Amorphous, I.e., Glassy Patents (Class 148/403)
  • Patent number: 11961646
    Abstract: A soft magnetic powder including particles having a composition represented by FexCuaNbb(Si1-yBy)100-x-a-b [provided that a, b, and x are each a number whose unit is at % and satisfy 0.3?a?2.0, 2.0?b?4.0, and 73.0?x?79.5, respectively, and y is a number satisfying f(x)?y?0.99, in which f(x)=(4×10?34)x17.56], wherein the particle contains a crystal grain having a grain diameter of 1.0 nm or more and 30.0 nm or less, and includes a Cu segregated portion in which Cu is segregated, the Cu segregated portion is present at a position deeper than 30 nm from a surface of the particle, and a maximum Cu concentration in the Cu segregated portion exceeds 6.0 at %.
    Type: Grant
    Filed: February 7, 2022
    Date of Patent: April 16, 2024
    Assignee: SEIKO EPSON CORPORATION
    Inventor: Mayu Watanabe
  • Patent number: 11932559
    Abstract: Electrode catalytic layers coated on outer surfaces of oxidation electrode and a reduction electrode used to generate sterile water, where the electrode catalyst layers are formed on the outer surfaces of the oxidation electrode and a reduction electrode to have predetermined thickness, and are composed of iridium (Ir), palladium (Pd), and tantalum (Ta), and wherein the palladium (Pd) has a weight ratio of 10% to 30%, and a sum of the weight ratios of the iridium (Ir) and the tantalum (Ta) is 70% to 90%.
    Type: Grant
    Filed: December 13, 2019
    Date of Patent: March 19, 2024
    Assignee: COWAY CO., LTD.
    Inventors: Sang-Young Lee, Sunhyeok Park
  • Patent number: 11905582
    Abstract: Ni—Cr—Nb—P—B alloys optionally bearing Si and metallic glasses formed from said alloys are disclosed, where the alloys have a critical rod diameter of at least 5 mm and the metallic glasses demonstrate a notch toughness of at least 96 MPa m1/2.
    Type: Grant
    Filed: March 8, 2018
    Date of Patent: February 20, 2024
    Assignee: Glassimetal Technology, Inc.
    Inventors: Jong Hyun Na, Kyung-Hee Han, Maximilien Launey, Marios D. Demetriou, William L. Johnson
  • Patent number: 11873548
    Abstract: Disclosed is a gear including a resettable metallic glass. The gear of the present disclosure includes, as a base material, a resettable metallic glass, wherein the resettable metallic glass includes at least one metal element selected from each of (a) the group consisting of Ti, Zr, and Hf and (b) the group consisting of Fe, Co, Ni, Cu, and Zn, and further includes at least one metal element to maximize the complexity in the thermodynamic enthalpy of mixing among constituent elements, thereby including multiple resetting cores in various atomic-scale cluster forms in an amorphous matrix, leading to a structure with maximized structural complexity.
    Type: Grant
    Filed: September 28, 2021
    Date of Patent: January 16, 2024
    Assignee: SEOUL NATIONAL UNIVERSITY R&DB FOUNDATION
    Inventors: Eun Soo Park, Geun Hee Yoo, Kook Noh Yoon, Ji Young Kim, Wook Ha Ryu
  • Patent number: 11821064
    Abstract: Cu-based bulk amorphous alloys in the quaternary Cu—Zr—Hf—Al alloy system are disclosed. A method of casting such alloys and articles comprising such alloys also are disclosed.
    Type: Grant
    Filed: October 22, 2021
    Date of Patent: November 21, 2023
    Assignee: Oregon State University
    Inventors: Donghua Xu, Jaskaran Singh Saini, Collin J. Palian
  • Patent number: 11781205
    Abstract: Embodiments disclosed herein relate to the production of bulk amorphous metal (BAM) alloys comprising chromium, manganese, molybdenum, tungsten, silicon, carbon, boron, and the balance of iron to replace tungsten carbide-based welded material. The BAM alloy embodied herein can be applied through PTA welding, HVOF, TWAS, flame spraying, plasma spraying, laser, their combinations, and other coating and welding processes. When used as welded material, the density of the embodiment of around 7 grams per CC, which is less dense than the tungsten carbide customarily used, resulting in even hard faces during welding spread uniformly across the weld, therefore creating a harder and more wear-resistant weld.
