Quinacridone Pigment Or Derivative Patents (Class 106/497)
  • Publication number: 20030217672
    Abstract: Processes for preparing modified pigments are described. In one embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiol reagent comprising at least one —SH group and at least two ionic or ionizable groups. In a second embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiopolymer comprising at least one —SH group. Modified pigments are also described.
    Type: Application
    Filed: May 10, 2002
    Publication date: November 27, 2003
    Inventor: Paul S. Palumbo
  • Publication number: 20030205171
    Abstract: The present invention relates to a process for preparing a polymer-modified pigment comprising the step of: combining, in any order, at least one pigment having attached at least one nucleophilic group, at least one polymer comprising at least one carboxylic acid group or salt thereof, and at least one coupling agent. At least one mediator compound may also be used. The modified pigments can be used in applications such as inkjet ink applications.
    Type: Application
    Filed: May 6, 2002
    Publication date: November 6, 2003
    Inventors: Curtis E. Adams, Ronald J. Gambale
  • Patent number: 6641656
    Abstract: The present invention describes a dispersion comprising a vehicle and a modified pigment. The modified pigment has, when measured in an aqueous medium, a zeta potential of 0.0 mV at a pH of between 5.0 and 11.0. Inkjet ink compositions and an inkjet consumable set are also disclosed.
    Type: Grant
    Filed: October 17, 2001
    Date of Patent: November 4, 2003
    Assignee: Cabot Corporation
    Inventors: Yuan Yu, Paul S. Palumbo
  • Publication number: 20030183128
    Abstract: The method for preparation quinacridone pigment nanocrystals with sub micrometer to nanometer in average size comprising, supplying supercritical or semi-critical liquid, which dissolves quinacridone pigment, into a specimen tube (ST) composing a reactor possessing a filter of desired opening to the upper stream side and to the down stream side in which quinacridone pigment is set up, flowing out the supercritical or semi-critical liquid in which quinacridone pigment is dissolved from said reactor to a mixing apparatus to which coolant is supplied, and by selecting the kind of supercritical or semi-critical liquid and combination of conditions e.g. supplying speed of each liquids, temperature of the liquid and the reacting pressure.
    Type: Application
    Filed: March 13, 2003
    Publication date: October 2, 2003
    Inventors: Hittoshi Kasai, Hachiro Nakanishi, Kunio Arai
  • Patent number: 6626990
    Abstract: The present invention relates to a process for producing alpha, gamma-I, gamma-II and gamma-III crystal modifications of quinacridone and transparent quinacridone pigments including the solid solutions of various quinacridones, using a variety of tris-aryl-s-triazines, particularly resorcinol triazine derivatives, or aromatic- or heteraromatic-compounds having at least one hydroxyl or keto group bonded to the ring, as an additive, prior to or concurrently with the oxidation of corresponding dihydroquinacridone salts.
    Type: Grant
    Filed: March 18, 2002
    Date of Patent: September 30, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Shivakumar Basalingappa Hendi, Suruliappa Gowder Jeganathan, James Barry Ganci
  • Patent number: 6620235
    Abstract: Compositions comprising a) a mixture of i) C.I. Pigment Violet 19 together with either C.I. Pigment Blue 15 or C.I. Pigment Blue 60, or ii) C.I. Pigment Red 177 together with either C.I. Pigment Blue 15 or C.I. Pigment Blue 60, and b) a dispersant, c) optionally a biocide, and d) water. A process for shading of paper using said compositions or by applying separate pigment dispersions of a) C.I. Pigment Violet 19 and either C.I. Pigment Blue 15 or C.I. Pigment Blue 60, or b) C.I. Pigment Red 177 and either C.I. Pigment Blue 15 or C.I. Pigment Blue 60.
    Type: Grant
    Filed: January 9, 2002
    Date of Patent: September 16, 2003
    Assignees: Ciba Specialty Chemicals Corporation, Stora Enso AB
    Inventors: Ian William Knowles, Robert Watsfeldt, Kjell Erik Kumlin
  • Publication number: 20030164118
    Abstract: Organic pigments are conditioned by introducing a liquid prepigment suspension into a miniaturized continuous reactor and thermally treating therein.
