Abstract: A process of preparing a continuous cast lead-based alloy strip for use in the manufacture of a battery grid of a lead-acid battery, the process comprising mechanically deforming, at a deformation temperature in a range of about 15 to about 150° C., a continuous cast lead-based alloy strip having a thickness of tcast that is in a range that is from about 0.6 to about 2 mm to reduce the thickness of the strip to a thickness of treduced that is in a range that is from about 0.4 to about 1.5 mm such that the reduction in thickness is in a range of about 10 to about 50%, wherein the lead-based alloy comprises lead and silver and is essentially free of calcium, and wherein the silver is at a concentration that is in a range of about 0.003 to about 0.015 weight percent.

Abstract: The present invention relates to a method of simultaneously recovering cobalt (Co) and manganese (Mn) from lithium-based BATTERY, and more particularly, to a method that is capable of simultaneously recovering cobalt and manganese from lithium-based BATTERY, i.e., recycled resources that contain large amounts of cobalt and manganese, with high purities using multistage leaching and electrowinning methods. According to the method of the present invention, cobalt and manganese can be simultaneously recovered from lithium-based BATTERY as recycled resources, and a recovery method that is cost-effective compared to conventional methods can be provided.

Abstract: A valve regulated lead-acid battery includes a positive electrode current collector which is a punched current collector obtained by punching a rolled sheet of lead alloy and in which the average interlayer distance in a layered current collector structure at a cross-section parallel to the rolling direction and along the thickness direction of the current collector is not less than 25 ?m and not more than 180 ?m.

Abstract: A battery grid comprising a continuous cast and mechanically deformed lead-based alloy that comprises lead and silver and is essentially free of calcium, wherein the silver is at a concentration that is in a range of about 0.003 to about 0.015 weight percent, and has a predominant equiaxed grain structure that comprises grain sizes that are in a range of about 0.1 to about 5 microns. Other alloy constituents include bismuth at a concentration that is in a range of about 0.003 to about 0.002 weight percent and tin at a concentration that is in a range of about 0.2 to about 1.8 weight percent. A process for making strip of said alloy for use in manufacturing said grid. A battery comprising said grid.

Abstract: A method of forming a wrought material having a refined grain structure is provided. The method comprises providing a metal alloy material having a depressed solidus temperature and a low temperature eutectic phase transformation. The metal alloy material is molded and rapidly solidified to form a fine grain precursor that has fine grains surrounded by a eutectic phase with fine dendritic arm spacing. The fine grain precursor is plastic deformed at a high strain rate to cause recrystallization without substantial shear banding to form a fine grain structural wrought form. The wrought form is then thermally treated to precipitate the eutectic phase into nanometer sized dispersoids within the fine grains and grain boundaries and to define a thermally treated fine grain structure wrought form having grains finer than the fine grains and the fine dendritic arm spacing of the fine grain precursor.

Abstract: The present invention relates to a method for producing a lead-base alloy grid for lead-acid battery having excellent mechanical strength, corrosion resistance and growth resistance, including two-step heat treatment of a Pb—Ca—Sn alley grid containing 0.06% by mass or less of calcium, the first heat treatment being conducted at a temperature of 40° C. to 110° C., the second heat treatment being conducted at a temperature of 90° C. to 140° C., and the first heat treatment being conducted at a lower temperature than the second heat treatment.

Abstract: The present invention relates to a method for producing a lead-base alloy grid for lead-acid battery having excellent mechanical strength, corrosion resistance, and growth resistance the method including heat treatment of a Pb—Ca—Sn alloy grid being subjected to natural aging for 2 to 750 hours before heat treatment.

Abstract: A method of manufacturing a lead or a lead alloy plate lattice for a lead-acid battery, featured in that a melt of lead or a lead alloy is continuously extruded under temperatures lower by 10 to 100° C. than the melting point of the lead or the lead alloy, followed by subjecting the extrudate to cold rolling under temperatures lower by 50 to 230° C. than the melting point of the lead or the lead alloy with the total draft rate set at 10 to 90% and subsequently cooling and processing the cold rolled extrudate so as to manufacture a plate lattice.

Abstract: A process for enhancing chemical stability and corrosion resistance is described for perforated current collectors made by continuous production processes for use in electrochemical cells, including storage batteries such as lead-acid batteries. The process relies on utilizing a strip processing method, selected from the group of reciprocating expansion, rotary expansion and punching, to perforate the solid metal strip to form a grid or mesh, as a deformation treatment. The perforation-deformation treatment is followed in rapid succession by a heat-treatment to obtain a recrystallized microstructure in the current collector and optionally by quenching to rapidly reduce the temperature to below approximately 80° C. The process yields an improved microstructure consisting of a high frequency of special low &Sgr; CSL grain boundaries (>50%), exhibiting significantly improved resistance to intergranular corrosion and cracking.