    Type: Grant
    Filed: December 31, 2019
    Date of Patent: October 10, 2023
    Assignee: LIQUIDMETAL COATINGS ENTERPRISES, LLC
    Inventors: John Kang, Evelina Vogli
  • Patent number: 11739403
    Abstract: A soft magnetic metal powder that has low coercivity Hcj and high saturation magnetic flux density Bs, and has high powder resistivity and high insulating performance is obtained. The soft magnetic metal powder is soft magnetic metal powder containing Fe. The soft magnetic metal powder has particles each including a soft magnetic metal portion and a coating portion coating the soft magnetic metal portion. The coating portion includes a first coating portion and a second coating portion. The first coating portion is closer to the soft magnetic metal portion than the second coating portion. The first coating portion and the second coating portion have oxides containing at least one element selected from Si, Fe, and B as a main component. The first coating portion includes amorphous material, the second coating portion includes crystals, and the second coating portion has a higher crystal content ratio than the first coating portion.
    Type: Grant
    Filed: March 25, 2020
    Date of Patent: August 29, 2023
    Assignee: TDK CORPORATION
    Inventors: Satoko Mori, Kazuhiro Yoshidome, Hiroyuki Matsumoto
  • Patent number: 11733429
    Abstract: This invention relates generally to the field of quasicrystalline structures.
    Type: Grant
    Filed: April 23, 2019
    Date of Patent: August 22, 2023
    Assignee: THE TRUSTEES OF PRINCETON UNIVERSITY
    Inventors: Chaney Lin, Paul J. Steinhardt, Salvatore Torquato
  • Patent number: 11732361
    Abstract: A method for manufacturing a metal plate, the metal plate including a first surface and a second surface positioned on the opposite side of the first surface, may include a step of rolling a base metal having an iron alloy containing nickel to produce the metal plate. The metal plate may include particles containing as a main component an element other than iron and nickel. In a sample including the first surface and the second surface of the metal plate, the following conditions (1) and (2) regarding the particles may be satisfied: (1) The number of the particles having an equivalent circle diameter of 1 ?m or more is 50 or more and 3000 or less per 1 mm3 in the sample, and (2) The number of the particles having an equivalent circle diameter of 3 ?m or more is 50 or less per 1 mm3 in the sample.
    Type: Grant
    Filed: October 14, 2020
    Date of Patent: August 22, 2023
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Hiroki Oka, Chikao Ikenaga, Sachiyo Matsuura, Shogo Endo, Chiaki Hatsuta, Asako Narita
  • Patent number: 11676009
    Abstract: A method for designing a material for an aircraft component according to one example includes training a neural network to correlate microstructural features of an alloy with material properties of the alloy by at least providing a set of images of the alloy. Each of the images in the set of images has varied constituent compositions and at least one patch of corresponding data is embedded into the image. The method also includes determining non-linear relationships between the microstructural features and corresponding empirically determined material properties via a machine learning algorithm, receiving a set of desired material properties of the alloy for aircraft component, and determining a set of microstructural features capable of achieving the desired material properties of the alloy based on the determined non-linear relationships.
    Type: Grant
    Filed: October 4, 2019
    Date of Patent: June 13, 2023
    Assignee: Raytheon Technologies Corporation
    Inventors: Nagendra Somanath, Ryan B. Noraas, Michael J Giering, Olusegun T Oshin
  • Patent number: 11326229
    Abstract: Provided is a monatomic amorphous palladium, a method for preparing the same and use thereof. The method comprises a) loading a monatomic palladium powder on a silicon nitride substrate; b) heating the silicon nitride substrate loaded with the monatomic palladium powder obtained in a) up to a temperature of 800° C. to 1000° C. and keeping the temperature for at least 3 minutes; and c) cooling a system of palladium and silicon nitride obtained in b) to room temperature at an apparent cooling rate greater than 103° C./second, thus obtaining the monatomic amorphous palladium.
    Type: Grant
    Filed: February 27, 2018
    Date of Patent: May 10, 2022
    Assignee: SOUTH UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA
    Inventors: Jiaqing He, Dongsheng He, Yi Huang, Yi Zhou
  • Patent number: 11150288
    Abstract: The present disclosure discloses a system for measuring a charge-to-mass ratio of an electrostatic atomization nozzle and a measurement method using the same. The system includes an electrostatic atomization nozzle, an upper cylinder, a lower cylinder, an ammeter, a liquid level tube, an ultrasonic level meter, a water storage tank, and a liquid pump. The electrostatic atomization nozzle, the upper cylinder, and the lower cylinder are sequentially connected from top to bottom. The ammeter is connected to the lower-cylinder flange. The liquid level tube is communicated with the lower cylinder. The ultrasonic level meter is mounted on an upper end of the liquid level tube. The water storage tank is located below a lower-cylinder water outlet pipe. The liquid pump can deliver a liquid in the water storage tank to the electrostatic atomization nozzle. Measurement data of the ammeter is acquired and processed by a computer in real time.
