of extender each having a particle size of less than 100 .mu.m. The powder compositions of the invention provide a simple, effective guide coat which readily highlights surface imperfections, such as scratches, orange peel effect and dry over-spray without the need for solvents. Also, there are disclosed methods of using such a powder composition to detect surface imperfections, an apparatus for applying same, a device for refilling such applying apparatus, and coated surfaces formed thereby.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: July 4, 2000
    Assignee: 3M Innovative Properties Company
    Inventor: David R. Bastow
  • Patent number: 6083317
    Abstract: An improved form of calcium carbonate which is acid resistant to enable its use as a filler material in the making of neutral to weakly acidic paper, and a process for producing this acid-resistant calcium carbonate is provided. This acid-resistant calcium carbonate composition comprises calcium carbonate and at least about 0.1% to about 25% based on the dry weight of the calcium carbonate, of sodium silicate, together with at least 0.1% to about 25 percent, based on the dry weight of the calcium carbonate, of a weak acid, such as phosphoric acid, formic acid, fluoroboric acid, polyacrylic acid, or alum, or a mixture of weak acids, such as phosphoric acid and polyacrylic acid.
    Type: Grant
    Filed: November 5, 1996
    Date of Patent: July 4, 2000
    Assignee: Imerys Pigments, Inc.
    Inventors: Kevin J. Snowden, Kuan-Ting Wu, Jose M. Rodriguez
  • Patent number: 6074474
    Abstract: A multi-component pigment slurry which comprises at least 50% solids. The slurry is formulated to be admixed into paint and coating compositions to promote TiO.sub.2 extension. The slurry includes a structured pigment, a coarse particle size pigment, and a fine particle size pigment. The structured pigment comprises about 20% to about 55% of the slurry by dry weight and has a median particle size diameter of about 0.7.mu. to about 6.0.mu.. The coarse particle size pigment preferably comprises about 20% to about 60% by weight of the slurry and has a median particle size diameter of about 3.0.mu. to about 10.0.mu.. The fine particle size pigment preferably comprises up to about 50% by dry weight of the slurry and has a median particle size diameter of about 0.2.mu. to about 1.0.mu..
    Type: Grant
    Filed: April 17, 1998
    Date of Patent: June 13, 2000
    Assignee: J.M. Huber Corporation
    Inventors: Thad T. Broome, Mark E. Wozniak, James Ray Lamb
  • Patent number: 6051059
    Abstract: A liquid art medium for creating three dimensional art comprises sodium bicarbonate, starch, acrylic polymer emulsion, water, and calcium carbonate. The liquid art medium can be applied to a variety of surfaces for various art projects. Once applied, the medium can be manipulated while still wet and different colors of the medium can be used together without the colors running into each other or bleeding. When dry, the medium can be colored, etched, carved, or sanded to make further artistic effects.
    Type: Grant
    Filed: August 2, 1999
    Date of Patent: April 18, 2000
    Inventor: Leslie Aisner
  • Patent number: 6051060
    Abstract: A method for making coated pigment particles by forming a suspension of the desired pigment particles in a medium that also comprises a polymer characterized by having hydrophobic moieties on the polymer backbone and ionic moieties that are present on, or can be formed on a polymer side chain or at the polymer terminals; allowing the suspension of pigment particles to contact said polymer at a temperature above the softening point of the polymer, allowing the resultant suspension to cool to a temperature below the solidification temperature for the polymer while maintaining the pigment particles in suspension, and, if required, forming the ionic moieties.
    Type: Grant
    Filed: December 4, 1997
    Date of Patent: April 18, 2000
    Assignee: Marconi Data Systems, Inc.
    Inventor: Yoshikazu Mizobuchi
  • Patent number: 5989332
    Abstract: A slurry containing water, carbonate-containing pigment, and dispersant consisting of 25-70 % by weight of agglomerated carbonate-containing pigment, 0.1-1.0% by weight of a dispersant, the balance being water up to 100%, can be used advantageously in papermaking as well as in the paint and lacquer industry. In a novel process for agglomerating ultra-fine particles in slurries the slurry is subjected to heat treatment until the agglomeration is complete.
    Type: Grant
    Filed: July 24, 1998
    Date of Patent: November 23, 1999
    Assignee: Pluess-Staufer AG
    Inventors: Hans-Joachim Weitzel, Claude Wermuth, Dieter Strauch
  • Patent number: 5972100
    Abstract: A filler of inorganic particles, cellulose reactive size and cationic dispersing agent is provided, the use of which results in the capability to obtain the desired sizing level practically unaffected by the level of filler addition.