Abstract: A grid for a battery having a current collection lug and a plurality of wires is made by a method that includes forming the grid utilizing a punching operation. The grid is formed of an alloy including calcium in an amount of about 0.05 percent by weight to about 0.08 percent by weight, tin in an amount of about 1.2 percent by weight to about 1.8 percent by weight, and bismuth in an amount of less than about 0.04 percent by weight. The balance of the alloy comprises lead.

Abstract: A method of producing lead alloy strip for fabrication of positive and negative electrodes of a lead-acid battery by extruding a lead alloy at elevated temperature to produce a lead alloy strip having a desired profile and rapidly cooling the extruded strip to acquire a desired microstructure. Battery grids produced from the lead alloy strip have reduced vertical growth and enhanced resistance to corrosion.

Abstract: Recrystallized lead and lead alloy positive current collectors and connectors such as straps and lugs for use e.g. in lead acid batteries and electrowinning anodes, having an increased percentage of special grain boundaries in at least part of the microstructure, which have been provided by a process comprising of (i) cold or hot rolling or cold or hot extrusion or (ii) steps of deforming the lead or lead alloy, and subsequently annealing the lead or lead alloy. Either a single cycle of working and annealing can be provided, or a plurality of such cycles can be provided.

Abstract: Provided for herein is a method of making an expanded metal grid, comprising: compression rolling a metal strip at a reduction ratio from about 1.25 to 1, to about 25 to 1 to produce a rolled strip, heating the rolled strip at a temperature of at least about 125° C., and at most about 325° C. for at least about 30 seconds, to produce a heat treated metal strip having an equiaxial grain structure within; and expanding the heat treated metal strip to produce the expanded metal grid.

Abstract: A tin-lead solder alloy containing copper and/or nickel and optionally silver, palladium, platinum and/or gold as its alloying constituents. The solder alloy consists essentially of, by weight, about 5% to about 70% tin, up to about 4% silver palladium, platinum and/or gold, about 0.5% to about 10% copper and/or nickel, the balance lead and incidental impurities. The presence of copper and/or nickel in the alloy has the beneficial effect of inhibiting the dissolution and leaching of silver from a silver-containing thick-film, such as a conductor or solder pad, into the molten solder alloy during reflow. In addition, solder joints formed of the solder alloy form a diffusion barrier layer of intermetallic compounds that inhibit solid-state interdiffusion between silver from a silver-containing thick-film and tin from the solder joint.

Abstract: Provided for herein is a method of making an expanded metal grid, comprising: compression rolling a metal strip at a reduction ratio from about 1.25 to 1, to about 25 to 1 to produce a rolled strip, heating the rolled strip at a temperature of at least about 125° C., and at most about 325° C. for at least about 30 seconds, to produce a heat treated metal strip having an equiaxial grain structure within; and expanding the heat treated metal strip to produce the expanded metal grid.

Abstract: Recrystallized lead and lead alloy positive electrodes for lead acid batteries having an increased percentage of special grain boundaries in the microstructure, preferably to at least 50%, which have been provided by a process comprising steps of working or straining the lead or lead alloy, and subsequently annealing the lead or lead alloy. Either a single cycle of working and annealing can be provided, or a plurality of such cycles can be provided. The amount of cold work or strain, the recrystallization time and temperature, and the number of repetitions of such steps are selected to ensure that a substantial increase in the population of special grain boundaries is provided in the microstructure, to improve resistance to creep, intergranular corrosion and intergranular cracking of the electrodes during battery service, and result in extended battery life and the opportunity to reduce the size and weight of the battery.

Abstract: An anode for use in electroplating semiconductor wafers, comprising a metal plate formed from a generally continuous casting process that is essentially free of voids or cracks, the casting being thermo-mechanically worked until the anode has an average grain size of less than 100 &mgr;m.

Abstract: A method of producing lead alloy strip for fabrication of positive and negative electrodes of a lead-acid battery by extruding a lead alloy at elevated temperature to produce a lead alloy strip having a desired profile and rapidly cooling the extruded strip to acquire a desired microstructure. Battery grids produced from the lead alloy strip have reduced vertical growth and enhanced resistance to corrosion.

Abstract: Recrystallized lead and lead alloy positive current collectors and connectors such as straps and lugs for use e.g. in lead acid batteries and electrowinning anodes, having an increased percentage of special grain boundaries in at least part of the microstructure, which have been provided by a process comprising of (i) cold or hot rolling or cold or hot extrusion or (ii) steps of deforming the lead or lead alloy, and subsequently annealing the lead or lead alloy. Either a single cycle of working and annealing can be provided, or a plurality of such cycles can be provided.

