Magnesium(mg) Or Magnesium Base Alloy Patents (Class 148/666)
  • Patent number: 11332814
    Abstract: A high-strength and high-toughness magnesium alloy includes a Mg—Al—Bi—Sb—Zn—Sr—Y—Mn alloy, prepared from the following components in percentage by mass: 7.0 to 10.0% of Al, 0.2 to 2.0% of Bi, 0.2 to 0.8% of Sb, 0.2 to 0.5% of Zn, 0.1 to 0.5% of Sr, 0.03 to 0.3% of Y, 0.05 to 0.1% of Mn and a balance of Mg.
    Type: Grant
    Filed: July 10, 2019
    Date of Patent: May 17, 2022
    Assignee: CITIC Dicastal CO., LTD.
    Inventors: Zuo Xu, Kedi Ding, Haibo Qiao, Lixin Huang, Lisheng Wang, Zhendong Zhang
  • Patent number: 11214857
    Abstract: The present disclosure provides a method for manufacturing an aluminum alloy member capable of suppressing deterioration in ductility thereof. In the method for manufacturing an aluminum alloy member, an aluminum alloy casting material that contains 2.0 to 5.5 mass % of Cu, and 4.0 to 7.0 mass % of Si in which a content of Mg is 0.5 mass % or less, a content of Zn is 1.0 mass % or less, a content of Fe is 1.0 mass % or less, a content of Mn is 0.5 mass % or less and the balance is made of Al and inevitable impurities is used. The method for manufacturing an aluminum alloy member includes a heating and holding step of heating and holding the aluminum alloy casting material within a solid-liquid coexisting temperature region; and a quenching step of rapidly cooling the aluminum ally casting material after performing the heating and holding step.
    Type: Grant
    Filed: February 5, 2019
    Date of Patent: January 4, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Yusuke Yokota, Hirotsune Watanabe, Makoto Kikuchi, Hiroshi Kawahara, Yasushi Iwata, Jun Yaokawa, Kazuma Hibi
  • Patent number: 10052405
    Abstract: This invention relates to a biodegradable implant including magnesium, wherein the magnesium contains, as impurities, (i) manganese (Mn); and (ii) one selected from the group consisting of iron (Fe), nickel (Ni) and mixtures of iron (Fe) and nickel (Ni), wherein the impurities satisfy the following condition: 0<(ii)/(i)?5, and an amount of the impurities is 1 part by weight or less but exceeding 0 parts by weight based on 100 parts by weight of the magnesium, and to a method of manufacturing the same.
    Type: Grant
    Filed: August 12, 2015
    Date of Patent: August 21, 2018
    Assignee: U&I Corporation
    Inventors: Ja-Kyo Koo, Hyun-Kwang Seok, Seok-Jo Yang, Yu-Chan Kim, Sung-Youn Cho, Jong-Tack Kim
  • Patent number: 10000836
    Abstract: The present invention discloses a Mg—Ca—Zn—Zr magnesium alloy sheet, having the chemical compositions in weight percentage: Ca: 0.5˜1.0%, Zn: 0.4˜1.0%, Zr: 0.5˜1.0%, the remainders being Mg and unavoidable impurities; wherein the magnesium alloy sheet has an average grain size of less than or equal to 10 ?m, an interarea texture strength of less than or equal to 5, an interarea texture strength after annealing at 250˜400° C. of less than or equal to 3, and a limiting drawing ratio at room temperature of more than AZ31; and the grain size thereof is remarkably less than that of AZ31B sheet produced in the same conditions, and the sheet texture is notably weakened.
    Type: Grant
    Filed: March 13, 2014
    Date of Patent: June 19, 2018
    Assignee: Baoshan Iron & Steel Co., Ltd.