    Type: Application
    Filed: March 31, 2003
    Publication date: September 4, 2003
    Applicant: Clariant Finance (BVI) Limited
    Inventors: Uwe Nickel, Klaus Kund, Erwin Dietz, Joachim Webber, Olaf Schupp
  • Patent number: 6596071
    Abstract: Organic and inorganic composite pigments having an average particle diameter of 0.01 to 10.0 &mgr;m composed of a white inorganic particle, an organosilane compound obtained from alkoxysilanes, or polysiloxanes coating on the white inorganic particle, and an organic pigment coat formed on said coating. An ultraviolet light-absorbing agent is present in any portion from the surface of the white inorganic particle to surface of the organic pigment coat. These composite pigments have reduced amounts of organic pigments desorbed from their surface and exhibit excellent light resistance due to their ultraviolet absorbing property.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: July 22, 2003
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Mineko Ohsugi, Yusuke Shimohata, Hiroko Morii
  • Patent number: 6596073
    Abstract: The invention relates to a solid pigment composition comprising a) at least one pigment, b) at least one compound selected from the group consisting of b0) a phenol-styrene-polyglycol ether or an ionically modified phenol-styrene-polyglycol ether, b1) a condensation product prepared from b1A) sulphonated aromatics b1B) aldehydes and/or ketones and b1C) optionally one or more compounds selected from the group of unsulphonated aromatics, urea and urea derivatives, and b2) phosphoric acid, phosphonic acid and derivatives thereof, and c) at least one organic thickener.
    Type: Grant
    Filed: August 6, 2001
    Date of Patent: July 22, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Roger Nyssen, Josef Witt
  • Publication number: 20030127023
    Abstract: The invention relates to a process for preparing pigments, which comprises
    Type: Application
    Filed: December 4, 2002
    Publication date: July 10, 2003
    Inventors: Yves Grandidier, Albert Riegler, Klaus Ruf, Urs Schlatter, Takashi Deno
  • Patent number: 6589330
    Abstract: Disclosed herein is a green pigment composition comprising (a) a green pigment comprising a mixture of fine particles of a halogen-free blue pigment and fine particles of a halogen-free yellow pigment and (b) a halogen-free pigment derivative. Since the green pigment composition of the present invention does not generate the harmful substances such as dioxin and PCB at the time of burning processing, it is environmentally friendly, sanitary, easily recycled, excellent in light resistance and heat resistance and has the hue of clearness.
    Type: Grant
    Filed: December 26, 2001
    Date of Patent: July 8, 2003
    Assignee: TOYO INK Mfg. Co., Ltd.
    Inventors: Shigeki Kato, Kosaku Tsuji
  • Patent number: 6582510
    Abstract: A pigment dispersion suitable for use in the manufacture of pigmented coating compositions is provided. The pigment dispersion comprises a) pigment, b) carrier, and c) an acrylic/polyether comb-branched copolymer dispersant wherein the polyether portion of the copolymer is free of any acidic groups. A method of making a present dispersion is also provided. The method comprises mixing together, in any combination: a) pigment, b) carrier, and c) an acrylic/polyether comb-branched copolymer dispersant wherein the polyether portion of the copolymer is free of any acidic groups. A pigmented coating composition is also provided comprising a pigment dispersion made in accordance with present invention.
    Type: Grant
    Filed: April 16, 2002
    Date of Patent: June 24, 2003
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Steven A. Schwartz
  • Patent number: 6582508
    Abstract: The invention provides a process for the fine division of pigments which comprises spraying a coarsely crystalline crude pigment and/or a poorly dispersible prepigment in suspension form through nozzles to a point of conjoint collision in a reactor chamber enclosed by a housing in a microjet reactor, a gas or an evaporating liquid being passed into the reactor chamber through an opening in the housing for the purpose of maintaining a gas atmosphere in the reactor chamber, and the resulting pigment suspension and the gas or the evaporated liquid being removed from the reactor through a further opening in the housing by means of overpressure on the gas entry side or underpressure on the product and gas exit side.
    Type: Grant
    Filed: October 5, 2001
    Date of Patent: June 24, 2003
    Assignee: Clariant GmbH
    Inventors: Erwin Dietz, Joachim Weber, Dieter Schnaitmann, Christian Wille, Leonhard Unverdorben
  • Patent number: 6562121
    Abstract: Organic pigments are conditioned by introducing a liquid prepigment suspension into a miniaturized continuous reactor and thermally treating therein.