    Type: Grant
    Filed: July 30, 2019
    Date of Patent: October 19, 2021
    Assignee: Jiangsu University
    Inventors: Mingxiong Ou, Minmin Wu, Weidong Jia, Chen Gong, Huitao Zhou
  • Patent number: 11078560
    Abstract: An embodiment relates to a composition comprising an amorphous alloy having a low coefficient of friction (COF) of 0.15 or less, wherein the amorphous alloy is substantially free of phosphor (P) and substantially free of boron (B). An embodiment relates to a method comprising solidifying a molten layer of an amorphous feedstock on a preexisting layer by controlling a heating source and a cooling rate so as to avoid formation of crystals in the molten layer and not affect a crystalline structure of the preexisting layer, and forming a specimen; wherein, the at least a portion specimen has the low COF. Another embodiment relates to a system comprising a drill string, wherein the drill string comprises a drilling bit and a drill pipe connected thereto, wherein at least a portion of the drill pipe comprises a coating having the low COF.
    Type: Grant
    Filed: October 11, 2019
    Date of Patent: August 3, 2021
    Assignee: CORNERSTONE INTELLECTUAL PROPERTY, LLC
    Inventors: John Kang, Evelina Vogli, Ricardo Salas
  • Patent number: 11059099
    Abstract: The present disclosure relates to a process and an apparatus for producing powder particles by atomization of a feed material in the form of an elongated member such as a wire, a rod or a filled tube. The feed material is introduced in a plasma torch. A forward portion of the feed material is moved from the plasma torch into an atomization nozzle of the plasma torch. A forward end of the feed material is surface melted by exposure to one or more plasma jets formed in the atomization nozzle. The one or more plasma jets being includes an annular plasma jet, a plurality of converging plasma jets, or a combination of an annular plasma jet with a plurality of converging plasma jets. Powder particles obtained using the process and apparatus are also described.
    Type: Grant
    Filed: February 25, 2021
    Date of Patent: July 13, 2021
    Assignee: Tekna Plasma Systems Inc.
    Inventors: Maher I. Boulos, Jerzy W. Jurewicz, Alexandre Auger
  • Patent number: 11053151
    Abstract: An amorphous alloy contains Ni and Nb and has a composition including at least one of: a composition containing Nb with a content in the range of 35.6 atomic % to 75.1 atomic %, Ir with a content in the range of 7.2 atomic % to 52.3 atomic %, and Ni with a content in the range of 4.0 atomic % to 48.5 atomic %; a composition containing Nb with a content in the range of 19.6 atomic % to 80.9 atomic %, Re with a content in the range of 7.4 atomic % to 59.2 atomic %, and Ni with a content in the range of 4.1 atomic % to 56.9 atomic %; and a composition containing Nb with a content in the range of 7.5 atomic % to 52.9 atomic %, W with a content in the range of 16.4 atomic % to 47.0 atomic %, and Ni with a content in the range of 22.0 atomic % to 53.3 atomic %.
    Type: Grant
    Filed: May 21, 2018
    Date of Patent: July 6, 2021
    Assignee: Canon Kabushiki Kaisha
    Inventors: Seiichi Hata, Satoko Midorikawa, Hirotaka Fukushima
  • Patent number: 11035029
    Abstract: A metal matrix composite material includes 60-90 wt. % of aluminum alloy powders and 10-40 wt. % Fe-based amorphous alloy powders. The aluminum alloy powders are used as the matrix of the metal matrix composite material, and the Fe-based amorphous alloy powders include FeaCrbMocSidBeYf, wherein 48 at. %?a?50 at. %, 21 at. %?b?23 at. %, 18 at. %?c?20 at. %, 3 at. %?D?5 at. %, 2 at. %?c?4 at. %, and 2 at. %?f?4 at. %.
    Type: Grant
    Filed: August 27, 2019
    Date of Patent: June 15, 2021
    Assignee: Industrial Technology Research Institute
    Inventors: Li-Shing Chou, Chih-Chao Yang, Chi-San Chen, Chih-Jung Weng, Heng-Yi Tsai
  • Patent number: 11027992
    Abstract: An iron-based amorphous electrode material for industrial wastewater treatment, wherein the material is amorphous alloy used as an electrode for electrochemical degradation of industrial wastewater, and the atom percentage of iron element in the alloy being 40-84%, wherein a method for treating dye wastewater by using the iron-based amorphous electrode material and a use of the iron-based amorphous electrode material in the electrochemical degradation of industrial wastewater are also disclosed.
