Zinc(zn), Zinc Base Alloy Or Unspecified Galvanizing Patents (Class 148/533)
  • Patent number: 6811624
    Abstract: Dual phase steel sheet is made using a time/temperature cycle including a soak at about 1340-1425F and a hold at 850-920F, where the steel has the composition in weight percent, carbon: 0.02-0.20; aluminum: 0.010-0.150; titanium: 0.01 max; silicon: 0.5 max; phosphorous: 0.060 max; sulfur: 0.030 max; manganese: 1.5-2.40; chromium: 0.03-1.50; molybdenum: 0.03-1.50; with the provisos that the amounts of manganese, chromium and molybdenum have the relationship: Mn+6Cr+10Mo)=at least 3.5%. The sheet is preferably in the form of a strip treated in a continuous galvanizing or galvannealing line, and the product is predominantly ferrite and martensite.
    Type: Grant
    Filed: January 15, 2003
    Date of Patent: November 2, 2004
    Assignee: United States Steel Corporation
    Inventor: David Paul Hoydick
  • Publication number: 20040213916
    Abstract: A corrosion-resistant coated brass metal coated with a corrosion resistant alloy. The corrosion resistant alloy is a tin metal alloy or a tin and zinc metal alloy. The corrosion resistant metal alloy may also include one or more metal additives to improve the coating process and/or to alter the properties of the tin or tin and zinc metal alloy.
    Type: Application
    Filed: May 26, 2004
    Publication date: October 28, 2004
    Applicant: The Louis Berkman Company, a corporation of Ohio
    Inventors: Jay F. Carey, Mehrooz Zamanzadeh, Nicholas R. Hesske
  • Publication number: 20040211495
    Abstract: Dual phase steel sheet is made using a time/temperature cycle including a soak at about AC1+45° F. to AC1+135° F. and a hold at 850-940F, where the steel has the composition in weight percent, carbon: 0.02-0.20; aluminum: 0.010-0.150; titanium: 0.01 max; silicon: 0.5 max; phosphorous: 0.060 max; sulfur: 0.030 max; manganese: 0.8-2.40; chromium: 0.03-1.50; molybdenum: 0.03-1.50; with the provisos that the amounts of manganese, chromium and molybdenum have the relationship: (Mn+6Cr+10 Mo)=at least 3.5%. The sheet is preferably in the form of a strip suitable for coating in a continuous galvanizing or galvannealing line, and the product is predominantly ferrite and martensite. The strip may be galvanized or galvannealed at a temperature within thirty degrees F. of the temperature of the bath.
    Type: Application
    Filed: May 17, 2004
    Publication date: October 28, 2004
    Applicant: United States Steel Corporation
    Inventor: David Paul Hoydick
  • Publication number: 20040214029
    Abstract: A corrosion-resistant coated base metal coated with a corrosion resistant alloy. The corrosion resistant alloy includes tin and zinc. The corrosion resistant coated base metal includes a heat created intermetallic layer primarily including copper and zinc.
    Type: Application
    Filed: May 20, 2004
    Publication date: October 28, 2004
    Applicant: The Louis Berkman Company, an Ohio corporation
    Inventors: Jay F. Carey, Mehrooz Zamanzadeh
  • Publication number: 20040202889
    Abstract: The present invention provides: a high-strength high-ductility hot-dip galvanized steel sheet and hot-dip galvannealed steel sheet having high fatigue resistance and corrosion resistance; a high-strength hot-dip galvanized steel sheet excellent in ductility, which improves non-plating defects and plating adhesion after severe deformation, and a method of producing the same; a high-strength and high-ductility hot-dip galvanized steel sheet having high fatigue resistance and corrosion resistance; a high-strength hot-dip galvanized steel sheet and hot-dip galvannealed steel sheet having superior appearance and workability, which suppresses the generation of non-plating defects, and a method of producing the same; and a high-strength hot-dip galvannealed steel sheet and a high-strength hot-dip galvanized steel sheet, which suppress non-plating defects and surface defects and have both corrosion resistance, in particular corrosion resistance in an environment containing chlorine ion, and high ductility, and a meth
    Type: Application
    Filed: December 5, 2003
    Publication date: October 14, 2004
    Inventors: Nobuhiro Fujita, Masafumi Azuma, Manabu Takahashi, Yasuhide Morimoto, Masao Kurosaki, Akihiro Miyasaka
  • Publication number: 20040177903
    Abstract: Process for the continuous hot-dip galvanizing of a steel strip (1) containing oxidizable addition elements in a proportion allowing the mechanical properties of the steel to be improved, in which process the strip passes through a galvanizing furnace (3) in a reducing atmosphere, this furnace consisting of heat treatment sections, for heating, soaking and cooling, and is then dipped into a galvanizing bath (2). The strip is subjected, upstream of the inlet section of the furnace, to an oxidation treatment under conditions as regards temperature, duration and oxygen content of a gas in which the strip is immersed, such that the oxidizable addition elements are essentially oxidized within the strip, before they can migrate to the surface in order to form thereat an oxide layer.
    Type: Application
    Filed: March 3, 2004
    Publication date: September 16, 2004
    Applicant: STEIN HEURTEY
    Inventor: Mignard Francois
  • Publication number: 20040159378
    Abstract: A workpiece having regions of different ductility is made by first coating opposite faces of a flat sheet-metal workpiece of low ductility and then stripping the coating from the faces in one region of the workpiece while leaving the coating on the faces in another region of the workpiece. The workpiece is then deformed into a three-dimensional profile. Only the one uncoated region of the workpiece is heated and thereby hardened while not significantly heating the other coated region of the workpiece.