    Type: Grant
    Filed: June 27, 2001
    Date of Patent: May 13, 2003
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Uwe Nickel, Klaus Kund, Erwin Dietz, Joachim Weber, Olaf Schupp
  • Patent number: 6562117
    Abstract: There is provided a method for regulating the average particle diameter of a pigment for an ink composition possessing excellent anti-clogging properties and ejection stability. The method comprises the steps of: dispersing the pigment in a solvent to prepare a stock pigment dispersion; and subjecting the stock pigment dispersion to crossflow membrane filtration.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: May 13, 2003
    Assignee: Seiko Epson Corporation
    Inventors: Tsuyoshi Sano, Teruhito Kojima
  • Publication number: 20030084820
    Abstract: A finely divided pigment is formed of an aggregate of primary particles. A number of primary particles of not greater than 0.1 &mgr;m in particle size is at least 95% of an entire number of the primary particles, and a number of primary particles of greater than 0.1 &mgr;m in particle size is at most 5% of the entire number of the primary particles. The finely divided pigment can be produced by grinding a parent pigment (pre-division pigment) together with a water-soluble inorganic salt and a water-soluble organic solvent in a grinding machine at a temperature of from 30 to 90° C. for 2 to 6 hours under a load, and then removing the water-soluble inorganic salt and the water-soluble organic solvent. A coloring composition comprises a dispersing medium and the finely divided pigment dispersed in the dispersing medium.
    Type: Application
    Filed: June 27, 2002
    Publication date: May 8, 2003
    Applicant: Dainichiseika Color & Chem. Mfg. Co., Ltd.
    Inventors: Hisao Okamoto, Yutaka Nakagawa, Yoshiyuki Zama, Koji Tsuchiya, Shotoku Takami, Yoshio Abe, Michiei Nakamura
  • Patent number: 6544325
    Abstract: The present invention relates to pigmentary solid solutions comprising copper phthalocyanine (Pigment Blue 15; C.I. 74160) as host and other blue to violet pigments as guests. Preferred hosts are the &agr; (Pigment Blue 15:1), &bgr; (Pigment Blue 15:3) and &egr; (Pigment Blue 15:6) crystal forms of copper phthalocyanine, especially the &egr; crystal form. The present invention also relates to dispersions comprising solid solutions as pigment particles, and pigment derivatives as rheology improvers. Preferred dispersions of solid solutions in the e crystal lattice may be used in particular to prepare color filters for liquid-crystal displays (LCDs). The present invention also includes a process for preparing the dispersions of the invention, the solid solutions themselves, and the use thereof to pigment high molecular mass organic materials.
    Type: Grant
    Filed: July 3, 2001
    Date of Patent: April 8, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Véronique Hall-Goulle, Gerardus De Keyzer, Yves Grandidier
  • Patent number: 6544321
    Abstract: Disclosed are pigment particles prepared by a process which comprises (a) preparing a solution of a polyalkylene oxide compound in water; (b) preparing a solution of a cationic dye in water; (c) admixing the solution containing the polyalkylene oxide compound with the solution containing the cationic dye to form a mixture; (d) adding to the mixture a solution containing a heteropolyacid in water, an alcohol, or a mixture thereof, thereby resulting in formation of pigment particles having an average particle diameter of no more than about 300 nanometers; and (e) after addition of the heteropolyacid to the mixture, neutralizing the mixture by addition of a base. Another embodiment of the present invention is directed to an ink composition comprising water and the aforementioned pigment particles.
    Type: Grant
    Filed: November 7, 2001
    Date of Patent: April 8, 2003
    Assignee: Xerox Corporation
    Inventors: Maura A. Sweeney, Thomas W. Smith, Melvin D. Croucher
  • Patent number: 6537364
    Abstract: The invention provides a process for the fine division of pigments which comprises dissolving coarsely crystalline crude pigments in a solvent and precipitating them with a liquid precipitation medium by spraying the pigment solution and the precipitation medium through nozzles to a point of conjoint collision in a reactor chamber enclosed by a housing in a microjet reactor, a gas or an evaporating liquid being passed into the reactor chamber through an opening in the housing for the purpose of maintaining a gas atmosphere in the reactor chamber, and the resulting pigment suspension and the gas or the evaporated liquid being removed from the reactor through a further opening in the housing by means of overpressure on the gas entry side or underpressure on the product and gas exit side.