    Type: Grant
    Filed: August 22, 1991
    Date of Patent: October 26, 1999
    Assignee: Hercules Incorporated
    Inventor: David Howard Dumas
  • Patent number: 5931999
    Abstract: A raised liquid art medium comprises baking soda, corn starch, water, gesso, and chalk. The medium can be applied to a variety of surfaces for various art projects. Once applied, the medium can be manipulated while still wet and different colors of the medium can be used together without the colors running into each other or bleeding. When dry, the medium can be colored, etched, carved, or sanded to make further artistic effects.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: August 3, 1999
    Inventor: Leslie Aisner
  • Patent number: 5913973
    Abstract: A method for producing a high solids slurry of an acid-resistant precipitated calcium carbonate for shipping purposes is disclosed. A low solids of about 18 wt. % to 20 wt. % solids slurry is treated with a chemical additive, such as sodium aluminate, in order to impart acid resistance to the calcium carbonate, and is dewatered to form an intermediate solids slurry of about 44 wt. %. This intermediate solids slurry is then diluted with a fraction of the low solids slurry which was treated with the chemical additive, in order to bring the intermediate slurry to a final high solids slurry of about 35 wt. %. Acid is added to the final product slurry in order to reduce the pH of the final slurry to within a buffering range of about 7.0 to 6.5. The final product slurry of about 35 wt. % comprises an acid-resistant calcium carbonate composition with a pH of about 7.0 which can be shipped for ultimate use when making paper under neutral pH conditions.
    Type: Grant
    Filed: July 8, 1997
    Date of Patent: June 22, 1999
    Assignee: ECC International Inc.
    Inventors: Jose M. Rodriguez, Steven M. Fortier
  • Patent number: 5910214
    Abstract: A process for producing calcium carbonate particles having an average size of 0.3.+-.0.1 .mu.m, the process comprising the steps of preparing light calcium carbonate particles of 0.6.+-.0.4 .mu.m in average size by carbonating calcium hydroxide suspended in water, drying and pulverizing the light calcium carbonate particles, admixing the dry powders thereof with a dispersing agent, and wet-grinding the slurry. The final product imparts high opacity and brightness to coated papers when it is used as a pigment.
    Type: Grant
    Filed: September 8, 1997
    Date of Patent: June 8, 1999
    Inventor: Kyu Jae You
  • Patent number: 5908498
    Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.
    Type: Grant
    Filed: March 31, 1998
    Date of Patent: June 1, 1999
    Assignee: Kerr-McGee Chemical LLC
    Inventors: James W. Kauffman, Phillip M. Story, John E. Halko
  • Patent number: 5882396
    Abstract: An inorganic particulate material suitable for use as a pigment material in a paper coating composition has a particle size distribution which when represented as a graph of percentage of weight of particles having an equivalent spherical diameter (esd) of given size versus particle esd expressed in microns and plotted on a logarithmic base 10 scale has the following features: (a) a first peak at the coarse particle size and a second peak at a finer particle size and a dip or trough between the first and second peaks; (b) the mean particle size x.sub.1 of the particles making up the first peak being 2 to 4 microns; (c) the relationship between the first and second peaks being such that the value of the mean particle size x.sub.2 of the particles making up the second peak is separated in the particle size distribution graph from the value of x.sub.1 by at least 0.5; and (d) the minimum of the dip or trough is at a given particle esd dimension of between 0.5 and 5 microns.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: March 16, 1999
    Assignee: ECC International Ltd.
    Inventor: Anthony Gordon Hiorns
  • Patent number: 5879442
    Abstract: Proposed is a method for the preparation of an aqueous slurry of calcium carbonate particles suitable as a base pigment in the preparation of a paper coating composition having excellent water retentivity and high solid concentration with good flowability, which contains precipitated and ground calcium carbonate particles in combination in a specified weight proportion and characterized by several parameters. The aqueous slurry is prepared in a process comprising the steps of: (a) subjecting an aqueous slurry or wet cake containing a specified amount of specific precipitated calcium carbonate particles to a primary dispersing treatment using a mixer to a specified extent; (b) admixing the aqueous slurry with a specified amount of specific ground calcium carbonate particles; (c) subjecting the aqueous slurry to a secondary dispersing treatment using a mixer to a specified extent; and (d) subjecting the aqueous slurry to a tertiary dispersing treatment using a sand grinder to a specified extent.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: March 9, 1999
    Assignee: Okutama Kogyo Co., Ltd.