    Type: Application
    Filed: February 6, 2004
    Publication date: August 19, 2004
    Applicant: Benteler Automobiltechnik GmbH
    Inventor: Ludger Gehringhoff
  • Patent number: 6767652
    Abstract: A galvannealed steel sheet superior in workability wherein the steel sheet is characterized by containing silicon in an amount no less than 0.8 mass % and retained austenite in an amount no less than 3% (in terms of packing factor) and the alloy zinc plating is characterized by containing Zn—Fe alloy crystal grains which exist in its surface layer and have a specific crystal grain size such that the longer side of a crystal grain is no larger than twice the shorter side of a crystal grain and the number of crystal grains with an average particle size no smaller than 4 &mgr;m is no more than 5 per 70×50 &mgr;m. The steel sheet with alloy zinc coating has good mechanical properties (such as total elongation) and good plating surface slidability.
    Type: Grant
    Filed: April 12, 2002
    Date of Patent: July 27, 2004
    Assignee: Kobe Steel, Ltd.
    Inventors: Takayuki Yamamoto, Masafumi Shimizu, Shunichi Hashimoto
  • Publication number: 20040134570
    Abstract: A hardenable steel workpiece having two regions is first hardened so that both regions are of generally the same low ductility. Then only one of the regions is hot coated so as to increase the ductility of the one region while not heating and changing the ductility of the other region. The workpiece can be hardened by hot working or tempering. The hot coating can be done by dipping the one region in molten zinc.
    Type: Application
    Filed: December 23, 2003
    Publication date: July 15, 2004
    Applicant: Benteler Automobiltechnik GmbH
    Inventor: Stefan Gosmann
  • Patent number: 6756134
    Abstract: The present invention relates to a zinc-diffused nickel alloy coating for corrosion and heat protection and to a method for forming such a coating. The coating method broadly comprises the steps of forming a plain nickel or nickel alloy coating layer on a substrate, applying a layer of zinc over the nickel or nickel alloy coating layer, and thermally diffusing the zinc into the nickel alloy coating layer. The coating method may further comprise immersing the coated substrate in a phosphated trivalent chromium conversion solution either before or after the diffusing step. The substrate may be a component used in a gas turbine engine, which component is formed from a steel material.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: June 29, 2004
    Assignee: United Technologies Corporation
    Inventors: Henry M. Hodgens, Thomas R. Hanlon, Promila Bhatia
  • Publication number: 20040105998
    Abstract: Diffusion metallic anticorrosive zinc-iron-aluminum coatings of iron and iron-based item surfaces, realized by heating of products at temperatures of 370−450° C. in a saturating powder mixture environment in a closed container. The coating compositions are multiphase-polymetallic, and comprise zinc, iron and aluminum. Other elements may be added to attain specific coating properties. This coating exhibits a high corrosion resistance (at least a 700-hour corrosion resistance level in a standard salt spray test), a relatively high hardness level and good adhesion to secondary coatings.
    Type: Application
    Filed: December 3, 2002
    Publication date: June 3, 2004
    Inventor: Itzhak Rosenthul
  • Patent number: 6743307
    Abstract: The invention relates to a higher-strength steel strip or steel sheet comprising a predominantly ferritic-martensitic microstructure with a martensite content of between 4 and 20%, wherein the steel strip or steel sheet, apart from Fe and impurities due to smelting, comprises (in % by weight) 0.05-0.2% C, ≦1.0% Si, 0.8-2.0% Mn, ≦0.1% P, ≦0.015% S, 0.02-0.4% Al, ≦0.005% N, 0.25-1.0% Cr, 0.002-0.01% B. Preferably the martensite content is approximately 5% to 20% of the predominantly martensitic-ferritic microstructure. Such a higher-strength steel strip or steel sheet made from a dual phase steel comprises good mechanical/technological properties even after being subjected to an annealing process which includes an overageing treatment. Furthermore, the invention relates to a method for producing steel strip or steel sheet according to the invention.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: June 1, 2004
    Assignee: Thyssen Krupp Stahl AG
    Inventors: Bernhard Engl, Thomas Gerber, Klaus Horn
  • Publication number: 20040099349
    Abstract: Dual phase steel sheet is made using a time/temperature cycle including a soak at about 1340-1425 F and a hold at 850-920 F, where the steel has the composition in weight percent, carbon: 0.02-0.20; aluminum: 0.010-0.150; titanium: 0.01 max; silicon: 0.5 max; phosphorous: 0.060 max; sulfur: 0.030 max; manganese: 1.5-2.40; chromium: 0.03-1.50; molybdenum:0.03-1.50; with the provisos that the amounts of manganese, chromium and molybdenum have the relationship: (Mn+6Cr+10 Mo)=at least 3.5%. The sheet is preferably in the form of a strip treated in a continuous galvanizing or galvannealing line, and the product is predominantly ferrite and martensite.
    Type: Application
    Filed: January 15, 2003
    Publication date: May 27, 2004
    Applicant: United States Steel Corporation
    Inventor: David Paul Hoydick
  • Publication number: 20040055667
    Abstract: Disclosed are a high strength hot-dip galvanized or galvannealed steel sheet, which has improved press formability and plating adhesion and is useful as a member for automobile, building, electric or other members, and a process for producing the same.
