Chromium Containing, But Less Than 9 Percent Patents (Class 148/333)
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Patent number: 11970753Abstract: A method for producing an ultra-high-strength hot-rolled structural steel includes producing a steel alloy with a carbon content not greater than 0.2%, avoiding a diffusive transformation of the austenite by achieving a transformation delay through the addition of manganese, chromium, and boron, and casting the steel alloy. The cast steel alloy is heated and hot rolled to form a steel strip which is then immediately hardened and mechanically straightened to produce mobile dislocations, wherein the boron, manganese and chromium delay diffusive transformation from an austenite structure to achieve formation of a martensite structure during the hardening. The steel strip is then annealed at a temperature between 100 and 200° C.Type: GrantFiled: September 17, 2019Date of Patent: April 30, 2024Assignee: voestalpine Stahl GmbHInventors: Markus Sonnleitner, Martin Klein, Gerhard Hubmer, Helmut Spindler
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Patent number: 11920209Abstract: One aspect, this invention relates to a carbide-free bainite and retained austenite steel including a composition designed and processed such that the carbide-free bainite and retained austenite steel meets property objectives comprising a yield strength in a range of about 1000-2000 MPa, a uniform ductility, a desired total elongation and hole-expansion ratio, a desired level of weldability and an austenite stability designed to have an austenite start temperature Ms? to be equal to an application temperature in range from about 50° C. to ?50° C. The property objectives are design specifications of the carbide-free bainite and retained austenite steel.Type: GrantFiled: March 8, 2019Date of Patent: March 5, 2024Assignee: NORTHWESTERN UNIVERSITYInventors: Kazuhiko Nishioka, Gregory B. Olson
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Patent number: 11917917Abstract: A thermoelectric conversion element that has a power generation layer containing an iron-aluminum based magnetic alloy material containing equal to or more than 70 weight percent of iron and aluminum in total. The power generation layer generates an electromotive force, due to an anomalous Nernst effect that develops in the magnetic alloy material in response to a temperature gradient applied thereto, in a direction intersecting both the magnetization direction of the magnetic alloy material and the direction of the applied temperature gradient.Type: GrantFiled: December 13, 2019Date of Patent: February 27, 2024Assignee: NEC CORPORATIONInventors: Akihiro Kirihara, Yasutomo Omori, Ryohto Sawada, Masahiko Ishida, Koichi Terashima, Yuma Iwasaki, Hiroko Someya
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Patent number: 11913087Abstract: Provided is a high-strength steel sheet having excellent ductility, bendability, and TS of 500 MPa or more, in particular, a high-strength thin steel sheet for cans having a sheet thickness of 0.1 to 0.8 mm, the steel sheet having a chemical composition containing C: 0.03-0.15%, Si: 0.01-0.05%, Mn: more than 0.6% and 1.5% or less, P: 0.025% or less, S: 0.02% or less, Al: 0.01-0.10%, N: 0.0005-0.0100%, Ti: 0.005-0.020%, B: 0.0005-0.0100%, and Nb: 0.0050-0.0200% with the balance being Fe and inevitable impurities, in which the steel sheet has a metallic structure containing, in area ratio, 85% or more of ferrite and 1-10% of martensite, the martensite has a grain size of 5 ?m or less, and a ratio of martensite having a grain size of 2 ?m or less is 80% or more.Type: GrantFiled: October 29, 2018Date of Patent: February 27, 2024Assignee: JFE STEEL CORPORATIONInventors: Fusae Shiimori, Hayato Saito, Nobusuke Kariya, Katsumi Kojima
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Patent number: 11898230Abstract: A high-strength steel sheet according to the present invention includes a specific chemical composition, and a steel structure in which a total area fraction of martensite and bainite in a position of ¼ of a sheet thickness is 95% or more and 100% or less, the balance in a case where the total area fraction is not 100% contains retained austenite, and an area fraction of ferrite in a region extending up to 10 ?m in a sheet thickness direction from a surface is 10% or more and 40% or less, in which a tensile strength is 1320 MPa or more, and a Vickers hardness in a position of 15 ?m in the sheet thickness direction from the surface satisfies a specified formula.Type: GrantFiled: June 10, 2019Date of Patent: February 13, 2024Assignee: JFE Steel CorporationInventors: Shimpei Yoshioka, Yoshihiko Ono
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Patent number: 11859260Abstract: A steel sheet has a predetermined chemical composition, in which a metallographic structure in a surface layer region ranging from a surface to a position of 20 ?m from the surface in a sheet thickness direction consists of ferrite and a secondary phase having a volume fraction of 1.0% to 15.0%, the metallographic structure in an internal region ranging from a position of more than 20 ?m from the surface in the sheet thickness direction to a ¼ thickness position from the surface in the sheet thickness direction consists of ferrite and a secondary phase having a volume fraction of 5.0% to 25.0%, the volume fraction of the secondary phase in the surface layer region is less than the volume fraction of the secondary phase in the internal region, and in the surface layer region, the average grain size of the secondary phase is 0.5 ?m to 4.0 ?m.Type: GrantFiled: January 7, 2020Date of Patent: January 2, 2024Assignee: NIPPON STEEL CORPORATIONInventors: Masahiro Kubo, Hiroyuki Kawata, Masahiro Saito, Kenichiro Otsuka, Masafumi Azuma
