Cobalt Base Patents (Class 148/408)
  • Patent number: 11779477
    Abstract: A stent having a cobalt-based alloy, wherein the cobalt-based alloy is free of nickel (Ni), the cobalt-based alloy including 10-65 weight % metal member selected from a platinum group metal, a refractory metal, or combinations thereof, 15-25 weight % chromium (Cr), 4-7 weight % molybdenum (Mo), 0-18 weight % iron (Fe), and 22-40 weight % cobalt (Co).
    Type: Grant
    Filed: December 27, 2021
    Date of Patent: October 10, 2023
    Assignee: ABBOTT CARDIOVASCULAR SYSTEMS, INC.
    Inventors: John A. Simpson, Puneet Kamal Singh Gill, Pamela A. Kramer-Brown
  • Patent number: 10718224
    Abstract: An aft frame assembly has a main body with an upstream facing surface, a downstream facing surface, a radially outer facing surface and a radially inner facing surface. Feed hole inlets are located on the upstream facing surface and radially outward of the outer sleeve so that the feed hole inlets are located to receive input from a high pressure plenum. The feed hole inlets are coupled to cooling channels that pass through the main body. Microchannels are formed in or near the radially inner facing surface and the downstream facing surface. The cooling channels are connected to and terminate in the microchannels. Exit holes are connected to the plurality of microchannels, and the exit holes are located radially outward of the transition piece and radially inward of the outer sleeve. The exit holes are located to exhaust into the cooling annulus.
    Type: Grant
    Filed: October 13, 2017
    Date of Patent: July 21, 2020
    Assignee: General Electric Company
    Inventors: Charles Lewis Davis, III, Kevin Weston McMahan, Wei Chen, Scott Robert Simmons
  • Patent number: 9206319
    Abstract: A surface hardening material being excellent in abrasion resistance and having impact resistance is provided. Provided are: a wear-resistant cobalt-based alloy containing 20.0 to 30.0 mass % of a sum of Mo and/or W, 0.8 to 2.2 mass % of B, 5.0 to 18.0 mass % of Cr, 5.0 mass % or less of a sum of Fe, Ni, Mn, Cu, Si and C, 1.0 mass % or less of Si, and 0.3 mass % or less of C, and the remainder comprising 55.0 to 70.0 mass % of Co and unavoidable impurities; and an engine valve coated with the same.
    Type: Grant
    Filed: May 23, 2011
    Date of Patent: December 8, 2015
    Assignees: Fukuda Metal Foil & Powder Co., Ltd., Nittan Valve Co., Ltd.
    Inventors: Katsunori Otobe, Shinichi Nishimura, Kazunori Kurahashi
  • Patent number: 8551265
    Abstract: A Co-base alloy which has a basic composition including, in terms of mass proportion, 0.1%-10% Al, 3.0-45% W, and Co as the remainder and has an intermetallic compound of the Ll2 type [Co3(Al,W)] dispersed and precipitated therein. Part of the Co may be replaced with Ni, Ir, Fe, Cr, Re, or Ru, while part of the Al and W may be replaced with Ni, Ti, Nb, Zr, V, Ta or Hf. The intermetallic compound [Co3(Al, W)] has a high melting point, and this compound and the matrix are mismatched little with respect to lattice constant. Thus, the cobalt-base alloy can have high-temperature strength equal to that of nickel-base alloys and excellent structure stability.
    Type: Grant
    Filed: February 25, 2008
    Date of Patent: October 8, 2013
    Assignee: Japan Science and Technology Agency
    Inventors: Kiyohito Ishida, Ryosuke Kainuma, Katunari Oikawa, Ikuo Ohnuma, Jun Sato
  • Patent number: 8529710
    Abstract: A Co-based alloy being useful as a spiral spring, common spring, wire, cable guide, steel belt, build-up material, guide wire, stent, catheter, etc. There is provided a Co-based alloy having a composition of Co—Al binary system containing 3-13% Al loaded with at least one workability enhancing element selected from among 001 to 50% Ni, 0.01 to 40% Fe and 0.01 to 30% Mn and having a lamellar structure wherein f.c.c. structure ?-phase and ?(B2)-phase are repeated in layers. The lamellar structure is so regulated that the occupancy ratio of the whole structure is 30 vol. % or above and the layer spacing is 100 ?m or less. The Co-based alloy may contain at least one optional component selected from among Ga, Cr, V, Ti, Mo, Nb, Zr, W, Ta, Hf, Si, Rh, Pd, Ir, Pt, Au, B, C and P may be added in a total amount of 0.01 to 60%.