    Type: Application
    Filed: June 27, 2003
    Publication date: March 25, 2004
    Inventors: Yoshihisa Takada, Masayoshi Suehiro, Takehide Senuma
  • Publication number: 20040058189
    Abstract: The present invention relates to a zinc-diffused nickel alloy coating for corrosion and heat protection and to a method for forming such a coating. The coating method broadly comprises the steps of forming a plain nickel or nickel alloy coating layer on a substrate, applying a layer of zinc over the nickel or nickel alloy coating layer, and thermally diffusing the zinc into the nickel alloy coating layer. The coating method may further comprise immersing the coated substrate in a phosphated trivalent chromium conversion solution either before or after the diffusing step. The substrate may be a component used in a gas turbine engine, which component is formed from a steel material.
    Type: Application
    Filed: September 23, 2002
    Publication date: March 25, 2004
    Inventors: Henry M. Hodgens, Thomas R. Hanlon
  • Patent number: 6706419
    Abstract: To provide a steel sheet excellent in painting bake hardenability and anti aging property at room temperature: containing, in mass, 0.0001 to 0.20% of C, 2.0% or less of Si, 3.0% or less of Mn, 0.15% or less of P, 0.015% or less of S, and, in addition, 010% or less of Al and 0.001 to 0.10% of N so as to satisfy the expression 0.52Al/N<5 and, further, one or more of 2.5% or less of Cr, 1.0% or less of Mo and 0.1% or less of V so as to satisfy the expression (Cr+3.5MO+39V) ≧0.1, with the balance consisting of Fe and unavoidable impurities; having the value of BH170, evaluated after applying a 2% tensile deformation and then a heat treatment at 170° C. for 20 min., being 45 MPa or more, and any of the value of BH160, evaluated after applying a 2% tensile deformation and then a heat treatment at 160° C. for 10 min., and the value of BH150, evaluated after applying a 2% tensile deformation and then a heat treatment at 150° C. for 10 min.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: March 16, 2004
    Assignee: Nippon Steel Corporation
    Inventors: Naoki Yoshinaga, Manabu Takahashi, Natsuko Sugiura, Akihiro Miyasaka, Masaaki Sugiyama
  • Patent number: 6699590
    Abstract: An object of the present invention is to provide a hot-dip galvanized steel sheet which is excellent in adhesion with a hot-dip galvanized zinc layer, and has high tensile strength and good formability even when a steel sheet containing Si and Mn in relatively larger amounts is used as a basis steel sheet. The hot-dip galvanized steel sheet is composed of: a basis steel sheet containing Si in an amount of 0.05 to 2.5% and Mn in an amount of 0.2 to 3%, by mass; a Fe plated layer formed on the basis steel sheet; and a hot-dip galvanized zinc layer formed on the surface layer of the basis steel sheet via the Fe plated layer, wherein oxides containing Si and/or Mn are discontinuously dispersed in the vicinity of the interface between the basis steel sheet and the Fe plated layer.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: March 2, 2004
    Assignee: Kobe Steel, Ltd.
    Inventors: Hiroyuki Takeda, Kouki Ikeda, Ikurou Hashimoto
  • Patent number: 6699592
    Abstract: The invention provides a galvannealed steel sheet which has an oxide layer having 10 nm or larger thickness on the plateau of the coating layer flattened by temper rolling. With the use of the galvannealed steel sheet, no powdering occurs during press-forming, and stable and excellent sliding performance is attained. By selecting the area percentage of the plateau of the flattened coating layer to a range from 20 to 80%, making the coating layer single layer of &dgr;1 phase, and letting &zgr; phase exist in the &dgr;1 phase, further improved sliding performance and anti-powdering property are obtained.
    Type: Grant
    Filed: October 21, 2002
    Date of Patent: March 2, 2004
    Assignee: NKK Corporation
    Inventors: Shoichiro Taira, Yoshiharu Sugimoto, Junichi Inagaki, Toru Imokawa, Shuji Nomura, Michitaka Sakurai, Masaaki Yamashita, Kaoru Sato, Masayasu Nagoshi, Akira Gamou, Yoichi Miyakawa, Shunsaku Node, Masahiro Iwabuchi
  • Publication number: 20040033386
    Abstract: A high strength dual phase cold rolled steel having controlled amounts of carbon, manganese, and molybdenum is used as a starting material in a hot-dip zinc coating process to manufacture a high strength dual phase cold rolled steel having a conventional galvanized or galvannealed coating applied to at least one surface thereof, the zinc coated steel product having a uniform coating of zinc in spite of the high manganese content of the steel.
    Type: Application
    Filed: July 25, 2003
    Publication date: February 19, 2004
    Applicant: ISG Technologies Inc.
    Inventors: Rajendra Pradhan, C. Ramadeva Shastry
  • Patent number: 6641931
    Abstract: The present invention aims to produce a cold rolled metal coated multi-phase steel, characterized by a tensile strength of at least 500 MPa, a yield ratio (Re/Rm) lower than 0.65 in skinned conditions, lower than 0.60 in unskinned conditions, and with good metal coating adhesion behavior. In the case of the aluminized steel according to the invention, the steel also has superior resistance to temperature corrosion up to 900° C. and excellent mechanical properties at this high temperature. The hot metal coated steel product having a steel composition with a manganese content lower than 1.5%, chrome content between 0.2 and 0.5%, molybdenum content between 0.1 and 0.25%, and a relation between the chrome and molybdenum content as follows Cr+2 Mo higher than or equal to 0.7%, undergoes a thermal treatment in the hot dip metal coating line defined by a soaking temperature between Ac1 and Ac3, a primary cooling speed higher than 25° C./sec and a secondary cooling speed higher than 4° C./sec.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: November 4, 2003
    Assignee: Sidmar N.V.