    Type: Grant
    Filed: October 5, 2001
    Date of Patent: March 25, 2003
    Assignee: Clariant GmbH
    Inventors: Erwin Dietz, Joachim Weber, Dieter Schnaitmann, Christian Wille, Leonhard Unverdorben, Klaus Brychcy
  • Patent number: 6537362
    Abstract: A method of conditioning an organic crude pigment by treating, under high shear, 1 part by weight of the crude pigment and about 0.5 to 1.9 parts by weight of polyphosphoric acid or polyphosphoric acid methyl ester at a temperature ranging from about 90 to 160° C.
    Type: Grant
    Filed: November 10, 2000
    Date of Patent: March 25, 2003
    Assignee: Sun Chemical Corporation
    Inventors: Edward H. Sung, Humberto Velasquez, George H. Roberston, Veronica L. Chambers
  • Patent number: 6530989
    Abstract: A process for the preparation of an organic pigment dispersion is disclosed and consists of dispersing a dried soft-textured organic pigment in a dispersion vehicle, wherein the dispersion vehicle contains an ink varnish and alkyd and the dispersion is carried out in a tank equipped with a sweep and a high speed dispersion blade.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: March 11, 2003
    Assignee: Sun Chemical Corporation
    Inventors: Kalpathy Anantharaman, Michael Lewis, Anthony Maliyackel, Alan Gregory, Sanjoy Ganguly, Allen Bauer
  • Patent number: 6524383
    Abstract: Disclosed is a pigment dispersion that can be used for an ink jet printing-use pigment ink that affords stable printing characteristics and has excellent storage stability in an ink jet printer having a head driven at a high frequency and having finer nozzles in order to enhance image quality and raise the speed. Disclosed is also a method for manufacturing this pigment dispersion. This manufacturing method includes a step of surface-treating a self-dispersing type of pigment, in which at least hydrophilic, dispersibility-imparting group is introduced to the pigment surface directly and/or via a polyvalent group, and a step of dispersing the self-dispersing pigment obtained in said surface-treating step in an aqueous medium, wherein the dispersion step is a step in which at least the self-dispersing pigment, a wetting agent, and water are dispersed in the form of a liquid mixture.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: February 25, 2003
    Assignee: Seiko Epson Corporation
    Inventors: Hidehiko Komatsu, Hiroto Nakamura, Hitoshi Ohta, Masahiro Yatake, Kazuhiko Hara
  • Patent number: 6524382
    Abstract: The present application relates to a process for the manufacture of pigmented vitreous materials, as well as to pigmented vitreous materials, characterized by the use of soluble pigment precursors and preferably the absence of significant amounts of dispersants. These pigmented vitreous materials can be used as colored materials for any known purposes. Soluble pigment precursors comprising a partial structure are also claimed, wherein X1 is an aromatic or heteroaromatic ring, B is hydrogen or a group of the formula but at least one group B is not hydrogen, and L is a solubilizing group.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: February 25, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Patrice Bujard, Véronique Hall-Goulle, Zhimin Hao, Hitoshi Nagasue, Gerardus De Keyzer
  • Patent number: 6521038
    Abstract: A near-infrared reflecting composite pigment comprises a near-infrared non-absorbing colorant and a white pigment coated with the near-infrared non-absorbing pigment. The near-infrared reflecting composite pigment can be produced by mixing a colorant dispersion, in which the near-infrared non-absorbing colorant is dispersed in a liquid medium, with the white pigment in a form selected from powder or a dispersion and then drying the resultant mixture. A near-infrared reflecting coating agent comprises as a coloring agent the near-infrared reflecting composite pigment. A near-infrared reflecting material comprises a base material coated on a surface thereof with the near-infrared reflecting coating agent.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: February 18, 2003
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Hiromitsu Yanagimoto, Yoshiyuki Zama, Hisao Okamoto, Tohru Hosoda, Yoshio Abe, Michiei Nakamura
  • Publication number: 20030019398
    Abstract: Disclosed is a pigment dispersion that can be used for an ink jet printing-use pigment ink that affords stable printing characteristics and has excellent storage stability in an ink jet printer having a head driven at a high frequency and having finer nozzles in order to enhance image quality and raise the speed. Disclosed is also a method for manufacturing this pigment dispersion. This manufacturing method includes a step of surface-treating a self-dispersing type of pigment, in which at least hydrophilic, dispersibility-imparting group is introduced to the pigment surface directly and/or via a polyvalent group, and a step of dispersing the self-dispersing pigment obtained in said surface-treating step in an aqueous medium, wherein the dispersion step is a step in which at least the self-dispersing pigment, a wetting agent, and water are dispersed in the form of a liquid mixture.