    Type: Grant
    Filed: April 7, 2008
    Date of Patent: September 10, 2013
    Assignee: Japan Science and Technology Agency
    Inventors: Kiyohito Ishida, Kiyoshi Yamauchi, Ryosuke Kainuma, Yuji Sutou, Toshihiro Omori
  • Patent number: 8524017
    Abstract: A process for manufacturing a component with a base of Co—Cr—Mo alloys having values of average ultimate elongation at 800° C. greater than 10% and of average yielding load at 800° C. greater than 400 MPa, comprising: obtaining a sintered component by additive sintering of powders of Co—Cr—Mo alloys containing carbides irregularly dispersed in the molten matrix; Conducting a first heat treatment on the sintered component for solubilization of the carbides at a temperature of between 1100° C. and 1300° C. for at least 2 hours to form a solubilization intermediate; and cooling the solubilization intermediate at a cooling rate at least equal to that of cooling in air to form a cooled intermediate; and conducting a second heat treatment on the cooled intermediate at a temperature of between 700° C. and 1000° C.
    Type: Grant
    Filed: July 26, 2010
    Date of Patent: September 3, 2013
    Assignee: AVIO S.p.A.
    Inventor: Giovanni Paolo Zanon
  • Patent number: 8398791
    Abstract: Cobalt based alloys exhibiting high-temperature mechanical strength in an oxidizing medium are provided. The alloys are free of W and Hf and include the following elements in percentage by weight of the alloy: 23 to 34% Cr; 6 to 12% Ni; 6.0 to 10% Ta; 0.3 to 1.2% C; less than 3% Fe; less than 1% Si; less than 0.5% Mn; less than 0.1% Zr; and a balance of cobalt and impurities. Ta/C molar ratios of the alloys are at least 0.3.
    Type: Grant
    Filed: August 23, 2007
    Date of Patent: March 19, 2013
    Assignees: Saint-Gobain Isover, Saint-Gobain Seva
    Inventors: Patrice Berthod, Jean-Luc Bernard, Christophe Liebaut
  • Patent number: 7578893
    Abstract: A material for electrical contacts comprising a martensitic cobalt-nickel-iron alloy with a high strength, a high bendability and a high electrical conductivity, with a cobalt content of 12.0?Co?60.0% by weight, a nickel content of 10.0?Ni?36.0% by weight, remainder iron and an impurity content of less than 0.2 atomic percent, with a martensite temperature Ms of 75° C.?Ms?400° C. in the case of the martensitic variant and ?50° C.?Ms?25° C. in the case of the variant which is naturally hard as a result of cold-forming.
    Type: Grant
    Filed: August 18, 2005
    Date of Patent: August 25, 2009
    Assignee: Vacuumschmelze GmbH & Co. KG
    Inventors: Hartwin Weber, Waldemar Döring, Matthias Schierling
  • Patent number: 7442338
    Abstract: The present invention develops a manufacture method, via conventional liquid metallurgy, of finished and semi-finished metallic parts as casting, ingot, blooms and slabs in alloys base Fe, base Ni and base Co, microstructurally reinforced with complex molybdenum and titanium carbide particles, by means of their previous elaboration and latter addition to the molten alloy in the melting furnace. Then, when the alloy solidifies, they are inserted and distributed within the grains of the base metallic matrix, enhancing their mechanical properties and behavior at room as well as at high temperatures.
    Type: Grant
    Filed: May 13, 2004
    Date of Patent: October 28, 2008
    Assignee: Fundacion Inasmet
    Inventors: Ignacio Erauskin Lopetegui, Manuel Gutierrez Stampa, Inigo Agote Beloki, Manuel Orbegozo Ibarguren
  • Publication number: 20080185078
    Abstract: A Co-base alloy which has a basic composition including, in terms of mass proportion, 0.1%-10% Al, 3.0-45% W, and Co as the remainder and has an intermetallic compound of the Ll2 type [Co3(Al,W)] dispersed and precipitated therein. Part of the Co may be replaced with Ni, Ir, Fe, Cr, Re, or Ru, while part of the Al and W may be replaced with Ni, Ti, Nb, Zr, V, Ta or Hf. The intermetallic compound [Co3(Al, W)] has a high melting point, and this compound and the matrix are mismatched little with respect to lattice constant. Thus, the cobalt-base alloy can have high-temperature strength equal to that of nickel-base alloys and excellent structure stability.
