Nickel Base Patents (Class 148/409)
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Patent number: 9617856Abstract: An Ni base forged alloy is easy to make hot forging and miniaturization of crystal grains while excellent high-temperature strength and segregation property are compatible. The Ni base forged alloy has solid solution temperature of a precipitation strengthening phase lower than or equal to 970° C., difference in the solid solution temperature between a ?-phase and the precipitation strength phase larger than or equal to 50° C., Al of 0.5 to 1.0%, Cr of 17 to 21%, Fe of 17 to 19%, Nb of 4.5 to 5.5%, Ti of 0.8 to 1.3%, W of 3.0 to 6.0%, B of 0.001 to 0.03%, C of 0.001 to 0.1% and Mo of 1.0% or less in mass percentage [%] and remainder made of Ni and inevitable impurities.Type: GrantFiled: August 20, 2013Date of Patent: April 11, 2017Assignee: Mitsubishi Hitachi Power Systems, Ltd.Inventors: Takashi Shibayama, Shinya Imano, Hironori Kamoshida, Hidetoshi Kuroki, Jun Sato
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Patent number: 9254518Abstract: A method of manufacturing a crankshaft comprising providing two parts, each part comprising two webs, a portion of a crank journal and a portion of a main journal, welding the two portions of the crank journal together, heating the crank journal, inserting a shim between the webs, and upset forging to reduce the length of the crank journal to form a forged segment. Alternatively, the portions of the main journal may be welded, heated, shimmed, and forged to form a forged segment. The crankshaft may be lengthened by adding additional parts or forged segments using the same steps. A production line for carrying out this method when producing a crankshaft with n number of crank journals, where n is an even integer.Type: GrantFiled: August 2, 2015Date of Patent: February 9, 2016Inventor: Dusan Milicevic
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Patent number: 8821654Abstract: An alloy comprising 5 at %?Al<16 at %, about 0.05 at % to 1 at % of a reactive element selected from the group consisting of Hf, Y, La, Ce, Zr, and combinations thereof, and Ni, wherein the alloy composition has a predominately ?-Ni+??-Ni3Al phase constitution.Type: GrantFiled: July 15, 2008Date of Patent: September 2, 2014Assignee: Iowa State University Research Foundation, Inc.Inventors: Brian M. Gleeson, Daniel J. Sordelet
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Publication number: 20140154093Abstract: A method of heat treating a superalloy article is disclosed. The method includes hot-working an article comprising an superalloy to produce a hot-worked microstructure throughout the article; solution treating the article at a temperature and for a time sufficient to form a partially recrystallized warm-worked microstructure throughout the article; and cooling the article. The method also includes precipitation aging the article at a first precipitation aging temperature of about 1300° F. to about 1400° F. for a first duration of about 4 hours to about 12 hours; cooling the article to a second precipitation aging temperature; precipitation aging the article at a second precipitation aging temperature of about 1150° F. to about 1200° F. for a second duration of about 4 hours to about 12 hours; and cooling the article from the second precipitation aging temperature to an ambient temperature.Type: ApplicationFiled: October 29, 2012Publication date: June 5, 2014Applicant: GENERAL ELECTRIC COMPANYInventors: JEFFREY ALLEN HAWK, ROBIN CARL SCHWANT
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Publication number: 20140020797Abstract: The method provides heat-resistant chromia- or alumina-forming Fe-, Fe(Ni), Ni(Fe), or Ni-based alloys having improved creep resistance. A precursor is provided containing preselected constituents of a chromia- or alumina-forming Fe-, Fe(Ni), Ni(Fe), or Ni-based alloy, at least one of the constituents for forming a nanoscale precipitate MaXb where M is Cr, Nb, Ti, V, Zr, or Hf, individually and in combination, and X is C, N, O, B, individually and in combination, a=1 to 23 and b=1 to 6. The precursor is annealed at a temperature of 1000-1500° C. for 1-48 h in the presence of a magnetic field of at least 5 Tesla to enhance supersaturation of the MaXb constituents in the annealed precursor. This forms nanoscale MaXb precipitates for improved creep resistance when the alloy is used at service temperatures of 500-1000° C. Alloys having improved creep resistance are also disclosed.Type: ApplicationFiled: July 20, 2012Publication date: January 23, 2014Applicant: UT-BATTELLE, LLCInventors: Michael P. BRADY, Gail M. LUDTKA, Gerard M. LUDTKA, Govindarajan MURALIDHARAN, Don M. NICHOLSON, Orlando RIOS, Yukinori YAMAMOTO
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Publication number: 20120037280Abstract: A method for manufacturing a blank part in Ni-base superalloy, wherein an alloy is prepared and heat treatments are conducted characterized in that: the said superalloy contains at least a total of 2.5% of Nb and Ta; heat treatment is conducted comprising a plurality of steps: a first step at between 850 and 1000° C. held for at least 20 minutes to precipitate the ? phase at the grain boundaries; a second step held at a temperature higher than the temperature of the first step allowing partial dissolution of the ? phase obtained at the first step; ageing treatment comprising a third step and optionally one or more additional steps at a temperature below the temperature of the first step and allowing precipitation of the hardening phases ?? and ??. Part thus obtained.Type: ApplicationFiled: February 5, 2010Publication date: February 16, 2012Applicants: AUBERT & DUVAL, SNECMA, TURBOMECAInventor: Alexandre Devaux