    Inventors: Serge Claessens, Dirk Vanderschueren
  • Publication number: 20030196732
    Abstract: A corrosion-resistant coated base metal coated with a corrosion resistant alloy. The corrosion resistant alloy includes tin and zinc. The corrosion resistant coated base metal includes a heat created intermetallic layer primarily including copper and zinc.
    Type: Application
    Filed: September 24, 2002
    Publication date: October 23, 2003
    Applicant: The Louis Berkman Company, an Ohio corporation
    Inventors: Jay F. Carey, Mehrooz Zamanzadeh
  • Patent number: 6635313
    Abstract: A method of coating dual phase high strength cold rolled steel having controlled amounts of carbon, manganese, and molybdenum is used as a starting material in a galvanizing/galvannealing process. Conditions in a multi-zone furnace of the galvanizing line can be controlled in a conventional manner while still effectively coating the high strength steel. A dual phase high strength steel product is made having a uniform coating of zinc in spite of the high manganese content of the steel.
    Type: Grant
    Filed: November 15, 2001
    Date of Patent: October 21, 2003
    Assignee: ISG Technologies, Inc.
    Inventors: Rajendra Pradhan, C. Ramadeva Shastry
  • Patent number: 6623691
    Abstract: The present invention describes an ultra-low carbon bake hardenable galvanized or galvannealed steel product, having a higher yield strength at the temperature of the molten zinc bath while maintaining a low yield strength and excellent bake hardening properties in a skinpassed condition, BH0 being higher than 35 MPa and BH2 higher than 40 MPa (GI) and BH0>20 MPa and BH2>30 MPa (GA), as well as having a superior paint appearance after stamping and painting. The content in the steel composition of the Ti is comprised between 3.42 N and 3.42 N+60 ppm for a fixed nitrogen content (N), and the Nb-content, comprised between 50 ppm and 100 ppm, is fixed so that no substantial precipitation of niobium carbides will occur during the process.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: September 23, 2003
    Assignee: Sidmar N.V.
    Inventors: Sven Vandeputte, Serge Claessens
  • Publication number: 20030170485
    Abstract: A corrosion-resistant coated brass metal coated with a corrosion resistant alloy. The corrosion resistant alloy is a tin metal alloy or a tin and zinc metal alloy. The corrosion resistant metal alloy may also include one or more metal additives to improve the coating process and/or to alter the properties of the tin or tin and zinc metal alloy.
    Type: Application
    Filed: January 17, 2003
    Publication date: September 11, 2003
    Applicant: The Louis Berkman Company, an Ohio corporation
    Inventors: Jay F. Carey, Mehrooz Zamanzadeh, Nicholas R. Hesske
  • Publication number: 20030168134
    Abstract: A galvannealed steel sheet having excellent surface appearance and press formability, characterized in that a steel sheet comprises a galvannealed layer at least one surface of the steel sheet, the steel sheet comprising 0.001 to 0.005% by mass of C, 0.010 to 0.040% by mass of Si, 0.05 to 0.25% by mass of Mn, and 0.010 to 0.030% by mass of P, wherein the Si, Mn, and P satisfy the relation 0.030%≦Si+P+Mn/20≦0.070%, and its production method.
    Type: Application
    Filed: October 2, 2002
    Publication date: September 11, 2003
    Inventors: Nobue Fujibayashi, Kazuaki Kyono
  • Patent number: 6613163
    Abstract: The invention relates to a method for producing band-shaped steel for components which are produced by drawing and ironing. The invention also relates to a steel band which can be drawn or ironed and which has been produced by the inventive method. The hot strip is cold-worked in one or more steps at a ratio of the cold roll of at least 86%. Furthermore, at least one side of the band material is provided with a galvanically produced coating containing Ni, Co, Cu, Fe, Sn, In, Pd, Bi and/or the alloys thereof or with a roll-bonded coating containing Cu and/or brass and/or the alloys thereof. The aim of the invention is to carry out the inventive method with the fewest processing steps possible and with low production costs. The method therefore comprises the steps: etching, cold rolling in one or two steps, annealing the coiled band (coil-annealing), optionally rerolling the band. The hot strip preferably contains boron with a percentile of 0.0013 and 0.
    Type: Grant
    Filed: October 3, 2001
    Date of Patent: September 2, 2003
    Assignee: Hille & Mueller GmbH
    Inventors: Karlfried Pfeifenbring, Andrew E. Munera, Ferdinand Schmidt, Rob Van Der Mije, Jaap Neeft, Uwe Schoelich
  • Patent number: 6610422
    Abstract: The method for manufacturing coated steel sheet has the steps of: immersing a steel sheet in a hot-dip coating bath to form an Al—Zn base coating layer containing 20 to 95 mass % Al on the steel sheet, forming a passivated layer on the coating layer; and applying thermal history to the coating layer. The thermal history is applied immediately after the steel sheet left the hot-dip coating bath or in a temperature range of from T(° C.) between 130° C. and 300° C. to 100° C.