    Type: Application
    Filed: February 25, 2008
    Publication date: August 7, 2008
    Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCY
    Inventors: Kiyohito ISHIDA, Ryosuke KAINUMA, Katunari OIKAWA, Ikuo OHNUMA, Jun SATO
  • Publication number: 20080185075
    Abstract: A Co-based alloy being useful as a spiral spring, common spring, wire, cable guide, steel belt, build-up material, guide wire, stent, catheter, etc. There is provided a Co-based alloy having a composition of Co—Al binary system containing 3-13% Al loaded with at least one workability enhancing element selected from among 001 to 50% Ni, 0.01 to 40% Fe and 0.01 to 30% Mn and having a lamellar structure wherein f.c.c. structure ?-phase and ?(B2)-phase are repeated in layers. The lamellar structure is so regulated that the occupancy ratio of the whole structure is 30 vol. % or above and the layer spacing is 100 ?m or less. The Co-based alloy may contain at least one optional component selected from among Ga, Cr, V, Ti, Mo, Nb, Zr, W, Ta, Hf, Si, Rh, Pd, Ir, Pt, Au, B, C and P may be added in a total amount of 0.01 to 60%.
    Type: Application
    Filed: April 7, 2008
    Publication date: August 7, 2008
    Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCY
    Inventors: Kiyohito ISHIDA, Kiyoshi YAMAUCHI, Ryosuke KAINUMA, Yuji SUTOU, Toshihiro OMORI
  • Patent number: 6986951
    Abstract: The present invention relates to a cobalt-based alloy for the coating of organs subject to erosion by liquid comprising chromium 28–32% by weight, tungsten 6–8% by weight, silicon 0.1–2% by weight, carbon 1.2–1.7% by weight, nickel 3–6% by weight, molybdenum 1–3%, cobalt the complement to 100%. The invention also relates to an application method of the alloy on organs subject to erosion by liquid, in particular vapour turbine blades, to reduce the metal erosion rate following impact with liquids.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: January 17, 2006
    Assignee: Nuovo Pignone Holdings S.p.A.
    Inventor: Massimo Giannozzi
  • Patent number: 6984458
    Abstract: The present invention relates to a method for treating organs subject to erosion by liquids, in particular vapour turbine components, which contemplates laser plating with a cobalt-based alloy comprising chromium from 28 to 32% by weight; tungsten from 5 to 7% by weight; silicon from 0.1 to 2% by weight; carbon from 1.2 to 1.7% by weight; nickel from 0.5 to 3% by weight; iron from 0.01 to 1% by weight; manganese from 0.01 to 1% by weight; molybdenum from 0.2 to 1% by weight; possible impurities or other elements from 0 to 0.5% by weight and cobalt the complement to 100%.
    Type: Grant
    Filed: October 31, 2003
    Date of Patent: January 10, 2006
    Assignee: Nuovo Pignone Holding S.p.A.
    Inventor: Massimo Giannozzi
  • Patent number: 6924046
    Abstract: A protective layer has the composition 0.5 to 2% of rhenium, 15 to 21% of chromium, 9 to 11.5% of aluminum, 0.05 to 0.7% of yttrium and/or at least one equivalent metal from the group consisting of scandium and the rare earths, 0 to 1% of ruthenium, remainder cobalt and/or nickel and production-related impurities, and is scarcely subject to any embrittlement from Cr/Re precipitations.
    Type: Grant
    Filed: November 5, 2003
    Date of Patent: August 2, 2005
    Assignee: Siemens Aktiengesellschaft
    Inventor: Werner Stamm
  • Patent number: 6720088
    Abstract: A group of alloys suitable for use in a high-temperature, oxidative environment, a protective coating system comprising a diffusion barrier that comprises an alloy selected from the group, an article comprising the diffusion barrier layer, and a method for protecting an article from a high-temperature oxidative environment comprising disposing the diffusion barrier layer onto a substrate are presented.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: April 13, 2004
    Assignee: General Electric Company
    Inventors: Ji-Cheng Zhao, Melvin Robert Jackson, Richard John Grylls, Ramgopal Darolia
  • Patent number: 6696176
    Abstract: A fusion weldable superalloy containing 0.005-0.5 wt. % scandium. In one embodiment, the superalloy may have a composition similar to IN-939 alloy, but having added scandium and having only 0.005-0.040 wt. % zirconium. A gas turbine component may be formed by an investment casting of such a scandium-containing superalloy, and may include a fusion weld repaired area. A scandium-containing nickel-based superalloy coated with an MCrAlY bond coat will have improved cyclic oxidation resistance due to the sulfur-gettering effect of the scandium.