    Type: Application
    Filed: October 19, 2001
    Publication date: January 30, 2003
    Applicant: SEIKO EPSON CORPORATION
    Inventors: Hidehiko Komatsu, Hiroto Nakamura, Hitoshi Ohta, Masahiro Yatake, Kazuhiko Hara
  • Patent number: 6508957
    Abstract: The present invention relates to methods for using a maleimide of formula (I) with the proviso that R1 and R2 do not simultaneously stand for phenyl or a maleimide of formula Ia as UV fluorescent material for void detection and for the preparation of scintillators films, luminescent solar energy collectors, organic electroluminescent devices, printing inks, non-impact printing inks, electrophotographic toners, color filters, and colored high molecular organic material.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: January 21, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Kazuhiko Kunimoto, Junji Otani, Kunihiko Kodama, Hiroshi Yamamoto, Patrick Verhoustraeten, Sonia Megert, Adalbert Braig
  • Patent number: 6506245
    Abstract: Colored pigments having one or more desired parameters and/or properties are described. These parameters and/or properties include: a) a particles size of from about 10 nm to about 300 nm; b) an accusizer number of less than 1010 particles/ml of dispersion at 15% solids which are greater than 0.5 micron; c) a filterability such that when in a liquid medium, 100 ml having 10% solids of the colored pigment filters through a 3 micron nylon absolute filter; d) a colored pigment purity of greater than about 80%, based on extractable material; and/or e) a stability such that the above-described properties do not change by more than 50% at 25 degrees C for at least one week. Colored pigments having at least one organic group and having one or more of the above-described characteristics is also described as well as a process for preparing surface-modified colored pigments.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: January 14, 2003
    Assignee: Cabot Corporation
    Inventors: Thomas A. Kinney, Friedrich K. von Gottberg, Yuan Yu, John F. Welch
  • Patent number: 6503317
    Abstract: Aqueous based pigment dispersions wherein the pigment is dispersed in a dispersant dye in the absence of any other dispersant or additive and aqueous based printing ink compositions containing these a pigment dispersions. Methods for preparing aqueous based pigment dispersions, wherein the pigment is dispersed in a dispersant dye, and method for preparing printing ink compositions incorporating these dispersions.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: January 7, 2003
    Assignee: Sun Chemical Corporation
    Inventors: Darren Mark Ortalano, Christopher Joseph Vissing
  • Patent number: 6494949
    Abstract: A process for producing beta-phase quinacridone by (a) reacting 2,5-dianilino-terephthalic acid with polyphosphoric acid in the presence of 2,5-dianisidino-terephthalic acid at a reaction temperature of at least 85° C.; (b) diluting the reaction mixture with water; (c) drowning the diluted mixture in a water-miscible alkanol; (d) heating the slurry at a temperature of from 100 to 130° C. at a pressure of 20 to 50 psi; and (e) recovering the beta-phase quinacridone.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: December 17, 2002
    Assignee: Sun Chemical Corporation
    Inventors: Edward Sung, Kathleen M. Kozak, George H. Robertson, Terrence R. Chamberlain
  • Patent number: 6494948
    Abstract: This invention relates to a process for preparing quinacridone pigment compositions by (a) heating a reaction mixture containing (i) 2,5-dianilinoterephthalic acid or 2,5-dianilino-6,13-dihydroterephthalic acid or a derivative thereof, (ii) about 0.1 to about 5 percent, based on component (a)(i), of 2,5-di(sulfamoylanilino)terephthalic acid and/or 2,5-di(sulfamoylanilino)-6,13-dihydroterephthalic acid or a derivative thereof, (iii) about 0.1 to about 15 percent by weight, based on component (a)(i), of other sulfonyl-containing derivatives of 2,5-dianilinoterephthalic acid and/or 2,5-dianilino-6,13-dihydroterephthalic acid, (iv) about 3 to about 20 parts by weight, per part of component (a)(i), of a dehydrating agent, and (v) optionally, a solvent; (b) drowning the reaction mixture from step (a) with a liquid in which the quinacridone pigment composition is substantially insoluble; and (c) isolating the quinacridone pigment composition.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: December 17, 2002
