Cellulose Material Patents (Class 127/37)
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Publication number: 20100319424Abstract: Systems and processes for converting bulky lignocellulosic biomass to high density biomass products, including biofuels, are described. The systems and processes relate to treating freshly harvested plant materials, generally at or in close proximity to sites where the plant materials are harvested, to effect saccharification, alcoholic fermentation, or simultaneous saccharification and fermentation, thereby providing a liquefied biomass. The liquefied biomass is extracted to provide liquid extracts comprising biomass-derived water and water soluble biomass saccharification and fermentation products, including fermentable sugars and alcohols. The liquid biomass extracts can be transported via pipeline to other locations for fermentation, further saccharification, and/or purification to provide biofuel. Alternatively, the liquefied biomass can be used to prepare a biomass slurry that can be transported via pipeline.Type: ApplicationFiled: February 3, 2009Publication date: December 23, 2010Applicant: SYNGENTA PARTICIPATIONS AGInventor: Gary Wietgrefe
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Publication number: 20100313882Abstract: A process is defined for the continuous steam pretreatment and fractionation of corn cobs and low lignin lignocellulosic biomass to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.Type: ApplicationFiled: April 23, 2010Publication date: December 16, 2010Applicant: GREENFIELD ETHANOL INC.Inventors: Frank A. Dottori, Robert Ashley Cooper Benson, Regis-Olivier Benech
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Publication number: 20100297704Abstract: The present invention relates to a clean process of preparing high grade biomass products, and their use in the production of health care products, bio-energy products, biochemicals, bio-originated chemicals and biodegradable plastics.Type: ApplicationFiled: February 18, 2010Publication date: November 25, 2010Inventor: Rongxiu LI
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Publication number: 20100275908Abstract: The present invention relates to a method to dispose plant cellulose materials, in particular to a method for preparing a main hydrolysate by hydrolyzing the plant cellulose materials with concentrated sulfuric acid. The plant cellulose materials are mixed with sulfuric acid in batches, and the main hydrolysate is obtained after hydrolysis. The batch mixing includes the following procedures: (1)sulfuric acid solution is used to dissolve part of the plant cellulose materials thereby forming a hydrolysate; (2)when the plant cellulose materials can not be dissolved any more, concentrated sulfuric acid with the concentration more than 80 wt % is successively added into the hydrolysate, and another part of the plant cellulose materials are added; (3)and then the procedure as step (2) is repeated until all the plant cellulose materials are completely hydrolyzed.Type: ApplicationFiled: July 29, 2008Publication date: November 4, 2010Inventor: Peihao Chen
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Publication number: 20100279372Abstract: Disclosed is a method of pretreating lignocellulose-based biomass by extracting lignin from biomass by adding a solvent for dissolving lignin to the lignocellulose-based biomass including lignin, hemicellulose and cellulose, and extracting the cellulose and/or hemicellulose by adding an ionic liquid to the remaining biomass after extracting the lignin.Type: ApplicationFiled: July 8, 2009Publication date: November 4, 2010Applicant: Samsung Electronics Co., Ltd.Inventors: Hwa Young CHO, Sang Jun SIM, Jin Woo KIM, Se Jong HAN, Jae Chan PARK, Sung Min PARK
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Patent number: 7819976Abstract: A method for treating biomass was developed that uses an apparatus which moves a biomass and dilute aqueous ammonia mixture through reaction chambers without compaction. The apparatus moves the biomass using a non-compressing piston. The resulting treated biomass is saccharified to produce fermentable sugars.Type: GrantFiled: August 22, 2007Date of Patent: October 26, 2010Assignees: E. I. du Pont de Nemours and Company, Alliance For Sustainable Energy LLCInventors: Julie Friend, Richard T. Elander, Melvin P. Tucker, III, Robert C. Lyons
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Patent number: 7815741Abstract: A reactor for hydrolytic splitting of cellulose under high pressure and heat has an inlet and outlet each with a cross-sectional area smaller than the cross-sectional area of the reactor. The pressure and heat in the reactor forms a cellulose plug within the inlet and the outlet. The inlet plug stops cellulose from escaping out the inlet. Cellulose begins to breakdown under heat, pressure, and if required an acid or a lubricant. The outlet plug slows downstream movement of cooking cellulose. Cellulose may be pre-treated by the addition of water, a weak acid, a lubricant, or a combination of the foregoing. The outer surface of the plug cooks faster than the inner core of the plug, becomes a liquefied slurry, and slides faster towards the outlet than the inner core.Type: GrantFiled: January 25, 2008Date of Patent: October 19, 2010Inventor: David A. Olson