    Inventors: Gaofei Liang, Yongjie Zhang, Qi Yang, Gang Wang
  • Patent number: 8636853
    Abstract: An Mg alloy provided with high strength and high ductility by matching the strength and ductility in tensile deformation and compressive deformation at the same levels is provided. The Mg alloy of the present invention is characterized by having a chemical composition consisting of Y: 0.1 to 1.5 at % and a balance of Mg and unavoidable impurities and having a microstructure with high Y regions with Y concentrations higher than an average Y concentration distributed at nanometer order sizes and intervals. The present invention further provides an Mg alloy characterized by having a chemical composition consisting of Y: more than 0.1 at % and a valance of Mg and unavoidable impurities, having a microstructure with high Y regions with Y concentrations higher than an average Y concentration distributed at nanometer order sizes and intervals and having an average recrystallized grain size within the range satisfying the following formula 1: ?0.87c+1.10<log d<1.14c+1.
    Type: Grant
    Filed: March 26, 2008
    Date of Patent: January 28, 2014
    Assignees: Toyota Jidosha Kabushiki Kaisha, National Institute for Materials Science
    Inventors: Tetsuya Shoji, Akira Kato, Toshiji Mukai, Hidetoshi Somekawa
  • Patent number: 8632326
    Abstract: A device for manufacturing finely powdered spherical magnesium includes a gas compressor that compresses argon gas, a gas heating unit that heats the compressed argon gas, and a tundish that receives molten magnesium. The device further includes a reactor having a nozzle injection unit that injects heated argon gas into the reactor, a recovery unit that recovers magnesium powder produced in the reactor, and a first gas cooler that cools the argon gas passing through the recovery unit. The device further includes a filtering unit that filters the cooled argon gas, a buffer tank that receives the filtered argon gas, and a compression blower that adiabatically compresses the argon gas. The device further includes a second gas cooler that cools the compressed argon gas, an adiabatic expansion duct that adiabatically expands the cooled argon gas, supplies the expanded argon gas to the reactor, and cools the magnesium powder.
    Type: Grant
    Filed: May 25, 2011
    Date of Patent: January 21, 2014
    Inventor: Kyu Yeub Yeon
  • Patent number: 8506733
    Abstract: The present invention provides a magnesium-based composite material that can achieve excellent performance such as high tensile strength not only at ordinary temperature but also at high temperature. The magnesium-based composite material of the present invention is Al2Ca-containing magnesium-based composite material, wherein said composite material is obtained by a solid-phase reaction of an aluminum-containing magnesium alloy and an additive, said additive being calcium oxide, and said composite material contains Al2Ca formed in the solid-phase reaction. In the magnesium-based composite material, CaO, in combination with Al2Ca, can be dispersed.
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: August 13, 2013
    Assignee: Topy Kogyo Kabusikikaisya
    Inventors: Keitaro Enami, Shoji Ono, Masaki Ohara, Takanori Igarashi
  • Patent number: 8414717
    Abstract: A method for the low temperature heat treatment of an age-hardenable magnesium based alloy, including following steps: (a) providing a solution heat-treated and quenched age-hardenable magnesium based alloy; and (b) subjecting said alloy to low temperature ageing below 100°C. for a period of time sufficient to develop an enhanced ageing response.
    Type: Grant
    Filed: April 29, 2008
    Date of Patent: April 9, 2013
    Inventor: Joka Buha
  • Patent number: 8349101
    Abstract: A method for the low temperature heat treatment of an age-hardenable magnesium based alloy, including following steps: (a) providing a solution heat-treated and quenched age-hardenable magnesium based alloy; and (b) subjecting said alloy to low temperature ageing below 100°C. for a period of time sufficient to develop an enhanced ageing response.