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Patent number: 7828915Abstract: A method for making Mg(magnesium)-based intermetallic compound uses a thermal process during a melting process to produce largely the Mg-based intermetallic compound. The vapor pressure of Mg is high, thereby Mg is prone to be vaporized from a melt and a wrought solid alloy in the melting process of high temperature, for purifying the wrought Mg-based intermetallic compound. The method may simplify the process and devices for making the Mg-based intermetallic compound, and produce efficiently a larger of high purity Mg-based intermetallic compound.Type: GrantFiled: December 10, 2007Date of Patent: November 9, 2010Assignee: National Central UniversityInventors: Sheng-Long Lee, Jing-Chie Lin, Che-Wei Hsu, Cheng-Yu Chou, Yin-Chun Cheng, Chia-Wang Weng, Chien-Chang Chiang, Chien-Wei Chen
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Publication number: 20100043924Abstract: A method for locally heat-treating a gas turbine engine superalloy article to improve resistance to strain-induced fatigue of the article is disclosed. The method comprises providing a gas turbine engine superalloy article having a gamma prime solvus temperature; and locally over aging only a selected portion of the article to locally improve fatigue resistance at the selected portion of the article, wherein the local over age cycle includes heating at about 843° C. for about 3 to 4 hours.Type: ApplicationFiled: December 18, 2008Publication date: February 25, 2010Inventor: Jon Raymond Groh
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Publication number: 20100012235Abstract: An alloy comprising 5 at % ?Al<16 at %, about 0.05 at % to 1 at % of a reactive element selected from the group consisting of Hf, Y, La, Ce, Zr, and combinations thereof, and Ni, wherein the alloy composition has a predominately ?-Ni+??-Ni3Al phase constitution.Type: ApplicationFiled: July 15, 2008Publication date: January 21, 2010Applicant: Iowa State University Research Foundation, Inc.Inventors: Brian M. Gleeson, Daniel J. Sordelet
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Publication number: 20090148337Abstract: Disclosed herein are a method of manufacturing a Ni-based superalloy component for a gas turbine using a one-step process of hot isostatic pressing (HIP) and heat treatment, and a component manufactured by the method. In the method, an HIP process and a heat treatment process, which have been performed to manufacture or repair a Ni-based superalloy component for a gas turbine, are performed as a one-step process using an HIP apparatus. Thus, component defects, such as micropores and microcracks, which are generated when casting, welding, or brazing the Ni-based superalloy component for a gas turbine used for a combined cycle thermal power plant or airplane, can be cured using an HIP apparatus at high temperature and high pressure and, at the same time, the physical properties of the Ni-based superalloy component can be optimized using the heat treatment process.Type: ApplicationFiled: October 31, 2007Publication date: June 11, 2009Applicant: Korea Electric Power CorporationInventors: Min-Tae KIM, Sung-Yong Chang, Jong-Bum Won, Won-Young Oh
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Patent number: 7537725Abstract: A compositionally graded gas turbine disk is made by placing a cylindrically symmetric slip case concentrically into an interior of a cylindrically symmetric outer container. A first nickel-base superalloy powder is loaded into a radially inner first portion of the interior and a second nickel-base superalloy powder is loaded into a radially outer second portion of the interior. The slip case is removed so that the first nickel-base superalloy powder and the second nickel-base superalloy powder contact in the transition region and form a non-compacted powder mass. The non-compacted powder mass is processed into a gas turbine disk, typically by compacting the non-compacted powder mass to form a compacted powder mass, and thereafter heat treating the compacted powder mass.Type: GrantFiled: September 19, 2005Date of Patent: May 26, 2009Assignee: General Electric CompanyInventors: Jon Raymond Groh, Eric Allen Ott, Robert Edward Schafrik, Daniel Donald Krueger
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Patent number: 7442338Abstract: The present invention develops a manufacture method, via conventional liquid metallurgy, of finished and semi-finished metallic parts as casting, ingot, blooms and slabs in alloys base Fe, base Ni and base Co, microstructurally reinforced with complex molybdenum and titanium carbide particles, by means of their previous elaboration and latter addition to the molten alloy in the melting furnace. Then, when the alloy solidifies, they are inserted and distributed within the grains of the base metallic matrix, enhancing their mechanical properties and behavior at room as well as at high temperatures.Type: GrantFiled: May 13, 2004Date of Patent: October 28, 2008Assignee: Fundacion InasmetInventors: Ignacio Erauskin Lopetegui, Manuel Gutierrez Stampa, Inigo Agote Beloki, Manuel Orbegozo Ibarguren