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Patent number: 7815876Abstract: The reactor pump for hydrolytic splitting of cellulose is configured to pump cellulose, under high pressure, with low availability of sugar into a reactor. The reactor has an upstream transition segment connected to a downstream reaction chamber. The transition segment has an inlet that is smaller than the outlet. The inner walls taper outward. The chamber has an inlet that is larger than the discharge outlet. The inner walls taper inward. The transition segment outlet has an area that is substantially the same as the area of the chamber inlet. Back pressure in the chamber forms a cellulose plug within the inlet of the transition segment. The plug stops cellulose from escaping out the inlet. High pressure pumping forms a cellulose plug within the discharge outlet of the chamber. The plug slows downstream movement of the cooking cellulose giving the cellulose time to cook. Cooking cellulose begins to breakdown under heat and the injection of acid, if required.Type: GrantFiled: October 31, 2007Date of Patent: October 19, 2010Inventor: David A. Olson
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Publication number: 20100196967Abstract: A method for fractionating a lignocellulosic material, the method comprising; contacting (2) the lignocellulosic material with an ionic liquid (3) and dissolving the lignocellulosic material therein, providing a second liquid (7) which is immiscible with the ionic liquid and is also a non-solvent for cellulose, adding the second liquid to the ionic liquid so as to form a biphasic system (6) which comprises an ionic liquid phase essentially free of lignocellulose and a second liquid phase comprising lignin in solution and cellulose as a precipitate, separating the two phases and recovering (8) the precipitated cellulose from the separated second liquid phase.Type: ApplicationFiled: February 7, 2008Publication date: August 5, 2010Inventors: Leslie Alan Edye, William Orlando Sinclair Doherty
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Publication number: 20100186736Abstract: A method and apparatus for conveying a cellulosic feedstock are disclosed. The apparatus, such as a holding tank, has a passage. At the outlet to the passage, a conveyance member is provided to convey the cellulosic feedstock laterally across the outlet. The conveyance member, e.g., at least one screw conveyor, may have a variable pitch along its length. The method comprises passing the cellulosic feedstock through an impregnation chamber to an outlet of the impregnation chamber; passing the cellulosic feedstock from the outlet of the impregnation chamber to an inlet of a holding tank; passing the cellulosic feedstock downwardly through the holding tank; maintaining a generally constant residence time in the holding tank; and subsequently subjecting the cellulosic feedstock to a hydrolysis process.Type: ApplicationFiled: January 28, 2009Publication date: July 29, 2010Applicant: SUNOPTA BIOPROCESS INC.Inventors: Murray J. Burke, Sunalie N. Hillier
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Publication number: 20100186735Abstract: A method and apparatus for preparing a cellulosic feedstock are disclosed. Embodiments of the method comprise passing the cellulosic feedstock out of at least one outlet of a vessel (such as a holding tank) and obtaining at least two streams of cellulosic feedstock wherein each stream may be fed different hydrolysis reactors. Embodiments of the apparatus comprise passing the cellulosic feedstock downwardly through the vessel and withdrawing the feedstock from the vessel in two different lateral directions.Type: ApplicationFiled: January 28, 2009Publication date: July 29, 2010Applicant: SUNOPTA BIOPROCESS INC.Inventors: Murray J. Burke, Sunalie N. Hillier
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Publication number: 20100175691Abstract: A process for recycling cellulose acetate ester waste comprising the steps of: providing a reactor, adding cellulose acetate ester waste and a hydrolyzing agent to the reactor to create an agent/waste mixture followed by hydrolyzing the cellulose acetate ester waste by agitating and heating the agent/waste mixture for a period of time to create a hydrolyzed mixture. The hydrolyzing agent is then distilled and/or separated from the hydrolyzed mixture followed by separating and removing solid material from the hydrolyzed mixture to create a water soluble product stream which includes monosaccharides, polysaccharides, partially hydrolyzed cellulose, acetic acid, or combinations thereof. The water soluble product stream is then collected.Type: ApplicationFiled: January 13, 2010Publication date: July 15, 2010Inventors: Michael T. Combs, Bruce Ray Woodson
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Publication number: 20100175690Abstract: A method and system for hydrolyzing cellulose and/or hemicellulose contained in a biomass into monosaccharides and oligosaccharides by using high-temperature and high-pressure water in a subcritical condition is provided. In hydrolyzing cellulose or hemicellulose into saccharides by using high-temperature and high-pressure water in a subcritical condition, a large amount of slurry is cooled into a condition below the subcritical condition by subjecting the slurry contained in a pressure vessel under a high-temperature and high-pressure condition to flash evaporation in a pressure vessel charged with a slurry of a cellulosic biomass and heated halfway. It is possible to prevent saccharides from degrading into organic acids and to save energy by recovery of thermal energy. The cellulosic biomass is charged into a water-permeable vessel and then the water-permeable vessel is encapsulated into the pressure vessel together with water.Type: ApplicationFiled: October 23, 2007Publication date: July 15, 2010Applicant: KAWASAKI PLANT SYSTEMS KABUSHIKI KAISHAInventors: Takeshi Nagahama, Noriaki Izumi