    Type: Grant
    Filed: April 29, 2008
    Date of Patent: January 8, 2013
    Inventor: Joka Buha
  • Patent number: 8293031
    Abstract: A magnesium alloy, comprising: Y: 0.5-10? Zn: 0.5-6?? Ca: 0.05-1?? Mn: ??0-0.5 Ag: 0-1 Ce: 0-1 Zr: 0-1 or Si: 0-0.4, wherein the amounts are based on weight-percent of the alloy and Mg, and manufacturing-related impurities constitute the remainder of the alloy to a total of 100 weight-percent. Also disclosed is a method for manufacturing such an alloy and a biodegradable implant formed therefrom.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: October 23, 2012
    Assignee: Biotronik VI Patent AG
    Inventors: Bodo Gerold, Heinz Mueller, Joerg Loeffler, Anja Haenzi, Peter Uggowitzer
  • Patent number: 8268235
    Abstract: An implant consisting entirely or in part of a biocorrodible magnesium alloy having the composition Gd: 2.7-15.0 wt %, Zn: 0-0.5 wt %, Zr: 0.2-1.0 wt %, Nd: 0-4.5 wt %, Y: 0-2.0 wt %, where magnesium and impurities due to the production process account for the remainder to a total of 100 wt %.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: September 18, 2012
    Assignee: Biotronik VI Patent AG
    Inventor: Bodo Gerold
  • Patent number: 8123877
    Abstract: A heat-resistant magnesium alloy is for casting, and includes Ca in an amount of from 1 to 15% by mass, Al in a summed amount of from 4 to 25% by mass with the amount of Ca, and the balance being Mg and inevitable impurities when the entirety is taken as 100% by mass. The heat-resistant magnesium alloy is not only inexpensive, but also effects an advantage that cracks are inhibited from occurring when being cast. For example, a process for producing heat-resistant magnesium alloy cast product includes the step of pressure pouring an alloy molten metal, which has a target composition around Mg—3% Ca—3% Al—from 0.2 to 0.3% Mn, into a cavity of metallic die, which is preheated to a die temperature of from 130 to 140° C. in advance. The process makes it possible to produce die-cast products, which are free from cast cracks.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: February 28, 2012
    Assignee: Kabushiki Kaisha Toyota Jidoshokki
    Inventors: Motoharu Tanizawa, Kyoichi Kinoshita, Eiji Kishi, Katsufumi Tanaka, Yuki Okamoto, Takayuki Kato
  • Publication number: 20110315282
    Abstract: The quasicrystal phase and/or quasicrystal-like phase particles, which is composed of the Mg—Zn—Al, are dispersed into Mg-base alloy material for strain working. The microstructure in this material does not include the dendrite structure, and the size of the magnesium matrix is 40 ?m or less than 40 ?m. The present invention shows that the quasicrystal phase and/or quasicrystal-like phase is able to form by addition of the Zn and Al elements except for the use of rare earth elements. In addition, the excellent trade-off-balancing between strength and ductility and reduction of the yield anisotropy, which are the serious issues for the wrought processed magnesium alloys, is able to obtain by the microstructure controls before the strain working process.
    Type: Application
    Filed: January 19, 2010
    Publication date: December 29, 2011
    Inventors: Hidetoshi Somekawa, Yoshiaki Osawa, Alok Singh, Toshiji Mukai
  • Patent number: 7837811
    Abstract: The present invention provides a method for manufacturing a composite of a carbon nanomaterial and a metallic material which has a homogeneous composite metal structure and thixotropic properties by compositing a metallic material of a non-ferrous metal alloy with a carbon nanomaterial by using both stirring and ultrasonic vibration. The method comprises compositing the metallic material of the non-ferrous metal alloy with the carbon nanomaterial by adding the carbon nanomaterial in a state where the metallic material shows thixotropic properties by spheroidization of solid phase in a semi-solid state, and the compositing is performed by a process for stirring and kneading the semi-solid metallic material while keeping the temperature thereof at a solid-liquid coexisting temperature, and a process for dispersing the carbon nanomaterial to liquid phase between solid phases by ultrasonic vibration.
    Type: Grant
    Filed: May 11, 2007
    Date of Patent: November 23, 2010
    Assignees: Nissei Plastic Industrial Co., Ltd., Chiba Institute of Technology
    Inventors: Tetsuichi Motegi, Fumi Tanabe, Masashi Suganuma, Kazuo Anzai
  • Patent number: 7677134
    Abstract: A forged product is made of a magnesium alloy and includes a through hole making portion to make a through hole that runs in a predetermined direction, and a bottom portion that lies on a plane intersecting with the predetermined direction. The through hole includes a first portion that has been formed by a forging process and a second portion that has been formed after the forging process. The second portion of the through hole has shifted toward the bottom portion with respect to the middle of the through hole in the predetermined direction.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: March 16, 2010
    Assignee: Yamaha Hatsudoki Kabushiki Kaisha
    Inventors: Toru Kitsunai, Osamu Matsushita
  • Patent number: 7641743
    Abstract: Methods and compositions that serve to both darken a zinc or other active! metal surface and impart corrosion-resistant properties thereto, are disclosed. The compositions include an aqueous solution containing about 0.1 percent to about 5 percent ammonium chloride and about 0.1 percent to about 5 percent ammonium molybdate. The compositions utilize particular ratios of concentrations of ammonium chloride and ammonium molybdate.