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Patent number: 6924046Abstract: A protective layer has the composition 0.5 to 2% of rhenium, 15 to 21% of chromium, 9 to 11.5% of aluminum, 0.05 to 0.7% of yttrium and/or at least one equivalent metal from the group consisting of scandium and the rare earths, 0 to 1% of ruthenium, remainder cobalt and/or nickel and production-related impurities, and is scarcely subject to any embrittlement from Cr/Re precipitations.Type: GrantFiled: November 5, 2003Date of Patent: August 2, 2005Assignee: Siemens AktiengesellschaftInventor: Werner Stamm
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Patent number: 6908691Abstract: The aim of the invention is to provide a metal strip for epitaxial coating with a biaxially textured layer, this metal strip, however, being able to be produced in an uncomplicated manner and having a high tensile strength, low magnetic losses and/or a high electrical conductivity. According to the invention, the metal strip is comprised of Nj, Cu, Ag or alloys thereof all serving as basic material, whereby the one-layer metal strip and, in the instance of a multilayer metal strip, at least one of its layers contains 10 nm to 5 ?m large, strength-increasing dispersoids comprised of carbides, borides, oxides and/or nitrides with a volume proportion ranging from 0.1 to 5%. In the instance of a multilayer metal strip, the layers form a composite, and at least one of the layers does not contain any dispersoids and has a biaxial texture. For the production, a starting material is used, which is comprised of Ni, Cu, Ag or of alloys thereof all serving as basic material and which contains 0.Type: GrantFiled: December 5, 2001Date of Patent: June 21, 2005Assignee: Institut fuer Festkoerper-und Werkstoffforschung Dresden e.V.Inventors: Bernd De Boer, Bernhard Holzapfel, Gunter Risse
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Publication number: 20040170896Abstract: A hydrogen absorbing alloy containing at least a rare-earth element, magnesium (Mg), nickel (Ni) and aluminum (Al), having an intensity ratio (IA/IB) of not smaller than 0.6 (where IA represents an intensity of the highest peak in a range of 2&thgr;=30°˜34° in the X-ray diffraction pattern using CuK&agr;-radiation as the X-ray source and IB represents the intensity of the highest peak in a range of 2&thgr;=40°˜44°), and not substantially including La as the rare-earth element.Type: ApplicationFiled: February 27, 2004Publication date: September 2, 2004Inventors: Tetsuyuki Murata, Shigekazu Yasuoka, Jun Ishida
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Patent number: 6780295Abstract: A method for making a nickel/silicon sputter target, targets made thereby and sputtering processes using such targets. The method includes the step of blending molten nickel with sufficient molten silicon so that the blend may be cast to form an alloy containing no less than 4.5 wt % silicon. Preferably, the cast ingot is then shaped by rolling it to form a plate having a desired thickness. Sputter targets so formed are capable of use in a conventional magnetron sputter process; that is, one can be positioned near a cathode in the presence of an electric potential difference and a magnetic field so as to induce sputtering of nickel ion from the sputter target onto the substrate.Type: GrantFiled: May 30, 2002Date of Patent: August 24, 2004Assignee: Tosoh SMD, Inc.Inventor: Eugene Y. Ivanvov
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Patent number: 6720088Abstract: A group of alloys suitable for use in a high-temperature, oxidative environment, a protective coating system comprising a diffusion barrier that comprises an alloy selected from the group, an article comprising the diffusion barrier layer, and a method for protecting an article from a high-temperature oxidative environment comprising disposing the diffusion barrier layer onto a substrate are presented.Type: GrantFiled: February 5, 2002Date of Patent: April 13, 2004Assignee: General Electric CompanyInventors: Ji-Cheng Zhao, Melvin Robert Jackson, Richard John Grylls, Ramgopal Darolia
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Patent number: 6632299Abstract: A nickel-base superalloy that exhibits outstanding mechanical properties under high temperature and high strain conditions when cast in an equiaxed and/or directionally solidified, columnar grain structure, and which exhibits increased grain boundary strength and ductility while maintaining microstructural stability includes, in percentages by weight, 5-6 chromium, 9-9.5 cobalt, 0.3-0.7 molybdenum, 8-9 tungsten, 5.9-6.3 tantalum, 0.05-0.25 titanium, 5.6-6.0 aluminum, 2.8-3.1 rhenium, 1.1-1.8 hafnium, 0.10-0.12 carbon, 0.010-0.024 boron, 0.011-0.020 zirconium, with the balance being nickel and incidental impurities. The superalloys of this invention are useful for casting gas turbine engine components exhibiting significantly improved low cycle fatigue life, improved airfoil high temperature stress rupture life, significantly reduced life cycle cost, and longer useful life.Type: GrantFiled: October 19, 2000Date of Patent: October 14, 2003Assignee: Cannon-Muskegon CorporationInventor: Kenneth Harris
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Patent number: 6607614Abstract: The present invention provides amorphous non-laminar nickel phosphorous alloys, amorphous non-laminar nickel cobalt phosphorous alloys, or amorphous non-laminar cobalt phosphorous alloys. These alloys are useful in the formation of metal articles and metal-coated articles, including high precision devices and molds for plastics. In addition, the alloys of the present invention are useful in repairing damaged metal surfaces.Type: GrantFiled: October 16, 1998Date of Patent: August 19, 2003Assignee: Techmetals, Inc.Inventors: Rick Alan Richardson, Daniel A. Brockman