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Patent number: 7754457Abstract: A continuous process for treating a lignocellulosic feedstock is provided. This method comprises pretreating the lignocellulosic feedstock under pressure in a pretreatment reactor at a pH between about 0.4 and about 2.0. One or more than one soluble base is added to this pressurized, pretreated feedstock after it exits the pretreatment reactor to adjust the pretreated lignocellulosic feedstock to an intermediate pH of between about pH 2.5 to about pH 3.5. This pressurized, partially-neutralized feedstock is then further processed at the intermediate pH. This may include flashing one or more than one time at the intermediate pH. The pH of the pressurized, partially-neutralized feedstock may then be adjusted with one or more than one base to produce a neutralized feedstock having a pH between about 4 and about 6. Prior to adjusting the pH to between about 2.5 and about 3.5, the pressurized, pretreated feedstock truly be partially depressurized.Type: GrantFiled: June 2, 2006Date of Patent: July 13, 2010Assignee: Iogen Energy CorporationInventors: Brian Foody, Jeffrey S. Tolan
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Publication number: 20100170504Abstract: Embodiments of the present invention overcome the well-known recalcitrance of lignocellulosic biomass in an economically viable manner. A process and system are provided for the efficient fractionation of lignocellulosic biomass into cellulose, hemicellulose sugars, lignin, and acetic acid. The cellulose thus obtained is highly amorphous and can be readily converted into glucose using known methods. Fermentable hemicellulose sugars, low-molecular—weight lignin, and purified acetic acid are also major products of the process and system. The modest process conditions and low solvent/solid ratios of some embodiments of the invention imply relatively low capital and processing costs.Type: ApplicationFiled: March 29, 2006Publication date: July 8, 2010Inventor: Y. H. Percival Zhang
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Publication number: 20100163018Abstract: Lignocellulosic biomass materials are fractionated by dissolving at least a portion of the lignocellulosic material in an ionic liquid and separating the resulting mixture into a cellulose-enriched fraction and/or a lignin-enriched fraction. The cellulose-enriched fraction contains about 10 percentage points more glucose than the weight percent glucose contained in the original lignocellulosic biomass material. In certain embodiments, the lignin-enriched fraction includes a lignin content that is 5 percentage points greater than the weight percent lignin present in the original lignocellulosic material. The techniques used to isolate the cellulose-enriched fractions and/or the lignin-enriched fractions from the ionic liquid mixture do not employ environmentally unfriendly solvents.Type: ApplicationFiled: December 29, 2008Publication date: July 1, 2010Applicant: WEYERHAEUSER COMPANYInventors: ANGELA P. GIFFORD, DAVID E. SEVEREID
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Publication number: 20100163019Abstract: A process for converting wet cellulosic biomass to at least one sugar, such as glucose. The process comprises treating the wet cellulosic biomass with a strong acid at a temperature no greater than 40° C., wherein the acid is present in an amount of at least 10 moles per mole of monomeric sugar present in the wet cellulosic biomass. The acid then is neutralized partially, and the cellulose is hydrolyzed to the at least one sugar at a temperature of at least 60° C. Such process provides improved yields of sugar from cellulose.Type: ApplicationFiled: October 6, 2009Publication date: July 1, 2010Inventors: Michel Chornet, Esteban Chornet, Jean-Michel Lavoie
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Publication number: 20100126501Abstract: Cellulose contained in plant fiber material is hydrolyzed with the use of a pseudo-molten cluster acid as a hydrolysis catalyst to produce saccharide, most of which is glucose. After the glucose is produced, the saccharide is precipitated with the use of an organic solvent, and the saccharide including a solidified saccharide during the hydrolysis and the precipitated saccharide is separated from residues and the cluster acid.Type: ApplicationFiled: April 25, 2008Publication date: May 27, 2010Inventors: Shinichi Takeshima, Akio Koyama
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Publication number: 20100116267Abstract: A biomass cooking device including: a treatment vessel having an biomass inlet adapted to receive biomass material to a processing chamber of the vessel, a biomass outlet adapted to discharge from the processing chamber the biomass material processed in the vessel, an extraction region of the vessel and a liquids outlet to the extraction region to discharge dissolved hemi-cellulosic material extracted from the biomass material in the processing chamber; a piston press in the cooking vessel defining a moveable wall of the processing chamber, wherein the piston press moves to reduce the processing chamber and thereby compress the biomass material; and a screen plate in the vessel forming a barrier between the processing chamber and an extraction region of the vessel, the screen plate having apertures to pass the dissolved hemi-cellulosic material through the screen plate from the processing chamber to the extraction region.Type: ApplicationFiled: July 15, 2009Publication date: May 13, 2010Applicant: ANDRITZ INC.Inventors: Peter Mraz, Thomas Pschorn, Bertil Stromberg, Namhee Shin