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: August 26, 2003
    Assignee: NKK Corporation
    Inventors: Toshihiko Ooi, Takafumi Yamaji, Keiji Yoshida, Yuichiro Tanaka, Junichi Inagaki, Masaaki Yamashita, Yasuhiro Majima, Nobuyuki Ishida, Yuichi Fukushima, Norio Inoue, Shinji Hori
  • Patent number: 6610423
    Abstract: The object of the present invention relates to a plated steel material and a method of production the same, having enhanced corrosion resistance and workability required for outdoor and exposed uses such as structures, revetments, fishing nets, fences, etc.
    Type: Grant
    Filed: October 26, 2001
    Date of Patent: August 26, 2003
    Assignee: Nippon Steel Corporation
    Inventors: Satoshi Sugimaru, Satoru Tanaka, Seiki Nishida, Akira Takahashi, Atsuhiko Yoshie, Kazumi Nishimura
  • Publication number: 20030155048
    Abstract: The present invention relates to a method for the manufacture of galvannealed metal sheet, wherein a hot strip is produced from an IF steel containing 0.01 to 0.1 wt. % silicon, wherein the hot strip is coiled at a coiler temperature no lower than 700° C. and no higher than 750° C., wherein a cold strip is rolled from the coiled hot strip, wherein the cold strip is recrystallisation-annealed in an annealing furnace in an annealing gas atmosphere, wherein the cold strip thus annealed is provided with a zinc coating in a zinc bath, and wherein the coated cold strip is post-annealed at a galvannealing temperature no lower than 500° C. and no higher than 540° C. The invention also relates to a galvannealed metal sheet which possesses improved adhesion of the coating layer to the base material and proposes a method which is suited for the manufacture of metal sheet having such properties.
    Type: Application
    Filed: April 1, 2003
    Publication date: August 21, 2003
    Inventors: Sabine Zeizinger, Horst Berndsen, Frank Friedel, Manfred Meurer, Michael Westholt
  • Publication number: 20030140989
    Abstract: A method for annealing and galvanizing wires which comprises induction heating the wires in a first chamber at a first higher temperature to anneal the wires, cooling the wires to a second lower temperature in a second chamber and galvanizing the wires in a third chamber. The chambers are in serial communication and the heating, cooling and galvanizing steps are effected in an oxygen free atmosphere.
    Type: Application
    Filed: November 13, 2002
    Publication date: July 31, 2003
    Inventor: James M. Knott
  • Patent number: 6586117
    Abstract: A steel for forming a high strength steel sheet contains, in mass %, C: at most 0.04%, Si: at most 0.4%, Mn: 0.5-3.0%, P: at most 0.15%, S: at most 0.03%, Al: at most 0.50%, N: at most 0.01%, and Mo: 0.01-1.0%. Steel sheet formed from the steel is suitable for use as automotive panels.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: July 1, 2003
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Shigeki Nomura, Hiroyuki Nakagawa, Yoshiaki Nakazawa
  • Publication number: 20030116232
    Abstract: A metallurgical product, made of carbon steel and to be galvanized, which is in the form of a strip or of a sheet obtained from a continuously cast intermediate product having the following composition by weight: 0.0005%≦C≦0.15%; 0.08%≦Mn≦2%; Si≦0.040%; Altotal≦0.010%; Alsoluble≦0.004%; 0.0050%≦Ototal≦0.0500%; P≦0.20%; S≦0.10%; each of Cu, Cr, Ni, Mo, W, Co≦1%; each of Ti, Nb, V, Zr≦0.5%; each of Sn, Sb, As≦0.1%; B≦0.1%; N≦0.0400%; and the remainder being iron and impurities. Also, a process for obtaining a metallurgical intermediate product, which includes: producing in a ladle a liquid steel the composition of which is as above, and in which the dissolved oxygen content is maintained between 0.0050 and 0.0500% by the establishment of a chemical equilibrium between the metal and the ladle slag; and casting said steel on a continuous casting machine.
    Type: Application
    Filed: December 20, 2002
    Publication date: June 26, 2003
    Applicant: USINOR
    Inventors: Christian Marchionni, Yann Le Papillon, Alain Leclercq, Michel Faral, Jean-Michel Damasse, Philippe Rocabois
  • Patent number: 6579615
    Abstract: This invention provides a plated steel wire with high corrosion resistance and excellent workability, wherein the average composition of the plating alloy in the plated steel wire comprises, in terms of weight percentage, Al: 4-20%, Mg: 0.8-5%, and if necessary one or more from among Si: ≦2%, Na: 0.001-0.1% and Ti: 0.01-0.1%, with the remainder Zn, and an Fe—Zn alloy layer of no greater than 20 &mgr;m thickness is present at the plating-base metal interface; it is produced by coating a steel wire with a molten zinc plating composed mainly of zinc as the first stage and then.coating it with a molten zinc alloy plating with the aforementioned average composition as the second stage. The maximum plating bath immersion time is 20 seconds, and the part of the plated steel wire drawn out from the plating bath is purged with nitrogen gas.