    Assignee: Bayer Corporation
    Inventors: Daphne J. Rice, Ibraheem T. Badejo
  • Patent number: 6494943
    Abstract: Colored pigments having one or more desired parameters and/or properties are described. These parameters and/or properties include: a) a particles size of from about 10 nm to about 300 nm; b) an accusizer number of less than 1010 particles/ml of dispersion at 15% solids which are greater than 0.5 micron; c) a filterability such that when in a liquid medium, 100 ml having 10% solids of the colored pigment filters through a 3 micron nylon absolute filter; d) a colored pigment purity of greater than about 80%, based on extractable material; and/or e) a stability such that the above-described properties do not change by more than 50% at 25 degrees C. for at least one week. Colored pigments having at least one organic group and having one or more of the above-described characteristics is also described as well as a process for preparing surface-modified colored pigments.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: December 17, 2002
    Assignee: Cabot Corporation
    Inventors: Yuan Yu, Friedrich K. von Gottberg, Robert M. Amici, Paul S. Palumbo
  • Patent number: 6488760
    Abstract: A universal tinting concentrate for both solvent- and water-based paints and coatings. The universal tinting concentrate is a composition which includes a colorant component, such as pigment, colorant, tinting agent and/or metal effect agent; a pigment dispersant including a moiety selected from the group consisting of an organic acid, anhydride, salt thereof, and derivative thereof, wherein the dispersant facilitates the dispersal of the colorant component in organic-based and aqueous-based vehicles; and a pH-neutralizing agent. In one embodiment of the invention, the pigment dispersant is represented by the following structure: where r and s are integers and r+s is 6 to 16; x and y are integers and x+y is 0 to 19; Z is H or COOH; and Z′ is H or COOH.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: December 3, 2002
    Assignee: The Valspar Corporation
    Inventors: Mark Binns, Dana L. Phillips, Don Diehl, Stephen Korenkiewicz, Larry Brandenburger
  • Patent number: 6485558
    Abstract: The invention relates to a process for the preparation of pigment granules, which comprises adding a wax or a waxy polymer to an organic pigment during the finish in an organic or aqueous organic medium and spray-drying the aqueous suspension obtained after removal of the organic solvent by steam distillation or washing out with water.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: November 26, 2002
    Assignee: Clariant GmbH
    Inventors: Hans Joachim Metz, Heinfred Ohleier
  • Patent number: 6478866
    Abstract: Aqueous pigment preparations containing a) at least one pigment, b) at least one condensation product based on A) suphonated aromatics, B) aldehydes and/or ketones and optionally C) one or several compounds selected from the group of non sulphonated aromatics, urea and urea derivatives, and c) at least one polyether polyol with a boiling point of above 150° C., at normal pressure. The inventive preparations are highly suitable for pigmenting natural or synthetic materials.
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: November 12, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Roger Nyssen, Wolfgang Zarges, Achim Brand, Thomas Roick, Hans Peter Geiger
  • Patent number: 6471764
    Abstract: An etheramine pigment dispersing salt for enhancing the dispersion performance of an organic pigment composition adding to 100 parts by weight of pigment about 1 to 40 parts by weight of an etheramine pigment dispersing salt.
    Type: Grant
    Filed: November 16, 2000
    Date of Patent: October 29, 2002
    Assignee: Sun Chemical Corporation
    Inventors: George H. Robertson, Kevin A. Arthur, Russell J. Schwartz, Stanislav Vilner, George McLaren
  • Patent number: 6471762
    Abstract: Colored lustrous pigments of superior quality are prepared by dry blending a platy substrate such as a metal oxide-coated mica nacreous pigment and a hydrophobic colorant at low shear. The resulting blend exhibits a well dispersed, stable coloration, increased hydrophobicity and is particularly useful in industrial and automotive applications. The technique can also be employed to prepare pigments for cosmetic application.
    Type: Grant
    Filed: August 23, 2000
    Date of Patent: October 29, 2002
    Assignee: Engelhard Corp.