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Patent number: 7670813Abstract: A method for recovering inorganic salt during processing of a lignocellulosic feedstock is provided. The method comprises pretreating the lignocellulosic feedstock by adding an acid or a base to the feedstock to produce a pretreated lignocellulosic feedstock. A soluble base or acid is then added to the pretreated lignocellulosic feedstock to adjust the pH and produce a neutralized feedstock. The neutralized feedstock is then hydrolyzed to produce an hydrolyzed feedstock and a sugar stream. Inorganic salt is recovered from a wash stream obtained from the pretreated lignocellulosic feedstock, a stream obtained from the neutralized feedstock, a stream obtained from the sugar stream, or a combination of these streams. The inorganic salt may be concentrated, clarified, recovered and purified by crystallization, electrodialysis, drying, or agglomeration and granulation, and then used as desired, for example, as a fertilizer.Type: GrantFiled: October 25, 2006Date of Patent: March 2, 2010Assignee: Iogen Energy CorporationInventors: Brian Foody, Jeffrey S. Tolan, Ziyad Rahme, Vijay Anand
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Publication number: 20100043782Abstract: The invention relates to a process for producing xylose and cellulose from a biomass comprising: (a) mixing a biomass with a reactive fluid comprising water and a supercritical C1-C5 alcohol to form a mixture at a first temperature and a first pressure; (b) maintaining the mixture at the first temperature and first pressure for a first time period, wherein a reaction occurs; and (c) quenching the reaction to form at least one reaction product mixture; wherein xylose and cellulose are produced by the process. Lignin may also be produced by the processes of the invention.Type: ApplicationFiled: July 16, 2009Publication date: February 25, 2010Inventors: Srinivas Kilambi, Kiran L. Kadam
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Publication number: 20100041119Abstract: The present invention provides an apparatus and a method for conversion of cellulosic material, such as chopped straw and corn stover, and household waste, to ethanol and other products. The cellulosic material is subjected to continuous hydrothermal pre-treatment without addition of chemicals, and a liquid and a fibre fraction are produced. The fibre fraction is subjected to enzymatic liquefaction and saccharification. The method of the present invention comprises: performing the hydrothermal pre-treatment by subjecting the cellulosic material to at least one soaking operation, and conveying the cellulosic material through at least one pressurised reactor, and subjecting the cellulosic material to at least one pressing operation, creating a fibre fraction and a liquid fraction; selecting the temperature and residence time for the hydrothermal pretreatment, so that the fibrous structure of the feedstock is maintained and at least 80% of the lignin is maintained in the fibre fraction.Type: ApplicationFiled: July 19, 2006Publication date: February 18, 2010Applicant: Holm Christensen Biosystemer ApSInventors: Børge Holm Christensen, Lena Holm Gerlach
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Publication number: 20100024808Abstract: A method and apparatus for pre-treating a cellulosic feedstock are disclosed. Embodiments of the method comprise conveying the cellulosic feedstock through an enclosed volume, adding moisture to the cellulosic feedstock simultaneously at multiple spaced-apart moisture injection points as the cellulosic feedstock travels through the volume, and heating the cellulosic feedstock as it travels through the volume to obtain a heated moistened feedstock. Embodiments of the apparatus comprise a shell defining a treatment chamber having a lower inner surface. The treatment chamber has an inlet and an outlet spaced longitudinally apart from the inlet to define an axial length. A conveyance member is housed within the shell and is configured to sweep the lower inner surface. A plurality of injection ports are provided in at least one of the shell and the conveyance member.Type: ApplicationFiled: July 29, 2008Publication date: February 4, 2010Applicant: SUNOPTA BIOPROCESS INC.Inventors: Murray J. Burke, Sunalie N. Hillier
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Publication number: 20100024806Abstract: A method and apparatus for preparing a cellulosic feedstock are disclosed. Embodiments of the method comprise obtaining a cellulosic feedstock having a moisture content of 30 wt % to 60 wt %; passing the cellulosic feedstock through a heated holding tank; withdrawing the cellulosic feedstock from the holding tank; and, subsequently subjecting the cellulosic feedstock to hydrolysis. Embodiments of the apparatus comprise at least one sidewall defining a volume having an upper portion and a lower portion. At least one inlet is provided adjacent the upper portion, and the inlet is in fluid communication with an impregnation chamber provided upstream from the holding tank. At least one outlet is provided adjacent the lower portion, and the outlet is in fluid communication with hydrolysis reactor positioned downstream from the holding tank. At least one conveyor is positioned adjacent the at least one outlet. A heating jacket provided on at least a portion of the apparatus.Type: ApplicationFiled: July 29, 2008Publication date: February 4, 2010Applicant: SUNOPTA BIOPROCESS INC.Inventors: Murray J. Burke, Sunalie N. Hillier