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: February 24, 2004
    Assignee: Siemens Westinghouse Power Corporation
    Inventors: David B. Allen, Gregg P. Wagner, Brij B. Seth
  • Patent number: 6607614
    Abstract: The present invention provides amorphous non-laminar nickel phosphorous alloys, amorphous non-laminar nickel cobalt phosphorous alloys, or amorphous non-laminar cobalt phosphorous alloys. These alloys are useful in the formation of metal articles and metal-coated articles, including high precision devices and molds for plastics. In addition, the alloys of the present invention are useful in repairing damaged metal surfaces.
    Type: Grant
    Filed: October 16, 1998
    Date of Patent: August 19, 2003
    Assignee: Techmetals, Inc.
    Inventors: Rick Alan Richardson, Daniel A. Brockman
  • Publication number: 20020064678
    Abstract: To provide a corrosion-resisting and wear resisting alloy including cobalt, nickel or iron as a base used for a sliding part or a valve seat for a machine, and restraining erosion and corrosion caused by eutectic carbide constituting the alloy in an atmosphere with dissolved oxygen.
    Type: Application
    Filed: August 28, 2001
    Publication date: May 30, 2002
    Inventors: Yoshihisa Kiyotoki, Yoshiteru Chiba, Shin Kumagai, Yasuhiro Ogawa, Akira Sakamoto, Hiroyuki Shinohara
  • Patent number: 6077615
    Abstract: A Co-base alloy including, by weight, 0.03-0.10% C, not more than 1.0% Si, not more than 1.0% Mn, 20-30% Cr, 15-23% Ni, 3-10% W, 5-10% Ta and 0.05-0.7% Zr, is used as a welding material. A gas turbine nozzle has a crack repaired with a multi-layer weld using the Co-base alloy and a gas turbine for power generation employs the nozzle.
    Type: Grant
    Filed: December 16, 1997
    Date of Patent: June 20, 2000
    Assignee: Hitachi, Ltd.
    Inventors: Masami Yada, Takao Funamoto, Takamitsu Nakazaki, Kei Kobayashi, Norio Yokoba, Nobuyuki Iizuka, Kazuhiko Kumata
  • Patent number: 6004661
    Abstract: An amorphous magnetic material possesses a composition essentially expressed by (Fe.sub.1-a-b N.sub.a M.sub.b).sub.100-x-y Si.sub.x B.sub.y (M denotes at least one kind of element selected from Mn, Cr, Co, Nb, V, Mo, Ta, W and Zr, 0.395.ltoreq.a.ltoreq.0.7, 0.ltoreq.b.ltoreq.0.21, 1-a-b<a, 6.ltoreq.x.ltoreq.18 at %, 10.ltoreq.y.ltoreq.18 at %, respectively). An amorphous magnetic material which has such a Ni rich Fe-Ni base possesses a Curie temperature T.sub.c of 473 to 573K, the maximum magnetic flux density B.sub.m of 0.5 to 0.9T. A ratio of residual magnetic flux density B.sub.r and the maximum magnetic flux density B.sub.m can be controlled according to a required characteristics, and, in the case of being used in a saturable core, is set at 0.60 or more. With an amorphous magnetic material of an inexpensive Fe-Ni base, magnetic characteristics applicable in a high frequency region, thermal stability, surface smoothness can be realized.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: December 21, 1999
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Kazumi Sakai, Takao Kusaka, Yasuaki Moriya
  • Patent number: 5925197
    Abstract: A sintered hard alloy for tools for cutting wood. The alloy according to the present invention comprises 30-98 volume % hard constituents in a binder phase based on nickel and/or cobalt. The hard constituents comprise oxides, carbides, nitrides and/or borides of Al, Zr, Si and/or Ti, preferably Al.sub.2 O.sub.3, ZrC, ZrO.sub.2, SiC, Si.sub.3 N.sub.4 and/or TiB.sub.2 with a mean grain size <1.5 .mu.m, preferably <1.0 .mu.m. The binder phase comprises in solution, in weight %, Co max 90, Ni max 90, Cr 5-45.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: July 20, 1999
    Assignee: Sandvik AB
    Inventor: Enrico Galli
  • Patent number: 5916518
    Abstract: An improved cobalt-base braze alloy composition and method for diffusion brazing are provided for use in repairing superalloy articles, such as gas turbine engines, power generation turbines, refinery equipment, and heat exchangers. The improved cobalt-base braze alloy composition includes nickel; at least one element selected from the group of rhenium, palladium, and platinum; at least one element selected from the group of boron and silicon; and the remaining balance consists of cobalt. This composition may also include aluminum, and the composition may be combined with one or more powdered base metal superalloy compositions to form an improved diffusion braze alloy mixture. In the improved method for repairing superalloy articles, the foregoing mixture is applied to a region of the superalloy article to be repaired. The mixture is then heated to melt the cobalt-base braze alloy, thereby joining the base metal superalloy powder particles together, and joining the entire mixture to the region being repaired.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: June 29, 1999