    Type: Grant
    Filed: July 24, 2001
    Date of Patent: June 17, 2003
    Assignee: Nippon Steel Corporation
    Inventors: Satoshi Sugimaru, Satoru Tanaka, Seiki Nishida, Akira Takahashi, Atsuhiko Yoshie, Kazumi Nishimura
  • Publication number: 20030106620
    Abstract: The invention relates to a high strength hot-dip galvanized steel sheet consisting essentially of 0.03 to 0.25% C, 0.7% or less Si, 1.4 to 3.5% Mn, 0.05% or less P, 0.01% or less S, 0.05 to 1% Cr, 0.005 to 0.1% Nb, by mass, and balance of Fe, and being made of a composite structure of ferrite and secondary phase, and having an average grain size of the composite structure of 10 &mgr;m or smaller. Since the high strength hot-dip galvanized steel sheet of the present invention hardly induces softening at HAZ during welding, it is applicable to structural members of automobiles for “Tailor Welded Blanks” (TWB).
    Type: Application
    Filed: October 17, 2002
    Publication date: June 12, 2003
    Inventors: Yasunobu Nagataki, Fusato Kitano, Kentaro Sato, Masahiro Iwabuchi, Akira Gamou
  • Patent number: 6569268
    Abstract: A process and an alloy for galvanizing non-reactive steel and mixed or moderately reactive steel for providing a decorative spangle to the galvanized coating. The alloy contains 0.1 to less than 0.8 wt % tin, 0.05 to 0.2 wt % bismuth, 0.001 to 0.008 wt % aluminum, and optionally 0 to 0.1 wt % nickel, the balance zinc of commercial purity.
    Type: Grant
    Filed: October 16, 2000
    Date of Patent: May 27, 2003
    Assignee: Teck Cominco Metals Ltd.
    Inventors: John Zervoudis, Victor M. Duarte, Graham W. Poag
  • Patent number: 6558815
    Abstract: The hot dip Zn galvanized steel sheet has excellent balance between tensile strength and ductility and excellent coating adhesion, an average composition of a base steel thereof includes: 0.05-0.25 mass % of C; not more than 2.0 mass % of Si; 1.0-2.5 mass % of Mn; and 0.005-0.10 mass % of Al, wherein the C content at the base steel surface layer portion right under a coating layer is not more than 0.02 mass %, the base steel structure contains not less than 50% of martensite phase, the martensite phase including both tempered martensite phase and fine size martensite phase, and the remaining portion of the base steel structure being formed by ferrite phase and residual austenite phase. A method of producing the hot dip Zn galvanizing steel sheet is described.
    Type: Grant
    Filed: October 30, 2001
    Date of Patent: May 6, 2003
    Assignee: Kawasaki Steel Corporation
    Inventors: Yoshitsugu Suzuki, Chiaki Kato
  • Publication number: 20030059643
    Abstract: Disclosed are a high-strength steel plate with excellent electromagnetic shield capacity and a method for manufacturing the same. The steel plate is manufactured from a composition comprising C, N and S in an amount of 0.0150% by weight or less in total; Mn in an amount of 0.2 to 0.8% by weight; Al in an amount of 0.6% by weight or less; Si in an amount of 0.4% by weight or less; Cu and/or Sn in an amount of 0.1 to 0.6% by weight in total; and Fe for the remainder, and inevitably present elements, whereby the steel plate can show excellent electromagnetic shield effect and hot-dip galvanization property.
    Type: Application
    Filed: August 16, 2002
    Publication date: March 27, 2003
    Inventors: Eel-Young Kim, Jae-Young Lee, Jin-Gun Sohn, Noi-Ha Cho, Young-Jin Kwak, Soon-Joo Kwon, Yong-Min Kim, Jung-Sik Lee
  • Patent number: 6537394
    Abstract: A hot-dip galvanized high-strength steel sheet having superior workability and galvanizability containing: 0.01% to 0.20% by weight of C; 1.0% by weight or less of Si; more than 1.5% to 3.0% by weight of Mn; 0.10% by weight or less of P; 0.05% by weight or less of S; 0.10% by weight or less of Al; 0.010% by weight or less of N; 0.010% to 1.0% by weight in total of at least one element selected from the group consisting of Ti, Nb, and V; and the balance being Fe and incidental impurities; in which the steel sheet has the metal structure in which the areal rate of the ferrite phase is 50% or more, the ferrite phase has an average grain diameter of 10 &mgr;m or less, and the thickness of a band-like structure composed of the second phase satisfies the relationship Tb/T≦0.005, where Tb is the average thickness in the sheet thickness direction of the band-like structure and T is the thickness of the steel sheet, and a method for producing the same.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: March 25, 2003
    Assignee: Kawasaki Steel Corporation
    Inventors: Kazunori Osawa, Kei Sakata, Osamu Furukimi, Yoshitsugu Suzuki, Akio Shinohara
  • Patent number: 6524726
    Abstract: Disclosed is a cold-rolled steel sheet excellent in formability, panel shapeability and dent-resistance, comprising 0.005 to 0.015% by weight of C, 0.01 to 0.2% by weight of Si, 0.2 to 1.5% by weight of Mn, 0.01 to 0.07% by weight of P, 0.006 to 0.015% by weight of S, 0.01 to 0.08% by weight of sol. Al, not higher than 0.004% by weight of N (N≦0.004%), not higher than 0.003% by weight of O (O≦0.003%), 0.04 to 0.23% by weight of Nb, 1.0≦(Nb %×12)/(C %×93)≦3.0, and a balance of Fe and unavoidable impurities, said cold-rolled steel sheet meeting the relationship given below: exp(&egr;)×(5.29×exp(&egr;)−4.19)≦&sgr;/&sgr;0.2≦exp(&egr;)×(5.64×exp(&egr;)−4.49) where 0.002<&egr;≧0.096, &egr; represents a true strain, &sgr;0.2 represents a 0.2% proof stress, and &sgr; represents a true stress relative to &egr;.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: February 25, 2003
    Assignee: NKK Corporation