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Patent number: 11795520Abstract: A hot-pressed member having excellent bending collapsibility, a method for manufacturing the same, and a method for manufacturing a steel sheet for the hot-pressed member. The hot-pressed member includes a steel sheet as a base material, the steel sheet having a specified chemical composition. The hot-pressed member has a microstructure in which a martensite microstructure is present in a volume fraction of 70% or greater, and a number density of inclusions having a longest diameter of 25 ?m or greater is 0.02/mm2 or less. The hot-pressed member has a tensile strength of 1.8 GPa or greater.Type: GrantFiled: November 21, 2019Date of Patent: October 24, 2023Assignee: JFE STEEL CORPORATIONInventors: Shimpei Yoshioka, Yoshihiko Ono, Katsutoshi Takashima, Takayuki Futatsuka, Kentaro Sato
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Patent number: 11795519Abstract: A cold rolled and heat treated steel sheet, the steel having a composition with, in weight percentage, 0.18%?carbon?0.24%, 1.5%?manganese?2.5%, 1.2%?silicon?2%, 0.01%?aluminum?0.06%, 0.2%?chromium?0.5%, phosphorus?0.02%, sulfur?0.03%, and optionally one or more of the following elements niobium?0.06%, titanium?0.08%, vanadium?0.1%, calcium?0.005% and the balance including iron and unavoidable impurities, the steel sheet having a microstructure having 0% to 15% of tempered martensite, 10% to 15% of residual austenite and optionally up to 30% of ferrite in area fractions, the balance being made of bainite, bainite content being at least 55% and having an internal oxide layer of 3 microns or less on both surfaces of the steel sheet. A manufacturing method and with use of such grade for making vehicle parts is also provided.Type: GrantFiled: November 5, 2018Date of Patent: October 24, 2023Assignee: ArcelorMittalInventor: Jean-Marc Pipard
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Patent number: 11788163Abstract: A high-strength steel sheet includes a steel structure with: ferrite being 35% to 80% and tempered martensite being greater than 5% and 20% or less in terms of area fraction; retained austenite being 8% or more in terms of volume fraction; an average grain size of: the ferrite being 6 ?m or less; and the retained austenite being 3 ?m or less; a value obtained by dividing an area fraction of blocky austenite by a sum of area fractions of lath-like austenite and the blocky austenite being 0.6 or more; a value obtained by dividing, by mass %, an average Mn content in the retained austenite by an average Mn content in the ferrite being 1.5 or more; and a value obtained by dividing, by mass %, an average C content in the retained austenite by an average C content in the ferrite being 3.0 or more.Type: GrantFiled: March 20, 2019Date of Patent: October 17, 2023Assignee: JFE STEEL CORPORATIONInventors: Kazuki Endo, Yoshiyasu Kawasaki, Yuki Toji, Yoshimasa Funakawa, Mai Aoyama
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Patent number: 11761054Abstract: An embodiment of the present invention provides a wire rod and a steel wire which are for springs and have excellent corrosion fatigue resistance properties, and a method for producing same, the wire rod and steel wire containing, in wt %, 0.40-0.70% of C, 1.20-2.30% of Si, 0.20-0.80% of Mn, 0.20-0.80% of Cr, 0.015% or less of P, 0.015% or less of S, and 0.010% or less of N, with the remainder comprising Fe and other unavoidable impurities, along with at least one among 0.01-0.20% of V and 0.01-0.10% of Nb, wherein the V and Nb satisfy relational expression 1 below, the average grain size of prior austenite is no greater than 20 ?m, and the surface decarburization depth is no greater than 0.1 mm. [Relational expression 1] [V]+[Nb]?0.08 (where the V and Nb contents are in wt %).Type: GrantFiled: September 13, 2018Date of Patent: September 19, 2023Assignee: POSCO CO., LTDInventor: Kwan-Ho Kim
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Patent number: 11753693Abstract: Provided is a high-strength cold rolled steel sheet, a high-strength hot-dip galvanized steel sheet manufactured using the cold rolled steel sheet, and manufacturing methods therefor, the high-strength cold rolled steel sheet comprising, by wt %, 0.17-0.21% of carbon (C), 0.3-0.8% of silicon (Si), 2.7-3.3% of manganese (Mn), 0.3-0.7% of chromium (Cr), 0.01-0.3% of aluminum (Al), 0.01-0.03% of titanium (Ti), 0.001-0.003% of boron (B), 0.04% or less of phosphorus (P), 0.02% or less of sulfur (S), 0.01% or less of nitrogen (N) and the balance of iron (Fe) and other inevitable impurities, wherein the amounts of carbon (C), silicon (Si) and aluminum (Al) satisfy the following mathematical relation (1). [Mathematical relation (1)] [C]+([Si]+[Al])/5?0.35% (wherein [C], [Si] and [Al] respectively mean the wt % of C, Si and Al.Type: GrantFiled: September 27, 2019Date of Patent: September 12, 2023Assignee: POSCO CO., LTDInventors: Young-Roc Im, Jong-Chan Park, Jai-Hyun Kwak, Min-Seo Koo
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Patent number: 11724338Abstract: A hot-stamped article and method of manufacturing same use a tailor welded blank (TWB) method capable of controlling the microstructure of a weld portion to prevent fracture of the weld portion. The hot-stamped article is manufactured by welding a first sheet and a second sheet made of different kinds of materials to each other using the TWB method and hot-stamping a welded sheet. The first sheet and the second sheet have different upper austenite transformation temperatures (A3 temperatures), the first sheet and the second sheet are welded to each other via a weld portion, each of the first sheet and the weld portion has a composite structure comprising ferrite, bainite, and martensite, and the second sheet has a martensite structure.Type: GrantFiled: April 30, 2021Date of Patent: August 15, 2023Assignees: HYUNDAI MOTOR COMPANY, KIA CORPORATIONInventors: Chang Wook Lee, Yeon Jung Hwang