Abstract: Recrystallized lead and lead alloy positive electrodes for lead acid batteries having an increased percentage of special grain boundaries in the microstructure, preferably to at least 50%, which have been provided by a process comprising steps of working or straining the lead or lead alloy, and subsequently annealing the lead or lead alloy. Either a single cycle of working and annealing can be provided, or a plurality of such cycles can be provided. The amount of cold work or strain, the recrystallization time and temperature, and the number of repetitions of such steps are selected to ensure that a substantial increase in the population of special grain boundaries is provided in the microstructure, to improve resistance to creep, intergranular corrosion and intergranular cracking of the electrodes during battery service, and result in extended battery life and the opportunity to reduce the size and weight of the battery.

Abstract: The process for manufacturing a metallic component, such as a wheel part for the rolling system of a vehicle, which includes, in an initial stage, forming the component of a metallic material in a semi-solid state and having a thixotropic structure, and in a subsequent cold-treatment stage, cold-treating at least part of said component by blasting it with projectiles with a view to plastic deformation thereof. A wheel in which a metallic disk is welded to a wheel rim and in which the metallic disk is obtained by the manufacturing process.

Abstract: Recrystallized lead and lead alloy positive electrodes for lead acid batteries having an increased percentage of special grain boundaries in the microstructure, preferably to at least 50%, which have been provided by a process comprising steps of working or straining the lead or lead alloy, and subsequently annealing the lead or lead alloy. Either a single cycle of working and annealing can be provided, or a plurality of such cycles can be provided. The amount of cold work or strain, the recrystallization time and temperature, and the number of repetitions of such steps are selected to ensure that a substantial increase in the population of special grain boundaries is provided in the microstructure, to improve resistance to creep, intergranular corrosion and intergranular cracking of the electrodes during battery service, and result in extended battery life and the opportunity to reduce the size and weight of the battery.

Abstract: A process for the production of sliding elements in which an overlay of lead-tin-copper is applied by electroplating to the prefabricated semi-finished product, and in which a ternary, fluoroborate-free electroplating bath is used without brighteners and with the addition of non-ionic wetting agents and free alkyl sulfonic acid. After the deposition of the galvanic overlay a heat treatment is carried out in the temperature range of 150° C. to 200° C. for between 1 and 100 hours. The multilayer material for sliding elements comprises at least a backing and an overlay of 12 to 16 wt. % tin and 7 to 11 wt. % copper, the rest being lead. The overlay comprises 15 to 25 wt. % particles of intermetallic compound Cu6Sn5.

Abstract: An anode for use in zinc electrowinning is described. The anode is made of a lead-silver alloy which has been cast as a billet rolled and subjected to heat treatment either during or after rolling. The temperature of treatment is high enough to cause recrystallization of the alloy and to prevent precipitation of any alloying elements. The anode has a surface grain structure which facilitates rapid oxidation of the anode to condition the anode. The anode preferably contains at least 0.03 to 0.45% silver and Lip to 0.08% calcium.

Abstract: Lead alloy strip material (4, 6, 8) is roll bonded on one or both opposite face surfaces of a core strip material (2). The core material can be commercially pure titanium, austenitic stainless steel, low carbon steel, copper, aluminum, alloys thereof or other suitable metal that has sufficient ductility and that can provide desired attributes of stiffness and corrosion resistance to the composite. The lead alloy material is strengthened by the addition of less than approximately 1% of calcium or antimony and the core material is softened by fully annealing it prior to bonding. The several strips are reduced in thickness, preferably in approximately the same proportion, by at least 40% in the bonding pass to create a solid phase bond among the strips. The bonded composite is then rolled to final gauge and, for selected applications, is corrugated and cut to form panels (20, 22, 24) and etched to form pockets (8b) for pasting of active materials such as lead oxide for battery plates.

Abstract: Lead and lead-alloy anodes for electrowinning metals such as zinc, copper, lead, tin, nickel and manganese from sulfuric acid solutions, whereby the electrodes are processed by a repetitive sequence of cold deformation and recrystallization heat treatment, within specified limits of deformation, temperature and annealing time, to achieve an improved microstructure consisting of a high frequency of special low .SIGMA. CSL grain boundaries (i.e.>50%). The resultant electrodes possess significantly improved resistance to intergranular corrosion, and yield (1) extended service life, (2) the potential for reduction in electrode thickness with a commensurate increase in the number of electrodes per electrowinning cell, and (3) the opportunity to extract higher purity metal product.

Abstract: A method of a hardening a solid metal object consisting essentially of lead which has been swaged cold wrought, such as a bullet, and a hardened swaged wrought bullet are disclosed in which the bullet is formed from a lead or lead alloy blank by swaging the blank under high pressure in a forming die, heating the formed wrought bullet to a temperature near but less than the slump temperature of the metal, and then quenching the heated swaged wrought bullet in a liquid to rapidly reduce its temperature. The swaged wrought bullet as thus formed is seamless and has a hardness which exceeds at least 15 Brinell.