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Patent number: 6592810Abstract: Disclosed is an Fe—Ni alloy consisting of, by mass, 30 to 50% of Ni (or 27 to 47% Ni and not more than 22% Co), 0.005 to 0.1% of Nb, less than 0.01% of C, 0.002 to 0.02% of N, and the balance of Fe and inevitable impurities, wherein the equation “0.000013≦(% Nb)×(% N)≦0.002”, is fulfilled. In the alloy, preferably, the maximum grain size of compounds primarily containing Nb and nitrogen and other compounds primarily containing Nb and C is less than 0.5 &mgr;m, which can be observed at an fractional section of metal structure, and a total number of the compounds is not less than 50,000/mm2 at an fractional section. An average grain size of the alloy structure is not less than 10 by the crystal grain size number as defined in JIS G0551. The alloy may applied to shadow masks for the Braun tube and lead frames for semiconductor elements.Type: GrantFiled: March 19, 2001Date of Patent: July 15, 2003Assignee: Hitachi Metals, Ltd.Inventors: Junichi Nishida, Ryoji Inoue, Takehisa Seo
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Patent number: 6531002Abstract: An article, such as a turbine engine component, formed from a nickel-base superalloy, the nickel-base superalloy containing a &ggr;″ tetragonal phase and comprising aluminum, titanium, tantalum, niobium, chromium, molybdenum, and the balance nickel, wherein the article has a time dependent crack propagation resistance of at least about 20 hours to failure at about 1100° F. in the presence of steam. The invention also includes a nickel-base superalloy for forming such and article and methods of forming the article and making the nickel-base superalloy.Type: GrantFiled: April 24, 2001Date of Patent: March 11, 2003Assignees: General Electric Company, INCO Alloys International Inc.Inventors: Michael Francis Henry, Elena Rozier Gearing, Samuel Vinod Thamboo, Sarwan Kumar Mannan, John Joseph deBarbadillo, II
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Patent number: 6494971Abstract: An iridium-containing nickel-base superalloy which has an orderly arrayed allow structure to be strengthened by precipitation and contains iridium dissolved in the &ggr; and &ggr;′ phases to be strengthened by solid solution, thus being improved in high-temperature strength and resistance to high-temperature corrosion.Type: GrantFiled: June 17, 1999Date of Patent: December 17, 2002Assignee: National Research Institute for MetalsInventors: Toshiharu Kobayashi, Yutaka Koizumi, Hideyuki Murakami, Yoshikazu Ro, Yoko Yamabe, Shizuo Nakazawa, Hiroshi Harada, Toshihiro Yamagata
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Patent number: 6478895Abstract: The sputter target deposits nickel from a binary alloy. The binary alloy contains, by weight percent, 9 to 15 titanium and the balance nickel and incidental impurities. The binary alloy has, by weight percent, 35 to 50 TiNi3 needle-like intermetallic phase and balance &agr;-nickel phase. The TiNi3 needle-like intermetallic phase and &agr;-nickel phase are formed from a eutectic decomposition. The &agr;-nickel phase has a grain size between 50 and 180 &mgr;m. The binary alloy has a Curie temperature of less than or equal to a temperature of 25° C. and exhibits paramagnetic properties at temperatures of 25° C. or lower.Type: GrantFiled: April 25, 2001Date of Patent: November 12, 2002Assignee: Praxair S.T. Technology, Inc.Inventors: Holger J. Koenigsmann, Paul S. Gilman, Thomas J. Hunt
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Patent number: 6475261Abstract: In an NiMnGa alloy represented by the chemical formula of Ni2+XMn1−X Ga, a composition ratio parameter X (mol) is selected within a range of 0.10≦X≦0.30. With this composition, the finish point of the reverse transformation of the martensitic transformation can be selected to a desired temperature within the range between −20° C. and 50° C., while the Curie point is also selected to a desired temperature within the range between 60° C. and 85° C. The alloy has the shape memory effect by the martensitic transformation and the reverse transformation. Furthermore, the alloy is induced with the reverse transformation by application of an external magnetic field at the martensite phase to exhibit the shape recovery.Type: GrantFiled: January 25, 1999Date of Patent: November 5, 2002Inventors: Minoru Matsumoto, Junji Tani, Toshiyuki Takagi, Kiyoshi Yamauchi
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Publication number: 20020159911Abstract: The sputter target deposits nickel from a binary alloy. The binary alloy contains, by weight percent, 9 to 15 titanium and the balance nickel and incidental impurities. The binary alloy has, by weight percent, 35 to 50 TiNi3 needle-like intermetallic phase and balance &agr;-nickel phase. The TiNi3 needle-like intermetallic phase and &agr;-nickel phase are formed from a eutectic decomposition. The &agr;-nickel phase having a grain size between 50 and 180 &mgr;m. The binary alloy has a Curie temperature of less than or equal to a temperature of 25° C. and exhibits paramagnetic properties at temperatures of 25° C. or lower.Type: ApplicationFiled: April 25, 2001Publication date: October 31, 2002Inventors: Holger J. Koenigsmann, Paul S. Gilman, Thomas J. Hunt