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Patent number: 11713502Abstract: A method for producing a high-strength steel sheet having high ductility, formability and weldability includes providing a cold-rolled sheet, with a composition containing: 0.15% ?C?0.23%, 1.4% ?Mn?2.6%, 0.6% ?Si?1.3%, with C+Si/10?0.30%, 0.4% ?Al?1.0%, with Al?6(C+Mn/10)?2.5%, 0.010% ?Nb?0.035%, 0.1% ?Mo?0.5%, annealing the sheet at 860° C.-900° C. to obtain a structure consisting of at least 90% austenite and at least 2% intercritical ferrite, quenching to a temperature between Ms-10° C. and Ms-60° C. at a rate Vc higher than 30° C./s, heating to a temperature PT between 410° C. and 470° C. for 60 s to 130 s, hot-dip coating the sheet, and cooling to room temperature. The microstructure includes 45% to 68% of martensite, consisting of 85% to 95% partitioned martensite having a C content of at most 0.45%, and fresh martensite; 10% to 15% retained austenite; 2% to 10% intercritical ferrite; 20% to 30% lower bainite.Type: GrantFiled: May 7, 2018Date of Patent: August 1, 2023Assignee: ARCELORMITTALInventors: Pavan C. Venkatasurya, Anirban Chakraborty, Hassan Ghassemi-Armaki
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Patent number: 11692254Abstract: Novel High-Entropy Alloy (HEA) compositions are particularly suited to welding applications. The mixtures contain at least the elements nickel, manganese, cobalt, chromium, vanadium, molybdenum, and iron. The % weight of the constituents varies in accordance with the detailed description contained herein, with tolerances in the range of ±4% for major alloying elements and ±1% for minor alloying elements. The mixture may also contain a small amount of Aluminum, Titanium, and Boron with a tolerance in the range of +/?1% or, more preferably, +/?0.5% In accordance with the invention, the compositions above may be integrated into HEA welding products using cored wire and welding electrode manufacturing techniques, preferably starting with vacuum melted rolled alloys. One manufacturing process uses the compositions as an alloyed strip formed around the appropriate ground/crushed alloys to make commercially viable fabricated welding products.Type: GrantFiled: September 3, 2021Date of Patent: July 4, 2023Inventors: Darryl Hammock, Prabir Chaudhury
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Patent number: 11661642Abstract: A high-strength steel sheet includes a steel structure with: ferrite being 35% to 80%, martensite being 5% to 35%, and tempered martensite being 0% to 5% in terms of area fraction; retained austenite being 8% or more in terms of volume fraction; an average grain size of: the ferrite being 6 ?m or less; and the retained austenite being 3 ?m or less; a value obtained by dividing an area fraction of blocky austenite by a sum of area fractions of lath-like austenite and the blocky austenite being 0.6 or more; a value obtained by dividing, by mass %, an average Mn content in the retained austenite by an average Mn content in the ferrite being 1.5 or more; and a value obtained by dividing, by mass %, an average C content in the retained austenite by an average C content in the ferrite being 3.0 or more.Type: GrantFiled: March 20, 2019Date of Patent: May 30, 2023Assignee: JFE STEEL CORPORATIONInventors: Kazuki Endo, Yoshiyasu Kawasaki, Yuki Toji, Yoshimasa Funakawa, Mai Aoyama
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Patent number: 11655514Abstract: The invention relates to a turnout rail production technology, in particular to a deeply-hardened-surface turnout rail with high degree of undercooling and the preparation method thereof. The invention aims to solve the technical problem by providing a deeply-hardened-surface turnout rail with high degree of undercooling featured in even hardness distribution and a deeply hardened surface layer and the preparation method thereof. The method is described as follows: feeding molten iron for converter smelting?furnace rear argon blowing station?LF refining?RH vacuumization?casting steel blanks?slow cooling in the slow cooling pit?austenitic homogenization?rail rolling?heat treatment; in the converter smelting process, adding 0.2-0.3% Cr, 0.04-0.06 V and 0.75-0.80% C; the heat treatment process is divided into two cooling stages.Type: GrantFiled: October 25, 2021Date of Patent: May 23, 2023Assignee: PANGANG GROUP PANZHIHUA IRON & STEEL RESEARCH INSTITUTE CO., LTD.Inventors: Jun Yuan, Ming Zou, Yong Deng, Ruoxi Li
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Patent number: 11649522Abstract: A method for producing a zinc or zinc-alloy coated steel sheet with a tensile strength higher than 900 MPa, for the fabrication of resistance spot welds containing in average not more than two Liquid Metal Embrittlement cracks per weld having a depth of 100 ?m or more, with steps of providing a cold-rolled steel sheet, heating cold-rolled steel sheet up to a temperature T1 between 550° C. and Ac1+50° C. in a furnace zone with an atmosphere (A1) containing from 2 to 15% hydrogen by volume, so that the iron is not oxidized, then adding in the furnace atmosphere, water steam or oxygen with an injection flow rate Q higher than (0.07%/h×?), ? being equal to 1 if said element is water steam or equal to 0.52 if said element is oxygen, at a temperature T?T1, so to obtain an atmosphere (A2) with a dew point DP2 between ?15° C. and the temperature Te of the iron/iron oxide equilibrium dew point, then heating the sheet from temperature T1 up to a temperature T2 between 720° C. and 1000° C.Type: GrantFiled: June 13, 2018Date of Patent: May 16, 2023Assignee: ArcelorMittalInventors: Jean-Marc Pipard, Sebastien Cremel, Anirban Chakraborty, Damon Panahi, Olga Girina, Hassan Ghassemi-Armaki, Pavan Challa Venkata Surya, Yacine Benlatreche