    Inventors: Fusato Kitano, Masaya Morita, Yoshihiro Hosoya, Takeshi Fujita, Tadashi Inoue, Masahiro Iwabuchi, Takeo Ishii
  • Patent number: 6517955
    Abstract: The invention relates to a high strength hot-dip galvanized and galvannealed steel sheets with excellent drawability for press forming and excellent plating adhesion that is useful as a member for automobiles, construction, electric devices and the like, and to a process for its manufacture. According to an embodiment of the invention, the steel sheet contains in terms of weight percent, C: 0.05-0.2%, Si: 0.2-2.0%, Mn: 0.2-2.5%, Al: 0.01-1.5%, Ni: 0.2-5.0%, P: <0.03% and S: <0.02%, the relationship between Si and Al being such that 0.4(%)≦Si+0.8 Al(%)≦2.0% and the remainder consisting of Fe and unavoidable impurities, the volume percentage of the retained austenite is 2-20% and the steel sheet surface wherein the relationship between the Ni and Si, Al in 0.5 &mgr;m of the steel sheet surface layer is such that Ni(%)≦¼ Si+⅓Al(%), has a Zn plating layer comprising Al: ≦1% with the remainder Zn and unavoidable impurities.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: February 11, 2003
    Assignee: Nippon Steel Corporation
    Inventors: Yoshihisa Takada, Masayoshi Suehiro
  • Publication number: 20030012978
    Abstract: The method for manufacturing galvanized steel sheet has a step of adjusting the surface texture thereof by blasting solid particles against the surface thereof. The surface texture is defined by at least one parameter selected from the group of parameters consisting of mean roughness Ra on the surface of steel sheet, peak count PPI on the surface of steel sheet, and filtered centerline waviness Wca on the surface of steel sheet. The galvanized steel sheet has a surface in dimple-pattern texture.
    Type: Application
    Filed: June 17, 2002
    Publication date: January 16, 2003
    Applicant: NKK CORPORATION
    Inventors: Yasuhiro Sodani, Yukio Kimura, Masayasu Ueno, Shogo Tomita, Hisato Noro, Kaoru Sato, Yoshiharu Sugimoto, Satoru Ando, Masaki Tada, Junichi Inagaki, Masaaki Yamashita, Yuji Yamasaki
  • Publication number: 20020197508
    Abstract: To provide a steel sheet excellent in painting bake hardenability and anti aging property at room temperature: containing, in mass, 0.0001 to 0.20% of C, 2.0% or less of Si, 3.0% or less of Mn, 0.15% or less of P, 0.015% or less of S, and, in addition, 010% or less of Al and 0.001 to 0.10% of N so as to satisfy the expression 0.52Al/N<5 and, further, one or more of 2.5% or less of Cr, 1.0% or less of Mo and 0.1% or less of V so as to satisfy the expression (Cr+3.5MO+39V) ≧0.1, with the balance consisting of Fe and unavoidable impurities; having the value of BE170, evaluated after applying a 2% tensile deformation and then a heat treatment at 170° C. for 20 min., being 45 MPa or more, and any of the value of BH160, evaluated after applying a 2% tensile deformation and then a heat treatment at 160° C. for 10 min., and the value of BH150, evaluated after applying a 2% tensile deformation and then a heat treatment at 150° C. for 10 min.
    Type: Application
    Filed: April 4, 2002
    Publication date: December 26, 2002
    Inventors: Naoki Yoshinaga, manabu Takahashi, Natsuko Sugiura, Akihiro Miyasaka, Masaaki Sugiyama
  • Patent number: 6491770
    Abstract: A method for annealing and galvanizing wires which comprises induction heating the wires in a first chamber at a first higher temperature to anneal the wires, cooling the wires to a second lower temperature in a second chamber and galvanizing the wires in a third chamber. The chambers are in serial communication and the heating, cooling and galvanizing steps are effected in an oxygen free atmosphere.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: December 10, 2002
    Inventor: James M. Knott, Sr.
  • Patent number: 6479168
    Abstract: A method is disclosed for laser lap welding a pair of metal members together. At least one of the pair of metals having a protective metal layer. Each of the metal members having a melt temperature greater than the melt temperature of the protective metal layer. The method includes placing one end of the pair of metal members in an overlapping relation to an other end of the pair of metal members to form an overlapping section. The method also includes inserting a metal alloying agent between the pair of metal members of the overlapping section to form a gap therebetween. A laser welder is used to join the pair of metal members and the alloy agent together so that the protective metal layer and the alloying agent are melted to form an alloy layer between the pair of metal members.
    Type: Grant
    Filed: April 3, 2001
    Date of Patent: November 12, 2002
    Assignee: The Regents of The University of Michigan
    Inventors: Jyoti Mazumder, Ashish Dasgupta, Michael Bembenek
  • Patent number: 6440584
    Abstract: A hot-dip galvanized steel sheet is produced by rough rolling a steel, finish rolling the rough rolled steel at a temperature of Ar3 point or more, coiling the finish rolled steel at a temperature of 700° C. or less, and hot-dip galvanizing the coiled steel at a pre-plating heating temperature of Ac1 to Ac3. A continuous hot-dip galvanizing operation is performed by soaking a pickled strip at a temperature of 750 to 850° C., cooling the soaked strip to a temperature range of 600° C. or less at a cooling rate of 1 to 50° C. per second, hot-dip galvanizing the cooled strip, and cooling the galvanized strip so that the residence time at 400 to 600° C. is within 200 seconds. The steel sheet has a structure consisting essentially of ferrite and martensite.