    Type: Grant
    Filed: March 10, 2017
    Date of Patent: June 8, 2021
    Inventors: Zhengwang Zhu, Xindong Qin, Haifeng Zhang, Aimin Wang
  • Patent number: 10934606
    Abstract: Nanostructured materials that contain amorphous intergranular films (AIFs) are described herein. Amorphous intergranular films are structurally disordered (lacking the ordered pattern of a crystal) films that are up to a few nanometers thick. Nanostructured materials containing these films exhibit increased ductility, strength, and thermal stability simultaneously. A nanocrystalline material system that has two or more elements can be designed to contain AIFs at the grain boundaries, provided that the dopants segregate to the interface and certain materials science design rules are followed. An example of AIFs in a nanostructured Cu—Zr alloy is provided to illustrate the benefits of integrating AIFs into nanostructured materials.
    Type: Grant
    Filed: February 14, 2018
    Date of Patent: March 2, 2021
    Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    Inventors: Timothy J. Rupert, Amirhossein Khalajhedayati
  • Patent number: 10927440
    Abstract: The disclosure provides Zr—Ti—Cu—Ni—Al metallic glass-forming alloys and metallic glasses that have a high glass forming ability along with a high thermal stability of the supercooled liquid against crystallization.
    Type: Grant
    Filed: February 24, 2017
    Date of Patent: February 23, 2021
    Assignee: Glassimetal Technology, Inc.
    Inventors: Jong Hyun Na, Glenn Garrett, Kyung-Hee Han, Georg Kaltenboeck, Chase Crewdson, Marios D. Demetriou, William L. Johnson
  • Patent number: 10854365
    Abstract: Provided is a soft magnetic alloy including Fe, as a main component, and including B. Among 80000 pieces of a grid having 1 nm×1 nm×1 nm in a continuous measurement range of the soft magnetic alloy, 4000 pieces of the grid from lower Fe content shows B content variation (?B) of 2.8 or more, and an amorphization ratio X of the soft magnetic alloy of 85% or more.
    Type: Grant
    Filed: February 26, 2018
    Date of Patent: December 1, 2020
    Assignee: TDK CORPORATION
    Inventors: Kazuhiro Yoshidome, Hiroyuki Matsumoto, Kenji Horino, Akito Hasegawa, Yu Yonezawa, Syota Goto, Seigo Tokoro
  • Patent number: 10801093
    Abstract: Pd—Cu—P metallic glass-forming alloy compositions and metallic glasses comprising at least one of Ag, Au, and Fe are provided, wherein the alloys demonstrate improved glass forming ability, as compared to Pd—Cu—P alloys free of Ag, Au, and Fe, and are capable of forming metallic glass rods with diameters in excess of 3 mm, and in some embodiments 26 mm or larger.
    Type: Grant
    Filed: February 8, 2018
    Date of Patent: October 13, 2020
    Assignee: GlassiMetal Technology, Inc.
    Inventors: Jong Hyun Na, Marios D. Demetriou, Maximilien Launey, William L. Johnson
  • Patent number: 10697049
    Abstract: One embodiment provides a structure, comprising: a display; at least one structural component disposed over a portion of the display, wherein the at least on structural component comprises at least one amorphous alloy; and wherein a portion of the display is foldable.
    Type: Grant
    Filed: May 28, 2019
    Date of Patent: June 30, 2020
    Assignee: CORNERSTONE INTELLECTUAL PROPERTY, LLC
    Inventor: James W. Kang
  • Patent number: 10676806
    Abstract: A wear resistant coating may comprise an amorphous metal comprising at least one refractory metal, at least two elements selected from periods 4, 5, 6, 9, and 10, and a metalloid. An amorphous metal may comprise at least one refractory metal, at least two elements selected from periods 4, 5, 6, 9, and 10, and a metalloid. A coating may comprise at least one refractory metal, at least two elements selected from periods 4, 5, 6, 9, and 10, and silicon. In some examples, the amorphous metal is TaWSi. In one example, the refractory metals may comprise Niobium, Molybdenum, Tantalum, Tungsten, Rhenium, or combinations thereof.
    Type: Grant
    Filed: July 30, 2014
    Date of Patent: June 9, 2020
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: James Elmer Abbott, Jr., Greg Scott Long, Roberto A. Pugliese
  • Patent number: 10519538
    Abstract: An Al—Te—Cu—Zr alloy sputtering target, comprising 20 at % to 40 at % of Te, 5 at % to 20 at % of Cu, 5 at % to 15 at % of Zr and the remainder of Al, wherein a Te phase, a Cu phase and a CuTe phase are not present in a structure of the target. An object of the present invention is to provide an Al—Te—Cu—Zr alloy sputtering target capable of effectively reducing particle generation, nodule formation and the like upon sputtering and further capable of reducing oxygen contained in the target.