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Patent number: 6471790Abstract: The invention relates to a process for the forming of precipitates of carbides and borides along the grain boundaries of an component made from an Ni based superalloy while in solid state. This follows from the finding that the carbides formed by carburization offer similar grain boundary strengthening properties as those cast into the article using the current art without the detrimental effects of adding more carbon to the alloy prior to casting. With advantage the process will be carried out in a way to form secondary caribides in the form Cr23C6, Cr7C, Cr6C and HfC and may take place before, during or after the normal solution and/or precipitation hardening heat treatments of the component.Type: GrantFiled: August 9, 2000Date of Patent: October 29, 2002Assignee: ALSTOM (Switzerland) LtdInventor: John Fernihough
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Publication number: 20020124915Abstract: The present inventions offer a nickel-based single crystal alloy which has a high strength, is easy in conducting the solution heat treatment, hardly gives a harmful phase and is resistant to corrosion at high temperature.Type: ApplicationFiled: May 7, 2002Publication date: September 12, 2002Inventors: Toshiharu Kobayashi, Yutaka Koizumi, Shizuo Nakazawa, Hiroshi Harada, Toshihiro Yamagata
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Patent number: 6287398Abstract: A high strength nickel-base alloy consisting essentially of, by weight percent, 50 to 60 nickel, 19 to 23 chromium, 18 to 22 iron, 3 to 4.4 aluminum, 0 to 0.4 titanium, 0.05 to 0.5 carbon, 0 to 0.1 cerium, 0 to 0.3 yttrium, 0.002 to 0.4 total cerium plus yttrium, 0.0005 to 0.4 zirconium, 0 to 2 niobium, 0 to 2 manganese, 0 to 1.5 silicon, 0 to 0.1 nitrogen, 0 to 0.5 calcium and magnesium, 0 to 0.1 boron and incidental impurities. The alloy forms 1 to 5 mole percent Cr7C3 after 24 hours at a temperature between 950 and 1150° C. for high temperature strength.Type: GrantFiled: December 9, 1998Date of Patent: September 11, 2001Assignee: Inco Alloys International, Inc.Inventors: Gaylord Darrell Smith, Norman Farr, Brian Allen Baker
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Patent number: 6165627Abstract: An INVAR.RTM. or iron nickel alloy or iron nickel cobalt alloy wire has an area ratio of carbide existing at the grain boundaries of the wire in the finished wire of at most 4%, or an average grain size in the transverse direction within a range of 1 to 5 .mu.m. Such a wire has a superior twisting property.Type: GrantFiled: March 2, 1998Date of Patent: December 26, 2000Assignees: Sumitomo Electric Industries, Ltd., Daido Steel Co., Ltd.Inventors: Kenji Miyazaki, Shinichi Kitamura, Atsushi Yoshida, Shinichiro Yahagi, Takanobu Saito
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Patent number: 6093264Abstract: A nickel-based alloy composition is disclosed comprising from about 0.05 to about 3 percent by weight beryllium; from about 1 to about 40 percent by weight copper; no greater than about 10 percent by weight chromium, the balance being nickel. The alloy composition may be adjusted to achieve a high, as-cast hardness alloy over a wide range of alloy component contents, or a moderate, as-cast hardness alloy useful for forming articles such as golf clubs which has relatively constant mechanical properties over a wide range of copper contents.Type: GrantFiled: August 2, 1999Date of Patent: July 25, 2000Assignee: NGK Metals CorporationInventors: Charles Walter Hershberger, Dennis Hall
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Patent number: 6066291Abstract: Castings based on the nickel aluminide intermetallic alloy IC-221M were melted and poured with an addition of enough molybdenum to bring its concentration to 5 weight %. This resulted in a minimization or elimination of the nickel-zirconium eutectic phase in the dies machined and prepared from these castings. The benefit of eliminating or minimizing the nickel zirconium eutectic phase with the addition of measurable amounts of molybdenum (Mo) to the nickel aluminide (Ni.sub.3 Al) alloy is the increase in the useful service life of the tooling made from it; thus providing the advantages of increased productivity, enhanced quality and reduced costs in a manufacturing setting. Heat treatment of the dies machined and prepared from these castings was also undertaken. The heat treatment regimen includes solution treatment at 2100.degree. F. for 24 hours and aging from between 1150.degree. F. and 1300.degree. F. for between 12 to 24 hours.Type: GrantFiled: August 29, 1997Date of Patent: May 23, 2000Assignee: United Defense, L.P.Inventors: Chien-Hua Chen, Guy Monroe Maddox, Jr., John Edward Orth, Elliott Lee Turbeville
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Patent number: 6001195Abstract: To remarkably improve shape memory properties without the need for strictly controlling the composition, the present invention provides a Ti--Ni-based shape-memory alloy having a titanium content within a range of from 50 to 66 atomic %, which comprises an amorphous alloy heat-treated at a temperature of from 600 to 800 K., in which sub-nanometeric precipitates generating coherent elastic strains are formed and distributed in the bcc parent phase(B2).Type: GrantFiled: December 18, 1996Date of Patent: December 14, 1999Assignee: National Research Institute for MetalsInventors: Setsuo Kajiwara, Takehiko Kikuchi, Kazuyuki Ogawa, Shuichi Miyazaki, Takeshi Matsunaga