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Patent number: 11643700Abstract: A high-strength steel includes a steel structure with: in area fraction, 60.0% to less than 90.0% of ferrite, 0% to less than 5.0% of unrecrystallized ferrite, 2.0% to 25.0% of martensite, 0% to 5.0% of carbide, and 0% to 3.0% of bainite; in volume fraction, more than 7.0% of retained austenite; in a cross-sectional view of 100 ?m×100 ?m, a value obtained by dividing number of retained austenite that are not adjacent to retained austenite whose crystal orientations are different by a total number of retained austenite being less than 0.80, an average crystal grain size of the ferrite being 6.0 ?m or less, an average crystal grain size of the retained austenite being 3.0 ?m or less, and a value obtained by dividing, by mass %, an average content of Mn in the retained austenite by an average content of Mn in steel being 1.50 or more.Type: GrantFiled: March 20, 2019Date of Patent: May 9, 2023Assignee: JFE STEEL CORPORATIONInventors: Yoshiyasu Kawasaki, Kazuki Endo, Yuki Toji, Yoshimasa Funakawa, Satoshi Maeda, Mai Aoyama
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Patent number: 11628512Abstract: Disclosed is a clad steel plate with further improved low temperature toughness along with excellent HIC resistance while ensuring a tensile strength of 535 MPa or more. A clad steel plate includes: a base steel; and a clad metal made of a corrosion resistant alloy bonded to one surface of the base steel, in which the base steel has: a chemical composition with appropriately controlled values of ACR and PHIC; and a steel microstructure in which bainite is present in an area fraction of 94% or more at a ½ thickness position in a thickness direction of the base steel, and with an average crystal grain size of 25 ?m or less, and shear strength at a bonded interface between the base steel and the cladding metal is 300 MPa or more.Type: GrantFiled: June 25, 2019Date of Patent: April 18, 2023Assignee: JFE STEEL CORPORATIONInventors: Ryosuke Sakai, Yota Kuronuma, Junji Shimamura, Tomoyuki Yokota
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Patent number: 11591665Abstract: A cold-rolled and heat treated steel sheet, has a composition comprising 0.1%?C?0.4%, 3.5%?Mn?8.0%, 0.1%?Si?1.5%, Al?3%, Mo?0.5%, Cr?1%, Nb?0.1%, Ti?0.1%, V?0.2%, B?0.004%, 0.002%?N?0.013%, S?0.003%, P?0.015%. The structure consists of, in surface fraction: between 8 and 50% of retained austenite, at most 80% of intercritical ferrite, the ferrite grains, if any, having an average size of at most 1.5 ?m, and at most 1% of cementite, the cementite particles having an average size lower than 50 nm, martensite and/or bainite.Type: GrantFiled: December 18, 2018Date of Patent: February 28, 2023Assignee: ARCELORMITTALInventors: Coralie Jung, Astrid Perlade, Kangying Zhu, Frédéric Kegel
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Patent number: 11583909Abstract: A method of manufacturing a hot-stamped part includes: inserting a blank into a heating furnace including a plurality of sections with different temperature ranges; step heating the blank in multiple stages; and soaking the blank at a temperature of about Ac3 to about 1,000° C., wherein in the step of heating the blank, a temperature condition in the heating furnace satisfies the following equation: 0<(Tg?Ti)/Lt<0.025° C./mm, where Tg denotes a soaking temperature (° C.), Ti denotes an initial temperature (° C.) of the heating furnace, and Lt denotes a length (mm) of step heating sections.Type: GrantFiled: December 2, 2020Date of Patent: February 21, 2023Assignee: Hyundai Steel CompanyInventor: Je Youl Kong
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Patent number: 11572600Abstract: A structural steel having excellent brittle crack propagation resistance, according to one aspect of the present invention, comprises, by wt %, 0.02-0.12% of C, 0.01-0.8% of Si, 1.7-2.5% of Mn, 0.005-0.5% of Al, and the balance of Fe and inevitable impurities, wherein an outer surface part and an inner center part thereof are microstructurally distinguished in the thickness direction, and the surface part comprises tempered bainite as a base structure, comprises fresh martensite as a second structure and can comprise austenite as a residual structure.Type: GrantFiled: November 30, 2018Date of Patent: February 7, 2023Assignee: POSCO CO., LTDInventors: Jae-Young Cho, Il-Cheol Yi, Sang-Deok Kang
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Patent number: 11565299Abstract: The entirety or a part of this hot stamped product includes, as a chemical composition, by mass %, C: 0.001% or more and less than 0.080%, Si: 2.50% or less, Mn: 0.01% or more and less than 0.50%, P: 0.200% or less, S: 0.0200% or less, sol.Al: 0.001% to 2.500%, N: 0.0200% or less, Cr: 0.30% or more and less than 2.00%, and a remainder: Fe and impurities, in which a metallographic structure contains, by vol %, ferrite: more than 60.0%, martensite: 0% or more and less than 10.0%, and bainite: 0% or more and less than 20.0%, a tensile strength is less than 700 MPa, and ?TS, which is a decrease in the tensile strength after a heat treatment at 170° C. for 20 minutes, is 100 MPa or less.Type: GrantFiled: October 2, 2018Date of Patent: January 31, 2023Assignee: NIPPON STEEL CORPORATIONInventors: Jun Haga, Kazuo Hikida