    Type: Grant
    Filed: February 6, 2015
    Date of Patent: December 31, 2019
    Assignee: JX NIPPON MINING & METALS CORPORATION
    Inventor: Yoshimasa Koido
  • Patent number: 10507444
    Abstract: A method and a device for producing honeycomb particles capable of absorbing harmful molecular elements are disclosed. A chemical element having a crystal structure is dissolved in water in a certain percentage to form a chemical element solution, and then it is pressurized. The pressurized chemical element solution is sprayed out in mist form toward a forming mirror by a high-pressure nozzle of a spray tube. When the chemical element solution in mist form contacts the heated forming mirror, the moisture quickly bursts and evaporates to form fine particles. The dried fine particles of the chemical element are made to fall by the high frequency vibration and are collected. Accordingly, the chemical element having a crystal structure is formed into fine particles having many air holes, increasing the area for chemical reaction and further increasing the efficiency of absorption of harmful elements such as various toxic elements or bacteria.
    Type: Grant
    Filed: September 6, 2017
    Date of Patent: December 17, 2019
    Inventors: Richard Chi-Hsueh, Chung-Yeh Hsu
  • Patent number: 10500766
    Abstract: A method of producing a mold includes obtaining a master mold, the master mold including surface details; exposing a curable material to the surface details; and curing the curable material with the surface details. A mold includes a surface for molding a composite part, the surface including surface details, wherein the mold is made of phenolic material.
    Type: Grant
    Filed: July 12, 2018
    Date of Patent: December 10, 2019
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Mark Vincent Greaney, Bing-Ling Chao, Herbert Stanley Heffernan, III
  • Patent number: 10487284
    Abstract: A sliding system includes a pair of sliding members having sliding surfaces that can relatively move while facing each other and a lubricant oil interposed between the sliding surfaces facing each other. At least one of the sliding surfaces includes a coating surface of a crystalline Cr plating film. The lubricant oil contains an oil-soluble molybdenum compound comprising a trinuclear Mo structure. In particular, considerably low friction properties can be developed by a combination of the Cr plating film, in which at least one of three types of peak area intensity ratios (P1 to P3) as obtained by X-ray diffraction falls within a predetermined range (P1?0.015, P2?0.02, P3?0.03), and the lubrication oil which contains the trinuclear Mo structure.
    Type: Grant
    Filed: January 26, 2018
    Date of Patent: November 26, 2019
    Assignee: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO
    Inventors: Shigeru Hotta, Hiroyuki Mori, Mamoru Tohyama, Toshihide Ohmori
  • Patent number: 10456870
    Abstract: A method for making a firmly-bonded connection involves a) providing an electronic component and a substrate having surfaces to be connected; b) applying a copper paste onto at least one of the surfaces and drying the layer of copper paste; c1) applying a solder agent onto the copper paste and arranging the component and the substrate in contact via the combination of copper paste and solder agent; or c2) arranging the component and the substrate in contact via the dried copper paste, and applying a solder agent next to the layer of dried copper paste; and d) soldering the arrangement. The copper paste contains (i) particles of copper, copper-rich copper/zinc alloy, and/or copper-rich copper/tin alloy containing a phosphorus fraction of 0 to ?500 wt-ppm, (ii) solder particles which are tin, tin-rich tin/copper alloy, tin-rich tin/silver alloy, and/or tin-rich tin/copper/silver alloy, and (iii) vehicle.
    Type: Grant
    Filed: August 21, 2015
    Date of Patent: October 29, 2019
    Assignee: Heraeus Deutschland GmbH & Co. KG
    Inventors: Sebastian Fritzsche, Jürgen Schulze, Jörg Trodler
  • Patent number: 10450636
    Abstract: A composition comprises, in weight percent: Al as a largest constituent; 3.0 6.0 Cr; 1.5 4.0 Mn; 0.1 3.5 Co; and 0.3 2.0 Zr.
    Type: Grant
    Filed: July 9, 2014
    Date of Patent: October 22, 2019
    Assignee: United Technologies Corporation
    Inventors: Thomas J. Watson, Iuliana Cernatescu
  • Patent number: 10435773
    Abstract: High-strength, lightweight alloy components, such as automotive components, capable of high temperature performance comprising aluminum, silicon, and iron and/or nickel are provided, along with methods of making such high-strength, lightweight alloy components. A high-energy stream, such as a laser or electron beam, may be selectively directed towards a precursor material to melt a portion of the precursor material in a localized region. The molten precursor material is cooled at a rate of greater than or equal to about 1.0×105 K/second to form a solid high-strength, lightweight alloy component comprising a stable ternary cubic phase having high heat resistance and high strength. The stable ternary phase may be AlxFeySiz, where x ranges from about 4 to about 5 or about 7.2 to about 7.6, y is about 1.5 to about 2.2, and z is about 1. The stable ternary phase may also be Al6Ni3Si.