    Assignee: Allison Engine Company
    Inventor: Richard Patrick Chesnes
  • Patent number: 5801630
    Abstract: A harmonic-type EAS marker includes a wire segment formed of cobalt alloy. To form the wire segment, the cobalt alloy is cast as an amorphous wire, die-drawn to a smaller diameter, and then annealed with application of longitudinal tension. The annealed wire is cut to produce wire segments which have a magnetic hysteresis loop with a large Barkhausen discontinuity at a lower threshold level than has previously been achieved.
    Type: Grant
    Filed: November 8, 1996
    Date of Patent: September 1, 1998
    Assignee: Sensormatic Electronics Corporation
    Inventors: Wing K. Ho, Jiro Yamasaki
  • Patent number: 5728279
    Abstract: Target for a magnetron-cathode sputtering apparatus is made from a cobalt base alloy containing additional elements in such concentrations that intermetallic phases are formed with at least one of these elements and intermetallic phases are observed on the basis of the phase diagram in the state of equilibrium at the operating temperature of the target. The grain boundaries, sub-grain boundaries, twin-grain boundaries or slip bands of the cobalt mixed crystal forming the matrix are decorated with the elements forming the intermetallic phases. X-ray diffraction diagrams made from the target display reflections of an intermetallic phase which is largely absent in the cast state and which forms only during a heat treatment in the temperature range below the solidus temperature of the alloy by a solid state reaction.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: March 17, 1998
    Assignee: Leybold Materials GmbH
    Inventors: Martin Schlott, Martin Weigert, Kwei Teng, Bruce Gehman
  • Patent number: 5702542
    Abstract: Metal-matrix composites and methods for producing these composites are provided. The manufacturing methods include providing a ceramic preform having a uniform distribution of ceramic particles sintered to one another. The particles include an average particle size of no greater than about 3 microns, and at least one half of the volume of the preform is occupied by porosity. The preform is then disposed into a mold and contacted by molten metal. The molten metal is then forced into the pores of the preform and permitted to solidify to form a solid metal-matrix composite. This composite is machinable with a high-speed steel (HSS) bit for greater than about 1 minute without excessive wear occurring to the bit. This invention preferably employs metal-matrixes including Al, Li, Be, Pb, He, Au, Sn, Mg, Ti, Cu, and Zn. Preferred ceramics include oxides, borides, nitrides, carbides, carbon, or a mixture thereof. Inert gas pressures of less than about 3,000 psi can be used to easily infiltrate the preforms.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: December 30, 1997
    Inventors: Alexander M. Brown, Eric M. Klier
  • Patent number: 5587259
    Abstract: A metal current collecting substrate for an air cathode in an electrochemical metal air cell is provided for, wherein the substrate is hardened by one of the steps of sandblasting, shotblasting, plastic deformation of the substrate below the recrystallization temperature range of the metal thereof, and heating the substrate to above the transformation temperature of the metal thereof followed by quenching the substrate below the transformation temperature of the metal thereof. Catalytically active materials, most preferably a mixture of carbon and manganese dioxide, are pressed or otherwise disposed upon the hardened substrate. The substrate is capable of being connected to electrical circuitry. Most preferably, the substrate is a metal screen that has been hardened, roughened and pitted by sandblasting before the catalytically active materials are disposed thereupon, and before the substrate is incorporated into an electrochemical metal air cell.