    Inventors: Carmine Vincent DeLuca, Jr., Jeannine M. Gale
  • Patent number: 6471765
    Abstract: The present invention relates to compositions comprising a sulfonated diketopyrrolopyrrole and a Mannich-type substituted dihydroquinacridone to produce colored materials having improved stability at high temperatures. The instant compositions can be used for pigmenting polymeric materials, such as color filters.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: October 29, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Gerardus De Keyzer
  • Patent number: 6468341
    Abstract: A pigment composition comprises a wet-ground pigment mixture of (A) &egr;-copper phthalocyanine and (B) at least one pigment selected from a group consisting of condensed polycyclic pigments and azo pigments. The weight ratio of thecomponent (A) to the component (B) is 100:0.1 to 100:50. The pigment composition can be produced by wet-grinding (A-1) &agr;-copper phthalocyanine and the component (B) at a weight ratio of from 100:0.1 to 100:50 in a non-aromatic solvent. A colorant comprises the pigment composition and at least one component selected from the group consisting of film-forming resins and liquid media. A colored article can be obtained using the colorant as a coloring agent.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: October 22, 2002
    Assignee: Dainichiseika Color & Chemicals
    Inventors: Nobuto Wada, Kazutaka Aoki, Yutaka Nakagawa, Shotoku Takami, Michiei Nakamura
  • Patent number: 6451103
    Abstract: There is disclosed a self-dispersible aqueous pigment dispersion and preparing method thereof, the dispersion comprising an aqueous solution, particles of a pigment and a water-soluble pigment derivative, said particles being dispersed in the aqueous pigment dispersion in a concentration within the range from 2 to 25 wt. % based on the amount of the aqueous pigment dispersion, wherein a part of the water-soluble pigment derivative is adsorbed on the surface of the particles of the pigment to form dispersed particles comprising the particles of the pigment adsorbed by said part of the pigment derivative, and the remaining parts of the water-soluble pigment derivative are free in the dispersion without being adsorbed on the surface of the pigment in a concentration less than the critical flocculation concentration on which flocculation is initiated on said particles of the pigment dispersed under said concentration.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: September 17, 2002
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Toshiyuki Uemura, Tsukasa Iguchi, Mikiya Kato, Akimitsu Mochizuki
  • Patent number: 6440207
    Abstract: This invention relates to a process for preparing dispersible organic pigments by (a) milling a mixture containing (1) one or more organic pigments, (2) at least about 1% by weight, relative to the organic pigment, of one or more aromatic polyalkylene oxide dispersants, (3) 0 to about 10 parts by weight, relative to the organic pigment, of a milling liquid in which the organic pigment is substantially insoluble, (4) 0 to about 50% by weight, relative to the organic pigment, of one or more milling additives other than dispersant (2), and (5) 0 to about 20% by weight, relative to the organic pigment, of one or more surface treatment additives; (b) optionally, adding to the milled pigment (6) one or more liquids in which the organic pigment is substantially insoluble in amounts such that the total solids content is not reduced below about 10%, and (7) one or more multivalent metal salts and/or one or more quaternary ammonium salt; and (c) isolating the milled organic pigment
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: August 27, 2002
    Assignee: Bayer Corporation
    Inventor: Gregory R. Schulz
  • Patent number: 6436182
    Abstract: The invention relates to an advantageous process for producing highly concentrated pigment presscakes which comprises concentrating a pigment suspension on a high-pressure filter press with a pressure of at least 16 bar to a pigment content of at least 50% by weight without adding nonionic surfactants which have a cloud point in water.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: August 20, 2002
    Assignee: Clariant GmbH
    Inventors: Leonhard Unverdorben, Uwe Nickel, Andreas Harz, Gunnar Tilch
  • Patent number: 6432194
    Abstract: Various modified pigment products are described which are preferably capable of being dispersed in a variety of materials such as coatings, inks, toners, films, plastics, polymers, elastomers, and the like. The modified pigments are pigments having attached groups, such as polymeric groups, onto the pigment by means other than adsorption. A modified pigment product is described comprising a pigment having attached at least one group comprising the formula: —X—[NIon]pR wherein X comprises an aromatic group or an alkyl group, NIon comprises at least one type of non-ionic group, R represents hydrogen or comprises an aromatic group or an alkyl group, and p represents an integer from 1 to 500. Modified pigment products are also described comprising a pigment having attached at least one alkylene oxide group or at least one polymeric group.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: August 13, 2002
    Assignee: Cabot Corporation
    Inventors: Joseph E. Johnson, Nanying Bian, Collin P. Galloway
  • Patent number: 6423132
    Abstract: The present invention is drawn to pigment granules having a particle size from 0.5 to 4 mm, which consist of at least 90% by weight of at least one organic pigment selected from the group consisting of diketopyrrolopyrrole, quinacridone, perylene, indanthrone, flavanthrone, isoindolinone or amino- anthraquinone pigments and from 0 to 10% by weight of a binder having from 2 to 7 mol of carboxyl groups per 1000 g and from 0 to 5% by weight of a neutral emulsifier. The binder and the emulsifier together do not represent more than 10% by weight of the oveerall amount of pigment granules. The pigment present in the pigment granules has a particle size of from 0.01 to &mgr;m.