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Patent number: 11535905Abstract: The invention relates to the use of a Q&P steel for production of a formed component (2) for high-wear applications, wherein the Q&P steel has a hardness of at least 230 HB, especially at least 300 HB, preferably at least 370 HB, and a bending angle ? of at least 60°, especially at least 75°, preferably at least 85°, determined to VDA238-100, and/or a bending ratio of r/t<2.5, especially r/t<2.0, preferably r/t<1.5, where t corresponds to the material thickness of the steel and r to the (inner) bending radius of the steel.Type: GrantFiled: August 22, 2017Date of Patent: December 27, 2022Assignee: thyssenkrupp AGInventors: Nina Kolbe, Patrick Kuhn, Clemens Latuske, Richard Georg Thiessen
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Patent number: 11512362Abstract: A method for producing a coated steel sheet having a tensile strength TS of at least 1450 MPa and a total elongation TE of at least 17% includes the successive steps of providing a cold rolled steel sheet made of a steel having a chemical composition comprising, in weight %: 0.34%?C?0.45%, 1.50%?Mn?2.30%, 1.50?Si?2.40%, 0%<Cr?0.7%, 0%?Mo?0.3%, 0.10%?Al?0.7%, and optionally 0%?Nb?0.05%, the remainder being Fe and unavoidable impurities, annealing the cold-rolled steel sheet at an annealing temperature AT higher than the Ac3 transformation point of the steel, quenching the annealed steel sheet by cooling it down to a quenching temperature QT lower than the Ms transformation point of the steel and comprised between 150° C. and 250° C., and reheating the quenched steel sheet to a partitioning temperature PT between 350° C. and 450° C.Type: GrantFiled: November 2, 2020Date of Patent: November 29, 2022Assignee: ARCELORMITTALInventors: Olga A. Girina, Damon Panahi
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Patent number: 11492679Abstract: This hot-rolled steel sheet has a predetermined chemical composition, in which in a case where the thickness is denoted by t, a metallographic structure at a t/4 position from the surface includes, by area fraction, 77.0% to 97.0% of bainite or tempered martensite, 0% to 5.0% of ferrite, 0% to 5.0% of pearlite, 3.0% or more of residual austenite, and 0% to 10.0% of martensite, in the metallographic structure, the average grain size excluding the residual austenite is 7.0 ?m or less, the average number density of iron-based carbides having a diameter of 20 nm or more is 1.0×106 carbides/mm2 or more, a tensile strength is 980 MPa or more, and an average Ni concentration on the surface is 7.0% or more.Type: GrantFiled: October 21, 2019Date of Patent: November 8, 2022Assignee: NIPPON STEEL CORPORATIONInventors: Tatsuo Yokoi, Hiroshi Shuto, Teruki Hayashida, Jun Ando, Mutsumi Sakakibara
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Patent number: 11473162Abstract: The invention relates to a carburizing bearing steel and a preparation method thereof. The carburizing bearing steel of the invention comprises: 0.18˜0.24 wt % of C, 0.4˜0.6 wt % of Cr, 0.20˜0.40 wt % of Si, 0.40˜0.70 wt % of Mn, 1.6˜2.2 wt % of Ni, 0.15˜0.35 wt % of Mo, 0.001˜0.01 wt % of S, 0.001˜0.015 wt % of P, 0˜0.20 wt % of Nb, 0˜0.20 wt % of V and the remaining is iron, wherein the contents of Nb and V are not 0 at the same time. In the invention, an appropriate amount of Nb and V is added in combination with other elements so as to refine the grain size, inhibit the generation of large granular carbides in the steel during carburization and improve the uniformity of the microstructure of steel materials, thus further enhancing the contact fatigue life of the carburizing bearing steel.Type: GrantFiled: February 26, 2021Date of Patent: October 18, 2022Assignee: CENTRAL IRON & STEEL RESEARCH INSTITUTEInventors: Wenquan Cao, Feng Yu, Cunyu Wang, Haifeng Xu, Hui Wang, Da Xu, Yuqing Weng
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Patent number: 11466336Abstract: Provided is a high-strength steel sheet having excellent burring workability in a low temperature range, which is mainly used for automobile chassis parts such as members, lower arms, wheel disks, etc.; and a manufacturing method therefor.Type: GrantFiled: November 30, 2017Date of Patent: October 11, 2022Assignee: POSCOInventors: Seok-Jong Seo, Sung-Il Kim, Hyun-Taek Na
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Patent number: 11447844Abstract: A method for the fabrication of a hot rolled steel includes providing a liquid metal comprising a certain chemical composition; carrying out a vacuum or SiCa treatment, the chemical composition including, expressed by weight 0.0005%?Ca?0.005%, if a SiCA treatment is carried out; dissolving quantities of Ti and N in the liquid metal so as to satisfy (% [Ti])×(% [N])<6.10?4%2; casting the steel to obtain a cast semi-finished product; rolling the cast semi-finished product with an end-of-rolling temperature between 880° C. and 930° C., a reduction rate of the penultimate pass being less than 0.25, and a start-of-rolling temperature of the penultimate pass being less than 960° C. to obtain a hot-rolled product, then cooling the hot rolled product at a rate between 20 and 150° C./s to obtain a hot rolled steel sheet; and coiling the hot rolled product to obtain a hot rolled steel sheet.Type: GrantFiled: November 3, 2020Date of Patent: September 20, 2022Assignee: ArcelorMittalInventors: Jean Marc Pipard, Astrid Perlade, Bastien Weber, Florence Pechenot, Aurelie Milani
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Patent number: 11415599Abstract: A contact probe may include a Ni pipe that may include a coiled spring structure, and the Ni pipe 11 may contain 0.5 to 10 wt % of phosphorus (P). The contact probe may have improved durability, by reducing shrinkage, after probing performed in a high temperature environment.Type: GrantFiled: October 4, 2017Date of Patent: August 16, 2022Assignee: NIDEC READ CORPORATIONInventors: Masami Yamamoto, Norihiro Ota, Shigeki Sakai