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Patent number: 5985054Abstract: An age precipitation-containing rare earth metal-nickel alloy of AB.sub.5 type having a composition represented by a formula (1)R(Ni.sub.1-x M.sub.x).sub.5+y (1)wherein R stands for a rare earth element including Y or mixtures thereof, M stands for Co, Al, Mn, Fe, Cu, Zr, Ti, Mo, W, B, or mixtures thereof, x satisfies the relation of 0.05.ltoreq.x.ltoreq.0.5, and y satisfies the relation of -0.45.ltoreq.y.ltoreq.0.45, the alloy containing a precipitated phase having an average size of 0.1 to 20 .mu.m as measured along the longitudinal axis. A method of producing the alloy as defined above including the steps of subjecting a raw alloy material having a composition represented by the formula (1) to a solid solution treatment at a temperature of not less than 1000.degree. C., and ageing the alloy material subjected to said solution heat treatment at a temperature T (.degree. C.) of not less than 700.degree. C. and less than 1000.degree. C.Type: GrantFiled: December 3, 1998Date of Patent: November 16, 1999Assignee: Santoku Metal Ind. Co., Ltd.Inventors: Yuji Tanibuchi, Kazuhiko Yamamoto, Chikara Okada
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Patent number: 5980653Abstract: A nickel-based alloy composition is disclosed comprising from about 0.05 to about 3 percent by weight beryllium; from about 1 to about 40 percent by weight copper; no greater than about 10 percent by weight chromium, the balance being nickel. The alloy composition may be adjusted to achieve a high, as-cast hardness alloy over a wide range of alloy component contents, or a moderate, as-cast hardness alloy useful for forming articles such as golf clubs which has relatively constant mechanical properties over a wide range of copper contents.Type: GrantFiled: January 23, 1997Date of Patent: November 9, 1999Assignee: NGK Metals CorporationInventors: Charles Walter Hershberger, Dennis Hall
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Patent number: 5958154Abstract: Magnetically-controlled actuator materials are provided that produce large actuation stroke, that exhibit fast actuation response time and corresponding high-frequency operation, and that enable efficient actuation energy conversion at convenient operating temperatures. The actuator materials exhibit an austenitic crystal structure above a characteristic phase transformation temperature and exhibit a martensitic twinned crystal structure below the phase transformation temperature. One actuator material provided by the invention is an alloy composition that can be defined generally as (Ni.sub.a Fe.sub.b Co.sub.c).sub.65-x-y (Mn.sub.d Fe.sub.e Co.sub.f).sub.20+x (Ga.sub.g Si.sub.h Al.sub.i).sub.15+y, where x is between about 3 atomic % and about 15 atomic % and y is between about 3 atomic % and about 12 atomic %, and where a+b+c=1, where d+e+f=1, and g+h+i=1.Type: GrantFiled: August 18, 1997Date of Patent: September 28, 1999Assignee: Massachusetts Institute of TechnologyInventors: Robert C. O'Handley, Kari M. Ullakko
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Patent number: 5925197Abstract: A sintered hard alloy for tools for cutting wood. The alloy according to the present invention comprises 30-98 volume % hard constituents in a binder phase based on nickel and/or cobalt. The hard constituents comprise oxides, carbides, nitrides and/or borides of Al, Zr, Si and/or Ti, preferably Al.sub.2 O.sub.3, ZrC, ZrO.sub.2, SiC, Si.sub.3 N.sub.4 and/or TiB.sub.2 with a mean grain size <1.5 .mu.m, preferably <1.0 .mu.m. The binder phase comprises in solution, in weight %, Co max 90, Ni max 90, Cr 5-45.Type: GrantFiled: April 28, 1995Date of Patent: July 20, 1999Assignee: Sandvik ABInventor: Enrico Galli
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Patent number: 5810981Abstract: There is provided a hydrogen occluding alloy exhibiting high absorption and desorption speeds. A hydrogen occluding alloy comprising as an overall composition: 25 to 45 weight % Zr+Hf, wherein the Hf comprises not more than 4%, 1 to 15 weight % Ti, 10 to 20 weight % Mn, 2 to 12 weight % V, 0.6 to 5 weight % rare earth elements, and a balance Ni (of which content is not less than 25 weight %) and unavoidable impurities, and basically having a three-phase structure consisting of: a net-shaped continuous phase which is made of a Ni--Zr type alloy, a main phase (in the net-shaped continuous phase) made of a Zr--Ni--Mn based alloy, and a dispersed granular phase made of a rare earth elements-Ni type alloy distributed along the net-shaped continuous phase.Type: GrantFiled: March 8, 1996Date of Patent: September 22, 1998Assignee: Mitsubishi Materials CorporationInventors: Norikazu Komada, Mitsugu Matsumoto, Shinichiro Kakehashi, Yoshitaka Tamo, Chris N. Christodoulou
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Patent number: 5725691Abstract: Alloys for use in structural applications based upon NiAl to which are added selected elements to enhance room temperature ductility and high temperature strength. Specifically, small additions of molybdenum produce a beneficial alloy, while further additions of boron, carbon, iron, niobium, tantalum, zirconium and hafnium further improve performance of alloys at both room temperature and high temperatures. A preferred alloy system composition is Ni--(49.1.+-.0.8%)Al--(1.0.+-.0.8%)Mo--(0.7.+-.0.5%)Nb/Ta/Zr/Hf--(nearly zero to 0.03%)B/C, where the % is at. % in each of the concentrations. All alloys demonstrated good oxidation resistance at the elevated temperatures. The alloys can be fabricated into components using conventional techniques.Type: GrantFiled: February 29, 1996Date of Patent: March 10, 1998Assignee: Lockheed Martin Energy Systems, Inc.Inventor: Chain T. Liu