    Type: Grant
    Filed: February 15, 2001
    Date of Patent: July 23, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Paolo Balliello, Horst Olaf Brücker
  • Publication number: 20020088377
    Abstract: A process for producing beta-phase quinacridone by (a) reacting 2,5-dianilino-terephthalic acid with polyphosphoric acid in the presence of 2,5-dianisidino-terephthalic acid at a reaction temperature of at least 85° C.; (b) diluting the reaction mixture with water; (c) drowning the diluted mixture in a water-miscible alkanol; (d) heating the slurry at a temperature of from 100 to 130° C. at a pressure of 20 to 50 psi; and (e) recovering the beta-phase quinacridone.
    Type: Application
    Filed: January 5, 2001
    Publication date: July 11, 2002
    Inventors: Edward Sung, Kathleen M. Kozak, George H. Robertson, Terrence R. Chamberlain
  • Patent number: 6413309
    Abstract: Pigment preparations comprising a) at least one organic base pigment, b1) at least one perylene pigment dispersant of the formula (I)  and b2) at least one acidic, carboxyl- or sulfo-containing perylene pigment dispersant have advantageous rheological and coloristic properties.
    Type: Grant
    Filed: January 25, 2000
    Date of Patent: July 2, 2002
    Assignee: Clariant GmbH
    Inventors: Joachim Weber, Manfred Urban, Manfred Opravil, Erwin Dietz
  • Publication number: 20020078860
    Abstract: This invention relates to a process for preparing quinacridone pigment compositions by
    Type: Application
    Filed: December 22, 2000
    Publication date: June 27, 2002
    Inventors: Daphne J. Rice, Ibraheem T. Badejo
  • Patent number: 6409816
    Abstract: Pigment preparations comprise a) at least one diketopyrrolopyrrole pigment, and b) at least one perylene pigment dispersant of the formula (I)  and have advantageous rheological and coloristic properties.
    Type: Grant
    Filed: February 16, 2000
    Date of Patent: June 25, 2002
    Assignee: Clariant GmbH
    Inventors: Joachim Weber, Erwin Dietz
  • Patent number: 6410619
    Abstract: This invention relates to a process for preparing conditioned organic pigments by (a) milling a mixture comprising: (1) one or more crude organic pigments; (2) at least about 0.1% by weight, relative to the organic pigment, of one or more acrylic copolymer dispersants; and (3) 0 to about 100 parts by weight, relative to the organic pigment, of a milling liquid in which the organic pigment is substantially insoluble; and (b) isolating the milled organic pigment.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: June 25, 2002
    Assignees: Bayer Corporation, E.I. DuPont De Nemours and Company
    Inventors: Michael J. Greene, Patrick F. McIntyre, James G. King, Gregory R. Schulz, Karyn B. Visscher
  • Publication number: 20020073896
    Abstract: An improved process for producing a substantially pure gamma phase a quinacridone pigment or pigment derivative involving preparing an aqueous slurry of a crude quinacridone in the presence of caustic alkali and a non-polar, water immiscible solvent; and heating said slurry at a temperature above about 120° C.
    Type: Application
    Filed: December 20, 2000
    Publication date: June 20, 2002
    Inventors: Edward H. Sung, George H. Robertson, Humberto Velasquez
  • Patent number: 6406533
    Abstract: A 6,13-dihydroquinacridone derivative of formula I: (MO3S)m—Q—[CH2—(X)—(Y)n]o  (I) wherein: Q represents a 6,13-dihydroquinacridone moiety of formula II; A and B each independently represent a substituent selected from H, F, Cl, C1-C3alkyl and C1-C3alkoxy M represents a metal cation, quaternary N cation or H; X is an aromatic group, a cyclo-hetero aliphatic group with at least one 5 or 6 atom ring or a hetero aromatic group with at least one 5 or 6 atom ring and which is not a phthalimido group; Y is a sulfonic or carboxylic acid or salt thereof; m and n independently from each other are numbers from zero to 2.5; and o is a number from zero to 4, wherein m and o are not zero simultaneously.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: June 18, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Bäbler