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Patent number: 11390936Abstract: There is provided a spring steel including predetermined chemical composition, in which ([Ti mass %]?3.43×[N mass %])/[S mass %]>4.0, and [Ni mass %]+[Cu mass %]<0.75 are satisfied, and an appearance frequency of MnS is less than 20% among inclusions having an equivalent circle diameter of 1 ?m or more which are observed at a ¼ position of a diameter from a surface.Type: GrantFiled: January 26, 2017Date of Patent: July 19, 2022Assignee: NIPPON STEEL CORPORATIONInventors: Takahisa Suzuki, Suguru Yoshida, Yutaka Neishi
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Patent number: 11390930Abstract: A steel sheet and a manufacturing method therefor are provided. A steel sheet has a component composition and contains 6 to 80% of ferrite and 20 to 94% of a microstructure composed of one or two or more of upper bainite, fresh martensite, tempered martensite, lower bainite, and retained ?, and contains 7 to 20% of retained ?, where: an area ratio (S?UB) of retained ? having a particle width of 0.18 to 0.60 ?m, a particle length of 1.7 to 7.0 ?m, and an aspect ratio of 5 to 15 is 0.2 to 5%; and a total area ratio (S?Block) of fresh martensite having an equivalent circle diameter of 1.5 to 15 ?m and an aspect ratio of 3 or less and/or retained ? particles having an equivalent circle diameter of 1.5 to 15 ?m and an aspect ratio of 3 or less is 3% or less (including 0%).Type: GrantFiled: April 13, 2018Date of Patent: July 19, 2022Assignee: JFE STEEL CORPORATIONInventors: Yoshihiko Ono, Junya Tobata, Hiroyuki Akimoto
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Patent number: 11365460Abstract: A high-carbon cold rolled steel sheet having a specified chemical composition, and a method for manufacturing the same. The method includes forming a hot rolled steel sheet, performing cooling at an average cooling rate of 30° C./s or more and 70° C./s or less through a temperature range of a finish rolling end temperature to 660° C., coiling a hot rolled steel sheet at a temperature of 500° C. or more and 660° C. or less, and, optionally, pickling the coiled hot rolled steel sheet, and then performing a first box-annealing of holding at an annealing temperature in a temperature range of 650 to 720° C., then performing cold rolling at a rolling reduction ratio of 20 to 50%, and then performing a second box-annealing of holding at an annealing temperature in a temperature range of 650 to 720° C.Type: GrantFiled: February 20, 2019Date of Patent: June 21, 2022Assignee: JFE STEEL CORPORATIONInventors: Yuka Miyamoto, Yoichiro Matsui, Shogo Sato, Takeshi Yokota
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Patent number: 11359267Abstract: Provided are a high-carbon hot-rolled steel sheet with excellent formability and hardenability and a method for manufacturing the same. The high-carbon hot-rolled steel sheet has a composition containing, on a mass basis, C: 0.10% to 0.33%, Si: 0.15% to 0.35%, Mn: 0.5% to 0.9%, P: 0.03% or less, S: 0.010% or less, sol. Al: 0.10% or less, N: 0.0065% or less, and Cr: 0.90% to 1.5%, the remainder being Fe and inevitable impurities, has a microstructure containing ferrite and cementite, a cementite density being 0.25 grains/?m2 or less, and has a hardness of 110 HV to 160 HV and a total elongation of 40% or more.Type: GrantFiled: February 13, 2018Date of Patent: June 14, 2022Assignee: JFE Steel CorporationInventors: Yuka Miyamoto, Yasuhiro Sakurai, Takashi Kobayashi, Shunsuke Toyoda
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Patent number: 11143257Abstract: A steel wire for a spring includes a steel wire that has Ca or Na adhered thereto in an amount of 0.2 g/m2 or less. The steel wire has an oxide film on a surface thereof, and the oxide film has a thickness of, for example, from 2.0 ?m to 20 ?m.Type: GrantFiled: January 24, 2017Date of Patent: October 12, 2021Assignee: Sumitomo Electric Industries, Ltd.Inventors: Takafumi Uwano, Taketoshi Sasaki, Takao Yamazaki
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Patent number: 11111566Abstract: The steel pipe of the present invention is a low alloy high strength seamless steel pipe for oil country tubular goods including a composition containing, in terms of mass %, C: 0.23 to 0.27%, Si: 0.01 to 0.35%, Mn: 0.45 to 0.70%, P: 0.010% or less, S: 0.001% or less, O: 0.0015% or less, Al: 0.015 to 0.080%, Cu: 0.02 to 0.09%, Cr: 0.8 to 1.5%, Mo: 0.5 to 1.0%, Nb: 0.02 to 0.05%, B: 0.0015 to 0.0030%, Ti: 0.005 to 0.020%, and N: 0.005% or less, and having a ratio of the Ti content to the N content (Ti/N) of 3.0 to 4.0, with the balance being Fe and inevitable impurities, the steel pipe having a ratio of a stress at a strain of 0.7% to a stress at a strain of 0.4% in a stress-strain curve of 1.02 or less and a yield strength of 655 MPa or more.Type: GrantFiled: August 22, 2018Date of Patent: September 7, 2021Assignee: JFE Steel CorporationInventors: Mitsuhiro Okatsu, Masao Yuga, Hiroki Ota, Kazuki Fujimura
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Patent number: 11091825Abstract: Provided is a prehardened steel material containing: 0.05?C?0.25 mass %, 0.01?Si?1.00 mass %, 0.40?Mn?1.80 mass %, 0.0002?S?0.3000 mass %, 0.30?Cu?1.80 mass %, 2.00?Ni?3.90 mass %, 0.05?Cr?3.20 mass %, 0.05?Mo?0.80 mass %, and 0.30?Al?1.50 mass %, with a balance being Fe and unavoidable impurities, in which the prehardened steel material has: a cross-sectional size of 350 mm or more in width and 350 mm or more in height, a hardness of 34 to 43 HRC, an average value of prior austenite grain size being 85 ?m or less, and an average value of impact value being 18 J/cm2 or higher.Type: GrantFiled: April 10, 2018Date of Patent: August 17, 2021Assignee: DAIDO STEEL CO., LTD.Inventor: Masamichi Kawano