    Type: Grant
    Filed: April 4, 2019
    Date of Patent: October 8, 2019
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Zhongyi Liu, Anil K. Sachdev
  • Patent number: 10428413
    Abstract: A hydrophobic alloy film and a manufacturing method thereof are provided. The hydrophobic alloy film includes Al, Cu, O, and at least one selected from the group consisting of Fe, Co, Ni, and Cr, or Ti, Zr, O, and at least one selected from the group consisting of Fe, Co, Ni, and Cr. The content of each of Al and Ti is in the range of 40 at. % to 70 at. %. The content of each of Cu and Zr is in the range of 10 at. % to 40 at. %. The total content of at least one selected from the group consisting of Fe, Co, Ni, and Cr is in the range of 10 at. % to 30 at. %. The content of O is in the range of 10 at. % to 30 at. %. The hydrophobic alloy film has a quasicrystal structure and nanoparticles.
    Type: Grant
    Filed: December 29, 2015
    Date of Patent: October 1, 2019
    Assignee: Industrial Technology Research Institute
    Inventors: Tai-Sheng Chen, Ming-Sheng Leu, Wu-Han Liu, Jia-Jen Chang
  • Patent number: 10370752
    Abstract: A technique is disclosed for straining an amorphous alloy at ambient temperature to plastically and homogeneously deform the amorphous alloy, such that at least an exterior surface of the deformed amorphous alloy is substantially free of shear bands. An amorphous alloy may be strained at a rate of less than about 9×10?5 s?1 or by multiple passes of cold rolling. A pattern from a die may be imprinted into the amorphous alloy when strained, and the amorphous alloy may be used as a die to plastically strain other materials.
    Type: Grant
    Filed: April 7, 2016
    Date of Patent: August 6, 2019
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Min Ha Lee, Eun Soo Park, Ryan Timothy Ott, Jürgen Eckert
  • Patent number: 10329432
    Abstract: A cost-effective method of forming a hydrophobic coating on a substrate and coated substrates are disclosed. Specifically, the method comprises applying amorphous powders of an alloy to the substrate through a cold spray process. Also provided is a novel type of hydrophobic coating made of metallic glasses or amorphous alloys. The hydrophobic coatings offer advantages such as, low cost, low maintenance, and high corrosion resistance.
    Type: Grant
    Filed: May 29, 2014
    Date of Patent: June 25, 2019
    Assignee: UNITED TECHNOLOGIES CORPORATION
    Inventors: Neal Magdefrau, Daniel G. Goberman, Paul Sheedy, Aaron T. Nardi
  • Patent number: 10301708
    Abstract: One embodiment provides a structure, comprising: a display; at least one structural component disposed over a portion of the display, wherein the at least on structural component comprises at least one amorphous alloy; and wherein a portion of the display is foldable.
    Type: Grant
    Filed: December 26, 2017
    Date of Patent: May 28, 2019
    Assignee: Cornerstone Intellectual Property, LLC
    Inventor: James W. Kang
  • Patent number: 10294552
    Abstract: Methods of making high-strength, lightweight alloy components capable of high temperature performance comprising aluminum, silicon, and iron and/or nickel are provided. A high-energy stream, such as a laser or electron beam, may be selectively directed towards a precursor material to melt a portion of the precursor material in a localized region. The molten precursor material is cooled at a rate of greater than or equal to about 1.0×105 K/second to form a solid high-strength, lightweight alloy component comprising a stable ternary cubic phase having high heat resistance and high strength. The stable ternary phase may be AlxFeySiz, where x ranges from about 4 to about 5 or about 7.2 to about 7.6, y is about 1.5 to about 2.2, and z is about 1. The stable ternary phase may also be Al6Ni3Si. Materials and components, such as automotive components, made from such methods are also provided.
    Type: Grant
    Filed: December 20, 2016
    Date of Patent: May 21, 2019
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Zhongyi Liu, Anil K. Sachdev
  • Patent number: 10240227
    Abstract: Various embodiments of zirconium based bulk metallic glass with hafnium are described herein. In one embodiment, an alloy composition includes zirconium (Zr), hafnium (Hf), copper (Cu), aluminum (Al), at least one element from a group consisting of niobium (Nb) and titanium (Ti), and at least one element from a group consisting of nickel (Ni), iron (Fe), and cobalt (Co).