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Publication number: 20100024807Abstract: A method and apparatus for treating a cellulosic feedstock, such as for subsequent ethanol production, are disclosed. The method comprises determining an initial moisture content of the cellulosic feedstock and adding an amount of moisture to the cellulosic feedstock to obtain a predetermined moisture content of the cellulosic feedstock, wherein the cellulosic feedstock may subsequently be subjected to hydrolysis. The apparatus comprises a moisture sensor that provides an initial moisture content reading of the cellulosic feedstock, and a weight sensor providing the weight of the cellulosic feedstock. A processor is configured to determine an amount of moisture to be added to the cellulosic feedstock based on the weight and the initial moisture content of the cellulosic feedstock to obtain treated cellulosic feedstock having a predetermined moisture content.Type: ApplicationFiled: July 29, 2008Publication date: February 4, 2010Applicant: SUNOPTA BIOPROCESS INC.Inventors: Murray J. Burke, Sunalie N. Hillier
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Publication number: 20100024809Abstract: A method and apparatus for preparing a cellulosic feedstock are disclosed. Embodiments of the method comprise passing the cellulosic feedstock through an optional impregnation chamber to an outlet of the impregnation chamber, passing the cellulosic feedstock from the outlet of the impregnation chamber to a holding tank having an inlet and an outlet, and conveying the cellulosic feedstock downwardly and laterally as it travels through the holding tank. Embodiments of the apparatus comprise at least one sidewall defining a passage. The passage has an upper portion and a lower portion, and the lower portion has a greater cross-sectional area than the upper portion. At least one inlet is provided adjacent the upper portion, and at least one outlet is provided adjacent the lower portion, at an elevation below the inlet.Type: ApplicationFiled: July 29, 2008Publication date: February 4, 2010Applicant: SUNOPTA BIOPROCESS INC.Inventors: Murray J. Burke, Sunalie N. Hillier
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Publication number: 20100024810Abstract: The present invention provides a process for treating biomass to produce sugars. The process is directed to decrystallizing cellulose by contacting biomass with an acid mixture comprising sulfuric acid and phosphoric acid at particular molar ratios. Following decrystallization, the biomass may be hydrolyzed with the acid mixture to produce a saccharification product comprising sugars.Type: ApplicationFiled: July 20, 2009Publication date: February 4, 2010Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: MARK ANDREW HARMER, Ann Y. Liauw
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Publication number: 20090320831Abstract: The invention provides polynucleotides, preferably synthetic polynucleotides, which encode processing enzymes that are optimized for expression in plants. The polynucleotides encode mesophilic, thermophilic, or hyperthermophilic processing enzymes, which are activated under suitable activating conditions to act upon the desired substrate. Also provided are “self-processing” transgenic plants, and plant parts, e.g., grain, which express one or more of these enzymes and have an altered composition that facilitates plant and grain processing. Methods for making and using these plants, e.g., to produce food products having improved taste and to produce fermentable substrates for the production of ethanol and fermented beverages are also provided.Type: ApplicationFiled: August 20, 2009Publication date: December 31, 2009Applicant: SYNGENTA PARTICIPATIONS AGInventors: Michael B. Lanahan, Shib S. Basu, Christopher J. Batie, Wen Chen, Joyce Craig, Mark Kinkema
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Patent number: 7632479Abstract: A process for producing ammonia and sulfuric acid from a stream comprising ammonium sulfate is provided. The process comprises the steps of heating the stream to produce ammonia and a decomposition product comprising one or more than one of a bisulfate salt, a pyrosulfate salt, or a combination thereof. The ammonia produced is recovered, and water is added to the decomposition product to produce a stream comprising the decomposition product. The stream comprising the decomposition product is processed by acid retardation to obtain a sulfuric acid stream and a stream comprising one or more than one sulfate salt.Type: GrantFiled: August 29, 2007Date of Patent: December 15, 2009Assignee: Iogen Energy CorporationInventors: Meredith Curren, Brian Foody, Jeff Tolan
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Publication number: 20090229599Abstract: Embodiments of the present invention overcome the well-known recalcitrance of lignocellulosic biomass in an economically viable manner. A process and a system are provided for the efficient fractionation of lignocellulosic biomass into cellulose, hemicellulose, and lignin. The cellulose and hemicellulose thus obtained are highly amorphous and can be readily converted into highly concentrated mixtures of five and six carbon sugars using known methods. Typical yields of sugars exceed 100 grams of sugars per liter of sugar solution. Other products, such as alcohols, can easily be prepared according to methods of the invention. The modest process conditions and low solvent/solid ratios of some embodiments of the invention require relatively low capital and processing costs.Type: ApplicationFiled: March 16, 2009Publication date: September 17, 2009Inventor: Y.H. Percival ZHANG