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Patent number: 5718867Abstract: An alloy based on a silicide containing at least chromium and molybdenum contains the following constituents in atomic percent: chromium 41-55, molybdenum 13-35 and silicon 25-35, or chromium 35-55, molybdenum 13-35, silicon 13-35, yttrium 0.001-0.3, and/or tungsten 0.001-10. This alloy is distinguished by a high oxidation resistance and still has a mechanical strength at temperatures of over 1000.degree. C. which favors its use as structural material in gas turbines.Type: GrantFiled: September 19, 1995Date of Patent: February 17, 1998Assignee: Asea Broan Boveri AGInventors: Mohammed Nazmy, Corrado Noseda, Markus Staubli
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Patent number: 5702542Abstract: Metal-matrix composites and methods for producing these composites are provided. The manufacturing methods include providing a ceramic preform having a uniform distribution of ceramic particles sintered to one another. The particles include an average particle size of no greater than about 3 microns, and at least one half of the volume of the preform is occupied by porosity. The preform is then disposed into a mold and contacted by molten metal. The molten metal is then forced into the pores of the preform and permitted to solidify to form a solid metal-matrix composite. This composite is machinable with a high-speed steel (HSS) bit for greater than about 1 minute without excessive wear occurring to the bit. This invention preferably employs metal-matrixes including Al, Li, Be, Pb, He, Au, Sn, Mg, Ti, Cu, and Zn. Preferred ceramics include oxides, borides, nitrides, carbides, carbon, or a mixture thereof. Inert gas pressures of less than about 3,000 psi can be used to easily infiltrate the preforms.Type: GrantFiled: December 18, 1995Date of Patent: December 30, 1997Inventors: Alexander M. Brown, Eric M. Klier
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Patent number: 5638594Abstract: A multi-stage telescopic antenna for use in vehicles and a method for manufacturing such an antenna in which the antenna element, which comprises uppermost rod and conductive pipes, is free of any bending or breaking damage even if a large load is applied to the antenna element from a lateral direction, and there is no permanent deformation occurs even after the load is removed, so that the antenna element can always be maintained straight and smooth and stable extension and retraction can be executed.At least the conductive pipes 12 through 14 are formed from a high-elasticity material obtained by heat-treating SUS 631. In the heat treatment, the material is heated at a standard temperature of 480.degree. C..+-.5.degree. C. and then gradually cooled.Type: GrantFiled: February 23, 1995Date of Patent: June 17, 1997Assignee: Harada Kogyo Kabushiki KaishaInventors: Misao Shinkawa, Misao Kimura
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Patent number: 5605584Abstract: Columnar grain and single crystal nickel base superalloys are heat treated to provide a damage tolerant microstructure. The microstructure contains large, irregularly shaped "barrier" .gamma.' particles interspersed in an ordered array of smaller cuboidal .gamma.' particles in a .gamma. phase matrix. The barrier particles interrupt the progression of cracks through the microstructure. The invention process includes solutioning the .gamma.' phase, cooling slowly to a temperature about 50.degree. F. to 150.degree. F. (28.degree. C. to 83.degree. C.) below the .gamma.' solvus temperature, further cooling at a rate of at least about 100.degree. F. (56.degree. C.) per minute to less than 1000.degree. F. (538.degree. C.), reheating to 1975.degree. F. to 2000.degree. F. (1079.degree. C. to 1093.degree. C.) and holding for about four to six hours, cooling at 100.degree. F. (56.degree. C.) per minute to less than 1000.degree. F. (538.degree. C.), and heating to 1600.degree. F. .+-.25.degree. F. (871.degree. C. .+-.14.Type: GrantFiled: January 30, 1995Date of Patent: February 25, 1997Assignee: United Technologies CorporationInventors: Daniel P. DeLuca, Howard B. Jones, Bradford A. Cowles
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Patent number: 5516380Abstract: A NiAl intermetallic alloy and article is provided with improved high temperature strength, particularly stress rupture strength, through the generation of a multiphase microstructure comprising a beta matrix and at least one precipitate phase. The strength properties and microstructure are the result of alloying with at least two elements selected from Ga, Hf, and optionally Ti, Zr, Ta, Nb, and V, in defined ranges. Preferred are at least two of the elements Ga, Hf, and Ti, and specifically preferred are all three. A specifically preferred form of the invention, in atomic percent, is about 45-59% Ni, about 0.02-0.5% Ga, about 0.2 to less than 1% Hf, about 0.1-10% Ti, with the balance A1 and incidental impurities.Type: GrantFiled: October 14, 1994Date of Patent: May 14, 1996Assignee: General Electric CompanyInventors: Ramgopal Darolia, James R. Dobbs, Robert D. Field, Edward H. Goldman, David F. Lahrman, William S. Walston