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Patent number: 11015232Abstract: A seamless steel tube with high strength and toughness, comprising the following chemical elements by mass: 0.1-0.25% of C, 0.1-0.5% of Si, 0.01-0.1% of Al, 0.6-2% of Mn, the balance of Fe and other unavoidable impurities, wherein C+Mn/6?0.35. Also provided is a method for preparing a seamless steel tube.Type: GrantFiled: September 21, 2016Date of Patent: May 25, 2021Assignee: BAOSHAN IRON & STEEL CO., LTD.Inventors: Yaoheng Liu, Zhonghua Zhang
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Patent number: 10995383Abstract: A method for producing a high strength coated steel sheet having a yield strength YS of at least 800 MPa, a tensile strength TS of >1180 MPa, a total elongation >14% and a hole expansion ratio HER >30%. The steel contains in weight %: 0.13%?C?0.22%, 1.2%?Si?1.8%, 1.8%?Mn?2.2%, 0.10%?Mo?0.20%, Nb?0.05%, Al?0.5%, the remainder being Fe and unavoidable impurities. The sheet is annealed at a temperature TA higher than Ac3 but less than 1000° C. for more than 30 s, then quenched by cooling temperature QT between 325° C. and 375° C., at a cooling speed sufficient to obtain a structure consisting of austenite and at least 60% of martensite, the austenite content being such that the final structure can contain between 3% and 15% of residual austenite and between 85 and 97% of the sum of martensite and bainite, without ferrite, then heated to a partitioning temperature PT between 430° C. and 480° C.Type: GrantFiled: July 3, 2015Date of Patent: May 4, 2021Assignee: ARCELORMITTALInventors: Dongwei Fan, Hyun Jo Jun, Rashmi Ranjan Mohanty
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Patent number: 10995396Abstract: A rail according to an aspect of the present invention is manufactured by melting steel using an electric furnace, satisfies a predetermined range as a chemical composition and particularly includes Pb: 0.0003% to 0.0020%, 95 area % or more of a region from an outer surface of a head portion to a depth of 20 mm is a pearlite structure, and a hardness in the region from the outer surface of the head portion to the depth of 20 mm is in a range of Hv 300 to Hv 500.Type: GrantFiled: May 19, 2017Date of Patent: May 4, 2021Assignee: NIPPON STEEL CORPORATIONInventors: Masaharu Ueda, Teruhisa Miyazaki
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Patent number: 10822677Abstract: A forged component having a chemical composition including, by mass %, C: 0.30 to 0.45%, Si: 0.05 to 0.35%, Mn: 0.50 to 0.90%, P: 0.030 to 0.070%, S: 0.040 to 0.070%, Cr: 0.01 to 0.50%, Al: 0.001 to 0.050%, V: 0.25 to 0.35%, Ca: 0 to 0.0100%, N: 0.0150% or less, and the balance being Fe and unavoidable impurities, and satisfying formula 1. Metal structure is a ferrite pearlite structure, and a ferrite area ratio is 30% or more. Vickers hardness is in the range of 320 to 380 HV. 0.2% yield strength is 800 MPa or more. A Charpy V-notch impact value is in the range of 7 to 15 J/cm2.Type: GrantFiled: March 18, 2014Date of Patent: November 3, 2020Assignees: AICHI STEEL CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Takeyuki Uenishi, Susumu Owaki, Hisanori Koma, Tomoyasu Kitano, Kazuhiro Tanahashi, Nobuyuki Shinohara
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Patent number: 10774412Abstract: A hot-dip galvanized cold-rolled steel sheet has a tensile strength of 750 MPa or higher, a composition consisting, in mass percent, C: more than 0.10% and less than 0.25%, Si: more than 0.50% and less than 2.0%, Mn: more than 1.50% and 3.0% or less, and optionally containing one or more types of Ti, Nb, V, Cr, Mo, B, Ca, Mg, REM, and Bi, P: less than 0.050%, S: 0.010% or less, sol. Al: 0.50% or less, and N: 0.010% or less, and a main phase as a low-temperature transformation product and a second phase as retained austenite. The retained austenite volume fraction is more than 4.0% and less than 25.0% of the whole structure, and has an average grain size of less than 0.80 ?m. A number density of retained austenite grains having a grain size of 1.2 ?m or more is 3.0×10?2/?m2 or less.Type: GrantFiled: June 29, 2012Date of Patent: September 15, 2020Assignee: NIPPON STEEL CORPORATIONInventors: Norio Imai, Masayuki Wakita, Takuya Nishio, Jun Haga, Kengo Hata, Yasuaki Tanaka, Mitsuru Yoshida, Hiroshi Takebayashi, Suguhiro Fukushima, Toshiro Tomida
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Patent number: 10494690Abstract: A high strength and toughness seamless steel tube for an automobile airbag, comprising the following elements, by wt %: C: 0.05-0.15%; Si: 0.1-0.45%; Mn: 1.0-1.9%; Ni: 0.1-0.6%; Cr: 0.05-1.0%; Mo: 0.05-0.2%; Cu: 0.05-0.50%; Al: 0.015-0.060%; Nb: 0.02-0.1%; V: 0.02-0.15%; and the balance being Fe and other inevitable impurities. A method for manufacturing the seamless steel tube comprises the steps: (1) heating a tube blank and then soaking; (2) hot piercing, reducing the diameter and the wall thickness of the tube blank with a stretch reducer and then cooling naturally; (3) annealing, pickling, phosphating and saponifying; (4) cold working to obtain a finished product size; and (5) carrying out stress relief annealing treatment.Type: GrantFiled: January 14, 2015Date of Patent: December 3, 2019Assignee: Boashan Iron & Steel Co., Ltd.Inventors: Guoli Zhai, Qingchao Tian, Qijiang Wang, Cailing Liu