    Type: Grant
    Filed: September 17, 2001
    Date of Patent: August 27, 2002
    Assignee: NKK Corporation
    Inventors: Yasunobu Nagataki, Toshiaki Urabe, Fusato Kitano, Akio Kobayashi, Kunikazu Tomita, Shunsaku Node, Kozo Harada, Shogo Sato, Toru Inazumi
  • Patent number: 6423426
    Abstract: A steel sheet having a composition comprising C: 0.05-0.20 mass %, Si: 0.3-1.8 mass %, Mn: 1.0-3.0 mass %, Fe of the balance and inevitable impurities is subjected to a primary step of primary heat treatment and subsequent rapid cooling to Ms point or lower, a secondary step of secondary heat treatment and subsequent rapid cooling, and a tertiary step of galvanizing treatment and rapid cooling, so as to turn the structure of the steel sheet into a composite structure of 20% or more by volume of tempered martensite, 2% or more by volume of retained austenite, ferrite and a low-temperature transformation phase. A galvanized layer is deposited on the surface of the steel sheet. It is preferred to cool the steel sheet to 300° C. at a cooling rate of 5 ° C./sec. or more after the galvanizing treatment. After the galvanizing treatment, alloying treatment may be conducted.
    Type: Grant
    Filed: March 5, 2001
    Date of Patent: July 23, 2002
    Assignee: Kawasaki Steel Corporation
    Inventors: Takashi Kobayashi, Kei Sakata, Akio Shinohara
  • Publication number: 20020088510
    Abstract: A hot-dip galvanized steel sheet is produced by rough rolling a steel, finish rolling the rough rolled steel at a temperature of Ar3 point or more, coiling the finish rolled steel at a temperature of 700° C. or less, and hot-dip galvanizing the coiled steel at a pre-plating heating temperature of Ac1 to Ac3. A continuous hot-dip galvanizing operation is performed by soaking a pickled strip at a temperature of 750 to 850° C., cooling the soaked strip to a temperature range of 600° C. or less at a cooling rate of 1 to 50° C. per second, hot-dip galvanizing the cooled strip, and cooling the galvanized strip so that the residence time at 400 to 600° C. is within 200 seconds. The steel sheet has a structure consisting essentially of ferrite and martensite.
    Type: Application
    Filed: September 17, 2001
    Publication date: July 11, 2002
    Applicant: NKK CORPORATION
    Inventors: Yasunobu Nagataki, Toshiaki Urabe, Fusato Kitano, Akio Kobayashi, Kunikazu Tomita, Shunsaku Node, Kozo Harada, Shogo Sato, Toru Inazumi
  • Patent number: 6410163
    Abstract: The present invention provides a high strength thin excellent workability and galvanizability, having a composition comprising from 0.01 to 0.20 wt. % C, up to 1.0 wt. % Si, from 1.0 to 3.0 wt. % Mn, up to 0.10 wt. % P, up to 0.05 wt. % S, up to 0.10 wt. % Al, up to 0.010 wt. % N, up to 1.0 wt. % Cr, from 0.001 to 1.00 wt. % Mo, and the balance Fe and incidental impurities, wherein a band structure comprising a secondary phase has a thickness satisfying the relation Tb/T≦0.005 (where, Tb: average thickness of the band structure in the thickness direction of steel sheet; T: steel sheet thickness), and a manufacturing method thereof, and a manufacturing method of a high strength hot-dip galvanized steel sheet or a high strength galvannealed steel sheet applying hot-dip galvanizing or further galvannealing, and giving an excellent workability, a high tensile strength, and excellent galvanizability, coating adhesion and corrosion resistance.
    Type: Grant
    Filed: May 30, 2000
    Date of Patent: June 25, 2002
    Assignee: Kawasaki Steel Corporation
    Inventors: Yoshitsugu Suzuki, Kazunori Osawa, Chiaki Kato, Yoichi Tobiyama, Kei Sakata, Osamu Furukimi, Akio Shinohara
  • Patent number: 6391126
    Abstract: In order to provide a cost-effective, time saving method for producing aging-resistant strip consisting of aluminum-killed steel, for which, initially, a strip is produced in the usual manner by rolling and the rolled strip is annealed continuously, the still hot strip is wound into a coil and cooled to room temperature, the strip, cooled in the coil, being finally finished.
    Type: Grant
    Filed: September 28, 2000
    Date of Patent: May 21, 2002
    Assignee: Thyssen Krupp Stahl AG
    Inventors: Bernhard Engl, Klaus-Dieter Horn
  • Patent number: 6379481
    Abstract: A method and an apparatus for carrying out the annealing step of a galvannealing process in which strips and sheets, particularly of steel, are subjected after galvanizing to an annealing step by heating the coated material and subsequently holding at final annealing temperature, wherein, during annealing, the heating step is interrupted by at least one additional holding step and, thus, a stepwise increase of the temperature over time is adjusted.
    Type: Grant
    Filed: May 12, 1999
    Date of Patent: April 30, 2002
    Assignee: SMS Schloemann-Siemag Aktiengesellschaft
    Inventor: Rolf Brisberger