    Type: Grant
    Filed: June 4, 2004
    Date of Patent: January 5, 2010
    Assignee: Metal Coatings International Inc.
    Inventors: Michelle R. Pearce, Brian G. Straka, Donald J. Guhde, Terry E. Dorsett
  • Publication number: 20080149231
    Abstract: A forged product is made of a magnesium alloy and includes a through hole making portion to make a through hole that runs in a predetermined direction, and a bottom portion that lies on a plane intersecting with the predetermined direction. The through hole includes a first portion that has been formed by a forging process and a second portion that has been formed after the forging process. The second portion of the through hole has shifted toward the bottom portion with respect to the middle of the through hole in the predetermined direction.
    Type: Application
    Filed: December 17, 2007
    Publication date: June 26, 2008
    Applicant: YAMAHA HATSUDOKI KABUSHIKI KAISHA
    Inventors: Toru KITSUNAI, Osamu MATSUSHITA
  • Patent number: 7048812
    Abstract: A magnesium based alloy consists of, by weight: 1.4–1.9% neodymium, 0.8–1.2% rare earth element(s) other than neodymium, 0.4–0.7% zinc, 0.3–1% zirconium, 0–0.3% manganese, and 0–0.1% oxidation inhibiting element(s) the remainder being magnesium except for incidental impurities.
    Type: Grant
    Filed: June 20, 2003
    Date of Patent: May 23, 2006
    Assignee: Cast Centre Pty Ltd
    Inventors: Colleen Joyce Bettles, Christopher Thomas Forwood
  • Patent number: 6893515
    Abstract: The present invention is related to a manufacturing process for highly ductile magnesium alloy, which is processable under plasticization at ambient temperature. The process includes melting in vacuum melt furnace or inert gas protected furnace, teeming into ingot, extrusion or rolling into finished material. Such highly ductile magnesium alloy has extremely excellent plastic deformability at ambient temperature and improves completely the deficiency associated with traditional commercial magnesium alloy that lacks plastic deformability at ambient temperature. The material is suitable for the structural components in automobiles, 3C products, appliances and office automation products.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: May 17, 2005
    Assignee: Hsu-Yang Technologies Co., Ltd.
    Inventors: Jin-Chin Guan, Ming-Tarng Yeh, Jian-Yih Wang
  • Patent number: 6827797
    Abstract: Carbon steels of high performance are disclosed that contain a three-phase microstructure consisting of grains of ferrite fused with grains that contain dislocated lath structures in which laths of martensite alternate with thin films of austenite. The microstructure can be formed by a unique method of austenization followed by multi-phase cooling in a manner that avoids bainite and pearlite formation and precipitation at phase interfaces. The desired microstructure can be obtained by casting, heat treatment, on-line rolling, forging, and other common metallurgical processing procedures, and yields superior combinations of mechanical and corrosion properties.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: December 7, 2004
    Assignee: MMFX Technologies Corporation
    Inventors: Grzegorz J. Kusinski, David Pollack, Gareth Thomas
  • Patent number: 6818080
    Abstract: A manufacturing method for a shaped light metal article includes the steps of forming a plastic worked article by plastic working an article for plastic working made of light metal material, and subjecting the plastic worked article to a post-plastic working heat treatment for between 20 minutes and 10 hours at a temperature in a range of 250 to 400° C. As a result, a shaped light metal article is produced with sufficient ductility.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: November 16, 2004
    Assignee: Mazda Motor Corporation
    Inventors: Kazuo Sakamoto, Yasuo Uosaki, Nobuo Sakate
  • Publication number: 20030110892
    Abstract: In devices used for the direct conversion of heat into electricity, or vice versa, known in the art as thermoelectric power generators, thermoelectric refrigerators and thermoelectric heat pumps, the efficiency of energy conversion and/or coefficient of performance have been considerably lower than those of conventional reciprocating or rotary, heat engines and/or vapor-compression systems, employing certain refrigerants. The energy conversion efficiency of power generating devices, for example, aside from the hot and cold junction temperatures, also depends on a parameter known in the art as the thermoelectric figure of merit Z=S2&sgr;/k, where S is the thermoelectric power, &sgr; is the electrical conductivity and k is the thermal conductivity, of the material that constitutes the p-type, and/or n-type, thermoelements, or branches, of the said devices.