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Patent number: 10358708Abstract: A steel plate has a chemical composition containing, by mass %, C: 0.03% or more and 0.08% or less, Si: 0.01% or more and 1.0% or less, Mn: 1.2% or more and 3.0% or less, P: 0.015% or less, S: 0.005% or less, Al: 0.08% or less, Nb: 0.005% or more and 0.07% or less, Ti: 0.005% or more and 0.025% or less, N: 0.010% or less, O: 0.005% or less and the balance being Fe and inevitable impurities, a structure being a dual-phase structure consisting of a bainite phase and island martensite, wherein the area fraction of the island martensite is 3% to 15%, the equivalent circle diameter of the island martensite is 3.0 ?m or less, and the remainder of the structure is a bainite phase.Type: GrantFiled: March 29, 2013Date of Patent: July 23, 2019Assignee: JFE Steel CorporationInventors: Junji Shimamura, Kimihiro Nishimura
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Patent number: 10174399Abstract: A steel wire rod includes required amounts of chemical components and a remainder including Fe and impurities; in which the area ratio of pearlite in a cross section perpendicular to a longitudinal direction is 95% or more and a remainder includes a non-pearlite structure which includes one or more of a bainite, a degenerate pearlite, a proeutectoid ferrite and a proeutectoid cementite; the average block size of the pearlite is 15 ?m to 35 ?m and the area ratio of the pearlite having a block size of 50 ?m or more is 20% or less; and the area ratio of a region where a lamellar spacing of the pearlite is 150 nm or less is 20% or less in a region within a depth from a surface of the steel wire rod of 1 mm or less.Type: GrantFiled: June 23, 2014Date of Patent: January 8, 2019Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Makoto Okonogi, Daisuke Hirakami
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Patent number: 10125405Abstract: A method thermally treats hot rails to obtain a desired microstructure having enhanced mechanical properties. The method includes an active cooling phase where the rail is fast cooled from an austenite temperature and subsequently soft cooled, to maintain a target transformation temperature between defined values. The cooling treatment is performed by a plurality of cooling modules. Each of the cooling modules has a plurality of devices spraying a cooling medium onto the rail. The method is characterized in that during the active cooling phase, each cooling device is driven to control the cooling rate of the rail such that the amount of transformed austenite within the rail is not lower than 50% on the rail surface and not lower than 20% at a rail head core.Type: GrantFiled: June 7, 2013Date of Patent: November 13, 2018Assignee: PRIMETALS TECHNOLOGIES ITALY S.R.L.Inventors: Alberto Gioachino Lainati, Luigi Langellotto, Andrea Mazzarano, Federico Pegorin, Alessio Saccocci, Augusto Sciuccati
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Patent number: 10125412Abstract: A composition includes tungsten (W); at least one element selected form the group of elements consisting of boron (B), beryllium (Be) and silicon (Si); and at least one element selected from the group of elements consisting of titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), hafnium (Hf), tantalum (Ta), rhenium (Re), osmium (Os), iridium (Ir), lithium (Li) and aluminum (Al). The composition satisfies the formula W1-xMxXy wherein X is one of B, Be and Si; M is at least one of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Hf, Ta, Re, Os, Ir, Li and Al; x is at least 0.001 and less than 0.999; and y is at least 4.0. A tool is made from or coated with this composition.Type: GrantFiled: April 23, 2012Date of Patent: November 13, 2018Assignee: The Regents of the University of CaliforniaInventors: Richard B. Kaner, Sarah H. Tolbert, Reza Mohammadi, Andrew T. Lech, Miao Xie
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Patent number: 9957582Abstract: A cold-rolled sheet is provided. The cold-rolled sheet includes a steel substrate with a carbon content C0 between 0.07% and 0.5%, expressed by weight, and a metal pre-coating on at least the two principal faces of the steel substrate. The substrate has a decarburized area on the surface of each of the two principal faces. The depth p50% of the decarburized area is between 6 and 30 micrometers, and p50% is the depth at which the carbon content is equal to 50% of the content C0. The sheet does not contain a layer of iron oxide between the substrate and the metal pre-coating.Type: GrantFiled: May 31, 2017Date of Patent: May 1, 2018Assignee: ArcelorMittalInventors: Juan David Puerta Velasquez, Jonas Staudte, Pascal Drillet
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Patent number: 9869009Abstract: The present invention relates to a wrought, quenched and tempered, fine-grained, with deep hardenability, high strength and low alloy steel having a sum of the alloying elements: nickel, molybdenum, tungsten, vanadium, titanium, and niobium in weight percent 1.0% to 1.60%. The air melted and hot forged steel of the present invention has hardness of HRC 55, an ultimate tensile strength of 300 ksi, a yield strength of 257 ksi, a total elongation of 9%, a reduction of area of 32%, and Charpy v-notch impact toughness energy of 15 ft-lb after normalizing, gas quenching, and tempering at 450° F.Type: GrantFiled: November 14, 2014Date of Patent: January 16, 2018Inventor: Gregory Vartanov
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Patent number: 9738945Abstract: A forging process is conducted in a temperature range of 350-600° C. on at least a portion that is required to have a fatigue strength in an intermediate forged product having a ferrite and pearlite texture obtained by conducting a hot forging on a steel in which N is not greater than an amount at which N is unavoidably dissolved as a solid, thereby improving strength of the portion that is required to have a fatigue strength. With this, there is provided a forged product having a good strength and a low price.Type: GrantFiled: January 31, 2012Date of Patent: August 22, 2017Assignee: Nissan Motor Co., Ltd.Inventors: Jun Yoshida, Daisuke Kaneko, Noriyuki Iwata