    Type: Grant
    Filed: April 29, 2016
    Date of Patent: March 26, 2019
    Assignee: Washington State University
    Inventors: Atakan Peker, Dongchun Qiao
  • Patent number: 10232589
    Abstract: A plated steel sheet with a quasicrystal includes a steel sheet and a plated-metal-layer arranged on a surface of the steel sheet. The plated-metal-layer includes, as a chemical composition, Mg, Zn. The plated-metal-layer includes, as a metallographic structure, a quasicrystal phase. A Mg content, a Zn content, and an Al content in the quasicrystal phase satisfy 0.5?Mg/(Zn+Al)?0.83 in atomic %. In addition, an average equivalent circle diameter of the quasicrystal phase is equal to or larger than 0.01 ?m and equal to or smaller than 1 ?m.
    Type: Grant
    Filed: March 28, 2014
    Date of Patent: March 19, 2019
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventor: Kohei Tokuda
  • Patent number: 10232590
    Abstract: A plated steel sheet with a quasicrystal includes a steel sheet and a plated-metal-layer arranged on a surface of the steel sheet. The plated-metal-layer includes, as a chemical composition, Mg, Zn, and Al, and satisfies 25%?Zn+Al in atomic %. The plated-metal-layer includes, as a metallographic structure, a quasicrystal phase. A Mg content, a Zn content, and an Al content in the quasicrystal phase satisfy 0.5?Mg/(Zn+Al)?0.83 in atomic %. In addition, an average equivalent circle diameter of the quasicrystal phase is larger than 1 ?m and equal to or smaller than 200 ?m.
    Type: Grant
    Filed: March 28, 2014
    Date of Patent: March 19, 2019
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventor: Kohei Tokuda
  • Patent number: 10210959
    Abstract: Radiation shielding structures comprising bulk-solidifying amorphous alloys and methods of making radiation shielding structures and components in near-to-net shaped forms are provided.
    Type: Grant
    Filed: September 29, 2011
    Date of Patent: February 19, 2019
    Assignee: Crucible Intellectual Property, LLC
    Inventors: Joseph Stevick, Theodore Andrew Waniuk, Tran Quoc Pham
  • Patent number: 10087505
    Abstract: Provided in one embodiment is a method of making use of foams as a processing aid or to improve the properties of bulk-solidifying amorphous alloy materials. Other embodiments include the bulk-solidifying amorphous alloy/foam composite materials made in accordance with the methods.
    Type: Grant
    Filed: May 18, 2015
    Date of Patent: October 2, 2018
    Assignee: APPLE INC.
    Inventors: Christopher D. Prest, Matthew S. Scott, Stephen P. Zadesky, Dermot J. Stratton, Joseph C. Poole
  • Patent number: 10066276
    Abstract: Disclosed is an improved bulk metallic glass alloy and methods of making the alloy in which the alloy has the structure ZraNbbCucNidAle, wherein a-e represent the atomic percentage of each respective element, and wherein b/a is less than about 0.040, and c/d is less than 1.15. The bulk metallic glass alloy has improved thermal stability and an increased super cooled liquid region rendering it capable of being thermoplastically formed into a variety of shapes and sizes.
    Type: Grant
    Filed: June 25, 2012
    Date of Patent: September 4, 2018
    Assignee: Crucible Intellectual Property, LLC
    Inventors: Quoc Tran Pham, Theodore A. Waniuk
  • Patent number: 10047420
    Abstract: In one embodiment, the invention provides a process for thermoplastic forming of a metallic glass. For example, in one embodiment, the invention provides a process for thermoplastic forming of a metallic glass ribbons having a thickness of between about 50 to about 200 microns. Related articles of manufacture and processes for customizing articles in accordance with the process as described herein are also provided.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: August 14, 2018
    Assignee: YALE UNIVERSITY
    Inventors: Jan Schroers, Thomas M. Hodges, Michael Kanik, Punnathat Bordeenithikasem
  • Patent number: 10046484
    Abstract: A method of producing a mold includes obtaining a master mold, the master mold including surface details; exposing a curable material to the surface details; and curing the curable material with the surface details. A mold includes a surface for molding a composite part, the surface including surface details, wherein the mold is made of phenolic material.
    Type: Grant
    Filed: August 26, 2014
    Date of Patent: August 14, 2018
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Mark Vincent Greaney, Bing-Ling Chao, Herbert Stanley Heffernan, III
  • Patent number: 10036087
    Abstract: The disclosure provides Pt—Cu—P glass-forming alloys bearing at least one of B, Ag, and Au, where each of B, Ag, and Au can contribute to improve the glass forming ability of the alloy in relation to the alloy that is free of these elements. The alloys are capable of forming metallic glass rods with diameters in excess of 3 mm, and in some embodiments 50 mm or larger. The alloys and metallic glasses can satisfy platinum jewelry hallmarks PT750, PT800, PT850, and PT900.