    Type: Application
    Filed: September 5, 2002
    Publication date: June 19, 2003
    Inventor: Michael C. Nicoloau
  • Patent number: 6544357
    Abstract: A new class of light or reactive elements and monophase &agr;′-matrix magnesium- and aluminum-based alloys with superior engineering properties, for the latter being based on a homogeneous solute distribution or a corrosion-resistant and metallic shiny surface withstanding aqueous and saline environments and resulting from the control during synthesis of atomic structure over microstructure to net shape of the final product, said &agr;′-matrix being retained upon conversion into a cast or wrought form. The manufacture of the materials relies on the control of deposition temperature and in-vacuum consolidation during vapor deposition, on maximized heat transfer or casting pressure during all-liquid processing and on controlled friction and shock power during solid state alloying using a mechanical milling technique.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: April 8, 2003
    Inventors: Franz Hehmann, Michael Weidemann
  • Patent number: 6530998
    Abstract: A ceramic hard layer is formed on the surface of a formed article by subjecting the formed article of a substantially amorphous alloy to a heat treatment in an atmosphere containing a reactive gas under the conditions of temperature and time falling within the amorphous region in the isothermal transformation curve (TTT curve) of the alloy. The heat treatment is carried out, for instance, in an atmosphere containing oxygen and/or nitrogen at a concentration of not less than 1 ppm or in the air at a temperature of not less than the lowest temperature required for the oxidation or nitriding reaction of at least one component element of the matrix material. By this heat treatment, it is possible to produce a ceramic hard layer on the surface of the article in such a manner that the content of oxide and/or nitride gradually decreases in the depth direction.
    Type: Grant
    Filed: November 1, 2000
    Date of Patent: March 11, 2003
    Assignee: YKK Corporation
    Inventor: Hitoshi Oofune
  • Publication number: 20030000608
    Abstract: A magnesium alloy having excellent castability and creep properties has compositions of 1.0-6.0 wt % Zn, 0.5-3.0 wt % Ca, 1.0 wt % or less Zr, 1.0-5.0 wt % at least one lanthanoid, the remainder being Mg and unavoidable impurities. This magnesium alloy undergoes heat treatment of heating the magnesium alloy to 430-470 ° C., quenching, and then heating to 150-250 ° C. for aging. Hot tearing and temperature strength are improved by the addition of an element which is effective for causing eutectic reaction and peritectic reaction with Mg and making Mg particles divied finely.