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Publication number: 20090226979Abstract: A method for the hydrolysis of cellulosic materials using spent liquor. The spent liquor is derived from a pulping operation or is hydrolyzate from another cellulosic biomass process. The process can be implemented in a batch or semi continuous or continuous process. The hydrolyzate is fermented to a useful product and purified. Combustible biomass residues and chemicals are used to provide energy and chemical recovery.Type: ApplicationFiled: March 3, 2009Publication date: September 10, 2009Inventors: Theodora Retsina, Vesa Pylkkanen
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Patent number: 7585652Abstract: A method for recovering inorganic salt during processing of a lignocellulosic feedstock is provided. The method comprises pretreating the lignocellulosic feedstock by adding an acid to the feedstock to produce a pretreated lignocellulosic feedstock. A soluble base is then added to the pretreated lignocellulosic feedstock to adjust the pH and produce a neutralized feedstock. The neutralized feedstock is then enzymatically hydrolyzed to produce an enzyme hydrolyzed feedstock and a sugar stream. Inorganic salt is recovered from either a stream obtained from the lignocellulosic feedstock prior to the step of pretreating, a stream obtained from the pretreated lignocellulosic feedstock, a stream obtained from the neutralized feedstock, a stream obtained from the sugar stream, or a combination of these streams. The inorganic salt may be concentrated, clarified, recovered and purified by crystallization, electrodialysis drying, or agglomeration and granulation, and then used as desired, for example as a fertilizer.Type: GrantFiled: April 13, 2005Date of Patent: September 8, 2009Assignee: Iogen Energy CorporationInventors: Brian Foody, Jeffrey S. Tolan, Ziyad Rahme, Vijay Anand
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Publication number: 20090221042Abstract: A process for the treatment of biomass to render structural carbohydrates more accessible and/or digestible using concentrated ammonium hydroxide with or without anhydrous ammonia addition, is described. The process preferably uses steam to strip ammonia from the biomass for recycling. The process yields of monosaccharides from the structural carbohydrates are good, particularly as measured by the enzymatic hydrolysis of the structural carbohydrates. The monosaccharides are used as animal feeds and energy sources for ethanol production.Type: ApplicationFiled: April 30, 2007Publication date: September 3, 2009Inventors: Bruce E. Dale, Lee R. Lynd, Mark Laser
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Publication number: 20090217922Abstract: A catalyst for cellulose hydrolysis and/or the reduction of hydrolysis products, in which a transition metal of group 8 to 11 is supported on a solid support. A method of producing sugar alcohols comprising: hydrolyzing cellulose in the presence of the catalyst in a hydrogen-containing atmosphere with pressurization; and reducing the hydrolysis product of cellulose. Provided are a catalyst for use in the production of sugar alcohols by the hydrolysis and hydrogenation of cellulose that affords easy separation of catalyst and product, and that does not require pH adjustment, acid or alkali neutralization, or activation of the catalyst during reuse, and a method of producing sugar alcohols from cellulose employing this catalyst.Type: ApplicationFiled: March 1, 2007Publication date: September 3, 2009Inventors: Atsushi Fukuoka, Paresh Dhepe
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Publication number: 20090178671Abstract: The present invention provides a method for treatment of lignocellulosic organic waste or biomass, by which the carbohydrates are rendered more available for subsequent hydrolysis, e.g. by means of addition of enzymes or direct fermentation to one or more desired products. The invention more specifically relates to a method comprising a combination of the following process steps: thermal hydrolysis, wet oxidation and wet explosion. The method according to the present invention can operate with undivided or only poorly divided substrate having a high dry matter concentration.Type: ApplicationFiled: September 23, 2005Publication date: July 16, 2009Inventors: Birgitte Kiaer Ahring, Jens Munck
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Patent number: 7514552Abstract: A cellulose powder which has an average degree of polymerization of 150 to 450, an average particle diameter of 30 to 250 ?m, an apparent specific volume exceeding 7 cm3/g, and a retention of polyethylene glycol having a molecular weight of 400 to 190% or higher.Type: GrantFiled: May 28, 2004Date of Patent: April 7, 2009Assignee: Asahi Kasei Chemicals CorporationInventors: Naoaki Yamasaki, Kazuhiro Obae, Ichiro Ibuki
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Patent number: 7507391Abstract: Sulphur oxides are generated from a liquid stream of hydrogen sulphide by feeding the liquid stream to a vacuum stripper where the stream is contacted with a stripping gas including steam under reduce pressure. Hydrogen sulphide is transferred to the stripping gas, whereby a loaded stripping gas is obtained. Water in the loaded stripping gas is condensed producing a H2S rich stream. The H2S is then burned in the stream to produce a stream rich in oxides of sulphur.Type: GrantFiled: August 10, 2007Date of Patent: March 24, 2009Assignee: Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Onderzoek TNOInventors: Jacob Hendrik Obbo Hazewinkel, Johannes Wouterus Van Groenestijn, Koen Peter Henri Meesters