    Type: Grant
    Filed: March 9, 1994
    Date of Patent: December 24, 1996
    Assignee: Rayovac Corporation
    Inventors: Robert B. Dopp, John E. Oltman, Joseph L. Passaniti
  • Patent number: 5429883
    Abstract: An alloy having excellent corrosion resistance and abrasion resistance, is provided comprising a matrix metal phase comprised of at least one member selected from an Fe-base alloy, a Co-base alloy and a Ni-base alloy and, present in the matrix metal phase, 10 to 65%, in terms of the area, of a substantially homogeneously crystallized and/or precipitated VC particle phase having a particle diameter of 5 .mu.m or less.A surface-modified metallic member, is also provided comprising a metallic member and the above-described alloy, the alloy being integrally coated on the surface of the metallic member at its desired portion.
    Type: Grant
    Filed: May 20, 1993
    Date of Patent: July 4, 1995
    Assignees: Toshiba Kikai Kabushiki Kaisha, Daido Steel Co., Ltd.
    Inventors: Kyoichi Sasaki, Yoshihisa Kato
  • Patent number: 5238481
    Abstract: A heat-resistant sintered hard alloy comprises 35% to 95% by weight of a WCoB type complex boride in a cobalt base alloy. The alloy contains 1.5% to 4.1% boron, 19.1% to 69.7% tungsten, optionally to 25% chromium, the balance being cobalt and a maximum of 1% impurities. Nickel, iron and/or copper may be substituted for portions of the cobalt content.
    Type: Grant
    Filed: January 23, 1992
    Date of Patent: August 24, 1993
    Assignee: Toyo Kohan Co., Ltd.
    Inventors: Kenichi Takagi, Masao Komai, Yoshihiko Isobe
  • Patent number: 5169463
    Abstract: A work-strengthenable alloy which includes a gamma prime phase gamma prime particles comprising the following elements in percent by weight:______________________________________ molybdenum 6-16 chromium 13-25 iron 0-23 nickel 10-55 carbon 0-0.05 boron 0-0.05 cobalt balance, at least 20, ______________________________________said alloy also containing one or more elements which form gamma prime phase with nickel,the electron vacancy number, N.sub.v, of the alloy being defined byN.sub.v =0.61 Ni+1.71 Co+2.66 Fe+4.66 Cr+566 Mowherein the respective chemical symbols represent the effective atomic fractions of the respective elements present in the alloy, said value not exceeding the valueN.sub.v =2.82-0.017 W.sub.Fe,where W.sub.Fe is the percent by weight of iron in the alloy for those alloys containing no iron or less than 13 percent by weight iron and W.sub.Fe is 13 for the alloys containing from 13-23 percent by weight iron. The alloys are formed by a melt; and heating the alloy at a temperature of from 600.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: December 8, 1992
    Assignee: SPS Technologies, Inc.
    Inventors: Roger D. Doherty, Rishi P. Singh
  • Patent number: 4938805
    Abstract: Cobalt-base superalloys having special utility in the production of industrial gas turbine hot gas path components because of their unique combination of properties in specially heat-treated condition including excellent hot corrosion resistance, stress-rupture strength at high temperature, metallurgical stability, tensile ductility and weldability, consist essentially of 0.3 to 0.6% carbon, 27-35% chromium, 9-16% nickel, 6-9% tungsten, 0.45 to 2.0% tantalum, up to 3.0% hafnium, up to 0.7% zirconium, not more than 2.0% iron, 1.5% manganese and silicon and 0.
    Type: Grant
    Filed: July 14, 1986
    Date of Patent: July 3, 1990
    Assignee: General Electric Company
    Inventors: John S. Haydon, Adrian M. Beltran, John H. Wood
  • Patent number: 4908069
    Abstract: A method of making a work-strengthenable alloy which includes a gamma prime phase which method comprises forming a melt comprising the following elements in percent by weight:______________________________________ molybdenum 6-16 chromium 13-25 iron 0-23 nickel 10-55 carbon 0-0.05 boron 0-0.05 cobalt balance, at least 20, ______________________________________said alloy also containing one or more elements which form gamma prime phase with nickel, the electron vacancy number, N.sub.v, of the alloy being defined byN.sub.v =0.61 Ni+1.71 Co+2.66 Fe+4.66 Cr+5.66 Mowherein the respective chemical symbols represent the effective atomic fractions of the respective elements present in the alloy, said value not exceeding the valueN.sub.v =2.82-0.017 W.sub.Fe,where W.sub.Fe is the percent by weight of iron in the alloy for those alloys containing no iron or less than 13 percent by weight iron and W.sub.