    Type: Grant
    Filed: March 24, 2015
    Date of Patent: July 31, 2018
    Assignees: Glassimetal Technology, Inc., Apple Inc.
    Inventors: Jong Hyun Na, Marios D. Demetriou, Oscar Abarca, Maximilien Launey, William L. Johnson, Glenn Garrett, Danielle Duggins, Chase Crewdson, Kyung-Hee Han
  • Patent number: 9994932
    Abstract: Embodiments herein relate to a method of making roll formed objects of a bulk solidifying amorphous alloy comprising a metal alloy, and articles thereof. The roll forming includes forming a portion of the bulk solidifying amorphous alloy at a temperature greater than a glass transition temperature (Tg) of the metal alloy. The roll forming is done such that a time-temperature profile of the portion during the roll forming does not traverse through a region bounding a crystalline region of the metal alloy in a time-temperature-transformation (TTT) diagram of the metal alloy.
    Type: Grant
    Filed: March 23, 2012
    Date of Patent: June 12, 2018
    Assignee: Apple Inc.
    Inventors: Christopher D. Prest, Joseph C. Poole, Joseph Stevick, Theodore A. Waniuk, Quoc Tran Pham
  • Patent number: 9998828
    Abstract: A concept is provided which permits the implementation of MEMS microphone elements having a very good SNR, high microphone sensitivity and a large frequency bandwidth. The microphone structure of the MEMS element is implemented in a layer structure and includes at least one sound pressure-sensitive diaphragm (210), an acoustically permeable counter element (220) and a capacitor system for detecting the diaphragm deflections, the diaphragm (210) and the counter element (220) being situated on top of each other and a distance apart from one another in the layer structure and each bring equipped with at least one electrode of the capacitor system. According to the invention, the layer structure of the diaphragm (210) includes at least one thin closed layer (1) and at least one thick structured layer (2), a grid structure (100) covering the entire diaphragm area being provided in the thick layer (2), which determines the stiffness of the diaphragm (210).
    Type: Grant
    Filed: October 16, 2015
    Date of Patent: June 12, 2018
    Assignee: ROBERT BOSCH GMBH
    Inventor: Rolf Scheben
  • Patent number: 9975174
    Abstract: Methods and apparatus for creating an overall assembly formed from a transparent member and a metal member are disclosed. According to one aspect of the present invention, a method includes positioning a transparent member in a mold configured for insertion molding, and providing a liquid metal into the mold. The method also includes hardening the liquid metal in the mold. Hardening the liquid metal includes binding the metal to the transparent member to create the integral assembly.
    Type: Grant
    Filed: August 21, 2015
    Date of Patent: May 22, 2018
    Assignee: Apple Inc.
    Inventor: Kyle H. Yeates
  • Patent number: 9970089
    Abstract: Disclosed is the semi-amorphous, ductile brazing foil with composition consisting essentially of NibalCraBbPcSidMoeFef with approximately 24 atomic percent?a?approximately 31 atomic percent; b?approximately 3 atomic percent; approximately 9 atomic percent?c?approximately 11 atomic percent; approximately 2 atomic percent?d?approximately 4 atomic percent; e?approximately 2 atomic percent; f?approximately 1 atomic percent; and the balance being Ni and other impurities; where b+c+d<approximately 16 atomic percent.
    Type: Grant
    Filed: December 13, 2013
    Date of Patent: May 15, 2018
    Assignee: Metglas, Inc.
    Inventors: William Coughlan, Eric Theisen
  • Patent number: RE47321
    Abstract: Bulk amorphous alloys based on quaternary Ni—Zr—Ti—Al alloy system, and the extension of this quaternary system to higher order alloys by the addition of one or more alloying elements, methods of casting such alloys, and articles made of such alloys are provided.
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: March 26, 2019
    Assignee: California Institute of Technology
    Inventors: William L. Johnson, Donghua Xu
  • Patent number: RE47863
    Abstract: The present invention relates to novel non-ferromagnetic amorphous steel alloys represented by the general formula: Fe—Mn-(Q)-B-M, wherein Q represents one or more elements selected from the group consisting of Sc, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, and M represents one or more elements selected from the group consisting of Cr, Co, Mo, C and Si. Typically the atomic percentage of the Q constituent is 10 or less. An aspect is to utilize these amorphous steels as coatings, rather than strictly bulk structural applications. In this fashion any structural metal alloy can be coated by various technologies by these alloys for protection from the environment. The resultant structures can utilize surface and bulk properties of the amorphous alloy.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: February 18, 2020
    Assignee: University of Virginia Patent Foundation
    Inventors: Gary J. Shiflet, S. Joseph Poon, Xiaofeng Gu