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Patent number: 7503981Abstract: Disclosed is a method for removing minerals from a cellulosic biomass. For example, the biomass may be prewashed with an acid solution and rinsed with water to remove minerals prior to acid saccharification. The removal of minerals may reduce overall acid requirements, and decrease pretreatment costs.Type: GrantFiled: December 2, 2005Date of Patent: March 17, 2009Assignee: The Trustees of Dartmouth CollegeInventors: Charles E. Wyman, Todd A. Lloyd
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Patent number: 7501025Abstract: The invention is directed to a process for the conversion of cellulosic biomass, in particular lignocellulose-containing biomass into fermentable sugars. The invention is further directed to apparatus suitable for carrying out such processes. According to the invention biomass is converted into fermentable sugars by contacting in a reactor said biomass with an acid, while passing an inert gas stream capable of taking up water through said reactor, by which the pH in said reactor can be controlled.Type: GrantFiled: August 10, 2007Date of Patent: March 10, 2009Assignees: Agrotechnology & Food Innovations B.V., Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Onderzoek TNO, Techno Invent Ingenieursbureau voor Milieutechniek B.V.Inventors: Robert Reurd C. Bakker, Jacob Hendrik O. Hazewinkel, Johannes Wouterus Van Groenestijn
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Publication number: 20090050134Abstract: A method for treating biomass was developed that uses an apparatus which moves a biomass and dilute aqueous ammonia mixture through reaction chambers without compaction. The apparatus moves the biomass using a non-compressing piston. The resulting treated biomass is saccharified to produce fermentable sugars.Type: ApplicationFiled: August 22, 2007Publication date: February 26, 2009Inventors: Julie Friend, Richard T. Elander, Melvin P. Tucker, III, Robert C. Lyons
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Publication number: 20090020112Abstract: The present invention describes a process for the degradation of cellulose by dissolving the cellulose in an ionic liquid and treating it at elevated temperature, if appropriate in the presence of water.Type: ApplicationFiled: February 28, 2007Publication date: January 22, 2009Applicant: BASF SEInventors: Klemens Massonne, Giovanni D'Andola, Veit Stegmann, Werner Mormann, Markus Wezstein, Wei Leng, Stephan Freyer
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Publication number: 20090023187Abstract: A process for obtaining a product sugar stream from cellulosic biomass is disclosed. In one process, the cellulosic biomass is pretreated at a pH between about 0.4 to 2.0 by adding one or more than one acid to produce a pretreated cellulosic biomass comprising acetic acid. One or more than one base is then added to the pretreated cellulosic biomass to adjust the pretreated cellulosic biomass to a pH of about 4.0 to about 6.0 to produce a neutralized cellulosic biomass comprising inorganic salt and acetate salt. The neutralized biomass is then hydrolyzed by cellulase enzymes to produce a crude sugar stream. Insoluble residue is separated from the crude sugar stream and the resulting clarified sugar stream is treated using ion exclusion chromatography at about pH 5.0 to about 10.0 to produce one or more raffinate streams and a product stream. The raffinate stream comprises inorganic salts and acetate salts, and the product stream comprises sugar.Type: ApplicationFiled: July 15, 2005Publication date: January 22, 2009Applicant: Iogen Energy CorporationInventors: Brian Foody, Jeffrey S. Tolan
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Publication number: 20080299628Abstract: A modular process for organosolv fractionation of lignocellulosic feedstocks into component parts and further processing of said component parts into at least fuel-grade ethanol and four classes of lignin derivatives. The modular process comprises a first processing module configured for physico-chemically digesting lignocellulosic feedstocks with an organic solvent thereby producing a cellulosic solids fraction and a liquid fraction, a second processing module configured for producing at least a fuel-grade ethanol and a first class of novel lignin derivatives from the cellulosic solids fraction, a third processing module configured for separating a second class and a third class of lignin derivatives from the liquid fraction and further processing the liquid fraction to produce a distillate and a stillage, a fourth processing module configured for separating a fourth class of lignin derivatives from the stillage and further processing the stillage to produce a sugar syrup.Type: ApplicationFiled: August 15, 2007Publication date: December 4, 2008Applicant: Lignol Energy CorporationInventors: Christer Hallberg, Donald O'Connor, Michael Rushton, Edward Kendall Pye, Gordon Gjennestadt
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Patent number: 7455997Abstract: A process of producing fermentation product comprising the steps of, (i) forming an acidified suspension of particulate plant derived material comprising a first polysaccharide which is more readily hydrolysable and a second polysaccharide which is more difficult to hydrolysable, (ii) allowing the first polysaccharide to undergo hydrolysis by action of the acid at a temperature of at least 50° C.Type: GrantFiled: July 28, 2003Date of Patent: November 25, 2008Assignee: Ciba Specialty Chemicals Water Treatments LtdInventor: Jonathan Hughes