    Type: Grant
    Filed: October 19, 1987
    Date of Patent: March 13, 1990
    Assignee: SPS Technologies, Inc.
    Inventors: Roger D. Doherty, Rishi P. Singh
  • Patent number: 4789412
    Abstract: A cobalt-base alloy comprises 0.2-1 wt % C 0.4-2 wt % Si, 0.2-1.5 wt % Mn, 5-15 wt % Ni, 20-35 wt % Cr, 3-15 wt % W, 0.003-0.1 wt % Ni, 20-35 wt % Cr, 3-15 wt % W, 0.003-0.1 wt % B, 0.05-1 wt % Nb, 0.01-1 wt % Ta, 2 wt % or less Fe, 30 ppm or less oxygen, 100 ppm or less nitrogen, and the balance of 45 wt % or more Co, wherein the content of Si is larger than that of Mn. The alloy is in a form of casting and has a structure containing a eutectic carbide and a secondary carbide dispersed therein. The cast alloy is produced through solution treatment at 1,100.degree.-1.200.degree. C., and aging treatment at 950.degree.-1,050.degree. C., and cooling rate after the solution treatment and after the aging treatment is 150.degree. to 300.degree. C./h. A gas turbine nozzle is made of a casting of the above-mentioned alloy.
    Type: Grant
    Filed: March 19, 1987
    Date of Patent: December 6, 1988
    Assignee: Hitachi, Ltd.
    Inventors: Shigeyoshi Nakamura, Tetsuo Kashimura, Nobuyuki Iizuka, Yutaka Fukui, Minoru Morikawa, Soichi Kurosawa
  • Patent number: 4761177
    Abstract: Fine cobalt or nickel powder is produced by hydrogen reduction of a sulfate solution in the presence of a base and a strong reductant such as a metal borohydride wherein the base is added stagewise to the solution with the initial addition of base being sufficient to insure an essentially neutral pH at the time of reductant addition.
    Type: Grant
    Filed: June 26, 1987
    Date of Patent: August 2, 1988
    Assignee: AMAX Inc.
    Inventors: Eddie C. Chou, Leo W. Beckstead, Luther R. Tinnin
  • Patent number: 4755240
    Abstract: The present invention provides Ni (and/or Co) base precipitation hardened alloy compositions having improved resistance to stress corrosion cracking and being comprised of:12-25 wt. % Cr;0-10 wt. % Mo;0-12 wt. % W, with the proviso that Mo+0.5 W is .gtoreq.2 wt. % and .ltoreq.10 wt. % and with the proviso that Cr+Mo+0.5 W is .ltoreq.28 wt. %;2-6 wt. % of one or more of Al, Nb, and Ti;<0.05 wt. % C;<0.05 wt. % O;<0.05 wt. % N; and the balance being Ni (and/or Co) and any incidental impurities,wherein the concentrations of Ni (and/or Co), Cr and Mo (and/or W) are correlated so that their combination represents a point within the area ABCD of FIG. 1 hereof. Preferably, the ratio, expressed in atomic percent, of Al to Nb+Ti is between about 0 and 4.0, preferably between about 0.8 and 1.5, more preferably about 1. In addition, Hf is preferably included in a concentration, expressed in weight percent, of between about 10 (C+O+N) and 30 (C+O+N), more preferably between about 15 (C+O+N) and 20 (C+O+N).
    Type: Grant
    Filed: May 12, 1986
    Date of Patent: July 5, 1988
    Assignees: Exxon Production Research Company, Exxon Research and Engineering Company
    Inventors: Reghavan Ayer, Glen A. Vaughn, Lawrence J. Sykes
  • Patent number: 4714468
    Abstract: A dispersion strengthened cobalt-chromium-molybdenum alloy produced by gas atomization containing a fine oxide dispersion, and characterized, after fabrication by gas atomization, thermomechanical processing and further high temperature exposure, by excellent corrosion resistance, high fatigue strength, high ductility and high temperature stability; a process for producing said alloy and prostheses formed from said alloy.