    Type: Application
    Filed: July 8, 2002
    Publication date: January 2, 2003
    Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO
    Inventors: Toshio Horie, Hiroaki Iwahori, Yoji Awano
  • Patent number: 6395224
    Abstract: A magnesium alloy of the present invention includes magnesium as a main component, boron of 0.0005 weight % or more, manganese of 0.03 to 1 weight %, and substantially no zirconium or titanium. This magnesium alloy may further include aluminum of 1 to 30 weight % and/or zinc of 0.1 to 20 weight %. Because of appropriate amounts of boron and manganese contained in the magnesium alloy, the grain of the mangnesium alloy is refined.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: May 28, 2002
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Naohisa Nishino, Hiroshi Kawahara, Yoshihiro Shimizu
  • Patent number: 6306231
    Abstract: A light metal alloy material has excellent plastic workability. The method of producing the light metal alloy material comprises a light metal as a matrix, which is injection-molded at a solid phase proportion of not more than 20%. The injection molded material has a limiting upsetting rate of not more than 70% and excellent moldability. This injection molded material can be molded into a final molded article by means of single-step forging.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: October 23, 2001
    Assignee: Mazda Motor Corporation
    Inventors: Kazuo Sakamoto, Kyoso Ishida, Yukio Yamamoto, Makoto Fujita
  • Patent number: 6264762
    Abstract: A magnesium alloy material includes magnesium; more than 1 wt. % manganese; and at least one sp-metal selected from the group consisting of zinc, cadmium, mercury, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, and bismuth, wherein the manganese and the at least one sp-metal together are a maximum of 5 wt. % of the alloy material. The magnesium materials are resistant to corrosion and are especially useful in articles exposed to aqueous electrolytes during use or production.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: July 24, 2001
    Assignee: DaimlerChrysler AG
    Inventors: Heike Bommer, Jürgen Lang, Felix Nitschke
  • Patent number: 5964965
    Abstract: Disclosed is a very light-weight, Mg and Be-based material which has the ability to reversibly store hydrogen with very good kinetics. This material is of the formula (M.sub.1-x A.sub.x) D.sub.y wherein M is Mg, Be or a combination of them; A is an element selected from the group consisting of Li, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Al, Y, Zr, Nb, Mo, In, Sn, O, Si, B, C and F; D is a metal selected from the group consisting of Fe, Co, Ni, Ru, Rh, Pd, Ir and Pt (preferably Pd); x is a number ranging from 0 to 0.3; and y is a number ranging from 0 to 0.15. This material is in the form of a powder of particles of the formula M.sub.1-x A.sub.x as defined hereinabove, having an average size ranging from 0.1 to 100 .mu.m, each particle consisting of nanocrystalline grains having an average size of 3 to 100 nm or having a nano-layered structure with a layer spacing of 3 to 100 nm. Some of these particles have clusters of metal D attached thereto, with an average size ranging from 2 to 200 nm.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: October 12, 1999
    Assignees: Hydro-Quebec, McGill University
    Inventors: Robert Schulz, John Strom-Olsen, Leszek Zaluski, Alicja Zaluska
  • Patent number: 5895518
    Abstract: A method for preparing controlled phase alloys useful for engineering and hydrogen storage applications. This novel method avoids melting the constituents by employing vapor transport, in a hydrogen atmosphere, of an active metal constituent, having a high vapor pressure at temperatures .apprxeq.300 C. and its subsequent condensation on and reaction with the other constituent (substrate) of an alloy thereby forming a controlled phase alloy and preferably a single phase alloy. It is preferred that the substrate material be a metal powder such that diffusion of the active metal constituent, preferably magnesium, and reaction therewith can be completed within a reasonable time and at temperatures .apprxeq.300 C. thereby avoiding undesirable effects such as sintering, local compositional inhomogeneities, segregation, and formation of unwanted second phases such as intermetallic compounds.
    Type: Grant
    Filed: April 23, 1996
    Date of Patent: April 20, 1999
    Assignee: Sandia Corporation
    Inventors: Stephen Everett Guthrie, George John Thomas, Walter Bauer, Nancy Yuan Chi Yang
  • Patent number: 5728239
    Abstract: A process for hardening aluminum comprises the steps of adding a magnesium hardener to molten aluminum wherein the hardener has a magnesium content in the range of 64-72 wt % based on the weight of the hardener, with a remaining portion of the hardener comprising aluminum. The process may further include the steps of preheating the hardener prior to adding the hardener to the aluminum for decreasing a temperature differential between the hardener and the aluminum so as to stabilize the hardener and prevent shattering thereof.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 17, 1998
    Assignee: KBAlloys, Inc.
    Inventors: William C. Setzer, Richard J. Malliris, David K. Young, Francis P. Koch
  • Patent number: 5679182
    Abstract: Disclosed is a practical magnesium based alloy containing 1 to 99 weight % beryllium and an improved method of semi-solid processing of magnesium alloys containing beryllium. The present method avoids agitation of molten alloys and the need for introducing shear forces by utilizing atomized or ground particles of beryllium mixed with solid, particulate or liquidus magnesium.