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Patent number: 7442359Abstract: The invention is directed to a process for the recovery of sulphuric acid from a mixture comprising sulphuric acid and hydrocarbons, in particular carbohydrates. In accordance with the present invention the mixture comprising sulphuric acid and carbohydrates, is contacted with an anion selective membrane, thus producing a sulphuric acid rich filtrate stream and a stream depleted in sulphuric acid.Type: GrantFiled: August 10, 2007Date of Patent: October 28, 2008Assignee: Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Onderzoek TNOInventors: Johannes Wouterus Van Groenestijn, Jacob Hendrik Obbo Hazewinkel, Raymond Johannes Maria Creusen, Koen Peter Henri Meesters
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Publication number: 20080202504Abstract: Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor, said lignocellulosic material being fed in different levels of a reactor and contacted with flows of lignin organic solvent, water and an extremely dilute solution of a strong inorganic acid, for obtaining a liquid phase of hydrolysis extract and a solid phase of non-reacted and non-dissolved material. A controlled steam flow is injected into the different levels of the reactor, so as to provide adequate temperatures of organic solvent and strong inorganic acid and forming the desired products (sugars). A flow of the liquid phase is recirculated in different levels of the reactor, the remainder thereof being withdrawn from the reactor, abruptly cooled with the solvent submitted to evaporation to obtain a concentrate. The lignin is transferred by decantation and the concentrate is transferred to subsequent process steps.Type: ApplicationFiled: October 31, 2006Publication date: August 28, 2008Applicant: Dedini S.A. Industrias De BaseInventor: Antonio Geraldo Proenca Hilst
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Publication number: 20080190013Abstract: The present invention provides a method for converting lignocellulosic material into biofuel. In particular embodiments, the method comprises pre-treating lignocellulosic material by dissolving the material in ionic liquids. The pretreated lignocellulosic material can be isolated, such as by precipitation with a regenerating solvent (e.g., water), and be used directly in the formation of biofuel, including undergoing hydrolysis to form sugar and fermentation to form fuel, such as bioethanol. The ionic liquid can be recycled for further use, such as by evaporation of the water introduced during precipitation, and the recycling provides a route to a hemicellulose rich fraction and an ionic liquid of consistent quality and wood dissolution characteristics. The recovered hemicelluloses are of significant utilization potential toward commodity and specialty applications.Type: ApplicationFiled: February 6, 2008Publication date: August 14, 2008Inventor: Dimitris Argyropoulos
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Publication number: 20080041366Abstract: A process for obtaining one or more than one salt of an organic acid(s), or organic acid(s), from an aqueous sugar stream comprising one or more than one mineral acid and the organic acid(s) is provided. The process comprises introducing the aqueous sugar stream to a separation system comprising one or more beds of anion exchange resin and obtaining a stream therefrom comprising the sugar. The one or more beds of anion exchange resin are then regenerated in one or more stages to produce at least one product stream comprising the organic acid, a salt of the organic acid, or a combination thereof, and a separate outlet stream comprising the mineral acid, a salt of the mineral acid, or a combination thereof. The product stream is then recovered. The separation may be conducted with two separation units, or using a single anion exchange unit.Type: ApplicationFiled: July 6, 2007Publication date: February 21, 2008Applicant: IOGEN ENERGY CORPORATIONInventor: Daphne Wahnon
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Publication number: 20070254348Abstract: A method for the production of fermentable sugars and cellulose from lignocellulosic material in a batch or continuous process. Lignocellulosic material is fractionated in a fashion that cellulose is removed as pulp, cooking chemicals reused, lignin is separated for the production of process energy, hemicelluloses are converted into fermentable sugars, while fermentation inhibitors are removed. High yield production of alcohols or organic acids can be obtained from this method using the final reaction step.Type: ApplicationFiled: April 27, 2007Publication date: November 1, 2007Inventors: Theodora Retsina, Vesa Pylkkanen
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Patent number: 7238242Abstract: A process wherein biomass is compacted at 300 kg/m3 by a helical feeder, degassed, flooded, heated, stirred, and pre-hydrolyzed. The sugar being recovered at a first washing within the reactor with values higher than 90%. The control of the process enables one to produce cellulignin with a high specific surface, 2 m2/g (measured by BET), compared with the value of 0.4 m2/g of non-hydrolyzed biomass, maintain crystallinity of the cellulose fibers, aiming at grinding it into fine particles (f<250 mm), globulizing the lignin, exposing the cellulose to attacks by micro-organisms from cud of ruminants, fungi, bacteria or enzymes in microbiological or enzymatic fermentation.Type: GrantFiled: March 15, 2005Date of Patent: July 3, 2007Assignee: RM Materials Refratarios LTDAInventors: Daltro Garcia Pinatti, Alvaro Guedes Soares