    Type: Grant
    Filed: January 27, 1987
    Date of Patent: December 22, 1987
    Assignee: Pfizer Hospital Products Group Inc.
    Inventors: Kathy K. Wang, Larry J. Gustavson, John H. Dumbleton
  • Patent number: 4668290
    Abstract: A dispersion strengthened cobalt-chromium-molybdenum alloy produced by gas atomization containing a fine oxide dispersion, and characterized, after fabrication by gas atomization, thermomechanical processing and further high temperature exposure, by excellent corrosion resistance, high fatigue strength, high ductility and high temperature stability; a process for producing said alloy and prostheses formed from said alloy.
    Type: Grant
    Filed: August 13, 1985
    Date of Patent: May 26, 1987
    Assignee: Pfizer Hospital Products Group Inc.
    Inventors: Kathy K. Wang, Larry J. Gustavson, John H. Dumbleton
  • Patent number: 4631082
    Abstract: An oxide dispersion strengthened cobalt-chromium superalloy produced by mechanical alloying containing a refractory oxide, preferably yttrium oxide, and characterized by excellent corrosion resistance, high fatigue strength and high temperature stability; and prostheses formed from said superalloy.
    Type: Grant
    Filed: February 20, 1985
    Date of Patent: December 23, 1986
    Assignee: Pfizer Hospital Products Group Inc.
    Inventors: Henry L. Andrews, Gregory E. Gardiner
  • Patent number: 4473417
    Abstract: There is disclosed an amorphous alloy for a magnetic core material represented by the formula(Co.sub.1-x.sbsb.1.sub.-x.sbsb.2 Fe.sub.x.sbsb.1 M.sub.x.sbsb.2).sub.x.sbsb.3 B.sub.x.sbsb.4 Si.sub.100-x.sbsb.3.sub.-x.sbsb.4wherein M is at least one element selected from the group consisting of Ti, V, Cr, Mn, Ni, Zr, Nb, Mo, Ru, Hf, Ta, W and Re, and x.sub.1, x.sub.2, x.sub.3 and x.sub.4 are numbers which satisfy relations of 0.ltoreq.x.sub.1 .ltoreq.0.10, 0.ltoreq.x.sub.2 .ltoreq.0.10, 70.ltoreq.x.sub.3 .ltoreq.79 and 5.ltoreq.x.sub.4 .ltoreq.9, respectively.According to the present invention, it could be provided an amorphous alloy suitable for a magnetic core material of a magnetic amplifier in which its coercive force is as low as 0.4 oersted or less at a high frequency of 20 KHz or more, particularly even at 50 KHz, and its rectangular ratio is as much as 85% or more.
    Type: Grant
    Filed: August 6, 1982
    Date of Patent: September 25, 1984
    Assignee: Tokyo Shibaura Denki Kabushiki Kaisha
    Inventors: Koichiro Inomata, Michio Hasegawa, Masakatsu Haga, Takao Sawa
  • Patent number: 4437913
    Abstract: A cobalt base alloy having a superior high-temperature strength and high-temperature ductility, containing, by weight, 0.15 to 2% carbon, less than 2% silicon, less than 2% manganese, 5 to 15% nickel, 18 to 35% chromium, 3 to 15% tungsten, 0.003 to 0.1% boron, 0.01 to 1% niobium, 0.01 to 1% zirconium, less than 110% iron, less than 1% tantalum, less than 1% hafnium and remainder cobalt. At least one of 0.01 to 1 wt% titanium and 0.01 to 1 wt% (combined amount) rare earth elements is added to the alloy. The alloy is used as a casting and contains eutectic carbides and secondary carbides precipitated substantially uniformly in the grains. If the secondary carbides are formed by an age-treatment conducted at a higher temperature than that at which the alloy is actually used, the high-temperature strength and the high-temperature ductility of the alloy are remarkably improved. The cobalt base alloy is formed into gas turbine nozzles by a precision casting.
    Type: Grant
    Filed: July 24, 1981
    Date of Patent: March 20, 1984
    Assignee: Hitachi, Ltd.
    Inventors: Yutaka Fukui, Tetsuo Kashimura