    Type: Grant
    Filed: September 28, 1994
    Date of Patent: October 21, 1997
    Assignee: Brush Wellman Inc.
    Inventors: James M. Marder, Warren J. Haws
  • Patent number: 5676774
    Abstract: A process for producing a magnesium alloy aluminum hardener comprises the steps of providing magnesium alloy scrap, wherein the scrap comprises aluminum present in a range of 1-10 wt. % based on the weight of the scrap and at least one of zinc present in a range of 0.1-3 wt. % based on the weight of the scrap and manganese present in a range of 0.1-3 wt. % based on the weight of the scrap, wherein a remaining portion of the scrap comprises magnesium; providing molten aluminum; and adding the scrap to the molten aluminum until the hardener is produced having a magnesium content in a range of 64-72 wt. % based on the weight of the hardener, with a remaining portion of the hardener comprising aluminum and at least one of zinc and manganese.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 14, 1997
    Assignee: KB Alloys, Inc.
    Inventors: William C. Setzer, Richard J. Malliris, David K. Young, Francis P. Koch
  • Patent number: 5626689
    Abstract: This invention relates to a catalytic fuel composition capable of reducing pollutants in the combustion gasses generated upon combustion of the same. A catalytic material is combined with a liquid, petroleum-based fuel, mixed and solid particles are separated out to give the catalytic fuel product. The catalytic material predominantly comprises a plagioclase feldspar belonging mainly to the albiteanorthite series, and contains small amount of mica, kaolinite and serpentine, and optionally contains magnetite. An alloy material is also disclosed, comprising a mixture of the above-described catalytic material and a metal. The alloy material exhibits unique properties relative to the metal component alone, such as increased tensile strength, improved heat resistance, improved acid resistance, improved corrosion resistance, as well as exhibiting unusual conductive properties.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: May 6, 1997
    Inventor: Jack H. Taylor, Jr.
  • Patent number: 5501748
    Abstract: Procedure for the production of a thixotropic magnesium alloy by adding a grain refiner combined with controlled, rapid solidification with subsequent heating to the two-phase area. It is preferable to use a solidification rate of >1.degree. C./s, more preferably >10.degree. C./s. It is essential that the solidification takes place at such a speed that growth of dendrites is avoided. Heating to the two-phase area is carried out rapidly in 1-30 minutes, preferably 2-5 minutes. By heating an alloy comprising 2-8 weight % Zn, 1.5-5 weight % RE, 0.2-0.8 weight Zr balanced with magnesium to a temperature in the two-phase area after casting, the structure will assume a form in which the .alpha.-phase is globular (RE=rare earth metal). The size of the spheres will be dependent on the temperature and the holding time at that temperature and they will be surrounded by a low-smelting matrix. It is preferable that the alloy has a grain size of not greater than <100 .mu.m, more preferably 50-100 .mu.m.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: March 26, 1996
    Assignee: Norsk Hydro A.S.