    Inventors: Hiroyuki Nishiguchi, Kazuhisa Shimono, Tetsuo Kumasaka
  • Patent number: 5873935
    Abstract: A coating color comprising 28-51% by weight of water, 43-64% by weight of carbonate-containing pigment with a specific particle distribution and a particle diameter of 0.18-0.28 .mu.m and a specific surface area of 19-26 M.sup.2 /g and 6-8% by weight of conventional binding agents and additives may be employed with advantage for coated papers. The coating color is produced by wet milling of the carbonate-containing pigment without the addition of dispersing or wetting agents at a solids concentration of 30-20% by weight in an agitating ball mill, subsequent concentration, re-dispersal and the addition of binding agents, water and additives.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: February 23, 1999
    Assignee: Pluss-Staufer AG
    Inventors: Max Schachenmann, Dieter Strauch
  • Patent number: 5855662
    Abstract: Aqueous pigment preparations comprisinga) 10 to 80% by weight, in particular 20 to 60% by weight, of a pigment,b) 0.1 to 20% by weight, in particular 0.1 to 15% by weight, of an oxyalkylation product which is obtained by addition of optionally substituted styrenes onto optionally substituted phenols and reaction with ethylene oxide and/or propylene oxide,c) 2 to 30% by weight of a polyether-polyol having a boiling point under normal pressure of greater than 150.degree. C. andd) if appropriate further additives, and water as the remainder,which are particularly suitable for pigmenting naturally occurring and synthetic materials, such as emulsion paints, emulsion coatings and emulsion printing inks, have been found.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: January 5, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Achim Brand, Josef Leitermann, Roger Nyssen, Klaus Schubert, Erhard Schuffenhauer, Karlheinz Wieser, Herbert Wigger
  • Patent number: 5843220
    Abstract: The present invention relates to a process for preparing a pigment composition whereby a mixture of an organic pigment and an inorganic filler is subjected to an air jet milling step. The inventive process is an environmentally friendly process which yields pigments having outstanding dispersibility and wetting characteristics when incorporated in plastics, aqueous or solvent based coatings and inks.
    Type: Grant
    Filed: December 1, 1997
    Date of Patent: December 1, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 5837045
    Abstract: A surface-modified colored pigment is disclosed which includes a colored pigment having no primary amines and at least one attached hydrophilic organic group, wherein said organic group comprises a) at least one aromatic group, and b) at least one ionic group or ionizable group, or a mixture of an ionic group or an ionizable group. The colored pigment may be blue, brown, cyan, green, violet, magenta, red, orange, yellow, mixtures thereof and the like. The surface-modified colored pigment, due to the hydrophilic groups on its surface, is readily dispersed in a liquid vehicle without the addition of a surfactant or other dispersing aid or additive. The surface-modified color pigment may be used in a variety of aqueous systems including, but not limited to, coatings, paints, papers, adhesives, latexes, inks, toners, textiles and fibers. In addition, an aqueous composition is disclosed including water-based liquid vehicle and the surface-modified colored pigment described above.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: November 17, 1998
    Assignee: Cabot Corporation
    Inventors: Joseph E. Johnson, James A. Belmont
  • Patent number: 5837049
    Abstract: A treated inorganic solid comprises particulate inorganic material the particles of which are coated with an alkylphosphonic acid or ester thereof, the alkylphosphonic acid containing 6 to 22 carbon atoms. The particulate material is usually a pigment, extender or filler which is treated by mixing with the alkylphosphonic acid or ester for example in an aqueous dispersion or during a process step such as milling. The treated inorganic solid is particularly useful for preparing polymer compositions such as masterbatches.
    Type: Grant
    Filed: October 23, 1997
    Date of Patent: November 17, 1998
    Assignee: Tioxide Group Services Limited
    Inventors: Colin Lloyd Watson, Peter James Allen
  • Patent number: 5783038
    Abstract: An improved thermal ink jet recording paper, incorporating heat aged precipitated calcium carbonate ("PCC") and a binder, is disclosed. Heat aging the PCC in the presence of an organophosphonate produces discrete particles of PCC with a surface morphology and chemistry that enhances the ability of the PCC to bind to ink jet ink without binding so strongly that the color of the ink is changed. Ink jet recording papers incorporating the PCC and binders of the present invention have reduced feathering, spreading, and penetration or backside showthrough, as well as improved optical density, dry time, and water fastness.
    Type: Grant
    Filed: April 14, 1997
    Date of Patent: July 21, 1998
    Assignee: Minerals Technologies, Inc.
    Inventors: Douglas Ward Donigian, Robert Kenneth Resnik, Michael Gregory McFadden
  • Patent number: 5743952
    Abstract: A process for improving the rheological properties of an aqueous suspension of a particulate inorganic material which comprises the steps of: (a) forming an aqueous suspension of the particulate inorganic material and an effective amount of an anionic polyelectrolyte dispersing agent; (b) diluting the suspension formed in step (a) with water while maintaining the particulate in the dispersed state of step (a) to give a solids concentration of not less than 20% by weight of the particulate inorganic material; and (c) reconcentrating the diluted suspension formed in step (b) to give a solids concentration of at least 50% by weight of the particulate inorganic material.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: April 28, 1998
    Assignee: ECC International Ltd.
    Inventors: David Robert Skuse, Warren Paul Eagles, Keith Robert Rogan
  • Patent number: 5744126
    Abstract: Cosmetics having good dispersibility, high sustained ultraviolet light ray shielding, suppressed photochemical reactivity and catalytic activity of the ultraviolet ray shielding material and high stability. A milky lotion containing fine particles of zinc oxide surface-modified with 5% dimethyl polysiloxane (mean particle size, 1.6.mu.) and titanium oxide surface-modified with 5% dimethyl polysiloxane (mean particle size, 1.2.mu.).
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: April 28, 1998
    Assignee: Miyoshi Kasei, Inc.
    Inventors: Masaakira Horino, Yukio Hasegawa