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Patent number: 5496419Abstract: The present invention provides a wear resistant high permeability magnetic lloy Ni, Nb, N, O and Fe as main components. The alloy may include secondary components of at least one element selected from the group consisting of Cr, Mo, Ge, Au, Co, V, W, Cu, Ta, Mn, Al, Si, Ti, Zr, Hf, Sn, Sb, Ga, In, Tl, Zn, Cd, rare earth element, platinum element, Be, Ag, Sr, Ba, B, P, C and S. The magnetic alloy has good wear resistance having easy forgeability, a large effective permeability, more than 4000 G of a saturated flux density and a recrystallization texture of {110}<112>+{311}<112>.Type: GrantFiled: June 6, 1994Date of Patent: March 5, 1996Assignee: The Foundation: The Research Institute of Electric and Magnetic AlloysInventors: Yuetsu Murakami, Katashi Masumoto
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Patent number: 5429883Abstract: An alloy having excellent corrosion resistance and abrasion resistance, is provided comprising a matrix metal phase comprised of at least one member selected from an Fe-base alloy, a Co-base alloy and a Ni-base alloy and, present in the matrix metal phase, 10 to 65%, in terms of the area, of a substantially homogeneously crystallized and/or precipitated VC particle phase having a particle diameter of 5 .mu.m or less.A surface-modified metallic member, is also provided comprising a metallic member and the above-described alloy, the alloy being integrally coated on the surface of the metallic member at its desired portion.Type: GrantFiled: May 20, 1993Date of Patent: July 4, 1995Assignees: Toshiba Kikai Kabushiki Kaisha, Daido Steel Co., Ltd.Inventors: Kyoichi Sasaki, Yoshihisa Kato
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Patent number: 5395464Abstract: A method for obtaining a product from pre-alloyed powders in which the powders are subjected to compaction treatment. The powders are first subjected to pre-treatment under low pressure (or without pressure) at a temperature such that segregating materials precipitate out in stable phases.Type: GrantFiled: April 7, 1994Date of Patent: March 7, 1995Assignee: TECPHYInventor: James Davidson
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Patent number: 5374319Abstract: A process is provided for welding a gamma-prime precipitation-strengthened nickel base superalloy by heating the weld area and adjacent region to a ductile temperature, welding while maintaining the entire weld area and adjacent region at the ductile temperature and holding the weldment, weld area and adjacent region at the ductile temperature until the entire weld has solidified. The ductile temperature is above the aging temperature but below the incipient melting temperature of the superalloy.Type: GrantFiled: November 4, 1991Date of Patent: December 20, 1994Assignee: Chromalloy Gas Turbine CorporationInventors: Richard J. Stueber, Thomas Milidantri, Moshen Tadayon
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Patent number: 5374323Abstract: Disclosed is a large alloy forging, the forging having an alloy composition selected from one of a nickel base alloy, a cobalt-chromium-nickel base alloy, a nickel-cobalt base alloy and an iron-nickel-chromium-molybdenum alloy, the forging having a grain size of ASTM grain size 3 or finer, as measured by ASTM method E112 and having a tensile strength in the range of 135 to 175 KSI.Type: GrantFiled: August 26, 1991Date of Patent: December 20, 1994Assignee: Aluminum Company of AmericaInventors: G. William Kuhlman, Richard A. Beaumont, Daniel F. Carbaugh, David Anderson, Al Farrell, Amiya K. Chakrabarti, Kenneth P. Kinnear
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Patent number: 5360496Abstract: Disclosed is a large alloy forging and method for making it. The forging having an alloy composition selected from one of a nickel base alloy, a cobalt-chromium-nickel base alloy, a nickel-cobalt base alloy and an iron-nickel-chromium-molybdenum alloy and having a grain size of ASTM grain size 4 or finer, as measured by ASTM method E112 and having a tensile strength in the range of 135 to 175 KSI. The process includes: (1) four upset forgings, (2) a rapid cooling after the final upset cooling, (3) a first and second upset forging with a reduction greater than 50%, (4) a third upset forging with a reduction greater than 25.%, and (5) a forging process with a fourth upset forging with a reduction greater than 50%.Type: GrantFiled: April 7, 1993Date of Patent: November 1, 1994Assignee: Aluminum Company of AmericaInventors: G. William Kuhlman, Richard A. Beaumont, Daniel F. Carbaugh, David Anderson, Amiya K. Chakrabarti, Kenneth P. Kinnear
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Patent number: RE40501Abstract: An article, such as a turbine engine component, formed from a nickel-base superalloy, the nickel-base superalloy containing a ?? tetragonal phase and comprising aluminum, titanium, tantalum, niobium, chromium, molybdenum, and the balance nickel, wherein the article has a time dependent crack propagation resistance of at least about 20 hours to failure at about 1100° F. in the presence of steam. The invention also includes a nickel-base superalloy for forming such and article and methods of forming the article and making the nickel-base superalloy.Type: GrantFiled: March 10, 2005Date of Patent: September 16, 2008Assignee: General Electric CompanyInventors: Michael Francis Henry, Elena Rozier, Samuel Vinod Thamboo, Sarwan Kumar Mannan, John Joseph deBarbadillo, II