    Inventors: Haavard Gjestland, HAkon Westengen
  • Patent number: 5447583
    Abstract: Apparatus for cooling a metal extrusion, such as an aluminum extrusion, may include a carriage which houses the cooling liquid delivery system and is relatively movable with respect to the extrusion press in order to provide the desired amount of air cooling prior to quenching. The quenching apparatus may have a plurality of generally parallel cooling liquid delivery tubes, each having a plurality of nozzles which are preferably independently adjustable as to volume and spray pattern. The cooling liquid delivery tubes may be axially rotated and flow of the cooling liquid within each tube may be independently adjusted. The housing of the quenching unit may have an upper portion which is rotatable generally upwardly and is provided with a transparent window to facilitate viewing of the spraying action. A method of quenching an aluminum extrusion employing such apparatus is provided.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: September 5, 1995
    Assignee: Aluminum Company of America
    Inventors: William R. Arthur, Douglas T. Bozich, Richard B. Jacobus, Thomas J. Rodjom, Joseph R. Sikora
  • Patent number: 5409555
    Abstract: An article of manufacture made of a magnesium alloy is made by casting the magnesium alloy to provide a casting, forging the casting to render material of the casting to have an average crystalline particle size of not greater than 100 .mu.m, and carrying out a T6 treatment (a solution treatment and an artificial aging treatment) with respect to the casting. Physical properties such as, for example, the tensile strength, elongation and the like of the article are considerably improved by virtue of the synergistic effect of the micronized crystalline particles and the T6 treatment.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: April 25, 1995
    Assignee: Mazda Motor Corporation
    Inventors: Makoto Fujita, Yukio Yamamoto, Nobuo Sakate, Shoji Hirabara
  • Patent number: 5350468
    Abstract: A process for producing amorphous alloy materials having high toughness and high strength from various alloy powders, thin ribbons or bulk materials consisting of an amorphous phase by heating them to a temperature at which intermetallic compounds or other compounds are not produced. During this heating, fine crystal grains consisting of a supersaturated solid solution made of a main alloying element and additive elements and having a mean grain diameter of 5 nm to 500 nm are precipitated and uniformly dispersed in a volume percentage of 5 to 50% throughout an amorphous matrix. In the process, when deformation, pressing or other working is simultaneously conducted with the heating, consolidation or combining of the resultant alloy materials can also be effected in the same production procedure. The amorphous alloy used in the production process preferably comprises Al, Mg or Ti as a main element and, as additive elements, rare earth elements and/or other elements.
    Type: Grant
    Filed: September 2, 1992
    Date of Patent: September 27, 1994
    Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Yoshida Kogyo K.K.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue
  • Patent number: 5340416
    Abstract: A high-strength magnesium-based alloy possessing a microcrystalline composition represented by the general formula: Mg.sub.a Al.sub.b M.sub.c or Mg.sub.a,Al.sub.b M.sub.c X.sub.d (wherein M stands for at least one element selected from the group consisting of Ga, Sr, and Ba, X stands for at least one element selected from the group consisting of Zn, Ce, Zr, and Ca, and a, a', b, c, and d stand for atomic percents respectively in the ranges of 78.ltoreq.a.ltoreq.94, 75.ltoreq.a'.ltoreq.94, 2.ltoreq.b.ltoreq.12, 1.ltoreq.c.ltoreq.10, and 0.1.ltoreq.d.ltoreq.3). This alloy can be advantageously produced by rapidly solidifying the melt of an alloy of the composition shown above by the liquid quenching method. It is useful as high-strength materials and highly refractory materials owing to its high hardness, strength, and heat-resistance. It is also useful as materials with high specific strength because of light weight and high strength.
    Type: Grant
    Filed: December 28, 1992
    Date of Patent: August 23, 1994
    Assignees: Tsuyoshi Masumoto, Yoshida Kogyo K.K., Akihisa Inoue
    Inventors: Toshisuke Shibata, Akihisa Inoue, Tsuyoshi Masumoto
  • Patent number: 5316598
    Abstract: Magnesium base metal alloy sheet is produced by rolling the rolling stock extruded or forged from a billet at a temperature ranging from 200.degree. C. to 300.degree. C. The billet is consolidated from rapidly solidified magnesium based alloy powder that consists essentially of the formula Mg.sub.bal Al.sub.a Zn.sub.b X.sub.c, wherein X is at least one element selected from the group consisting of manganese, cerium, neodymium, praseodymium, and yttrium, "a" ranges from about 0 to 15 atom percent, "b" ranges from about 0 to 4 atom percent, "c" ranges from about 0.2 to 3 atom percent, the balance being magnesium and incidental impurities, with the proviso that the sum of aluminum and zinc present ranges from about 2 to 15 atom percent. The alloy has a uniform microstructure comprised of fine grain size ranging from 0.2-1.0 .mu.m together with precipitates of magnesium and aluminum containing intermetallic phases of a size less than 0.1 .mu.m.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: May 31, 1994
    Assignee: Allied-Signal Inc.
    Inventors: Chin-Fong Chang, Santosh K. Das